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Sphalerite is commonly floated in an alkaline environment and under such conditions the overall activation mechanism is obscured by the hydrolysis of Cu2+ and precipitation of Cu(OH)2. Electrokinetic and kinetic flotation tests show that the activation of sphalerite is a two-stage process; the activation products formed on the surface of sphalerite in near neutral and in alkaline solutions in the first rapid activation stage are "flotation-inactive". These layers, when formed in an alkaline solution, are unstable and are transformed into the "flotation-active" form in the second stage. However, the surface layers formed during activation in alkaline environment by copper in the presence of lead ions are very stable and even after a long conditioning time the flotation rate is not improved. Consequently, while both Cu2+ and Pb2+ activate sphalerite flotation, quite unpredictable effects may result when both are present in the solution.

Jan 1, 1997

By T. C. Souza Pinto

Because shape is an assessment of the three-dimensional form of a particle, it may be described in terms of sphericity (?), which is a measure of how closely a particle approaches a spherical configuration. In this study, Darcy?s law and the Kozeny-Carman model for fluid flow through porous media were applied to packed beds to determine the sphericity (?) of apatite particles. The beds were composed of glass spheres or particles of apatite (igneous from Brazil and sedimentary from the United States) of three classes of size (Class 1: -297 +210 µm; Class 2: -210 +149 µm; Class 3: -149 +105 µm). Glass spheres were used to validate the model because of its known sphericity (? = 1.00). Apatite particles, either igneous or sedimentary, showed very close values for particle sphericity (? ? 0.6). Observations on particle images conducted by scanning electron microscopy illustrated that igneous (? = 0.623) and sedimentary (? = 0.644) particles of apatite of Class 2 predominantly exhibit elongated shape. The close value of particle sphericity (? ? 0.6) showed by either igneous or sedimentary apatite may be justified by the similarity in particle shape.

Jan 1, 2009

By Key Rosebrook, Jennifer Laggan, Ashley Rivera

Significant quantities of waste rock at abandoned uranium mine (AUM) sites in the western United States require removal from steep slopes exceeding 45 degrees in remote locations. This prevents the use of traditional excavation equipment and poses significant challenges for safe, effective material removal. A pilot study was conducted using a spider excavator to demonstrate the feasibility of removing waste rock and transporting it to areas where conventional equipment could be employed. The spider excavator was evaluated for its effectiveness in excavation, material movement and control, container usage, dust mitigation, and ensuring human health and environmental safety. The study established constructability and engineering parameters for implementing spider excavators in these challenging environments. Key outcomes include the preservation of existing vegetation, improved waste movement control, and enhanced safety measures for workers, nearby residents, and the environment.

Feb 1, 2025

By S. S. Pathak, S. Mishra, M. H. Tyeb, A. K. Majumder

Roping in hydrocyclones is a well-known phenomenon in mining and mineral industries which put serious restrictions on their continuous and maintenance free operation. Roping is mostly observed in association with high underflow solid concentrations which can be attributed to higher fraction of solids reporting to the underflow or the feed solid concentration itself being higher. This paper proposes a newly designed spigot with a truncated conical geometry which can allow for a rope-free discharge at higher feed solid concentrations. The experimental observations revealed that in the operation of a 50.8-mm-diameter hydrocyclone, roping ensued at 10% to 12.5% (wt%) feed solid concentration depending on feed inlet pressure for the cylindrical spigot, whereas with the modified spigot, rope free discharge was attained even at 25% (wt%) feed solid concentration.

Jan 8, 2022

By John E. Auten

The computer program "Spike" is an "expert-rule based system" designed to fulfill two requirements. 1) acquaint unfamiliar personnel with big hole drilling techniques and 2) to stimulate the "old hands" in solving drilling problems. "Spike" will not make anyone a drilling expert The best way to understand a computer program is by example, but first some explanation of an? "expert-rule based system", As the name implies, the program tries to imitate a human expert. Unlike a normal computer program which uses a list of instructions to follow in a set order, a rule-base program has a collection of independent rules without an explicit list of things to do, one after the other. This type of program was mandatory to accommodate the ever changing situations and corrective actions that more accurately duplicate actual drilling operations and the advise of an experienced drilling expert.

