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By R. G. B. Pickering

The Faculty of Engineering at the University of the Witwatersrand and the Mining Technology Division of the CSIR have co-operated to define the problems associated with deep level mining and in this paper they will identify what they consider to be the critical areas requiring technological solutions. This perspective will then be applied to work currently being carried out by both the organizations and gaps for additional developments will be identified. Finally the Co-operative Research Centre methodology operating in Australia is described. The purpose of this CRC is to provide a vehicle for R&D co-operation to develop and implement technologies which will increase the competitiveness of the mining industry. A further objective is to develop an appropriately skilled human resource base.

Jan 1, 1996

By I. K. Craig, F. R. Camisani-Calzolari

Defects which occur at the surface of a continuously cast slab impede the throughput of final product, because an extra stage in the process is required to grind the defects away before further processing can take place. Defect prediction and the minimization of the occurrence of defects is required. The use of two models to define the defect propagation is explained. Both models are derived using system identification techniques such as auto-regression with exogenous input(ARX). One model is used to determine the effect of manipulated variables such as casting speed and measured disturbances such as mould level on temperatures within the mould. The other isused to determine or indicate the effect of the mould temperatures on the occurrence of defects such as transversal cracks. The latter model can be used to predict when the defects will occur and the former can be used to control the occurrence of the defects. Keywords: continuous casting, surface defect, control system, predictor, system identification, ARX

Jan 1, 2003

By C. Norden

The purpose of this article is to show how a representative overall equipment effectiveness (OEE) measurement can be calculated for an underground coal mining bord and pillar batch process. The calculation method, the typical losses (which include planned and unplanned availability losses, coal quality losses, and process rate losses) and the underlying logic are presented and discussed. It is argued that the current traditional underground bord and pillar mining process can currently provide a maximum theoretical OEE of only 49 per cent, while a realistic benchmark target should be in the order of 37 per cent, which relates to an average of 2400 t per shift or 1.2 Mt/a. In addition, it is argued that the current bord and pillar process is the current bottleneck to further improvement past the 2400 t per shift benchmark, and that fundamental process changes will be required to eliminate this bottleneck.

Jan 1, 2012

By V. Miguel-Silva, B. C. Afonseca

Drill-hole spacing analysis (DHSA) and optimization are becoming commonplace for uncertainty assessment and management in the mining industry. However, there is no standardized DHSA workflow, and the outputs of certain methodologies are not interchangeable. We group available simulation-based DHSA methods according to their accounted uncertainty into (i) raw uncertainty, assessed by drawing realizations from synthetic data-sets with the drilling spacings to be tested; and (ii) model uncertainty, in which these synthetic data-sets are used to assess the variation between the estimated model and the (unknown) actual value. DHSA workflows available in the literature ignore the differences between both types of uncertainty. Commonly, the DHSA algorithm is chosen without a detailed analysis of its uncertainty output, which may lead to misleading results and suboptimal decisions. While available solutions are based only on assessing raw or model uncertainty, the proposed approach simultaneously analyses both and their relationship for models at different stages of the mine. The integrated analysis results deliver more information to support decision-making than available methods. Principles, practical considerations, and discussions of the advantages of the proposed integrated analysis are presented. The approach is applied to a real gold deposit to illustrate its use.

