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The effect of microwave radiation on the processing of Palabora open pit ore has been investigated. Significant reductions in Bond work index are demonstrated for microwave treated samples. Reductions in work index were found to be sensitive to applied power level and method of application. After single stage magnetic separation tests, improvements in recovery of FeO were noted. However, these were curtailed by oxidation of the magnetite species as a result of continued heating. The effects of microwave radiation upon the recovery of copper after froth flotation were also quantified. Small initial increases in recovery of copper were note dafter microwave treatment. However, with prolonged exposure, recovery was found to decrease. Overall recovery of copper was not affected except for samples treated for extended duration. The influence of microwave treatment upon the conventional Palabora grinding circuit has been quantified with the use of USIMPAC software. Conclusions are made regarding the economics of microwave treatment for this ore. Keywords : Microwave; Grinding; Magnetic Separation; Flotation; Economic Analysis

Jan 1, 2000

By Petrus Christiaan Pistorius, Makunga Daudet Seke

The flotation response of a Pb-Zn sulphide ore from the Rosh Pinah Mine (Namibia) was studied in the presence of inorganic depressants such as sodium cyanide and zinc sulphate. Poor flotation selective was observed in the rougher concentrate of the galena circuit despite the use of excessive amount of sodium cyanide. Batch flotation tests have shown that the use of cyanide alone is not efficient for the depression of sphalerite from the Rosh Pinah ore when milling is carried out according to the current plant particle size distribution. The use of both cyanide and zinc sulphate improved the selectivity between galena and sphalerite much better than cyanide alone. Flotation selectivity is limited by the mineralogical texture of the Rosh Pinah ore sample. Microscopic analysis has shown that the presence of sphalerite in the galena concentrate is also due to poor liberation between galena and sphalerite, especially in the middlings. Hence selectivity could be improved by regrinding the rougher concentrate prior to the cleaning stage. Keywords- Sulphide ores, Flotation, Flotation depressant, Mineralogy.

Jan 1, 2005

By M. D. Seke

The flotation response of a Pb-Zn sulphide ore from the Rosh Pinah Mine (Namibia) was studied in the presence of inorganic depressants such as sodium cyanide and zinc sulphate. Poor flotation selectivity was observed in the rougher concentrate of the galena circuit despite the use of a large amount of sodium cyanide. Batch flotation tests have shown that the use of cyanide alone is not efficient for the depression of sphalerite from the Rosh Pinah ore when milling is carried out according to the current plant particle size distribution. The use of both cyanide and zinc sulphate improved the selectivity between galena and sphalerite much better than cyanide alone. Flotation selectivity is limited by the mineralogical texture of the Rosh Pinah ore sample. Microscopic analysis has shown that the presence of sphalerite in the galena concentrate is also due to poor liberation between galena and sphalerite, especially in the middlings. Hence, selectivity could be improved by regrinding the rougher concentrate prior to the cleaning stage. Keywords: sulphide ores, flotation, flotation depressant, mineralogy.

Jan 1, 2005

By V. Tathavadkar

Worldwide TiO2is extracted from natural ilmenite, rutile, and anatase minerals via the sulphateand chloride processes. The sulphate process generates large volumes of less toxic wastes, whereas the chloride process, including the ilmenite-chloride process of DuPont, yields much lower volume of wastes, which are highly toxic and hazardous. The treatment and disposal of such hazardous chloride wastes is both expensive and difficult in terms of long-term monitoring. Besides the waste management and disposal, there is also a shortage of high-grade titanium dioxide minerals in nature, which consequently yields much larger tonnages of sulphate and chloride wastes. In the present investigation we report the results of an alternative titaniferous mineral beneficiation process based on soda ash roasting of minerals. Compared to the conventional processes for beneficiation of TiO2- ores, the alkali roasting of titaniferous offers several advantages including the zero process wastes. In the soda ash roasting process, the mineral is mixed with sodium carbonate and heated above 1023 K in air. The oxidative roasting of ores yields several complex alkali compounds, some of which produce a liquid mixture above 1123 K. In this paper, we have attempted to characterize the composition and physical chemistry of alkali-rich liquid phase. The phase equilibria in the Ti-(M:Fe)-Na-O system are evaluated and compared with the phases formed as a result of roasting reaction. The experimental results revealed that the composition of complex alkali liquid at the reaction interface plays an important role in determining the transport of O2-ions and decomposition of ilmenite. The roles of the crystal structure of mineral phases and their energetics are also emphasized in controlling their decomposition during alkali roasting. The presence of molten alkali in controlling the partitioning of water-soluble alkali salts and insoluble sodium titanate is also explained. Keywords: ilmenite, anatase, alkali roasting, phase equilibria.

