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By R. Wiebe

During a recent investigation the authors were interested in determining: (1) How many points were necessary to locate the deviation curve for copper-constantan thermocouples within an accuracy of about 0.05° C., used in connection with the, "standard" thermocouple of L. H. Adams (2) Whether copper-constantan thermocouples showing considerable deviations from the "standard" were consistent throughout their calibration. (3) How reliable the extrapolated portion is - that is, the interval between -183 and -220° C. of the "standard" thermocouple.

Jan 1, 1931

By R. Wiebe

During a recent investigation the authors were interested in determining: (1.) How many points were necessary to locate the deviation curve for copper-constantan thermocouples within an accuracy of about 0.05° C., used in connection with the "standard" thermocouple of L. H. Adams. (2.) Whether copper-constantan thermocouples showing considerable deviations from the "standard' were consistent throughout their calibration. (3.) How reliable the extrapolated portion is - that is, the interval between -183 and -220° C. of the "standard" thermocouple. It seems that a calibration between 0 and -193° C. can be made within the stated accuracy by determining experimentally the e.m.f. of the particular couple at -78.50°, the normal sublimation point of carbon dioxide, and at -182.97°, the normal boiling point of oxygen. Substituting the values found for the two fixed points in the simple quadratic. Equation

Jan 1, 1931

By Paul Hatmaker

"The Bureau of Mines recently has issued a general information circular covering briefly the origin and occurrence, properties, uses, exploitation, and marketing of diatomite. Since this publication was prepared, additional information has become available regarding one of the newer uses of diatomite — that as a filler in battery boxes. As this market is rapidly becoming one of the important outlets, a brief discussion of such use may be of interest.Diatomite is a mineral substance composed principally of the skeletal remains of diatoms. The skeletons of these microscopic flowerless water plants are made from silica present in the water in which these tiny plants live. The minute shells or ""casts"" accumu¬late in the bottom of lakes, ponds, or inland seas, and eventually become more or less consolidated into beds of diatomite.The uses of diatomite depend largely upon its peculiar properties. Diatomite is a highly porous substance and possesses marked absorptive powers. The large percentage of pore space makes the material very light in weight. It is relatively insoluble in most solutions.The largest deposits in the world are found in California, but diatomite occurs in many other Western States and also is found in a number of places along the Atlantic seaboard. Outside of the United States diatomite occurs in many countries; Algeria and Germany are among the largest producers.Usually diatomite is mined either by underground or open—cut methods. In some instances it may be dredged from lake and swamp bottoms. It must be dried prior to grinding or other preparation for market, and for many purposes must undergo a complex sizing and grading system for removal of such impurities as sand and clay and for classification of the material to the various sizes desired,"

Mar 1, 1931

By A. C. Fieldner

"Decline of the Beehive Coke OvenTwenty years ago a favorite theme of the crusader for fuel conservation was the enormous waste of valuable by-products incurred in the manufacture of blast-furnace coke in beehive ovens. Indeed, there was good reason for arousing the national conscience to this needless' loss of an irreplaceable mineral resource. In 1910, 83 per cent of the coke production was made in beehive ovens, from which surplus gas, tar, light oil, and ammonia, aggregating in value (at 1910 prices) 40 million dollars annually, were discharged into the atmosphere.In 1929, proportions were reversed and 90 per cent of the production was made in by-product ovens. The average value of by-products obtained in the production of 1 ton of coke in 1929 was $3.60, as compared with $1.16 in 1910, although the value of a ton of coke had increased only from $3.47 to $4.80. As shown in Figure 1,1 the production of by-product coke progressed rather slowly until 1915. War needs suddenly expanded the demand for coke and the by-products benzol and toluol for the manufacture of explosives. Except during the depression of 1921, this accelerating rate of production was maintained up to 1929, largely at the expense of beehive plants. The 1929 production of 60 million tons of coke will probably remain a record-breaking figure for several years. The developments which are now in progress in long-distance transmission of rural gas and in the utilization of volatile petroleum products and refinery gases for augmenting, city gas supplies may retard an other- wise accelerating demand for coke and coke-oven gas for domestic and industrial heating, Trends in Value of By-ProductsThe increasing value of by-products in comparison to the value of coke is shown in Figure 2. In 1913, the average value of by-product coke was $3.38, the value of the by-products per ton of coke was $1.41, and the cost of coal per ton of coke was $3,27, In 1929 not shown in figure) the value of the coke had risen to $4.80 per ton, the value of the by-products to $3.60, and the cost of coal per ton of coke to $5.07. The by-product values in were 155 per cent higher than in 1913, although the coke value had increased only 25 per And the cost of the coal 55 per cent. Actually the increase or the total value of coke plus by-products in this period was very little more than the increase in the coat of the coal, being 55per cent for coal and 60 per cent for coke plus by-products."