Jun 2, 2022

By K. Sugawara, Y. Hirakawa, A. Sato

The rock mass properties such as deformability and permeability are highly dependent on the existence of cracks. The Ratio of Crack Opening Dependency (RCOD) was proposed as a new index to evaluate the deformability of infinite jointed rock mass. The RCOD is defined as the ratio of total amount of crack opening and the total deformation of jointed rock mass. The theoretical relation between the RCOD and the effective compliance of jointed rock mass is discussed and confirmed through two-dimensional numerical analysis by the SC-DDM, together with the applicability to the rock engineering. Les propriétés de masse rocheuse telles que la déformabilité et la perméabilité sont très dépendantes de l'existence de fissures. Le rapport de dépendance d'ouverture des fissures a été proposé comme un nouvel index d'évaluation de la déformabilité de masse rocheuse à assemblage infini. Le rapport de dépendance d'ouverture des fissures est défini comme étant le pourcentage de quantité totale d'ouverture des fissures et de déformation totale de la masse rocheuse assemblée. Le rapport théorique entre le rapport de dépendance d'ouverture des fissures et la compliance efficace de masse rocheuse assemblée sont traités et confirmés au travers d'une analyse numérique à deux dimensions par SC-DDM en même temps que l'applicabilité à l'ingénierie des roches. Die Felsmasseneigenschaften wie Verformbarkeit und Durchlässigkeit sind hochgradig abhängig von dem Vorhandensein von Rissen. Das Verhältnis der Riss-Öffnungsabhängigkeit (RCOD) wurde als neuer Index der Verformbargkeit von infinit zerklüfteter Felsmasse vorgeschlagen. Der RCOD wird als Verhältnis der Gesamtmenge der Rissöffnungen und der Gesamtverformung der zerklüfteten Felsmasse definiert. Die theoretische Beziehung zwischen RCOD und der effektiven Verformbarkeit von zerklüfteter Felsmasse wird diskutiert und durch zweidimensionale numerische Analyse mit SC-DDM bestätigt, zusammen mit der Anwendbarkeit auf Bergbautechnik.

Jan 1, 2003

By W. Lin, H. Endo, M. Kwasniewski, A. Kamei, M. Takahashi

Uniaxial tension tests were conducted on specimens of eleven granitic rocks which came from eastern Japan, and included a granite, four granodiorites, four tonalites and two gabbros. The axial and transversal deformability of these rocks was determined based on strain measurements using wire strain gauges. The experimental test results revealed that deformational properties of the rocks investigated varied depending on their petrographic features. However, the axial strain and the lateral strain characteristics showed a similar trend for all the rocks, i.e. the stress-strain curves were non-linear throughout the whole stress range from the initial point of loading to the point of ultimate failure. Moreover, the tangent Young's modulus and the ratio of the lateral strain to the axial strain decreased monotonously with the increasing of the axial stress. Still, the deformational properties were different for individual rocks in a quantitative sense. In particular, the difference in the lateral strains among different rocks was more distinct than that in the axial strains. For example, the Poisson's ratio at a stress level equal to 50% of the ultimate strength of a granodiorite was very low, close to zero. Furthermore, the Poisson's ratio of a tonalite was lower than that of a granodiorite, and assumed a negative value. This effect occurred because the lateral strain became positive as it changed from contraction at the initial stage of loading to extension at higher stress levels. There is no ready explanation for this phenomenon; it is believed, however, that it occurs due to microcracks pre-existing in rock materials and/or weak bonds between the adjacent mineral grains. Les essais de traction directe ont été conduits sur les échantillons de onze roches granitiques provenant de la région Est du Japon: un granit, quatre granodiorites, quatre tonalites et deux gabbros. Déformabilité axiale et transversale de ces roches s’était déterminée en utilisant des jauges extensométriques à fil. Les résultats obtenus à partir des essais montrent que la déformabilité des roches examinées varie selon leurs propriétés pétrographiques. Cependant, à partir des essais, une tendance semblable était observée dans les paramètres de la déformation axiale et la déformation latérale de toutes les roches; c'est-à-dire chaque courbe de contrainte-déformation était non-linéaire dans tout l'intervalle de contraintes à partir de l’état initial jusqu’à l’état d’une rupture finale au cours du chargement. De plus, le module tangent de Young et le rapport de la déformation latérale sur la déformation axiale a diminué de manière monotone avec l'augmentation de la contrainte axiale. Cependant, les différences quantitatives de propriétés de déformation sous traction étaient observées entre des roches individuelles. Particulièrement, la différence de déformations latérales était plus notable que celle-là de déformations axiales entre des roches différentes. Par exemple, le coéfficient de Poisson à un niveau de contrainte égal à 50 % de la résistance d'un granodiorite était très bas, près du zéro. En outre, le coéfficient de Poisson de la tonalite était inférieur que celui du granodiorite et a assumé une valeur négative. Cet effet est apporté parce que la déformation latérale est devenue positive en passant de la contraction dans l'étape de chargement initiale à l'extension sous les contraines plus hautes. Il n'y a aucune explication prête de ce phénomène; on prétend, cependant, qu'il est induit par des microfissures préexistantes dans des matériaux rocheux et/ou des joints faibles entre les grains minéraux adjacents. Einaxiale Zugversuche wurden auf Probestuecke von elf frischen, in Ostjapan vorkommenden, granitartigen Gesteinen durchgefuehrt, welche einen Granit, vier Granodiorite, vier Tonalite und zwei Gabbros umfassten. Die axiale und transversale Verformbarkeit von diesen Gesteinen wurde durch Verformungsmessungen mit Drahtdehnungsmessstreifen geklaert. Die experimentellen Versuchsergebnisse offenbarten, dass Verformbarkeitseigenschaften des untersuchten Gesteins in Abhaengigkeit von ihren petrographischen Eigenschaften variierten. Jedoch zeigten die axialen und die lateralen Spannungsdehnungslinien eine aehnliche Tendenz bei allen Gesteinen, d.h. die Verformungskurven waren nicht linear im ganzen Bereich vom Ausgangspunkt des Belastens bis zum Punkt des entgueltigen Bruchs. Ausserdem verringerten sich das tangentiale Elastizitaetsmodul und das Verhaeltnis der lateralen Verformung zur axialen Verformung monoton mit der Erhoehung der axialen Spannung. Dennoch waren die Verformbarkeitseigenschaften der einzelnen Gesteine in der quantitativen Wahrnehmung unterschiedlich. Insbesondere war der Unterschied bezueglich der lateralen Verformungen zwischen verschiedenen Gesteinen eindeutiger, als der in den axialen Verformungen. Z.B. war die Querkontraktionszahl auf einem Spannungsniveau, das 50% der Zugfestigkeit eines Granodiorits entspricht, sehr niedrig und nah an Null. Ausserdem war die Querkontraktionszahl eines Tonalits negativ und deshalb niedriger als die eines Granodiorits. Dieser Effekt trat auf, weil die laterale Verformung, als sie sich von der Kontraktion am Ausgangsstadium des Belastens bis hin zur Ausdehnung auf den hoeheren Spannungsniveaus aenderte, positiv wurde. Es gibt keine fertige Erklaerung fuer dieses Phaenomen; es wird jedoch angenommen, dass es wegen der Mikrorisse auftritt, die vorher im Gesteinsmaterial und/oder in den schwachen Bindungen zwischen den angrenzenden Mineralkoernern existieren.

