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By Y. Kurokawa, R. Kurosawa, I. Iwata, I. Fukuoka, N. Sugita

INTRODUCTION The Ningyo-toge Mine is located in the western part of Honshu, about 800 km from Tokyo. Since the discovery of uranium ore deposit at Ningyo-toge in 1955, different kinds of mining and milling tests have been carried out. A new pilot plant of milling and UF6 conversion is also being under construction. Operations are scheduled to start by the end of this year. In 1979, the uranium enrichment pilot plant was constructed at Ningyo-toge and test operations have started. Thus, the Ningyo-toge area is assigned to undertake the Research and Development of the upstream of the nuclear fuel cycle in Japan. PNC has been strengthening its security measures more than ever. This paper will focus on the disposal of wasted material, especially on the disposal of heap leaching residue, in Japan. URANIUM ORE DEPOSITS The uranium of the Ningyo-toge Mine is characterized genetically by epigenetic sedimentary type deposits. They occur in the host rock of Neogene tertiary fluviatile conglomerates and sandstones which unconformably overlies the Mesozoic-Palaeogene granitic basement covered with lucustrine deposits and volcanic ejecta. More than 12 deposits have been found over the area of approximately 160 km2, and distribution of the deposits are strongly controlled by the so-called channel structure, probably remnants of paleo-streams on the denudation surface of the underlying grantic basement. Each ore body has different shape and dimension respectively, but about 2-3 meters thickness with the average grade of 0.05-0.2% U308 is common feature of the ore bodies. The ore is soft and loose, and it is composed of common rock forming minerals of allogenic origin and their altered products. The chemical composition of the ore depends on the constituents of the country rocks or the pebbles. A primary mineral, ningyoite and secondary mineral, autunite are major ore minerals, although three primary tetravalent minerals and thirteen secondary hexavalent minerals have also been detected. MINING EXPERIMENT Since 1959, various types of underground mining tests have been carried out at Ningyo-toge Mine. The room and pillar method was safe and simple, although the uranium ore recovery was below 70%. After experiment of the retreating long-wall method and slicing mining method, it was found that the modified long wall method was the most appropriate for the underground mining of the Ningyo-toge uranium deposits. This method was completed successfully to increase efficiency up to 2 or 3 times, as compared to conventional methods. MILLING EXPERIMENT In 1964, a small test mill was constructed at Ningyo-toge, and a milling experiment using the Ningyo-toge uranium ore was started. Re-modelling of equipments and improvement of the process lead to the establishment of the technique of the so-called wet process, and produce UF4 directly from the ore. The flow diagram is shown in Fig. 1.

Jan 1, 1981

By D. A. Shock

Utilizing the technology developed for oil well stimulation by hydrofracing, a disposal system which permanently fixes the waste has been proven. Large quantities of radioactive waste can be processed by a single well system making this method an attractive method for permanent radioactive waste disposal. The system depends on locating a relatively thick formation of impermeable, but easily fracturable rock such as a shale, creating a horizontal fracture, pumping the waste into the fracture in a form which will subsequently solidify and seal the fracture from the well system. The paper presents the theoretical considerations from creating and extending horizontal fractures and how these considerations were used in designing a waste disposal system which is now operating.

Jan 1, 1964

By Devraj Sharma

This paper presents technical issues in the design and management of a retorted oil shale disposal site. Major physical and geochemical mechanisms which affect the disposal are: heat transport, moisture migration, chemical species transport, auto-ignition, and mechanical behavior alterations of the retorted oil shale pile. The interaction of these mechanisms and their relative magnitude will affect the environmental behavior of the pile. The paper discusses the coupling between the mechanisms, presents a framework to quantify the processes by laboratory and field measurements, and in addition discusses the use of mathematical models to provide quantitative predictions.

Jan 1, 1981

By Paul D. Bybee

The Freeport Sulphur Company operates four sulphur mines in the coastal marsh area-03 South Louisiana. Employing the Frasch process of mining, approximately 13-million gallons of water per day is heated to a mining temperature of 325°F and is injected into the sulphur bearing formations of the four mines. A volume of cold waste water, roughly equal to the Input, is removed from the formations and presents a disposal problem. Two additional mines are currently being developed and will increase the disposal volume by an additional 5-million gallons per day. Although these properties are in a relatively small area, geographically speaking, as shown in Figure 1, they each represent a separate disposal problem with the treatment methods designed for the individual mine.