Jan 1, 1988

By Alice Blount, F. Patrick Carr

The quantitative evaluation,of quartz and other minerals in acid-insoluble residues from carbonate rocks and other industrial mineral products derived from sedimentary and low-grade metamorphic rocks is difficult. Commonly there are a dozen or more minerals present, and the suites vary from sample to sample. Because of these factors, either the absorption coefficient must be determined on a sample to sample basis or an internal standard must be used. Internal standards in general use are unsatisfactory. For example, [A1203] is often present in product samples because of ceramic grinding elements used in their production; CaF and LiF have peaks which overlap or nearly overlap mineral peaks in the samples. A careful evaluation has shown that magnesium aluminate (synthetic spinel) works particularly well as an internal standard for these types of samples. Not only does it have few, strong diffraction peaks which do not overlap, the peaks are in the same 28 region as the minerals, usually quartz and silicates, for which quantification is desired. Spinel also consists of equidimensional particles without prominent cleavages; this promotes a random orientation of the minerals in X-ray diffraction mounts. In addition, spinel can be used to correct for loss of diffracted-beam intensity due to thin sample preparations which are often unavoidable.

Jan 1, 1991

By E. M. J. A. Pallone, F. N. Cunha, W. S. Resende, R. M. Stoll, R. C. Bradt

Utilization of the magnesium aluminate spinel in refractor' applications is briefly reviewed. The synthesis of a magnesia aluminate spinet aggregate from natural raw materials is considered in terms of the crystal chemistry of the spinet structure and expected impurities. Principles for the formation of this spinet refractory aggregate from different natural raw materials are presented. The basic concepts were then applied to the reaction of a bauxitic clay with a natural magnesite. This combination of raw materials has the potential to produce a low-cost refractor' aggregate that is a composite of spinel and forsterite. Experimental results are reported to produce a spinel refractor.' aggregate containing a small amount of forsterite. It possesses low apparent porosity and high bulk density suitable for industrial refractor' applications, including steelmaking, aluminum and copper foundries and cement production.

Jan 1, 2002

By L. F. Delgado

Environmental and cost pressures sparked renewed interest in gravity separation. Industrial sands in Mexico are generally processed by screening, desliming, and flotation. Gravity separation with spirals was evaluated as an alternative to flotation in order to lower operating costs and decrease water pollution. Outstanding operating results are obtained in glass and foundry sand operations, plus a more competitive position for Mexican producers due to lower operating costs. Coal fines, generally recovered by flotation, have the same cost and environmental advantages when processed with spirals.

Jan 1, 1994

By C. H. Sampaio

The effectiveness of modem spirals in the processing of fines from Brazilian coals is assessed and discussed. Coals representing the four major coalfields in Brazil have been cleaned in Reichert LD 9 spirals in pilot and industrial plants and performance results are here presented. Normalized distribution curves for all equipment and splitters are presented and were modeled using an empirical model. These data have been compared with those for shaking tables and water-only cyclones (WOC), and it has been observed that, in the size interval investigated, spirals have indeed superior accuracy than WOC and comparative performance to tables. By analyzing experimental as well as simulation results it could be observed that although limited by the poor liberation characteristics of most Brazilian coals, significant ash and sulfur removal could be achieved using spirals.