Jan 1, 2003

By H. Zhu, F. Xu, T. Wang

Abstract : The deformation monitoring data of the middle pier of the in permanent ship lock in Three Gorges revealed several interesting deformation phenomena. Conclusions and explanations are made concerning the phenomena in this paper, based on the finite element and engineering geology analyses. Firstly, the fluctuation of the horizontal transformations can be attributed to the alternate excavation of the two neighbouring ship lock rooms. Secondly, the rock mass discontinuities result in the displacement breaks. Lastly, the main reasons for the one-sided leaning phenomena are the natural stress, which is not evenly distributed, and the presence of discontinuities. This paper presents a valuable reference for studying the ‘individual phenomena’ in geotechnical engineering. ZUSAMMENFASSUNG: Die Beobachtungs claten an der Mittelpier deformation bezüglich Permannenter Schiffsschleuse in den Drei Schluchten offenbaren einige interessante Deformationsphänomene. Die Schlußforgerungen und Erklärungen dazu in dieser Arbeit basseren methodisch anf der ‚’ ‘Endlichen-Elemente-Analzse’ und der ‘Ingenieurnissen-Geograhnie-Analzse’. Erstens kann die Fluktuation der horiyontalen Transformation durch die ungleichzeitige Ausgrabung der zwei benachbarten Schiffsschleusenräume verursacht werden. Zweitens resultzert die Diskontinuität der Felsenmasse ans dem verlagerten Bruch. Drittens: Die Hauptgründe für das Zu-einer-Seite-Neigung-Phänomen in manchen Stellen sind der ungleich eigeteilte natürliche Druck und das vorhandersein der Diskontinuität. Diese Arbeit präsentiert eine wertvolle Referenz für die Untersuchung der Sonderfälle in geotechnischen Bau. Résumé: Cet article a analysé sérieusement et profondément , en utilisant des procèdes d’étude par exemple l’analyse d’éléments défini et celle de la condition géographique de traveaux , des règles typiques de la déformation montrées dans les données surveillantes à propos de la déformation des pierres centrales dans les écluses éternelles du Trois Gorges , on en a tiré une conclusion : 1) le changement des chiffres des déplacements horizontaux des pierres centrales est causé par les creusages séquentiels des cannelure voisines ; 2) l’inclinaison au Nord de toutes les pierres centrales entre les deuxième et troisième chambres d’écluse est causée par la différence de la gravitation entre les deux chambres d’écluse et par l’existence de la surface structurale ; 3) l’existence de la surface structurale cause le changement des chiffres des déplacements horizontaux des pierres centrales au niveau profond . Cet article donne une référence utile pour l’étude du ‘ problème d’indivudualité’( ou les situations anormaux) dans les données surveillantes de la déformation des pierres centrales de la génie civile.