Jan 1, 2004

By C. F. Vos, J. D. Miller, J. C. Davidtz

"This work presents the potential for improving the flotation recovery of slow-floating sulphide minerals with the use of starvation dosages of a normal dodecyl (n-C12) trithiocarbonate (TTC) co-collector, together with a sodium isobutyl xanthate (SiBX) and dithiophosphate (DTP) collector mixture.At potentials below –150 mV (SHE), addition of nC12-TTC with SiBX improves the hydrophobicity of pyrrhotite, yielding captive bubble contact angles greater than those measured for SiBX or nC12-TTC alone, suggesting a low potential synergistic effect. This synergistic effect is further studied using Fourier transform infrared (FTIR) spectroscopy, the results indicating an increase in the surface concentration of the collector species when in a mixture. Thus, nC12-TTC with SiBX may act as an immobile surface anchor to which SiBX/SiBX2 molecules bond, increasing the localized concentration of collector species.Bench-scale flotation tests using mixtures of SiBX/DTP/nC12-TTC on a platinum group element (PGE)-bearing ore from the Bushveld Complex in South Africa confirm an improved metallurgical performance at very low substitutions (approx. 5 molar per cent) of SiBX. The improved recoveries for PGE, Cu, and Ni are correlated with improvements in the flotation kinetics of their slow-floating components. IntroductionShort-chain (less than C6) xanthates are very effective for the bulk flotation of sulphides (Fuerstenau, 1982), and early work (Leja, 1968; Gaudin, 1957; Plaksin and Bessonov, 1957; Taggart, Giudice, and Ziehl, 1934) indicated that the presence of oxygen in flotation slurries is necessary for the oxidation of the xanthate collector at the sulphide mineral surface to induce hydrophobicity. Fundamental research into the chemistry and adsorption mechanisms of xanthates over the years (Finkelstein and Poling, 1977; Woods, 1976; Winter and Woods, 1973) has revealed that for iron-bearing sulphide minerals, adsorption occurs predominantly through a charge transfer process. Oxidation of the adsorbed collector to the corresponding dimer takes place if the mixed potential of the system is greater than the reversible potential for dimer formation. In oxygenated slurries the rate of adsorption and oxidation of the collector depends greatly on the substrate surfaces. For chalcopyrite (Guler et al., 2005; Leppinen, 1990; Roos, Celis, and Sudrassono, 1990) and pentlandite (Hodgson and Agar, 1989) a two-step interaction with xanthate is proposed in which the chemisorbed xanthate is further oxidized to the dimer. The initial interaction of xanthate with pyrrhotite is through physisorption where xanthate physisorbs onto positive surface sites followed by oxidation to dixanthogen (Khan and Kellebek, 2004; Bozkurt, Xu, and Finch., 1998). This process is, however, slow and increased reaction time is needed to improve flotation recovery (Buswell and Nicol, 2002)."

Oct 1, 2018

By A. Koursaris, Y. Turan

The object of this study was to investigate the i1Jfluence of nitrogen on the structure and properties of AISI 310S steel. Experimental ingots of the steel with nitrogen contents of up to 0,525 per cent by weight were prepared, hot-rolled, and tested after various treatments. The rollability of the material was adequate. The yield strength, tensile strength, hardness, and fatigue properties of the new alloys improved with increasing nitrogen content. The impact properties improved slightly. Empirical equations were developed for the calculation of the yield and tensile strengths, as well as the difference between these two properties, with increasing nitrogen content.