Jan 1, 1995

By M. G. Ayat

Although other methods of mineral concentration have been developed over the years, gravity separation remains one of the most efficient and economical for cleaning coal. The concentrating table and the spiral separator are popular devices used for the separation of minerals by exploiting the differences in specific gravities of the product material and the gangue. While the former device has been servicing the coal industry for over 75 years, the latter seems to have not been employed extensively for coal cleaning purposes in this country. As far as coal preparation is concerned, both separatory devices seem to be most efficient for intermediate to fine size fractions. As it stands there exists a great deal of confusion amongst preparation engineers and plant managers as to whether spirals can have a place in the coal industry. If so, whether their come back is the beginning of the end for concentrating tables, or can they be employed along with concentrating tables to contribute toward more efficient cleaning processes resulting in an improvement in the overall economics of the coal preparation industry. This paper examines the efficiency of both systems for coal processing operations as well as the basic principles, operational variables, economics, advantages and disadvantages associated with each unit operation. Attempts have been made to draw conclusions and make recommendations as to which system would be more beneficial for coals of known characteristics.

Jan 1, 1986

By P. C. Kapur

For mineral processing spirals, mathematical force equilibrium models are sought to extend the spiral performance envelop. In Part 1 of this report, a complete geometric description of the helical spiral and its trough or channel contour is provided. The secondary circulatory fluid motion in the transverse direction that develops when water flows down a tightly turning curvilinear path and its implications for gravity separation are discussed. Different forces that act on the particle during its passage through the spiral are enumerated and quantified for a better appreciation of their relative contributions and roles in the separation process. Three force equilibrium models from the hydrology literature on sed iment transport are employed to simulate a typical spiral. While the results are promising in that the models mimic the broad performance characteristics of the spiral, what is needed is a more general spiral model taking explicit cognizance of the missing components essential to the spiral description. These are such components as centrifugal force and the steep tangential slope of the channel deck. Results of this latter exercise are deferred to Part 2.

Jan 1, 1996

By J. Kemeny, B. Norton, T. W. BoBo

Digital image analysis systems to quantify particle size of crushed materials have successfully been applied in large-scale mining operations throughout the world. Particle size measurement at various crushing and sieving stages, especially in aggregate production, will facilitate the industry’s desire and need to achieve higher levels of process control and automation. This paper will 1) summarize applications of digital image analysis in the industrial minerals industries and introduce the Split-Online technology; 2) detail an actual recent test application of digital image analysis that ultimately lead to the installation of an automatic, non-invasive particle size distribution monitoring system; 3) document how this information is being applied: and 4) summarize the new Split-Online Aggregates Module now available.

Jan 1, 2004

By Emanuele Catelli, Paolo Vicentini, Manuel Petitat, Paolo Lanfranchi

"More than 800 million tons of material will be excavated during large underground projects such as tunnels, undergrounds and power plants by 2030 in Europe only. The raw material excavated is often classified as waste, which involves environmental impact and transport issues: landfill areas, CO2 emissions and noise. But how can such massive amounts of material be transported, processed and deposited? Using the example of the AlpTransit Ceneri Base Tunnel (15.4 km), we show that suitable excavated materials can be used sustainably as a primary resource for tunnel concrete. This requires careful planning of the installations and storage areas by the client, timely building of the processing plants and other handling facilities outside the tunnel and a continuous evaluation of the raw material quality. 1. INTRODUCTION Spoil management is a central element of large construction projects. The systematic reuse of suitable excavated material not only saves natural resources, reduces transport distances and landfill volume, but can also decrease overall construction costs. Ideally, all of the concrete needed for tunnel lining can be produced with this on-site material. Such a natural resource management concept was applied for the construction of the new Gotthard Base Tunnel (L = 57 km). Spoil management concepts are, how-ever, difficult to implement and call for innovative techniques, sophisticated logistics and organization. In the context of large projects, environmentally friendly transport, processing and storage of millions of tons of excavated loose material represent another logistics challenge (Simmen & Lieb, 2010). This paper shows key factors that led to the successful completion of spoil management at the Ceneri Base Tunnel, which constitutes a part of the AlpTransit Gotthard Project (Figure 1)."