Jan 1, 2003

By M. N. Mathabathe, A. S. Bolokang, C. W. Siyasiya, R. J. Mostert, G. Govender

The b-solidifying g-TiAl intermetallic alloys of nominal composition Ti-48Al (binary alloy), Ti-48Al-2Nb (ternary alloy), Ti-48Al-2Nb-0.7Cr (quaternary alloy), and Ti-48Al-2Nb-0.7Cr-0.3Si (quinary alloy) (in at.%) were developed. The materials produced were tensile tested at room temperature. The as-cast microstructures and fracture surfaces of the tensile tested specimens were examined using conventional metallographic methods. Microstructural examination indicated that the alloys were comprised of lamellar structures (a2+g) embedded in columnar dendritic cores in the as-cast condition. However, the quinary alloy contained a Ti5Si3 second phase. The alloys exhibited no detectable ductility during tensile deformation, indicating the brittleness of all the materials. The fracture surfaces revealed that the alloys failed by translamellar fracture with correspondingly few cleavage facets.

Apr 1, 2021

By Z. Gxowa, L. H. Chown, U. Curle, G. Govender

This work evaluates the deformation behaviour, at warm working temperatures, of green particle-reinforced aluminium composites produced by powder blending in a high-energy ball mill. The work focuses on metal matrix composites (MMCs) based on the 2124-Al alloy, reinforced with 10 or 15 vol.% SiC and metal matrix nanocomposites (MMNCs) based on the 2124-Al alloy, reinforced with 5 or 10 vol.% Al2O3. Three batches for each powder were blended and powder properties such as particle size distribution (PSD) and shape were consistent after blending. It was observed that a more uniform distribution of the reinforcement phase in the aluminium alloy matrix was achieved in 2124-Al/Al2O3 than in 2124- Al/SiC composites. The powders (unreinforced 2124-Al and blended) were initially over-aged at 350°C for 2 hours to reverse any natural ageing that may have occurred prior to use. The over-ageing was incorporated to improve compressibility of the powders with the aim of achieving green compacts with higher integrity. Uniaxial compression tests performed at ambient temperature on a Gleeble® 3500 thermomechanical simulator were unsuccessful as the green compacts fragmented. Engineering stress-strain curves showed that green compacts of unreinforced 2124-Al, 10%SiC MMC and 5%Al2O3 MMNC deformed in a similar manner at ambient temperature and had the same compressive fracture stress of approximately 170 MPa. When the deformation temperature was increased from ambient to warm working temperatures (170–280°C) it was observed that electrical resistance heating (the heating mode of the Gleeble®) of unreinforced Al alloy, MMC and MMNC green compacts did not occur. This was attributed to the high electrical conductivity of aluminium, which resulted in poor heat generation due to the low electrical resistance in the samples. It was presumed that the small sample size (d=8 mm, h=12 mm) also caused rapid heat loss. After further experimentation, the green compacts were heated successfully by insulating the samples to retain heat. It was found that at 280°C, increasing the soaking time from 6 to 20 minutes decreased flow stress and improved plastic flow in the 2124-Al/10%SiC green compact.

Jan 1, 2016

By X. Yu

Although many investigations of the deformation behaviour of rocks have been carried out, most of them are carried out in compression. In all rock engineering practice it is usually assumed that the deformation of rocks in tension is the same as that in compression. However, data from numerous researchers have shown that this assumption is not correct for some rocks. A new loading frame for testing rocks in compression and direct tension has recently been developed by the authors, with the capacity to conduct both compression and tensile tests on the same rock sample. The results obtained show that the ratios between the average Young?s modulus in compression (ECA) and in direct tension (ETA) are 1, 1.16, 2 and 6 respectively in four rock types tested. For Poisson?s ratios, analogous relations were obtained. It was observed that, in all cases, the tangent Young?s modulus intension reduces with an increase in the applied tensile stress, while the behaviour of Poisson?s ratio is similar, but shows greater variability. The difference between the Young?s modulus of rocks in tension and that in compression could lead, large errors in calculating induced stresses around underground openings, as well as in determining the Brazilian tensile strength of rocks. This may have a significant influence in rock engineering and therefore more investigation is necessary into the tensile deformation behaviour of rocks and its influence.

