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By V. J. Lynch, A. L. Peyton

"INTRODUCTION AND SUMMARYThe Brewer mine, near Jefferson, Chesterfield County, S.C., was originally operated as a gold mines as late as 1890 this mine was reported to have been one of the large gold producers in the southeast,Occurrence of topaz on the Brewer property was not reported until 1935, when it was discovered by Pardee and Parks. 3/ of the Federal Geological Survey while they were investigating gold deposits in the Piedmont province.During the 1940's the Chemical Engineering Branch of the Tennessee Valley Authority and the Electrotecbnical Laboratory of the Bureau of Mines at Norris, Tenn., investigated topaz from the Brewer mine to determine the possibilities of its use as mullite and for the production of calcium fluoride.From July 1950 through. April 1951 the Bureau of Mines conducted a diamond-drilling project at the Brewer mine to determine the grade and extent of the topaz deposits. Ten diamond-drill holes, totaling 2,344 feet, were completed, and 231 analyses of core samples were made during the course of the project.This report presents factual data relating only to the diamond-drilling project, The placer deposits on the Brewer property were previously investigated by the Federal Geological Survey 4/."

Aug 1, 1953

By W. L. Crentz

Knott County is one of the smaller coal-producing areas in the Eastern Kentucky coal field. It contains numerous coal beds, many too thin to support mining over a wide area, Coal produced in the county is from a few rail-shipping operations and many small truck mines. Many smaller mines are working beds whose exact location in the coal-bearing strata is uncertain. Samples were collected from 11 different coal beds, of which the Fire Clay, Hindman, Upper Elkhorn No. 3, and Flag are the most import ant from a product ion standpoint. Known reserves in the Hindman bed. are very limited, and almost the entire production from this bed is gathered from two comparatively, large rail-shipping mines in addition to the four principal beds, samples were taken in the Francis, Haddix, Fire Clay Rider, Whitesburg, Amburgy, Upper horn No. 2, and Upper Elkhorn No. I .beds. Figure 1 is a typical section of the strata, showing the more important coal beds and. readily identifying their location with respect to each other. The bed names as shown are particularly important because of the local tendency to assign several names to the same bed. To avoid confusion, the names by which each coal bed is known also are given in the following listing. The coal. beds., in descending order, follow: [ ]

Jan 1, 1953

By J. J. Burns

Disasters such as occurred at Oppau, Germany, in 1921, at Tessenderloo, Belgium, in 1942, and in this country at Texas City, Tex., in 1947 clearly indicate the explosive hazard associated with the manufacture, storage, and transport at ion of ammonium nit rate The importance and extent of the hazard may be Judged from the large amount of ammonium nitrate produced and transported annually in this country. Between July 1, 1947, and June 30, 1948, it was estimated that the United States produced 461,528 tons of ammonium nitrate commercially for agricultural purposes alone .5/ In addition, U. S. Army Ordnance plants have manufactured and shipped 779,730 tons of ammonium nitrate fertilizer to Germany, Japan, and Korea.6/