Mar 1, 1931

By T. L. Joseph

The size and accessibility of the Minnesota manganiferous iron ore deposits make them attractive as a potential source of ferromanganese, which is essential in the production of steel. For several years the Bureau of Mines has been conducting experiments to determine the feasibility of producing ferromanganese from these ores by a three-step process which involves (1) the smelting of the ores in the blast furnace to produce a high-phosphorus spiegel; (2) the treatment of the spiegel produced from step 1 in an electric or open-hearth furnace to separate the manganese from the phosphorus and the iron; and 3) the smelting of the high-manganese slag from step 2 to produce ferromanganese. The details of the first two steps of the process and the results of tests with the experimental furnaces have been given in previous reports.

Jan 1, 1931

By T. L. Joseph

The size and accessibility of the Minnesota manganiferous iron ore deposits make them attractive as a potential source of erromanganese, which is essential in the production of steel. For several years the Bureau of Mines has been conducting experiments to determine the feasibility of producing ferromanganese from these ores by a three-step process which involves (1) the smelting of the ores in the blast furnaoe to produce a high-phosphorus spiegel; (2) the treatment of the spiegel produced from step 1 in an electric or open-hearth furnace to separate the manganese from the phosphorus and the iron; and 3) the smelting of the high-manganese slag from step 2 to produce forromanganese. The details of the first two steps of the process and the results of tests with the experimental furnaces Lave been given in previous reports.5 The m$ or part of the experimental work on the second step has been conducted in a half-ton open-hearth furnace. Some preliminary tests showed, however, that the electric furnace has some distinct advantages over the open hearth for producing, from high-phosphorus spiegel, a slag containing from 45 to 55 per cent manganese and phosphorus and iron in amounts required for ferro-grade ore. The electric furnace tests described in this paper were made to get more information as to the possibilities of the electric furnace in connection with this problem and to study the fluxing effect of alumina on high-manganese slags. Herty, Conley, and Royer have reported' results of laboratory tests which showed that slags containing from 60 to 75 per cent MnO, from 8 to 10 per cent S102, and small amounts of CaO MgO, and FeO, were sufficiently fluid at 1,450° to 1,550° C. to pour readily if 12 to 14 per cent alumina was present. With a normal A1203 content resulting from the A1203 in the

Jan 1, 1931

By Jr. Herty

Manufacturers and consumers of steel have come to realize during the past few years that cleanliness is of great importance in steels which must meet rigid specifications for various physical properties. Of equal importance is the consistent production of steel which is uniform in these properties. For maximum utility, steels should be uniform not only from heat to heat, but also from ingot to ingot and within each ingot. In the manufacture of killed steels such as the higher carbon forging grades, uniformity as indicated by the usual chemical analysis is easy to obtain, provided that a normal top discard is taken, as is always the case in steels poured with hot-top practice. No such uniformity, however, holds true for the nonmetallic matter, which consists for the most part of the products of deoxidation of the steel. For a large tonnage of steels which go into articles manufactured by deep-drawing processes, killed steel has never been successfully applied because with the present deoxidation practice, low-carbon killed steel is almost invariably extremely dirty. To obtain the desired qualities for deep drawing, the steel is rimmed, - that is to say, deoxidized with manganese and perhaps a small amount of aluminum, - the resultant product being of high purity in the skin of the ingot, but very badly segregated at the center of the ingot, particularly in the upper-central section. This segregation necessitates a very heavy top discard, and one of the major segregates is carbon which renders the steel too hard to draw properly. If clean, low-carbon killed steel could be made successfully, much better ingot yields would be obtained than by the present rimming steel practice. Furthermore, banded structures and outside and inside seams, which are undoubtedly due in a large measure to blowholes in the ingot, are defects which are very difficult to control in rimmed steel.

