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By M. P. D. Ingunza, Júnior Santos, F. S. D. Araújo, A. L. C. Araújo, J. Y. P. Leite

Wastewater sludge is a problem for environmental control and it is necessary alternative researches for its reuse. Industries can research the association of clay and sewage sludge as a source of ceramic mass. This procedure can contribute for the industry sustainability including in its raw materials, wastes of environmental concern. This paper presents the results of sewage sludge and clays characterization being analyzed particle size distribution (sedimentation), mineralogical (X-ray diffraction), chemical composition (X-ray fluorescence), thermal analysis, density, and Atterberg proprieties (liquid and plastic limit; plasticity index) and also their applications in ceramics. Results were used to determine moisture for mass of raw material and sewage sludge and there were realized tests of fired in kiln at temperatures used in ceramic industry for bricks production. In the test pieces were analyzed the properties for application as bricks.

Jan 1, 2005

By S. R. Bryan, J. D. Stephens, D. R. Rothbard

The distributions of gold and associated elements in mineral grains from a pyritic gold ore were studied by optical microscopy, and by SEM and SIMS imagery. Products studied were a sulfide flotation concentrate, a calcined sulfide concentrate, a cyanide leached calcine, and a cyanide leached pressure oxidation residue. Individual pyrite grains are compositionally zoned and solid solution gold occurs in some, but not all zones. Most of the gold in calcined products is present as metallic coalesced grains that are smaller than 100 angstroms. Gold lost into cyanide leached residues from the calcines tends to be in “semi-dense” grains that cannot be distinguished from gold-free grains except by SIMS analysis. The gold in cyanide leached pressure oxidation residues occurs as solid solution gold in unoxidized pyrite remnants.

Jan 1, 1990

By Jakub Nalaskowski, Vamsi K. Paruchuri, Marcin Niewiadomski, Jan D. Miller

Spherical oxide particles can be used as mineral fillers, paint pigments, polishing materials and catalysts. They can be prepared using various techniques involving precipitation and spray drying. Melting of particles in a high-temperature flame is a simple technique which produces particles with a high degree of sphericity and high smoothness from non-spherical feed material. In current research the preparation of alumina particles by melting the feed material in a hydrogen- oxygen flame is described. The spherical particles obtained were characterized using scanning electron microscopy, atomic force microscopy, energy dispersive spectroscopy, X-ray difiaction, Fourier transform infrared spectroscopy and electrokinetic measurements. The particles pre- pared exhibit a high degree of sphericity and a low level of roughness. The chemical composition of the material after preparation is unchanged, however the crystallographic structure is different. It is suggested that alumina changes from pure a-alumina to a mixture of different transitional forms. Changes in the electrokinetic behavior were also observed for alumina which can be attributed to the strong dehydration of the oxide surface and/or change in the crystallographic structure. Also, the possible accommodation of trace amount of impurities in the surface zone during melting cannot be ignored.

Jan 1, 2003

By Stephen R. Hunt

This paper summarizes some preliminary results of the Illinois State Geological Surveys current investigation into surface subsidence resulting from coal mining in Illinois. The purpose of the study is to characterize-the vertical movements that may result from various types of underground coal mining. In general there is relatively little published information about subsidence from room-and-pillar mining as compared with longwall mining. The findings of this study, based on mining operations in a variety of geologic settings, delineate the magnitude, shape, and position of the subsidence profile. Comparisons of case histories of subsidence are based primarily on the extraction ratio and the general geometry of the mine (depth, panel width, and mining height).

Jan 1, 1979

By S. L. Huang, J. D. Rockaway, N. B. Aughenbaugh

Shale has long been recognized for its tendency to swell when exposed to the atmosphere. Interaction of moisture with exposed shale strata can cause serious ground stabi1ity problems, since the initial strength of a shale is reduced if the material is sensitive to moisture variations. In this paper, the authors present a classification system to estimate the response of swelling generated within shales. This characterization of the swelling potential is based upon plasticity, susceptibility to moisture, mineralogical constituents of clay size particles, and fabric. Use of this classification system in conjunction with other existing rock properties tests will provide data for more rational engineering design.