Jan 1, 1959

By Robert M. Matyas, P. E. Sperry, Robert J. Smith, A. A. Mathews

INTRODUCTION The first Dispute Review Board (DRB) was utilized on a tunnel project 20 years ago. Increasingly utilized on a wide range of construction projects, DRB's are becoming the norm on tunnel and underground projects. This paper summarizes the growth in this usage, uses observations and experience to establish that barriers to the utilization of DRB's are more perceived than real and that many arguments against the DRB concept are not valid, and notes some of the salient elements that should be considered in practice to optimize DRB effectiveness. The purpose of the paper is to provide an annotated checklist for current and prospective users. The basic concept, structure, and operation of DRB's are described elsewhere and will not be repeated here (ASCE, 1991). DISPUTE REVIEW BOARD USAGE A compilation of Dispute Review Board usage for tunnel and underground projects to January 1994 indicated use on 63 contracts with a cumulative construction value of $3.8 billion and a total of 60 disputes settled. As of that same date, DRB's were planned for another 63 contracts with an estimated construction value of $4.7 billion. (A listing of these 126 projects is available from the authors.) This success and popularity have spread to other civil projects as well as process and building construction. The increase in DRB usage has been exponential. See Figure 1.

Jan 1, 1995

By James F. Holzbach

Although Disputes Review Boards have been used for some time, they had not received wide publicity at the time Monroe County first used one. Public owners frequently resist adopting new contracting practices. This paper discusses an owner's experience with Dispute Review Boards, from learning about them to their use on two (2) projects. The experiences of potential and actual contractor claims are compared to a claim on an earlier contract and the ensuing litigation. Suggestions for possible use for Owner-Engineer disputes and recommendations for use are provided.

Jan 1, 1995

By O. D. Christensen

The Carlin Trend is a 60 km (38 mi) long northwest alignment of epithermal, sediment-hosted, disseminated gold deposits. Collectively, these orebodies contained more than 620 t (20 million troy ounces) of gold. The Carlin deposit, located near the center of the Trend, has become the "type" deposit of this class. There are, however, significant differences between the individual deposits. Six subdistricts can be distinguished, based upon geographic, structural, lithologic, alteration, mineralization style, and geochemical characteristics. They are, from northwest to southeast, the Bootstrap, Bluestar-Goldstrike, Lynn, Maggie Creek, Rain and Bullion (Railroad) subdistricts. Regional Geologic Setting The Carlin District is located centrally within the Great Basin Geologic Province. Host rocks for the deposits include sedimentary units that range in age from Ordovician to Mississippian, as well as a Jurassic-Cretaceous granodiorite stock. During the Early Paleozoic, the area that is now Nevada lay along the western margin of the North American continent. A westward-thickening wedge of sedimentary units was deposited offshore in a eugeoclinal basin; these vary from continental shelf carbonates toward the east to fine-grained siliceous clastic and cherty units to the west. Tectonic activity associated with the Antler Orogeny in Late Devonian to Early Mississippian time resulted in the eugeoclinal Western Assemblage rocks being thrust as much as 140 km (90 mi) eastward over time-equivalent transitional to miogeoclinal Eastern Assemblage rocks along the Roberts Mountains Thrust fault system. The leading edge of the Roberts Mountains Thrust plate formed the emergent Antler highland from which siliceous clastic sediment, eroded from the overriding eugeoclinal rocks, was shed eastward into the adjacent foreland basin. Erosional products derived from the overthrust plate are termed the Overlap Assemblage.

Jan 1, 1987

By P. Verhoeven, G. Hefter, P. M. May

The dissociation (ionisation) constant of hydrogen cyanide, pKa(HCN), has been measured by high precision glass electrode potentiometric titrations in saline solutions containing up to 5 mol/L sodium chloride. The dissociation constant of water that is necessary for the calculation of pKa(HCN) has also been measured. In saline solution, and in contrast to literature values, pKa(HCN) changes considerably at both high and low ionic strengths as a result of changes in activity coefficients. In addition an equation is presented, using literature data, that describes the variation of pKa(HCN) with temperature up to 150°C. The significance of the changes in pKa(HCN) for optimising the pH of alkaline cyanide gold recovery streams is briefly discussed.

Jan 1, 1991

By Jian Liu

The dissolubility of a natural sphalerite (ZnS) in the entire pH range was theoretically calculated, and its practical dissolution in an aqueous solution at different pH values in an inert environment, together with its surface properties after dissolution, was fully investigated. The results of the investigation indicate that the total concentration of Zn (CZnT) decreases significantly with the increase of pH value, while the pH value is set below 8; however, it reverses when the pH value reaches 8. Such a tendency is similar to that of the theoretical calculations, although the experimental CZnT were much higher than those of the theoretical calculations. The X-ray photoelectron spectroscopy (XPS) of the sphalerite surface after its dissolution under alkaline solution shows that a polysulfide (Sn 2-) surface layer with a binding energy (BE) value of 162.96-163.25 eV is present on the surface, and the percentage of Sn 2- increases significantly with an increase in pH value; the undissolved and dissolved sphalerites under the acidic solution have a negligible difference in S2p peaks. The surface S/Zn ratio of all dissolved sphalerites shows a marked Zn enrichment and S deficiency. An atomic force microscope (AFM) view of the sphalerite surface, after its dissolution under the alkaline solution at a pH of 12, shows that the surface is significantly different in morphology from that of the undissolved one.