Jan 1, 1931

By G. R. Fitterer, C. H. Herty

"INTRODUCTION Manufacturers and consumers of steel have come to realize during the past few years that cleanliness is of great importance in steels which must meet rigid specifications for various physical properties. Of equal importance is the consistent production of steel which is uniform in these properties. For maximum utility steels should be uniform not only from heat to heat, but also from ingot to ingot and within each ingot. In the manufacture of killed steels such as the higher carbon forging grades, uniformity as indicated by the usual chemical analysis in easy to obtain, provided that a normal top discard is taken, as is always the case in steels poured with hot—top practice. No such uniformity, however, holds true for the nonmetallic matter, which consists for the most part of the products of deoxidation of the steel.For a large tonnage of steels which go into articles manufactured by deep—drawing processes, killed steel has never been successfully applied because with the present deoxidation practice, low—carbon killed steel is almost invariably extremely dirty. To obtain the desired qualities for deep drawing, the steel is rimmed, — that is to say, deoxidized with manganese and perhaps a small amount of aluminum, — the resultant product being of high purity in the skin of the ingot, but very badly segregated at the center of the ingot, particularly in the upper—central section. This segregation necessitates a very heavy top discard, and one of the major segregates is carbon which renders the steel too hard to draw properly. If clean, low—carbon killed steel could be made successfully, much better ingot yields would be obtained than by the present rimming steel practice. Furthermore, banded structures and outside and inside seams, which are undoubtedly due in a large measure to blowholes in the ingot, are defects which are very difficult to control in rimmed steel. These defects would be minimized by clean killed steel."

Feb 1, 1931

By C. H. Herty

Manufacturers and consumers of steel have come to realize during the past few years that cleanliness is of great importance in steels which must meet rigid specifications for various physical properties. Of equal importance is the consistent production of steel which is uniform in these properties. For maximum utility, steels should be uniform not only from heat to heat, but also from ingot to ingot and within each ingot. In the manufacture of killed steels such as the higher carbon forging grades, uniformity as indicated by the usual chemical analysis is easy to obtain, provided that a normal top discard is taken, as is al¬ways the case in steels poured with hot-top practice. No such uniformity, however, holds true for the nonmetallic matter, which consists for the most part of the products of deoxidation of the steel. For a large tonnage of steels which go into articles manufactured by deep-drawing processes, killed steel has never been successfully applied because with the present deoxida¬tion practice, low-carbon killed steel is almost invariably extremely dirty. To obtain the desired qualities for deep drawing, the steel is rimmed, - that is to say, deoxidized with manganese and perhaps a small amount of aluminum, - the resultant product being of high purity in the skin of the ingot, but very badly segregated at the center of the ingot, particularly in the upper-central section. This segregation necessitates a very heavy top discard, and one of the major segregates is carbon which renders the steel too hard to draw properly. If clean, low-carbon killed steel could be made successfully, much better ingot yields would be obtained than by the present rimming steel practice. Furthermore, banded structures and outside and inside seams, which are undoubtedly due in a large measure to blowholes in the ingot, are defects which are very difficult to control in rimmed steel. These defects would be minimized by clean killed steel.