Jan 1, 1986

By M. Bennett, L. Twidwell

Montana Tech has embarked on a coordinated series of studies to delineate the characteristics of the Berkeley Pitlake containing over 36 billion gallons of acidic, metal-contaminated water formed after the cessation of open-pit copper mining in Butte, Montana, USA. The objectives of the overall series of studies are to summarize presently available information and to generate new and needed information to formulate a conceptual environmental model for the pitlake and to provide characterization data for the development of advanced treatment technologies. In this presentation, the chemistry of the Berkeley Pitlake water is partially reviewed. It is known that the pitlake consists of two distinct layers of water referred to as surface and deep water. Samples of deep water were collected and placed in a 12-ft high and 6-inch diameter column and exposed to different wavelengths of UV radiation as well as atmospheric conditions. Measurements of pH, redox potential (EH), dissolved O2, turbidity, conductivity, temperature, and elemental composition show that the water reacts differently and indicates that the diurnal effects of sunlight likely play a major non-biological role in its chemistry. Resulting technology could be useful for developing an alternative to treating acid-rock drainage.

Jan 1, 2007

By C. L. Schneider

The problem of predicting the liberation spectra produced by a closed continuous grinding circuit is of fundamental importance for the design, optimization and control of most operations in an ore dressing plant. The only known approach through which such a calculation can be performed is the population balance model equation. The latest and certainly most significant progress made in this area is the solution proposed by King (1990), which requires one textural parameter that can be measured directly from the ore being studied. The main advantage of King's solution is that it does not require the estimation of hundreds of arbitrary parameters that cannot be independently measured, as required by the existing conventional solutions. However, King's solution relies heavily on a knowledge of the detailed internal structure of the Andrews-Milm diagram (Andrews and Mika, 1975). This has never been measured for any ore. The characterization of the internal structure of the Andrews-Mika diagram requires the measurement of the liberation spectra at several progeny sizes produced by the breakage of monosize, monograde particles at several different grades. In this paper, a procedure based on magnetic fluid fractionation for generating seven narrow-size, narrow-grade samples is presented. Each of these samples was then broken into six progeny size classes in an ultrasonic mill. The one-dimensional liberation spectra of each of the 42 progeny and seven parent particle samples were then measured by image analysis. The measured linear-grade distributions are presented in this paper. The calculation of the correspondent volumetric-grade distributions is discussed.

Jan 1, 1994

By Isabel F. Barton, Eytan Bos Orent, Mark D. Barton

A new examination of tabular uranium (U)-vanadium (V) deposits within the La Sal district places mineralization in the context of the complex fluid flow history that has occurred in the Paradox Basin and Colorado Plateau. As the only currently producing district of this deposit type in the region, the La Sal district provides excellent opportunities to study deposit- and district-scale features that can serve as exploration guides where exposure is limited. The absence of major structures along a narrow and elongate mineral trend that runs E-W across the southern part of the Utah-Colorado border indicates a regional lithologic control. The trend was likely influenced by Jurassic drainage patterns, as indicated by paleocurrent directions shown in Fig. 1. Fluvial sandstone host rocks in the Jurassic Morrison Formation contain significant evidence of multiple superimposed fluid systems that have progressively changed local mineralogy. Apart from the presence of ore minerals, remnants of fluid systems are preserved as cements including quartz overgrowths, compositionally distinct carbonates, and sheet silicates. New geochronology methods provide constraints on the timing of initial mineralization and later remobilization. U-Pb ages of calcite associated with ore minerals provide evidence for Early Cretaceous mineralization, whereas textures and K-Ar ages show that early-formed V-minerals were replaced at the expense of V-bearing micas and clays during the Eocene. The paragenesis of minerals in U(-V) deposits of the La Sal district reflects the complexity of a sedimentary

Feb 1, 2025

By Jacob Petersen, Jon J. Kellar, Samuel Kessinger, Kiran Green

 The paper demonstrates that Belle Fourche Shale (BFS), an abundant shale, can be transformed into a ceramic through careful characterization and thermal processing. The study explores the potential of BFS ceramics for use as refractories and thermal energy-storage devices, highlighting their high thermal storage capacity, good thermal shock resistance, and cost-effectiveness.