Jan 1, 1995

By R. Altındag, D. Akbay

The point load index is a simple, fast, and inexpensive method for determining rock strength and can be applied both in the field and in the laboratory. There are, however, some disadvantages and limitations to the method, and the test results can be affected by the person carrying out the test, the rock characteristics, or the test device. In this study we describe an investigation into how the point load index value is affected by the shape of the conical platens used in the test. Point load index tests were carried out using different devices fitted with conical platens of different spherical radii, and on a modified device which circumvented the limitations/disadvantages. It was seen that the point load index value increased as the platen radius increased, as expected. In the case of testing using non-standard conical platens, an equation is proposed to normalize the point load index value with respect to the standard spherical radius value.

Nov 1, 2021

By L. C. Woollacott, A. K. Tripathy, J. H. Potgieter

This paper presents the second of a two part study on density stratification in a laboratory batch jig. The first study, reported elsewhere, investigated the effect of operating conditions on the stratification profile achieved at equilibrium. The study reported in this paper investigated their effect on the kinetics of density stratification under 18 different sets of operating conditions - five for binary systems with different particle densities; and 13 for a ternary system with different configurations of the jig cycle. Although the study was academic in nature (it involved simple systems of 8 mm glass beads) it has a number of practical implications. It found that the most influential operating variables affecting stratification kinetics are the amplitude of water displacement, the pulsion hold time, and, to a lesser extent, the pulsion time. It also found that reasonable rates of stratification can be expected in systems with density differences as low as 237 kg/m3 but below this the kinetics deteriorate significantly. The two studies together suggest that, within a broad range of operating conditions, the equilibrium stratification profile is independent of control variables and it is the control of stratification kinetics that has the primary influence on the quality of density separations in a jig. Keywords: Jigging kinetics, stratification, equilibrium stratification, batch jig

Jan 1, 2020

By S. W. Jacobsz, E. P. Kearsley, N. K. Schoeman

A physical modelling approach was adopted to simulate the process of cave mining propagation at various horizontal to vertical stress state ratios, and image data was captured and used to characterize the resulting failure mechanisms. Image processing was integrated into the study to determine minor principal strains in models to identify where critical extensional strains had been exceeded relative to crack propagation. The study exhibited a scale factor magnitude of 119 using a calculated critical extensional strain value of 0.014% for the modelling material used. It was perceived that cave propagation occurred through successive parallel extensional ‘fracture bands’ in all cases, as noticed in models of prior studies, deviating from that described by the Duplancic model. Cracks tended to bisect regions of minor principal strain equal to the critical extensional strain, which suggests ‘fracture banding’ is an acceptable failure mode for brittle, rock-like materials. Moreover, it was found that models with lower horizontal to vertical stress ratios (K ratios) showed a greater degree of vertical development of the caving mechanism (at similar vertical stresses), while the vertical extent of the cave was suppressed in models with higher K ratios. Models subjected to larger vertical stresses experienced slower cave formation in latter time-steps. These models exhibited larger two-dimensional caved perimeters and areas, respectively.

Nov 30, 2022

By M. A. van Nierop

Load behaviour in an industrial mill has been measured directly by inserting probes through liner bolts. The data from conductivity probes have indicated the presence of premature centrifuging during manipulation of the load mass. Overloading conditions were also encountered. Overloading and premature centrifuging both reduce the power drawn by the mill. These effects have been successfully modelled.

Jan 1, 1997

The relationships between backfill-transportation parameters (solids concentration, velocity, and pipe diameter) and the wear rate of backfill-transportation pipelines is well understood. However, the degree of wear experienced by a pipeline depends not only on the transportation parameters, but also on the characteristics of the solids making up the backfill, i.e. the particle-size distribution, hardness, shape, and sharpness of the particles. Therefore, unless data corresponding to the specific wear rate of the solids are available, the determination of the wear rate for pipes transporting an uncharacterized backfill is largely guesswork. This paper describes an evaluation of particle characteristics with special reference to particle sharpness so that pipe wear rates can be correlated with solids of different size distributions and sharpnesses.