Jan 1, 1931

By C. B. Barmore, B. W. Gandrud, B. M. Bird

"The Bradford mine of the Alabama By-Products Corporation is located in the Warrior coal field of Alabama, in the northern part of Jefferson County, about 25 miles north of Birmingham. The coal mined from the Black Creek bed at this point is not considered to be ideal for coke making by itself but because of its exceptionally low ash content is mixed with the higher-ash coking coals from other beds of the district to control the ash content of coking mixtures. Further reasons for using this coal only as a diluent of the higher-ash opals are that the thinness of the bed renders the production costs relatively high and the reserves are somewhat limited.This paper, which is the fourth of a series on the washability of Alabama coals, Like its predecessors dealing with the Mary Lee beds and the Clark bed,6 contains screen-sizing and float-and-sink tests of a representative sample of the raw coal, and flakiness tests showing the proportions of flaky particles in certain selected sizes. However, inasmuch as the float-and-sink tests of the coarse sizes showed excellent liberation of coal from impurities, crushing tests have not been considered necessary.The data on which this report is based have been obtained in connection with an exhaustive study of coal preparation in Alabama now being conducted by the U. S. Bureau of Mines and the University of Alabama with the cooperation of the different coal operators. As the work progresses other papers will follow containing further data on Alabama coals and giving results obtained in preparing these coals by various methods."

Apr 1, 1931

By G. St. J. Perrott, N. A. Tolch

"PURPOSE OF TESTSThe propulsive strength4 developed by the Cardox blasting device depends on the thickness of disk, weight of heater element, and weight of carbon dioxide charge. It might be supposed that the maximum weight of carbon dioxide that can be charged into the shell should give the greatest strength. However, according to the ballistic pendulum, the maximum weight of carbon dioxide with certain conditions of heater and disk has less propulsive strength than a smaller charge; in one condition of test a loss of 39 per cent in propulsive strength was noted. It is therefore of interest to study the effect of the variables that determine the strength of Cardox.ACKNOWLEDGMENTGrateful acknowledgment is made to A. B. Coates, associate mechanical engineer who developed the testing method for measuring pressures in the Cardox shell.DESCRIPTION OF DEVICEThe Cardox blasting device as fully described by the bureau in Report of Investiga¬tions 2920 (1929), consists essentially of hollow—steel shell, cylindrical in shape, an electrode, valve assembly, shearing disk, and discharge cap. The shell is prepared for use by inserting a heater element, closing the open end with a shearing disk, and screwing in place the discharge cap. The charge of carbon dioxide enters the shell through the electrode.The heater element is fired by an electric igniter of the match—head type. The heat released by the heater element completely gasifies the carbon dioxide and raises the pressure of the gas until it is enough to shear the disk."

Apr 1, 1931

By F. F. Hintze

In the group of minerals used in making this study, the cyanite is associated with quartz, mica, and feldspar in the schist. The amount of quartz is variable, but it is always an abundant mineral. Both large and small crystals of quartz occur in irregular masses, rarely ever showing crystal outline. Mica is of the clear and dark varieties, the larger crystals being dark as a rule, and the finer crystals of light color. The present mineralogical composition of the mina is rather variable, as most of the original biotite and muscovite have suffered alteration, and much secondary mioa is present as a result of alteration of the original mica and other minerals present, especially the larger cyanite crystals. A large part of the mica now found in the ore is chlorite, with varying amounts of Jefferisite and others, especially sericite. These are in the form of aggregates, or felt-like intergrowths filling the spaces between the quartz, cyanite, and feldspar.

Jan 1, 1931

By L. H. Lange, F. F. Hintze

"Mineralogical Composition of Cyanite RockIn the group of minerals used in making this study, the cyanite is associated with quartz, mica, and feldspar in the schist. The amount of quartz is variable, but it is always an abundant mineral. Both large and small crystals of quartz occur in irregular masses, rarely ever showing crystal outline. Mica is of the clear and dark varieties the larger crystals being dark as a rule, and the finer crystals of light color, The present mineralogical composition of the mica is rather variable as most of the original biotite and muscovite have suffered alteration, and much secondary mica is present as a result of alteration of the original mica and other minerals present, especially the larger cyanite crystals. A large part of the mica now found in the ore is chlorite, with varying amounts of Jefferisite and others, especially sericite. These are in the form of aggregates, or felt-like intergrowths filling the spaces between the quartz, cyanile, and feldspar.The feldspar is plagioclase probably mostly albite. It is white, possesses good cleavage, and is one of the hard brittle minerals of the rock. It alters to kaolin, and sericite, and more or less of these alteration minerals are present within the feldspar crystals but not separated from them.The cyanite is of two varieties, distinguished by their colors as blue and white cyanite. The blue color varies in intensity, being a pronounced blue in some crystals and paler in shade in others. Some crystals have been seen which possess the blue color in one-half of their mass and are pure white or clear in the other half. The purity of the cyanite is probably not affected by the color, but it is difficult to detect the white cyanite in the ore by macroscopic examination, so that great care has to be exercised in the selection of the ore in the field."