Jan 1, 1953

By C. J. Mains

The gas -flow oil-shale retort is a continuous, crass flow, gas -to -broken solid heat-exchange system in which heat is transferred by convection from the gas to the solide.2/ This type of heat transfer presents a problem of analysis that cannot be solved by methods in common use. Solution of this problem is necessary for design, operation analysis, and predict ion wherever that type of heat exchanger is used. This report embodies a method for calculation of heat transfer coefficient and temperature histories of gas and solid in the gas- flow retort operating at equilibrium conditions. Detailed calculations are presented to show the application of the method explained in this report to conditions of an actual run made in the gas-flow retort. Although used here for a specific case, the method is applicable to all heat exchangers that are characterized by continuous, crossflow, gas -to-broken solid heat transfer. INTRODUCTION In any direct, gas -to -broken solid heat -transfer system, it is difficult to measure the temperatures of the gas and solid inside the heat exchanger. The driving force for heat transfer between the two media in the bed there- fore usually is unknown. The major resistance to heat transfer is in the gas film surrounding the solid particles, and the thickness of this gas film is neither uniform nor can it be determined readily. It is well to point out also that determination of the surface area of the particles is of poor accuracy. Since the driving force, the major resistance, and the surface area in the heat-transfer system are such uncertain quantities, It is not feasible to calculate the heat transfer by usual methods. All of the fore- going statements are true of the gas-flow retort; as a result, efforts were made to determine apparent heat-transfer coefficients and temperature histories of gas and solid in the heat -exchange bed by calculation using those data that were available. The heat -transfer coefficient calculated has the following dimensions: B .t .u. per second, °F., cubic foot of bed volume, where heat - transfer coefficients normally have the units; B .t .u . per hour, square foot, °F. Only the Schumann-Furnas formulas may be used to determine the heat- transfer coefficient and temperature histories in this type of heat exchanger.

Jan 1, 1953

By J. F. Barkley

Two major problems in the operation of air preheaters for boilers are corrosion and the accumulation of deposits on the heating surfaces. Corrosion or loss of metal necessitates replacement of parts; the accumulation of deposits decreases the size of the gas and air passages, resulting in increased pressure drop for the same gas flow, and also affects the heat transfer. These items, either singly or together, limit the capacity and efficiency at which the equipment can be operated and affect its availability, even causing undesirable shutdowns under extreme conditions The field and laboratory work on regenerative air preheaters described in this report covers research on the relative corrosion resistance of different materials, such as various metals, special metal coverings, and fired clays, and studies on deposits, their nature, analyses, and corrosive effects. This is the first report on cooperative work of The Air Preheater Corp., of New York City, and the Federal Bureau of Mines.

Jan 1, 1953

By A. C. Burr

This progress report covers the period from January 1949 to the end of the fiscal year, June 30, 1950. Three runs were successfully completed, and one run was terminated as the result of failure of a cast reaction tube. Including the abbreviated run, the gasifier was operated for 1,915 hours, during which some 428 tons of natural and steam- dried lignite was partly gasified In producing 20 million cubic feet of gas. Gas-production rates varied from 7.8 to 16.4 thousand cubic feet per hour, the latter being the highest production rate yet reached; hydrogen-carbon monoxide ratios of the product gas varied from 1.85, the lowest ratio yet produced, to 6.5; and heat-transfer rates through the heated wall of the outer tube varied from 2,100 to 4,400 B.t.u. per square foot an hour. The general objective of the project is to establish the technology and economy of the gasification of lignite in an externally heated, metal, annular retort. Specific objectives include determination of the useful life of the metal retort tube, which is a continuing problem, and special objectives that were established for each run as part of the systematic investigation of the basic variables of the gasification process. For runs 10 and 11 the special objective was the influence of the lignite feed rate on gasification; for run 12, a comparison of dried and natural lignite, and the production of gas having a hydrogen-carbon monoxide ratio less than 2; and for run 13, the influence of a gradually increasing steam rate with steam admitted to either the upper or lower reaction zones. In addition, during each run the sulfur distribution and concentration in the product gas and char were investigated. Experimental results obtained using the lignite feed rate as the variable indicated that the gas yield per ton of natural lignite varied inversely with the feed rate. Comparison of the gasification of natural and steam-dried Dakota Star lignite indicated that the dried lignite was a superior gasification material because: 1. The hourly gas production was higher at normal combustion space temperatures under nearly equal experimental conditions. 2. On the moisture- and ash-free basis, a considerably higher feed rate could be maintained at a relatively high percentage of carbon gasified. 3. At nearly equal moisture- and ash-free feed rates, the specific gas yield was higher. The location of steam admission was found to be important because the gas yield per ton of natural lignite was higher when at least a portion of' the process steam was admitted to the upper reaction zone. Heat balances showed the potential heat in the gas and char to be 71.8 to 83.6 percent of the total heat input. The sulfur concentration in the product gas was low, being in the range of 35 to 140 grains per 100 cu. ft., of which 1.5 to 2.3 grains was organic sulfur. Careful measurements and inspection of the 310-alloy rolled plate tube following runs 11, 12, and 13 showed no excessive corrosion; however, some radial deformation had occurred indicating that deformation or creep might be the limiting factor in the life of the tube.