Dec 1, 2023

By Jacob Petersen, Jon J. Kellar, Samuel Kessinger, Kiran Green

Belle Fourche Shale was processed and characterized for use as a clay-based ceramic. The shale was wet sieved to produce particles that were ± 150 μm. X-ray diffraction (XRD) revealed that the -150 μm material was enriched in clay content compared to the unprocessed materials, whereas the oversize material was enriched in quartz compared to the undersize sample. Particle size analysis was performed on the—150 μm sample, which showed that the median particle size was around 10 μm. Scanning electron microscopic (SEM) analysis further confirmed the small plate size, which appeared to be primarily layered clay particles. Next, the -150 μm particles were rolled into a green body, dried at room temperature, and fired at 998°C. The fired piece was analyzed by XRD and contained 6 wt% hematite, 55% quartz, 19% microcline, and various other minor amounts of minerals. When fired at 1152 ℃, mullite was found with increasing hematite compared to the 998 ℃ firing. A multi-spectral analyzer was used to quantify the color change of the 998 ℃ fired (orange) to the 1152 ℃ fired (red) samples. Micro-computed tomography (Micro-CT) of the unfired body exhibited very few large pores, while the piece fired at 998°C also exhibited few and small pores, the overall porosity of the fired body increased. Microhardness data, obtained from the aforementioned samples, resulted in Vickers Hardness (HV1.0) values of 70.8 HV1.0 (998 ℃) and 485.7 HV1.0 (1152 ℃). Three-point bend testing was performed, giving an average strength of 23 MPa on pieces fired at 998 ℃. The average bending strength of the samples fired at 1152 ℃, was 55 MPa.

Sep 26, 2023

By Yuchen Wu, Jing Mei, GUOZHONG LIU, KE GAO, Songjie Tian, Jianwei Cheng, Yu Wang, Yuhang Wu, Hui Wang

The stability and integrity of protective coal pillars between the longwall working face and development roadways are greatly affected by the mining activities such as the development face advancing or retreat mining. Due to underground strata pressure, the coal pillar cracks could be further developed and then the air leakage passages (mainly cracks) could be produced greatly. The air circulation caused by the atmospheric pressure difference between the two sides of the coal pillar may also provide suitable conditions for the possible spontaneous combustion of the residual coal in the mine gob. In this paper, a typical the protective coal pillar in a Chinese coal mine is studied. The deformation and stress of coal pillars during the mining process of longwall working face are simulated by using FLAC3D. The displacement and strain of coal pillars are analyzed. Two indexes, the linear fracture rate (LFR) and area fracture rate (AFR), are introduced to characterize the development of internal cracks’ development within coal pillars. By using field measurement, the air leakage intensity distribution due to coal pillar cracks is obtained; the equation of air leakage resistance of coal pillar under the influence of mining is derived. Then, the possible location of large air leakage of coal pillar is determined, which can be used as guidelines to study the possibilities of coal spontaneous combustions happening in pillar or mine gob. The research results help to control such potential hazards in advance.

Jun 16, 2022

By L. Zhou, L. Yuan, D. Bahrami, Y. Xue

Underground mine accidents, such as mine fires, remain a health and safety risk to mine workers. Researchers at the National Institute for Occupational Safety and Health (NIOSH) are developing a data-driven, predictive model for characterizing the location and size of unknown underground fires. This study examines applying a machine learning-based model to predict fire size and location in a large underground metal mine based on hypothetical scenarios on the model performance. The results show that the size and location of an unknown fire can be determined with over 80% and 90% accuracy, respectively, and potentially help to reduce the risk of hazardous conditions for emergency response.