Apr 1, 1931

By F. F. Hintze

In the group of minerals used in making this study, the cyanite is associated with quartz, mica, and feldspar in the schist. The amount of quartz is variable, but it is always an abundant mineral. Both large and small crystals of quartz occur in irregular masses, rarely ever showing crystal outline. Mica Is of the clear and dark varieties, the larger crystals being dark as a rule, and the finer crystals of light color. The present mineralogical composition of the mina is rather variable, as most of the original biotite and muscovite have suffered alteration, and much secondary mica is present as a result of alteration of the original mica and other minerals present, especially the larger cyanite crystals. A large part of the mica now found in the ore is chlorite, with varying amounts of Jefferisite and others, especially sericite. These are in the form of aggregates, or felt-like intergrowths filling the spaces between the quartz, cyanite, and feldspar. The feldspar is plagioclase probably mostly albite. It is white, possesses good cleavage, and is one of the hard brittle minerals of the rock. It alters to kaolin, and sericite, and more or less of these alteration minerals are present within the feldspar crystals but not separated from them. The cyanite is of two varieties, distinguished by their colors as blue and white cyanite. The blue color varies in intensity, being a pronounced blue in some crystals and paler in shade in others. Some crystals have been seen which posses the blue color in one-half of their mass and are pure white or clear in the other half. The purity of the cyanite is probably not affected by the color, but it is difficult to detect the white cyanite in the ore by macroscopic examination, so that great care has to be exercised in the selection of the ore in the field. Of the above minerals, cyanite is the heaviest, having a specific gravity of 3.6; none of the others approach it in specific gravity. The usual as opiates of cyanite in the mica schists are garnet, magnetite, and tourmaline, but these have not been noted in the group of minerals treated, and their absence is a point of great value in favor of this ore, as they possess high specific gravities and interfere in separation processes, and if not separated they are detrimental because of their easily fusible character. Small amounts of apatite and titanite have been noted, but not enough to cause trouble.

Jan 1, 1931

By M. J. Brevoort

Research work in the Bureau of Mines cryogenic laboratory requires the use of high-sensitivity galvanometers of the d'Arsonval type in a building that is subject to unusually severe vibrations. A modified form of the galvanometer suspension described by Julius3 has damped the vibrations so successfully that a short note concerning it is thought to be desirable, The laboratory is on the site of the Amarillo helium plant near a building that houses gas engines of from 180 to 250 hp., driving compressors and electric generators. The distances from the galvanometers to the individual engines range from about 80 to 180 feet. The subsoil, consisting of black clay loam, transmits the impulses without much damping. The usual methods of protecting galvanometers from vibration were tried and proved fruitless. A Julius suspension purchased on the market was carefully installed in the hope that it would overcome the difficulty, but the conditions were too severe even for this elaborate arrangement. Several mudifications of the original Julius suspension, which were then introduced, resulted in almost complete elimination of all vibrational effects.