Jan 1, 2016

By E. B. Kroeger

Spoil instability has been a problem at a coal mine in interior Alaska. Parameters such as original site topography, groundwater conditions, material properties, spoil-pile geometry, geology, permafrost, natural slope instability, changing weather conditions, and dense, near-surface vegetation have interacted to produce unstable slopes. Several failure modes have been identified including deep seated earth block slides, bimodal earth flows, and solifluction. Thawing of permafrost also created conditions where sliding of spoil along the interface separating the spoil and the natural ground surface occurred when the cohesion and the friction angle of that zone was reduced to zero and below 15?respectively.

Jan 1, 1992

By Z. Yanni, W. Xuan, Z. Jingyu, D. Jun

"In order to conserve the coal resources, many coal mines which have been mined begin to re-mine. Re-mining face is of complicated circumstances and coal spontaneous combustion is unknown, so experiments are designed to study the characteristics of multiple oxidized coal samples. The investigation into the oxidation of coal is conducive to the safe mining of the coal seam groups and thick coal seams. The non-caking coal is collected as coal samples. The raw coal sample with initial oxidation and the sample after second oxidation and third oxidation are obtained after a certain treatment of the coal. The temperature-programmed system, and proximate and ultimate analysis are adopted to compare the releases of gaseous products of spontaneous combustion characteristic parameters of the multiple oxidized coal sample. With the increase of oxidation times, experimental results indicate that the oxygen consumption rate, the release rate of carbon monoxide and the intensity of heat release are significantly decrease. The characteristic temperature dropped and the size of the pores in coal is smaller as well. INTRODUCTION China accounts for 13% of global coal resources [1-2]. In recent years, more and more coal mines begin to re-mine in order to conserve resources. This production mode is to mine coal pillar left by last exploitation or unavailable for mining. In the process of slicing mining for coal seam groups or thick coal seams, the second or multiple oxidation due to the mining-induced effect, may take place in the goaf of the lower seam. So the spontaneous combustion is prone to occur in this area. The study on oxidation of coal is conducive to the safe mining of the coal seam groups and thick coal seams. Scholars [3-7] have discussed the workability of re-mining for coal mines, verify the feasibility of the existing mining technology for re-mining area, and set up the prevention measures of coal spontaneous combustion. But all these measures are only based on on-site observation data, instead of experiment on spontaneous combustion characteristic parameters of re-mining coal samples which have a great importance for early prediction and forecast. The authors aim at investigating the multiple-oxidated coal spontaneous combustion law, and perfecting the coal spontaneous combustion mechanism to provide a basis for the prediction and forecast."

Jan 1, 2015

By Thomas H. Koenning, James R. Boulton

The coal mined by Cyprus at the Shoshone mine near Hanna, WY is highly susceptible to spontaneous combustion. Spontaneous heatings have occurred in the gob of several of the longwall panels and, in some cases, following roof falls. Prevention and detection methods have evolved over the years as more has been learned about the occurrences. Seal design and construction have progressed to reduce air leakage into the gob. Pressure balancing has been successful as a supplement to good workmanship in reducing leakage. Early heating detection has improved as knowledge has been gained. Prior methods of detection relied upon thermocouples detecting a temperature change. Later a gas chromatograph was used to analyze gob gas samples. Initially the products of combustion (POC) were relied upon for detection. Most recently, lack of oxygen depletion in the gob has been used as an early warning of problems. Examples are presented to illustrate the evolution of spontaneous combustion control at the Cyprus Shoshone coal mine. Methods have been developed which minimize the oxygen concentration in the gob and reduce the potential for spontaneous combustion.

Jan 1, 1997

By Thomas H. Koenning

The number of spontaneous combustion incidents in the U.S. is expected to increase as the consumption of lower rank coals and the use of longwall mining becomes more prevalent. A spontaneous combustion incident holds the potential for substantial loss of life from a mine fire or explosion if not prevented or controlled at an early stage. Laboratory tests have been developed which are useful in ranking the susceptibility of various coals to spontaneous combustion. Ventilation circuits and mining methods can be designed to minimize the risk of spontaneous combustion. Early detection of spontaneous combustion is possible with the combined use of continuous monitoring, periodic gas sampling, and inspection.