Jan 1, 1993

By C. B. Espag de Klerk, J. de Goede, M. Le Roux, Q. P. Campbell

"Excessive amounts of moisture in product coal can influence the efficiency of downstream utilization processes due to a decreased calorific value and handling problems. Stockpiles can be used to decrease the moisture content of coal by means of gravity drainage and evaporation. This paper is focused on the evaporation of moisture from a coal stockpile surface with the aim of investigating the effect of particle size on the rate of evaporation as well as the depth to which evaporation extends.It was observed that moisture initially evaporates at a higher rate from a stockpile consisting of fine particles (-6.7 mm) than from coarser particles (-13.2 mm +6.7 mm). This high rate of evaporation is restricted to the outer shell of the fine coal stockpile. However, for coarse coal, the porous nature increases the depth at which evaporation occurs. Evaporation of moisture was observed up to the fourth day of each experimental run, after which steady state was obtained. It was shown the water can evaporate from the surface into the body of the stockpile, depending on the coal particle size and void spacing. An experimental reclaim depth of 0.4 m was achieved after 4 days. IntroductionCoal stockpiles serve as surge capacity for downstream utilization processes and can also be used for moisture reduction by means of gravity drainage and evaporation. Excessive amounts of moisture in coal can cause handling problems and, most importantly, will decrease the calorific value, leading to inefficient combustion.Research has shown that evaporation by means of wind and solar action is considerably more effective than gravity drainage(Williams, D.J. 2006), but the effect is limited to a restricted depth from the exterior of the stockpile (Boyapati, E. and Oates, A. 1994; CSEM-UAE, 2010). The effectiveness of wind and solar action can be improved by orienting the stockpile perpendicular to the predominant wind direction, maximizing the surface area of the pile, and reclaiming the coal from the pile gradually in shallow cuts over a large area (Williams, D.J. 2006)."

Jan 1, 2016

By N. Mangesana

The effect of high solids concentration and coarse particle sizes (d50 ranges 90?300 µm) on the viscosity of a suspension of water and silica sand was investigated. The experiments were designed to include conditions that have been tested by other authors and those encountered in the operation of tumbling mills. The rheological data was measured using a tube rheometer with operating pseudo shear rates of up to 1500 s-1. The rheograms obtained depicted dilatant behaviour. The Otswald-de Waele, Bingham, Herschel-Buckley and Casson models were fitted to the experimental data. The Herschel-Buckely model, which approximates the yield point and gives an indication of the shear thinning or shear thickening behaviour of the suspension, was found to provide the best description of the flow curves for all slurries. The Herschel-Buckely model was then used to determine the apparent viscosity of all the tests. The apparent viscosity and yield stress increased with solids concentration and particle size at the different pseudo shear rates. The increase in slurry viscosity with solids concentration was attributed to increased frequency of particle-particle interactions. The increase in slurry viscosity with particle size was attributed to increased inertial effects. At low shear rates the sand slurry exhibited shear thinning behaviour for all solids concentrations. At higher shear rates above 1000 s-1the high solids concentration suspensions exhibited a transition from shear thinning to a shear thickening behaviour.

Jan 1, 2008

By N. Wagner, P. den Hoed, J. D. Steenkamp, S. Soqinase

In pyrometallurgical processes, metal oxides are reduced from molten slag through carbothermic reduction. It is of interest to evaluate the reactivity of the carbonaceous materials towards substances such as slag. Characterization techniques such as coal petrography can provide insight into the influence of feed coal properties and how they potentially dictate reductant performance. This study aimed to compare the petrographically determined organic composition of coal to reductant reactivity. Two South African medium-rank C bituminous coals and one anthracite sample were investigated together with high-carbon ferromanganese industrial slag. The reductant reactivity tests were conducted at 1500°C in a muffle furnace to assess the potential of carbonaceous reductant in reacting with the main slag components. SEM-EDS was applied to understand the extent of MnO (and to a lesser extent, SiO2) reduction from the slag. Coal 2, consisting of a greater proportion of vitrinite (59.5 vol% on a mineral matter-free basis and 54.7 vol% including mineral matter) was the most reactive reductant. The anthracite sample, with the highest inert maceral proportions (71.8 vol% including mineral matter and 76.8 vol% on a mineral matter-free basis), was the least reactive reductant.