Feb 1, 2024

By Barry R. Doyle, Emma C. Ross

This paper presents a 20-year global account of tunneling in gassy ground demonstrating high probability of schedule delays, cost overruns, worker injuries and fatalities. Causes of these failures are systemic. Gas is seldom characterized in terms relevant to design of effective ventilation systems. Control measures deployed in tunnels are often based on outdated industrial safety codes. A change in approach is needed. This paper describes how to perform a desk study to determine if field investigation for gas is warranted, and lists the content of an effective characterization of gas in a geotechnical report.

Dec 1, 2022

By C. Zhou, J. Srednicki

Electronic systems have been increasingly used in underground mines to improve mine safety. These electronic systems emit electromagnetic (EM) energy which can adversely impact the performance of other electronic systems nearby and thus should be characterized. Researchers at the National Institute for Occupational Safety and Health (NIOSH) characterized the magnetic fields emitted from devices that can potentially interfere with the performance of proximity detection systems (PDSs) and compared the emission levels of these devices to the susceptibility of PDSs. In this paper, we present our measurement results pertaining to this effort. Particularly, magnetic fields emitted from the different orientations of a powered air purifying respirator (PAPR) and two lite trackers are evaluated based on the RE101 protocol specified in the MIL-STD-461G standard. The results show that both devices emit strong magnetic fields which strongly depend on the orientation of the devices. At some frequencies, the maximum emission levels from the two devices exceed both the emission limit given in MIL-STD-461G and the maximum magnetic fields that a PDS can withstand without a failure. The results and findings in this paper can help the mining industry better understand electromagnetic interference (EMI) underground and provide critical scientific data that support mining-specific recommendations to address EMI-related challenges.

Feb 1, 2023

By V. K. Srivastava, T. Gupta, T. Ghosh

"In recent years, the demand for rare earth elements (REEs) has grown due to increasing demand and global supply shortage. The supply deficit of these critical elements has encouraged the search for new sources, with coal and coal byproducts as possibilities. Coals from certain parts of the world can be rich in REEs and can approach a total concentration of 1,000 ppm. Two Alaskan coal samples, from Healy and Wishbone Hill, were investigated for the effects of density and particle size on REE concentrations for three selected size fractions, and flotation tests were conducted on finer fractions. Additionally, bottom ash and fly ash samples from a power plant were examined for their REE concentrations. The results show that the upgrade potential for REEs on an ash basis from a whole-coal basis ranges from 2:1 for the Wishbone Hill samples to 4:1 for the Healy coal samples. Flotations of the finer fractions of the two coal samples, conducted under similar conditions, revealed higher concentrations of REEs in the tailings. Both coal samples had comparatively higher contents of light-group rare earth elements (LREEs) than heavy-group rare earth elements (HREEs). REE content trends for the power-plant products on an ash basis indicate that fly ash has slightly higher concentrations of both LREEs and HREEs than bottom ash. IntroductionRare earth elements (REEs), also known as rare earth metals, and their compounds are vital components in industrial, automotive, petrochemical, defense and medical applications. Dysprosium in combination with other elements is used in laser materials and nuclear control applications. Neodymium is present in magnets that are used in the manufacture of wind turbines and hybrid cars. Europium, terbium and yttrium are used in devices that have visual displays such as computer screens and laptops (Haxel, Hedrick and Greta, 2002; Bunzli, 2013). REEs pose fewer environmental problems of disposal and recycling than their conventional heavy metal counterparts (Haxel, Hedrick and Greta, 2002). They are key materials for radar systems, avionics, modern national defense and satellites (Cammarata and Sieradzki, 1994; Hedrick, 2010; Martin, 2010; Szumigala and Werdon, 2011; Cordier, 2011; Bunzli, 2013). REEs are often classified into light-group rare earth elements (LREEs) and heavy-group rare earth elements (HREEs). This classification is primarily based on the electronic configuration in the outermost shell. LREEs, ranging from lanthanum to gadolinium, have a single or no spinning electron in the outermost 4f shell while HREEs, ranging from terbium to lutetium, have paired electrons in the 4f shell. This difference in electronic configuration is responsible for the differences in physical and chemical properties of REEs."