Jan 1, 2005

By M. D. G. Salamon

In view of an urgent need for a simple means of simulating the behaviour of stratified rock masses, a long-dormant linear model is revived, generalized, and discussed in some depth. The model is piecewise homogeneous, consisting of a pile of homogeneous isotropic laminae in which the interfaces between beds are parallel and free of shear stresses and cohesion. The continuity of stresses and normal displacements is assured across the bedding planes and, to maintain simplicity, the theory of thin plates is used as the kernel of the model. The paper covers the case where the rock mass consists of discrete beds in which the layers are arranged either heterogeneously or systematically. The stratification is regarded as uniform when all the layers are of the same thickness and their Young's modulus changes exponentially with depth; and as homogeneous when all the laminae have identical thickness and properties. The case of uniform stratification is also treated on the basis of an equivalent quasi-continuum derived from the basic model. Attention is focused on the derivation of influence functions. It is demonstrated that the quasi-continuous models, when they are available, can replace their distinct-layer counterparts. The homogeneous quasi-continuum, which permits the derivation of its influence functions in closed form, facilitates the determination of the roof and floor convergence. In the case of a significant class of problems, the convergence distribution is defined by a second-order differential equation in the xy plane, which simplifies to a Poisson's equation if the mining excavations are unsupported. With this result, the paper prepares for the solution of a host of practical problems. These solutions are presented in a series of papers that are in the course of publication.

Jan 1, 1991

By Rodney Ishak, Merete Tangstad

In the HC FeMn production, better utilisation of coke and electric power is vital for reducing the production costs. The higher manganese oxides in the charge are reduced to MnO in the prereduction zone, where also the Boudouard reaction is active. These gas-solid reactions are to a large extent decisive for the total consumption of both coke and electrical power in ferromanganese production. In the present work formulas for calculating the Degree of prereduction have been developed for industrial practice. It shows that the typical Degree of prereduction is between 10-40%, but it may in good periods be as high as 60%. Statistical analysis has been done in order to find how various operational parameters influence the Degree of prereduction. A few parameters were observed to have an effect on the prereduction. Comilog ore definitely had a positiveinfluence on the prereduction, Comilog sinter and Mamatwan ore probably had a positive influence on the prereduction, all in relation to the average prereduction in the selected periods. Meanwhile, As man ore definitely, % H2O in raw materials and increasing Hd probably, had a negative influence on the prereduction. The findings for these raw materials were very much in coherence with the results of laboratory scale experiments performed, where the CO-reactivity of different ore materials was studied.

Jan 1, 2007

By H. Lieberwirth, M. Klichowicz

The comminution at grain size level for the liberation of valuable minerals usually requires the highest size-specific energy. Therefore, the full understanding of the comminution process at this level is essential. Models based on the Discrete Element Method (DEM) could be a helpful tool for this purpose. In those, the mineral microstructure, which has a dominant influence on the fracture behaviour, can be described in great detail. One major concern, however, is the missing representativeness of simulated models. In this study, a method to overcome this limitation is presented. The authors show how a realistic microstructure can be implemented into a particle bed comminution simulation using a two-dimensional Bonded Particle Model (BPM). The improved algorithm based modelling approach is exemplarily compared to an equivalent real experiment. Thereby, the focus is set on the analysis of the interfacial breakage and the capability of the simulation to reproduce the experimental results. The comparison of the results shows that simulations at grain size level allow a more detailed evaluation of the fracturing behaviour. This is of special interest as the aim of comminution in mineral processing is not only the size reduction of coarse particles, but an efficient liberation of the valuable components. Hence, simulations with automatically generated real mineral microstructures will help to further improve the efficiency of ore processing. Keywords: Discrete Element Method, grain modelling, particle bed comminution, realistic synthetic