Feb 6, 2023

By E. Saari, B. Musuku, K. Jansson

The quality of the concentrator plant process water is crucial for high performing mineral flotation circuits. Significant metal recovery and concentrate grade losses have been noticed particularly in more closed water loops. The recovery and quality losses have started to emerge mainly with decreased freshwater usage and because of changes in tailings management towards tailings thickening, paste, or dry stacking. These changes result in shorter, closed water loops with a rapid build-up of harmful components with negative impact on the beneficiation process. Consequently, water quality has a direct link to decreased product value and sales returns. Complete cleaning or water blending might not be the right way to achieve high recovery and high-quality products. Instead, the key is to understand what kind of water qualities are needed for the flotation of specific minerals. In this study harmful substances in various plant water streams were removed and/or modified by pilot-scale dissolved air flotation. Batch-scale mineral flotation tests with the untreated and treated water were then performed by using fresh ore samples and the plant’s own laboratory flotation procedure. The results indicate that because of dissolved air flotation, the mineral flotation recoveries were enhanced by 1‒3.3%. Keywords: Mineral recovery, metal recovery, mineral quality, process water, concentrator, beneficiation, mineral processing, flotation, process water treatment

Jan 1, 2020

By T. Lindstad, J. Kaczorowski

The Boudouard reactivity of single cokes produced from selected bituminous coals and commercial cokes has been investigated in a thermo gravimetric furnace. The effect of potassium as a catalyst for this reaction was studied, as it is known to accumulate in ferromanganese furnaces. A gaseous impregnation technique using K2CO3 as the potassium source was applied to impregnate the coke samples. The reactivity experiments were designed to simulate conditions occurring in an industrial furnace, as used for production of Mn-alloys. The coke particle size varied from 3.35 to 6.63 mm, while the temperature was maintained between 800- 1100oC with a gas composition from 50 to 75% CO2 in a CO/CO2 mixture. To determine the catalytic effect of potassium, the concentration varied from a fraction of a percent up to 15%wt. The results show that single chars vary significantly in reactivity, depending on the properties of the parent coal, while commercial cokes exhibit similar reaction rates. Temperature and partial pressure of CO2 have the strongest influence on the reactivity, while the influence of gas flow rate and coke particle size were found to be negligible. The catalytic studies revealed that the relative reactivity of non-impregnated samples are preserved after the impregnation, so the least reactive coke is still the least reactive after the impregnation for the whole range of potassium loads. Also, it has been confirmed that the Boudouard reactivity reaches a plateau at potassium concentration of 4%wt.

Jan 1, 2007

A diverse selection of rockbolt designs and resin anchors are available for use in underground mines. Research in recent years at the UNSW Mining Research Centre led to the construction of a rockbolt pull-testing facility. This facility has subsequently been upgraded, commissioned and initial test work has been completed to verify the pull-test process. A test program has been completed with the objective to understand the load transfer mechanism and improve the general performance of rockbolts. This paper describes the results of this research. Une sélection diverse de dessins du rockbolt et ancres de la résine est disponible pour usage dans les mines de métro. Faites des recherches ces dernières années à l'UNSW que le Centre de la Recherche Minier a mené à la construction d'une facilité de l'essai de la traction du rockbolt. Cette facilité a été améliorée par la suite, le travail de l'épreuve en commission et initial a été complété pour vérifier le processus de la traction-épreuve. Un programme de l'épreuve a été complété avec l'objectif comprendre le mécanisme du transfert de la charge et améliorer la performance générale de rockbolts. Ce papier décrit les résultats de cette recherche. Eine verschiedenartige Auswahl an rockbolt-Designs und Harzankern ist dafür verfügbar, benutzen Sie in unterirdischen Bergwerken. Forschung in letzten Jahren beim UNSW-Bergbau Forschung Zentrum führte Ruckerprobung-Einrichtung zur Konstruktion eines rockbolt. Diese Einrichtung ist anschließend befördert worden, ist beauftragt worden und wird abgezeichnet, prüfen Sie, die Arbeit ist vervollständigt worden, um den Ruckprüfung-Prozeß zu verifizieren. Ein Prüfungsprogramm ist mit dem Objektiv vervollständigt worden, den Lastübertragungsmechanismus zu verstehen und die allgemeine Aufführung von rockbolts zu verbessern. Dieses Papier beschreibt die Ergebnisse dieser Forschung.