Jan 1, 1953

By Joseph J. Wallace

1. From the standpoint of known recoverable reserves, the following is the order of importance of the beds: Upper Kittaoning, Lower Kittanning, Upper Freeport, Lower Freeport, Middle Kittaning, Clarion, Pittsburgh, and Redstone. 2. mown measured and indicated reserves in all beds, based on a minimum thickness of 14 inches and on 1,800 tons per acre-foot of coal in place, me estimated at 1,859 million short tons as of January 1, 1952. Of this, 1,351 million short tons me in beds 28 inches and more thick. Areas in each bed were omitted from the estimates because available data relative to the bed characteristics are too meager to make an estimate that conforms with the definitions of measured and indicated coal adopted for this study. Should future drilling or development prove reserves in these areas, such reserves should be added to the total estimated reserves.

Jan 1, 1953

By H. Kenworthy

Sulfide-ore concentrates containing cobalt, nickel, copper, lead, and iron from the operations of the National Lead Co. at. Fredericktown, Mo., were treated successfully on a laboratory scale to recover more than 90 percent of the cobalt, nickel, and copper. A cobalt -nickel-bearing, lead-copper matte., produced by the St. Joseph Lead Co. at Herculaneum, Mo., was treated to produce a lead-zinc fume, a copper sulfide concentrate, and a cobalt nickel-iron product, netting a recovery of over 75 percent of the cobalt and about 90 percent of the nickel and copper. National Lead Co. bulk concentrates were chlorinated with gaseous chlorine to form anhydrous metal chlorides and sulfur chlorides, sulfur chlorides were recovered by distillation, a high percentage of the ferric chloride was converted to ferric oxide, and the chlorinated residual metals were extracted with water. Metal ions were removed from leach liquors by pH-controlled fractional precipitation as hydroxides. Cobalt solutions "were prepared from cobaltic hydroxide, and procedures were developed to remove contaminating metal ions. Purified cobalt solutions were employed as electrolytes for deposition of high-purity cobalt.

Jan 1, 1953

By O. C. Blade

This report on the properties of motor fuels sold through service stations-in the United States was made in accordance with a cooperative agreement between the American Petroleum Institute and the Bureau of Mines of the United States Deparment of the Interior. It presents analytical data for 4,397 samples, representing the products of 130 companies. The samples were collected during December 1952 and January and February 1953. As in previous surveys, the gasolines covered by this survey include those from both large and small suppliers. The data were obtained by laboratories of various refiners, motor manufacturers, and chemical companies and submitted to the Bureau of Mines for compilation. A list of the National Motor-Gasoline Survey reports published during the past ten years is given on page 5.

Jan 1, 1953

By R. W. Geehan

The Bureau of Mines has been investigating deposits of critical and essential minerals in the United States since 1939. Bureau engineers made a preliminary examination of the Morefield mine early in 1943 and recommended investigation by trenching and diamond drilling, The Bureau of Mines conducted work from August to December of 1943, which indicated that the Morefield mine was a favorable location for an experimental mining program. The Bureau of Mines carried on such a program from September 1947 to March 1949. The property investigated is 30 miles southwest of Richmond in Amelia County, Va. (fig. 1). During World War II mica and beryl were shipped from the Morefield mine, but after the high prices and premiums paid during the war years were not available the mine was closed.