Jan 1, 2020

By L. Zhou, J. Qiu, M. Tang, J. Wang, G. Dai

Coal spontaneous combustion in longwall gobs is a major concern in coal mines. In comparison to other hazards, this phenomenon is difficult to detect. Fifteen factors influencing coal spontaneous combustion in longwall gobs were identified from the literature. The logical relationships between these factors were evaluated and quantified by decision-making trial and evaluation laboratory (DEMATEL) and interpretive structural modelling (ISM) methods. A four-level hierarchical structure model was established. The research shows that combining DEMATEL and ISM can reveal the key factors that influence coal spontaneous combustion in longwall gobs and establishthe interactions and relationships among these factors. The results can provide the basis for preventing and controlling coal spontaneous combustion in longwall gobs.

Jun 10, 2024

By M. -A. de Ville d’Avray, J. Bosman, S. Brochot

Dense Medium Separation (DMS) technologies are used for light (coal, lithium) or heavy (chromite, iron ore, diamonds) minerals concentration, but also for ore pre-concentration (Pb/Zn) or waste (plastics). Dense media are mainly formed from a suspension of magnetite or ferrosilicon in water. Such DMS circuit design or optimisation requires a full and detailed material balance which can be obtained by the aid of modelling and simulation tools. This balance is not limited to ore and its valuable minerals, but also the recovery of the dense medium itself. If the density is the main property used for separation, the particle size plays a non-negligible role, and, more precisely, the liberation classes which can be associated to the washability curve. The paper presents how the modelling and simulation platform USIM PAC can answer this challenge with the set of models for DMS operating units such as drums or cyclones, and their associated screens (drainage, rinsing) and magnetic separators for medium recovery. Some examples for mineral concentration will illustrate this approach. Keywords: Process simulation, process modelling, dense medium separation, process optimisation

Jan 1, 2020

By G. J. de Korte

Dense-medium beneficiation of fine (minus 0.5 mm) coal is not a new concept and has been used in South Africa previously. The dense-medium fine coal plant at Greenside Colliery operated for almost 18 years and, despite proving a difficult plant to operate, did succeed in producing a fine coal product with a low ash content of 7%. No other beneficiation process available could achieve this. Dense-medium beneficiation of fine coal was also used in other countries, of which the plants at Homer City in the USA and Curragh in Australia were the best known. The first application of dense-medium cleaning of fine coal was, however, at the Tertre plant in Belgium1. This plant was built in 1957. About nine years later, a second fine coal dense-medium plant was built at the Winterslag Mine, also in Belgium. According to reports, this plant operated satisfactorily for a period of some 17 years.

Jan 1, 2002

By M. Buchmann, T. Mütze, F. Heinicke

Dry air classification is a well-known technique used for decades in the cement industry to separate material in the size range of 0.01-1.0 mm. Additionally, in corresponding dry grinding circuits with effective machines such as High Pressure Grinding Rolls (HPGR), the energy consumption can be reduced compared to wet applications. These dry systems are not state of the art in minerals processing plants, but first prototypes have been installed and an increasing number of projects are starting to evaluate this option. One challenge in this field is the mineral composition of ores, which have, by far, a higher variety in density and size than those of cement. High density particles such as iron- containing ones have higher settling rates than low density silica particles of the same size. The main question to answer in this paper is how to evaluate this effect, so a quantitative method using Mineral Liberation Analyses was developed to calculate two-dimensional partition curves. Additional statistical analyses allow for isolation and quantifying the interaction of density and size, enabling engineers to consider this effect for the sizing of process plants. The paper will present the method and selective results for a compounded ore of iron and silica. Keywords: HPGR, air classification, partition curve, MLA