Jan 1, 2017

By T. Gupta, T. Ghosh

"In recent years, the demand for Rare Earth Elements (REE) have grown rapidly due to increasing demand and global supply shortage. The supply deficit of these critical elements has encouraged the search for new sources of REEs, possibly Coal and Coal byproducts. Coals from certain parts of the world can be rich in REEs, and can approach a total concentration of 1000 ppm. Two Alaskan coal samples were investigated for the effect of size and density on the concentration of REEs on three selected size fractions. Flotation tests were conducted for finer fractions. Additionally Bottom ash and Fly Ash samples from a power plant have been examined for REE concentration. The results show that the upgrade potential for REEs on ash basis from whole coal basis ranges from 2:1 to 4:1 for Wishbone Hill and Healy coal samples respectively. Flotation of the finer fraction for both coal samples, conducted under similar conditions, reveal higher concentration of REE’s in the tailings. Both coal samples have a comparatively higher LREE content than HREE. Trends of REE content of the power plant products on ash basis revealed that Fly Ash has a slightly higher concentration of both LREE and HREE than Bottom Ash. Keywords: Rare Earth Elements, Coal, Coal Ash INTRODUCTION Rare Earth Elements (REEs) and their compounds are vital components in industrial, automotive, petrochemical, defense and medical applications. Dysprosium in combination with other elements is used in laser materials and nuclear control applications. Neodymium is present in magnets that are used in green power generation such as the manufacture of wind turbines and also in hybrid cars. Europium, Terbium and Yttrium are used for devices that have visual displays such as computer screens and laptops [1, 2]. REEs pose fewer environmental problems of disposal and recycling than conventional heavy metal counterparts [1]. Rare-earth metals are key ingredients for radar systems, avionics, modern national defense and satellites [2-8]. In the last 25 years China has been mining, processing and refining Rare Earth elements at affordable prices thus gaining a virtual monopoly in the market. The many fold rise of the prices of REE elements over the last few years and frequent disruptions in supply has forced various nations to invest in indigenous extraction of REEs by increasing production from previously productive sites and to expand the production from new alternate sources including coal and coal byproducts [9]. Coal and Coal beds have been found to be significantly enriched with certain critical metals and can be a potential source for both Light Rare Earth Elements (LREE) and Heavy Rare Earth Elements (HREE) [10]. Moreover, coals with high REE concentrations have been discovered in Pavlovka and Rakovka coal deposits in Russia, Appalachian deposits in USA, Sichuan Basin deposits in China and others across the globe [10-13]. A recent study from China looked at how different trace elements (including numerous REEs) partition in various size fractions of Antaibao coal from China. The finding indicates that the REEs, phosphorous, and thorium all have their high concentrations in the particle sizes 0.5 to 3 mm, and 6 to 25 mm. REEs are also often present in the form of phosphates such as monazite in coal [13, 14]. The objective of the study is to identify the concentration of REEs in Alaskan coals and to investigate the effect of density and size in the distribution of REEs in coal and coal byproducts."