Jan 1, 1953

By F. W. Brown

In 1942 the Explosives Division investigated electrostatic hazards associated with the manufacture, storage, and use of explosives. A report was issued in 19454/ presenting the data on the spark sensitivities of explosives. In 1948, the apparatus was redesigned and rebuilt to make the routine testing of explosives safer and more convenient. The rebuilt apparatus is described in this re-issue of the former report. Included are details of construction and a list of parts. PRINCIPLES OF METHOD In normal procedures without special precautions, it is possible for static charges to be accumulated on individuals or on ungrounded equipment or structures.5/ Static charges may be produced in many ways, but they are most commonly produced by rubbing or successive contact and separation of unlike surfaces, at least one of which is usually an insulator.

Jan 1, 1953

By Joseph J. Wallace

1. From the standpoint of present production and recoverable reserves, there are two beds of major importance in Allegheny County -Pittsburgh and Upper Freeport -and one of lesser importance -Redstone. 2. Known measured and indicated reserves in all beds, based on a minimum thickness of 14 inches and 1,800 short tons per acre-foot of coal in place, are estimated at 832 million short tons as of January 1, 1953. Of this total, 768 million short tons is in beds 28 inches and more thick. Areas in some beds were omitted from the estimate because available data relative to the bed characteristics are too meager for making an estimate that conforms with the definitions of measured and indicated coal adopted for this study. Should future drilling or development prove reserves in these areas, such reserves should be added to the total estimated reserves.

Jan 1, 1953

By C. W. Owings

The Bureau of Mines has conducted a survey to determine potential exposure of mine workers to dust produced in connection with intermittent rock drilling in coal mines. Eighteen mines in 3 states were visited, and 30 different operations were observed, as follows: 10 drilling in draw slate, 8 drilling top rock for brushing or grading, 2 drilling in the coal face, 4 drilling in the bottom, 2 drilling top rock for overcasts, 2 drilling in faults or boulders, 1 drilling for roof bolting, and 1 drilling for trolley hangers. Dust respirators were worn by drilling crews during 16 of the 30 operations. Three hundred thirty-two samples of air-borne dust were collected during the survey. ACKNOWLEDGMENTS The information in this report is based on samples collected and observations made in bituminous-coal mines. Operating officials at these mines have contributed to this study, and their cooperation is gratefully acknowledged. All samples were counted by Thomas B. Kirby, chemist, and Dominick A. Ambrosia, scientific aid, and were analyzed by Gretta S. Baur, physicist, and Patricia M. Gussey, scientific aid, of the Health Branch of the Bureau of Mines.

Jan 1, 1953

By M. M. Fine

"Button" type ore from the Cason mine, Batesville, Ark., can be up-graded to plus-40-percent manganese by mineral-dressing procedures. A simple process including gravity concentration and. magnetic separation yielded more than 50-percent recovery of concentrates containing 38.1 to 40.6 percent manganese. These values in turn could be raised to 41.4 and 42.8 percent, respectively, upon sintering to conform to size specifications. The Bureau of Mines in the past has surveyed and tested many manganese ores and prospects in an endeavor to alleviate the shortage of manganese. The present period of emergency again emphasizes the strategic position of the metal, and manganese investigative work is being stressed to find new ore bodies and to apply newer beneficiation techniques to the known deposits.

Jan 1, 1953

By Bernard Lewis

This report summarizes fundamental research end technical studies conducted in the Explosives and Physical Sciences Division, Region VIII, of the Bureau of Mines in the 2 years July l, 1950, to June 30, 1952. It is the fifteenth of a series of, ordinarily, annual reports whose aim has been to provide the reader with a resume of the research results that have appeared in published form during each fiscal year under the authorship of members of the staff. These are referred to throughout the report. ACKNOWLEDGMENTS Acknowledgments art, made to the following members of the Division wider whose mediate supervision the described studies were carried out. Stuart R. Brinkley, Jr., chief, Mathematical and Theoretical Physics Section, and special assistant to the chief of the division.