Jan 1, 2020

By D. Kumar, B. Rai, S. G. Srinivasan, V. Jain

Chalcopyrite and pyrite are among the major gold bearing minerals in the world. The gold content in chalcopyrite and pyrite varies from 0.02 to 200 ppm and 0.01 to 20 ppm, respectively. Apart from gold, chalcopyrite is also the primary source of copper. Thus, the recovery of gold and copper are often associated with the recovery of chalcopyrite and pyrite. Flotation is one of the most successful methods applied to beneficiate chalcopyrite and pyrite. The success of a flotation process depends on an appropriate choice of the flotation collector used to achieve the desired selectivity. A thorough understanding of the atomic structure of the predominantly exposed mineral surfaces can immensely aid in developing highly selective collectors that can exploit both the physical and chemical characteristics of these surfaces. In the present study, density functional theory calculations within the plane wave framework are used to understand the surface structure and reconstruction of the most stable chalcopyrite (001), (100), (110) and (112) and most stable pyrite (100) surfaces. The chalcopyrite (001) and (100) metal-terminated surfaces undergo significant reconstruction and result in metal-metal bond formation in the sub-surface layer while the surface layer is replaced by S-atoms. On the other hand, the (001) and (100) S-terminated surfaces show S—S disulfide bond formation upon relaxation, which are consistent with literature reports. The chalcopyrite (110), (112) surfaces and pyrite (100) surface undergo rearrangement, but no reconstructions in terms of metal-metal or disulfide bond formation are observed on these surfaces. Keywords: DFT, surface reconstruction, pyrite, chalcopyrite, adsorption

Jan 1, 2020

By A. P. I. Popoola, D. O. Okanigbe

Copper smelter dust (CSD) is a byproduct of copper smelting and is composed of considerable amounts of copper values and also contaminants (like silica and mullite). Silica in CSD forms Siloxane, a low density material, which is difficult to separate from the aqueous phase during solvent extraction. The need therefore arises to reduce/remove the aluminosilicates for better grade and recovery of copper in subsequent processes. This paper reports the use of two types of centrifugal gravity concentrators, namely Knelson (KGC) and Falcon (FGC), for upgrade of copper in CSD. The aim was achieved by an initial characterisation (Particle Size Distribution (PSD) and mineralogical analysis), together with Density Separation (DS) experimentation, premised on a hypothetical density difference between copper oxide and silicon/aluminum oxide. Wet screening results showed that 88.52 % of CSD particles were in -53 μm fraction. Further PSD study using laser diffraction showed the -53 μm fraction to be composed mainly of 26 μm, 22 μm and 18.5 μm fractions. Mineralogical analysis showed copper to occur mainly as oxides (24.34 wt%), but also as sulphides (7.95 wt%), and a substantial amount of aluminosilicates (42.97 wt%) were identified. Density of CSD was determined as 2.83 g/cm3. Copper content (18.02 wt%) in CSD was upgraded to 35.94 wt% in concentrate using KGC. In conclusion, the results showed good convergence between hypothesis and experiment. Additionally, it was also concluded that KGC performed better than FGC for copper upgrade in CSD. However, roasting CSD prior density separation was recommended for enhanced copper upgrade. Keywords: Copper smelter dust, density separation, solvent extraction, mineralogy

Jan 1, 2020

By L. Roux

The initial evaluation of a coal deposit often raises uncertainty with regard to the accuracy of the reported Resources and Reserves. Reconciliation of results from mining and beneficiation with the original raw field data highlights deficiencies in original estimations. Credible Resource and Reserve estimation forms the basis on which an entire mining enterprise is motivated, initiated, funded, and established as a commercially viable proposition. This is required for sustainable extraction purposes and to support vital downstream industries such as power generation. Accurate determination of the density of the matrix of the material being evaluated is the key to credible values being obtained for Resources and Reserves. Losses between 15% and 20% of the Resource/Reserve can be realized if incorrect densities are applied to the tonnage derivation. Coal plies and particles have different relative densities, determined by the maceral composition, rank, and mineral and moisture content. These factors in turn contribute to the moisture, volatile matter, ash and carbon contents of a coal, which affect the overall density of the raw coal. More specifically, the relationship of ash to density and the effective matrix porosity were found to be critical in solving the greater majority of the problems in predictive calculations. A major deficiency identified is the inability to determine effective porosity, allowing absorption of adventitious moisture and altering the mass of the core sample. Although the volume of the raw material is altered through crushing, the change in mass after controlled air-drying, used with the original geometrical volume of the raw material, provides a credible air-dry density and allows the determination of the volumetric change related to effective porosity. This parameter can be validated through the evaluation of proximate ash using the ash-adjusted algorithm and a correction for the inherent moisture applied to also give a credible relative density value for an air-dried sample. A combination of theoretical, empirical, and reconciliatory evaluations of the available data, taken from the exploration phase through the mining process to final production, has shown that an integrated approach using the ash-adjusted density (AAD) methodology, in conjunction with other evaluative techniques, provides credible results with a considerably higher degree of accuracy than is currently possible.

May 1, 2021