Jan 1, 2016

By M. Ishaq, J. Rosami, J. Brune, E. Sidrow, C. Tsai, S. Slouka

Respirable rock dust poses serious long-term health effects to workers in mining and tunneling underground hard rock environments. When inhaled, respirable silica particles commonly found in quartz and other minerals will scar sensitive lung tissue and cause irreversible lung diseases. Characteristics such as concentration, type of mineral, particle size, and particle shape inhaled can harm workers to various extents. Therefore, this study characterizes rock dust particles less than 100µm in aerodynamic diameter that are released from cutting hard rock in the underground mining environment. In this study, laboratory full scale cutting tests on samples of potash rock were performed with radial picks to generate dust. Three stages of pick wear were tested: new, moderately worn, and severely worn. Comparisons between different stages of pick wear to dust concentration, size distribution, and particle shape characteristics are drawn from this study to start determining the scenarios when the released airborne dusts become potentially most hazardous for workers. Although further testing needs to be conducted to make viable conclusions, the moderately worn pick, or the pick with the most blunt tip, in these experiments are potentially the most dangerous. The blunt pick tip released the highest concentration of dust and generated particle shapes with the highest aspect ratio compared to the other two picks. The preliminary results of this study allow for the further development of optimum bit management and maintenance systems to control the exposure of respirable dust to mine workers.

Mar 2, 2022

By B. Akwasi Osei

The lack of metrics to assess clamshell formation dredgeability limits the ability of engineers to predict the dredgeability of compact material and increases the risks associated with clamshell selection. Research is needed to develop metrics for predicting clamshell dredgeability. The objective of this paper is to evaluate possible metrics to predict the dredgeability of compact aggregates by hydraulically actuated clamshell dredges. Data on cylinder pressures and displacements, motor current, bucket tilt and cycle time (CT) were collected from a dredge. Work done and motor energy, potential metrics, were computed and their suitability in predicting dredgeability evaluated. Data analysis shows that; there is no correlation between tilt angle and work done or motor energy; a low correlation between CT and work done, and a strong correlation between CT and motor energy. Work done is a better measure of formation dredgeability, than motor energy, as it shows lower variability. However, in difficult digging conditions, work done alone does not accurately predict dredgeability. This work shows that, it is feasible to use cylinder pressures and motor signals data to predict dredgeability.

Jan 1, 2010

By ERIK CHARRIER, HUGH MILLER, JOSEF BOURGEOIS

In this study, a unique excavation system was characterized, utilizing waterjet technology as the primary tool for material removal during rehabilitation of reinforced concrete and shotcrete structural liners. Through empiric testing, this research seeks to validate the hypothesis that waterjet removal of these support systems will result in less unintended damage than conventional removal methods. The intent is to develop a viable technology that will reduce the collateral damage caused to surrounding liners during excavation, improve the adhesion between shotcrete and the substrate for longer lasting ground support, and improve overall safety for workers in underground environments. An analysis on the fracture mechanisms and operating parameters of each method was completed. Instrumented shotcrete panels were physically tested and examined through visual inspection and ground penetrating radar (GPR) to compare substrate damage according to each testing method. After testing was completed, the data strongly indicates that waterjet cutting causes less collateral damage to the surrounding intact liner and substrate when compared to that of conventional impact hammers. This research is intended to provide a scientific basis for additional applied research in the rapid excavation and repair of shotcrete support systems.

Sep 23, 2021

By ERIK CHARRIER, HUGH MILLER, JOSEF BOURGEOIS

In this study, a unique excavation system was characterized using waterjet technology as the primary tool for material removal during rehabilitation of reinforced concrete and shotcrete structural liners. Through empirical testing, this research seeks to validate the hypothesis that waterjet removal of these support systems will result in less unintended damage than conventional removal methods. The intent is to develop a viable technology that will reduce the collateral damage caused to surrounding liners during excavation, improve the adhesion between shotcrete and the substrate for longer lasting ground support, and improve overall safety for workers in underground environments. An analysis on the fracture mechanisms and operating parameters of each method was completed. Instrumented shotcrete panels were physically tested and examined through visual inspection and ground penetrating radar (GPR) to compare substrate damage according to each testing method. After testing was completed, the data strongly indicate that waterjet cutting causes less collateral damage to the surrounding intact liner and substrate than conventional impact hammers. This research is intended to provide a scientific basis for additional applied research in the rapid excavation and repair of shotcrete support systems.