Jan 1, 2003

By F. Bornman

Ore quality is declining, and the current spirals in mineral sands extraction is deemed inadequate to efficiently extract the valuable minerals. A new spiral was developed, the 117HM with the aim to extract the total heavy minerals in the order of 4.0% - 6.0% and the economic heavy minerals in the range 1.0% - 2.2% from the feed. An important measurable in the gravity concentration of mineral sands is recovery. Recovery measures how effectively the separator has extracted the valuable mineral contained in the input stream. The number of turns on the spiral trough influences the residence time of the feed slurry. A further optimisation followed with the development of the twelve-turn 117HM spiral. Four more turns were added for better recovery. The paper quantifies the effect of residence time on recovery.

Mar 30, 2026

By R. Abela

Heavy mineral sands are usually beneficiated in a spiral concentrator circuit prior to separation of heavy minerals into streams of zircon, rutile and ilmenite. The performance of the spiral concentrators is heavily affected by the presence of slimes in the rougher feed. The paper quantifies the effect of slimes content and discusses the beneficial effect of spiral feed de-sliming. The net effect of inefficient slimes removal can cause significant recovery losses of the heavy minerals present in the feed.

Jan 1, 2003

By K. G. Matshika

"Nickel electroplating from sulphate electrolyte is an efficient process. To achieve good quality cathode, however, parameters such as temperature, nickel concentration, pH, electrode alignment, electrolyte flowrate and additives must be optimised, because these affect cathode morphology and current efficiency. It is also important to control the clarity and contamination of the electrolyte, as these have a considerable effect on the quality of the cathode surface. Delamination, surface roughness and pitting on the cathode surface can be caused by incorporation of solid particles or impurities form the electrolyte. Three types of solid particles were investigated: cuprous selenide, barium/ lead sulphate (co-precipitated) and ferric hydroxide. These particles can be found in industrial electrolytes, especially if there is a problem with the filtration step or contaminants have reacted to form insoluble particles. A rotating cylinder Hull cell was used for this investigation. It is found that the effects on morphology depend on the type of solid, concentration, particle size, current density and electrolyte flowrate. Cuprous selenide is the most detrimental, especially at higher concentrations, higher current densities and low flowrates. Increased rotational speed offers a uniform sheet of fine gas bubbles across the surface of the cathode which reduces the thickness of the diffusion layer of liquid adjacent to the cathode and increases the rate of mass transport to the cathode from the bulk liquid. INTRODUCTION Electrowinning operations are important when recovering associated by-products of nickel production, such as copper, cobalt and zinc, from pressure leach solutions. The base metal mineralization associated with platinum-group metal (PGM) production yields significant quantities of copper and nickel as by-products. The base metal refinery is vital in PGM processing as it increases the PGM concentration from mined ore by a factor of 400, in comparison with concentration by flotation (20 times) and pyrometallurgical processing (20 times) (Crundwell et al., 2011). Anglo American Platinum Ltd produces nickel cathodes by electrowinning and purges sodium from the base metal refinery in the form of sodium sulphate at the Rustenburg Base Metals Refinery (RBMR), as shown in Figure 1. This is the Sherritt acid leach process used in most base metal refineries to ensure no loss of PGMs and shows the subsequent purification steps for copper and nickel. Other refineries in Zimbabwe, such as Bindura and Empress, use the Outokumpu leach process (Pavlides, 2001)."

Jan 1, 2015