Jan 1, 1953

By A. K. Schellinger

1. In the United States, the industrial application of centrifugal force for separating phase constituents has been confined almost entirely to aqueous systems at room temperature. This paper presents results for experimental tests on the use of centrifugal force for separating the liquid and solid phases in molten nonferrous alloys. 2. The development and use of a small centrifuge for treating molten metals is described. The centrifugal apparatus was, in essence, a 3-inch diameter spinner pot, which revolved, within -a gas -fired furnace, at speeds up to 3,000 r.p.m.

Jan 1, 1953

By O. C. Blade

The use of Diesel fuel continues to increase. In the United States during 1951 over 120,000,000 barrels of Diesel fuel oil were sold. The railroads used approximately 43.5 percent of this volume; industries such as smelters, mines, and manufacturing plants used about 12 percent; trucks, busses, tractors and bulldozers 20 percent; water craft 14.5 percent; and the remaining 10 percent was consumed by gas and electric utilities, the military forces, and oil companies. These figures were calculated from data issued by the Bureau of Mines. 2/ Complete data for 1952 are not yet available, but it is known that by December 1952 over 13 3/4 million barrels of Diesel fuel per month were produced by the country's refineries and by April 1953 the monthly production had increased to 1 4,333,000 barrels.3/ Information on the properties of this type of engine fuel is very important to the petroleum industry, engine manufacturers, and consumers. To supply this information the American Petroleum Institute and the Bureau of Mines, United States Department of the Interior, under cooperative agreement, are conducting annual surveys of Diesel fuel oil produced in refineries in this country.

Jan 1, 1953

By Manuel Gomez

This report presents experimental work conducted on a number of coals found within the boundaries of the Missouri River Basin, which were, to an extent, a selection of coals typical of that region. In the min, the laboratory work falls into three general classifications: (1) Laboratory distillation assay of coal to establish yields on carbonization; (2) chemical analyses of the coal samples before drying or carbonization; and (3) chemical analyses of the products of carbonization. It will be seen in the following discussion that these data derived from the small-scale laboratory apparatus are useful in predicting yields from pilot plants or industrial units. Coal is produced in about 48 general areas or mining fields in the Western States, of which approximately 18 fall within the limits of the Missouri Basin.3/ Beginning with the Northern Colorado field, through the Central and Western Wyoming fields, the coal is principally bituminous and subbituminous rank. The western Montana coals are also of these ranks. Progressing northeast from central Wyoming the coal decreases in rank, as shown by the subbituminous C coals of the Gillette field in northern Wyoming and the lignites of eastern Montana and North Dakota.

Jan 1, 1953

By W. L. Crentz

Before Korea was partitioned along the 38th parallel following World War II, the coal fields of South Korea, with the possible exception of the Samchok area, were not considered important to the industrial needs or Japan or Korea. Much of the demand for electric power in South Korea was met by hydroelectric installations north of the 38th parallel. Following cessation of hostilities between Japan and the' Allied nations in 1945, hydroelectric power continued to flow into South Korea from the north until 1949, when the North Koreans severed the power lines into South Korea, thereby forcing that section of the country to depend almost entirely upon coal to generate electric power.

Jan 1, 1953

By John B. Gayle

A new, experimental coke oven was installed at the Southern Experiment Station, Tuscaloosa, Ala., in 1948. This oven, designated as the Tuscaloosa oven, features a 17-inch carbonizing chamber, globar heating elements, and silica-brick heating walls designed to simulate as closely as possible carbonizing conditions in commercial, slat-type coke ovens. Zoned heat-input arrangements maintain uniform temperatures over approximately 95 percent of the total flue area. The reasons for constructing an oven of this size, the details of the design, and the operating characteristics of the oven were given in an earlier publication.2/ This report presents the results obtained from the first series of carbonizing tests on Alabama coals with the new oven. Factors leading to the development of standardized operating and testing procedures and the results of crosscheck determinations with a commercial oven producing foundry coke are included also.

Jan 1, 1954