Jan 1, 1989

By William Laird

In the process of mining coal today, our greatest asset, the coal miner, is faced with the indirect and direct consequence of underground mining operations. The indirect considerations may be the rank of the coal seam, the amount of overburden, geological factors, seam permeability and cracks. The introduction of newer, bigger and faster coal-producing face equipment having the capability to cut or rip through the bedding planes, cleats and micropores of the coal seam brings about rapid liberation of gas accompanied by greater concentrations of coal dust, has exerted a direct consideration and greater demand upon mine ventilation systems and dust control. The purpose of mine ventilation is to provide sufficient pure air to the miners working underground and to dilute, render harmless, and carry away all the dangerous and noxious gases. The mining operations which create coal dust are cod cutting, drilling, blasting, loading, hauling, dumping and movement of face equipment. The created fine dust causes the propagation of explosions. When quantities of coal dust with no methane present are raked in a sufficiently dense cloud in the presence of a source of ignition, an explosion is possible.

Jan 1, 1980

By Charles R. Nelson

INTRODUCTION The support of openings in weak sandstones can be achieved by spraying on a liquid grout which will soak in and harden to form a shell. In the St. Peter sandstone of the Minneapolis-St. Paul area of Minnesota compressive strength is increased from about 0.7 MPa (100 psi) to over 7 MPa (1000 psi) to depths of 152 mm (6 in.). A shell of this strength and thickness can pro¬vide support much as shotcrete does but at lower cost. If the spray-grouted shell is inadequate for the support needed, it provides a good base for shotcrete application, which is often difficult in weak or friable sand¬stones because the fresh shotcrete peels off along with a thin layer of sandstone. The spray-grouted technique was initially developed at the Civil and Mineral Engineering Dept. of the University of Minnesota using funds provided by RANN Div. of the National Science Foundation. It was used as temporary support in a 3-m (10-ft) wide, 3700-m (12,000-ft) long storm water drain tunnel by the Minneapolis Sewer Construction Dept. Much of the field development at this construction project was carried out with the cooperation of the personnel of the city of Minneapolis. It also was used for temporary support in a 3.3-m (11-ft) wide, 1800-m (6000-ft) long storm water tunnel built in 1978-1980 for the Minnesota Dept. of Transportation in Minneapolis. In 1975, 2000 m (6500 ft) of 1.5-m (5-ft) wide utility tunnels were spray-grouted for final lining. A 50-m (150-ft) long, 1.2-m (4-ft) wide test tunnel built at the university in 1974 was sprayed for half its length and is being observed for long-term behavior which to date (1981) is good. GROUT MATERIALS The requirements for the liquid grout are more severe than those for injection grouting. Besides being able to penetrate the rock and develop sufficient strength, it must have the following properties: (1) be nontoxic, noncombustible, and have a low odor for spraying under¬ground; (2) have controllable viscosity and setting time for adjusting to the permeability of the sandstone and the required depth of penetration; and (3) must "wet" the sandstone and develop capillary "draw" to penetrate to the required depth. A sodium silicate-based grout with the proper setting agent meets these requirements in the local St. Peter sandstone which has a uniform grain size dis¬tribution curve with D,,, = 0.1 mm, permeability of about 10 to 20 darcys, a porosity of about 25%, and less than 5% of silt size or smaller. It is 97 to 99% pure SiO2. The grout mix consists of Philadelphia Quartz Co. Type N sodium silicate and Celtite 55 Terraset Spray Grade (SG) distributed by Celtite Inc., Cleveland, OH. A volume mix ratio of 100:9:125 for sodium silicate to setting agent to water produces a grout with two to four centipoise viscosity, and initial set at 20°C of 20 min. Setting time is temperature dependent, being longer at lower temperatures, but can be adjusted by varying the setting agent concentration a few percentage points. APPLICATION The application is simple. Spray the grout on the surface until the desired penetration is achieved. Penetration rates of about 5 mm (0.2 in.) per min. are realized in the St. Peter sandstone for up to 152 mm (6 in.) of penetration (30 min. of spraying). The set time must be longer than the spraying time. The spray nozzle should be moved back and forth at a rate that minimizes runoff due to surface buildup. Both a single large hand-propelled nozzle and multiple small machine propelled nozzles have been used successfully. The pumping and mixing equipment used consisted of: (1) a hand-held, hand-pumped, 11-L (3-gal) gar¬den sprayer for test patches (mix by shaking); (2) 76-L (20 gal) batch mixing in barrels with small electric pumps for spraying and mixing; (3) two component pumps consisting of Hypro Model 5300 piston pumps (Hypro Pump Co., St. Paul, MN) on a common shaft driven by an electric motor. The sodium silicate is premixed with a portion of the water and the setting agent is mixed with the rest of the water. The two components are combined and mixed just before the nozzle; and (4) a proportioner metering the setting agent just before the nozzle with the water and sodium silicate premixed and pumped from the surface. The proportioner permits the bulk of the grout to be pumped through a single pipe or hose with only the setting agent stored underground. This is efficient and low in cost. COST The grout mix costs about $0.20/L ($0.75 per gal) in 1978 dollars. Filling all the voids 100 mm (4 in.) deep (25% initial porosity) would have a materials cost of about $5.40/m2 ($0.50 per sq ft). The labor cost of application is usually less than the material cost for normal tunnel jobs. A pump and proportioner cost less than $1000. Sodium silicate storage tanks and pip¬ing costs would depend on the particular site conditions. REFERENCES AND BIBLIOGRAPHY Nelson, C. R., 1977, "Spray Grouting for Tunnel Support and Lining," Underground Space, Vol. 1, No. 3, pp. 241¬ 245. Yardley, D. H., Nelson, C. R., Stocker, T. H., 1974, "So¬dium Silicate Spray Impregnation of Tunnels in the St. Peter Sandstone," Research Report, University of Min¬nesota, 118 pp.