Jan 1, 1931

By M. J. Brevoort

Research work in the Bureau of Mines cryogenic laboratory requires the use of high-sensitivity galvanometers of the d'Arsonval type in a building that is subject to unusually severe vibrations. A modified form of the galvanometer suspension described by Julius' has damped the vibrations so successfully that a short note concerning it is thought to be desirable. The laboratory is on the site of the Amarillo helium plant near a building that houses gas engines of from 180 to 250 hp driving compressors and electric generators. The distances from the galvanometers to the individual engines range from about 80 to 180 feet. The subsoil, consisting of black clay loam, transmits the impulses without much damping. The usual methods of protecting galvanometers from vibration were tried and proved fruitless. A Julius suspension purchased on the market was carefully installed in the hope that it would overcome the difficulty, but the conditions were too severe even for this elaborate arrangement. Several modifications of the original Julius suspension, which were then introduced, resulted in almost complete elimination of all vibrational effects. These modifications were suggested by careful study of the original idea embraced in the Julius construction. They were designed to give further constraint to motion in any direction other than that parallel to a line from the point of support through the center of gravity of the suspension, This was accomplished by making the suspended frame more rigid and by improving the means of adjusting each of the supporting wires to the same degree, thereby transmitting any impulse symmetrically through the three wires. The result was a suspension that is more effective, particularly for severe vibration, than the form described by Julius; also, it is believed to have advantages in stability, simplicity, and ease of adjustment over the few suspensions for this type of service that the author has found described in the literature.

Jan 1, 1931

By G. L. Oldright

In the previous study that has been made by the authors on smelting in the lead blast furnace,4 the furnace examined was one that operated under conditions that have been considered as more or less normal up to the present time. That is, although the furnace had in its charge a large portion of sinter, it also handled considerable quantities of naturally oxidized direct-smelting ore. Other ingredients, such as the limestone, were also added as fairly coarse material. The charges contained only about 24 per cent of lead. Until the changes incident to modern flotation began to take effect, many lead plants doing semicustom smelting in districts where competition was keen and much of the bonanza ore was exhausted were faced with the difficulty of obtaining enough lead to get a sufficient "lead fall" in the blast furnaces to clean the slag thoroughly and to separate it from the lead. A charge containing 24 per cent of lead would have been considered a very rich one by such smelters.

Jan 1, 1931

By G. L. Oldright

In the previous study that has been made by the authors on smelting in the lead blast furnace, the furnace examined was one that operated under conditions that have been considered as more or less normal up to the present time. That is although the furnace had in its charge a large portion of sinter, it also handled considerable quantities of naturally oxidized direct-smelting ore. Other ingredients, such as the limestone, were also added as fairly coarse material. The charges contained only about 24 per cent of lead. Until the changes incident to modern flotation began to take effect, many lead plants doing semicustom smelting in districts where competition was keen and much of the bonanza ore was exhausted were faced with the difficulty of obtaining enough lead to get a sufficient "lead fall" in the blast furnaces to clean the slag thoroughly and to separate it from the lead. A charge containing 24 per cent of lead would have been considered a very rich one by such smelters.

Jan 1, 1931

By Doerner H. A.

From thermodynamic calculations Maier predicted that zinc oxide and methane would react at specified temperatures substantially according to equation (1). (1.) ZnO + CH4 = Zn (gas) + CO + 2H2. Other reactions that may take place are (2.) CH4 = C + 2H2. (3.) ZnO + CO = Zn (gas) + CO2. (4.) ZnO + H2 = Zn (gas) + H2O. Maier predicted that 870°C would be the critical temperature above which reaction (1) would take precedence over reaction (2) and that reaction (1), at equilibrium, would be substantially complete at or above 927°C. Theoretical considerations indicate that reaction (1) is reversible: this is supported, but not proved, by experimental data. The other reactions are known to be reversible. At low temperatures reaction (2) requires a catalyst and it is slow below 1000°C. Reactions (3) and (4) are rapid, but the equilibrium constants are such that only small concentrations of CO2 or H2O can be produced below 1000°C. Maier calculated that CO2 should not exceed 0.5 per cent at 870°C., and the calculation for water vapor gives a still smaller order of magnitude.

Jan 1, 1931

By H. A. Doerner

From thermodynamic calculations3 Maier predicted that zinc oxide Land methane would react at specified temperatures substantially according to equation (1). (1) ZnO + CH; = Zn (gas) + CO + 2H2 Other reactions that may take place are: (2) CH4 = C + 2H2. (3) ZnO + CO = Zn (gas) + CO2 (4) ZnO + H 2 = Zn (gas) + H2O . Maier predicted that 870°C. would be the critical temperature above which reaction (1) would take precedence over reaction (2) and that reaction (1), at equilibrium, would be substantially complete at or above 927°C.

Jan 1, 1931