Jan 1, 1982

By Kenny Lo

"SummaryFor more than a century, ground freezing has been a construction technique used in stabilization of ground by means of lowering the temperature of surrounding soil strata. This technique is used in circumstances where conventional grouting method is unable to achieve the degree of consolidation required to prevent settlement and water ingress during the execution of underground excavation. Whilst ground freezing is effective in imparting self-supporting characteristics to the excavation profile, it poses significant challenges when it comes to the New Austrian Tunneling Method (NATM) where sprayed concrete is used to support the freshly excavated ground. Sprayed concrete, if used in an appropriate manner, provides a fast, efficient and structurally-reliable means of supporting the structure, especially in underground construction. The evolvement in sprayed concrete technology is attributed to the development of concrete know-how, improvement of spraying technique with the use of automation spraying equipment, more in-depth understanding of sprayed concrete behavior and enhancement of materials used in production of high quality sprayed concrete Not only has this markedly escalated the prominence of sprayed concrete on wider perspective,. the positive development has also pushed sprayed concrete beyond its boundaries, enabling it to be embarked on area of application not considered possible decades ago. Nevertheless, sprayed concrete, for all its placement versatility, still depends largely on the technicality provision very similar to concrete to achieve the required quality. Parameters such as raw material grading composition, curing temperature and cement quality are some of the factors that can easily sway the quality of concrete from one extreme to another. Conducive ambient temperature is critical in ensuring optimum hydration of concrete. This is more important in sprayed concrete where temperature plays a pivotal role in influencing the early strength and long term strength development. The low temperature imposed by ground freezing is everything but ideal for competent hydration to take place. This paper outlines how the innovative use of sprayed concrete helps to overcome the adverse ambient temperature in the construction of a 110m underground pedestrian walkway utilizing ground freezing technique in Hong Kong."

Jan 1, 2016