May 1, 2012

By K. N. Han

The dissolution kinetics of cobalt in iodine/ iodide solutions were investigated using a rotating-disc technique. Variables studied included temperature, rotating speed, concentration of lixiviants and the pH of the solution. The overall dissolution reaction appeared to be limited by the mass transfer of tri-iodide through the diffusion boundary layer with an Arrhenius activation energy of <16.2 kJ/mol (4 kcal/mol) over the temperature range of 2 to 42ºC. The pH of the solution had little effect, as long as the pH of the solution was <8. However, when the pH of the solution became >8, the dissolution rate decreased dramatically, due to passivation. The rate of dissolution was in good agreement with the dissolution model developed by the authors earlier.

Jan 1, 1995

By K. N. Han, K. Peri, Y. Guan

The leaching behavior of gold in ammonical solutions with iodine as an oxidant was investigated using cyclic voltammogram and Tafel polarization. The majority of the experiments were carried out at 75°C, and the results were compared with consideraton given to the equilibrium of the iodine-ammonia system. The distribution of nine iodide-containing species at various pH values in the absence and presence of ammonia were considered at three different temperatures. It was found that, with the introduction of ammonia into the system, the concentration of iodide (I-), iodine (I2) and triiodide (I3-) is increased substantially, which in turn helps the rate of gold dissolution. The apparent activation energy was found to be about 46 kJ/mole, indicating a chemical-controlled mechanism.

Jan 1, 2002

By K. Peri

The leaching behavior of gold in ammonical solutions with iodine as an oxidant has been investigated using cyclic voltammogram and Tafel polarization. The majority of experiments was carried out at 75°C and the results were compared with the equilibrium consideration on the iodine-ammonia system. The distribution of nine iodide containing species at various pH values in the absence and presence of ammonia was considered at three different temperatures. It was found that by introduction of ammonia into the system, the concentration of iodide (r), iodine (12) and triiodide (13&apos;) is increased substantially which in turn helps the rate of dissolution of gold. The apparent activation energy was found to be about 46 kJ/mole, indicating a chemical controlled mechanism.

Jan 1, 1999

By K. N. Han, N. S. Kim, H. Yoon, J. S. Sohn

The leaching behavior of silver and silver oxides in ammonical solutions has been studied. The current study is concerned with an effective recovery of silver from secondary sources such as spent silver batteries. Silver associated with these batteries appears in various forms including metallic silver, argentous oxide, Ag2O and argentic oxide, AgO. The leaching behavior of metallic silver in ammoniacal solution has been studied using an electrochemical mehtod. Oxidants used in this study include hyperchlorite, hydrogen peroxide, bromine and iodine. Results on cyclic polarization and Tafel plots on the silver anode in ammoniacal solutions are presented and the results are discussed. The dissolution rate of metallic silver in ammoniacal solutions is also compared with those of silver oxides.

Jan 1, 2002

By K. N. Han

The kinetics of gold dissolution in iodide solutions with oxygen in an autoclave was investigated. The leaching process was described by a gas-liquid-solid heterogeneous reaction. The effects of stirring speed, temperature, oxygen partial pressure and lixiviant, concentrations on the overall leaching rate was investigated. It was found that the dissolution of gold could be represented by a heterogeneous chemical reaction. Under the conditions studied, the apparent activation energy ranged from 34.7 to 54.3 kJ/mol. Experimental findings were in good agreement with the kinetic model proposed.

Jan 1, 1998

By Mustapha A. Raji, Alafara A. Baba, Christianah O. Adeyemi, Aishat Y. Abdulkareem, Rafiu B. Bale, Malay K. Ghosh

The increasing demand for pure aluminum and aluminum compounds of industrial quality from kaolinite ore cannot be overemphasized. Nigeria is one of the African countries endowed with abundant solid mineral resources that have not been sufficiently exploited to assist its indigenous industries. A wide array of applications of pure aluminum and its compounds are available, such as paper filling, refractories, adsorbent, catalysis, and paint additives. In this study, the upgrading of a Nigerian biotite-rich kaolinite ore by a hydrometallurgical route was investigated in oxalic acid media. During leaching studies, the effects of parameters including reaction temperature, lixiviant concentration and particle size on the extent of ore dissolution were examined. At optimal conditions (1.0 mol/L C2H2O4, 75 °C), 92.0% of the initial 10 g/L ore was reacted within 120 min. The dissolution curves from the shrinking core model were analyzed and found to conform to the assumption of surface diffusion reaction, and the calculated activation energy of 33.2 kJ/mol supported the proposed model. The unreacted product (~8.0%) analyzed by XRD was found to contain siliceous impurities and could serve as a valuable by-product for certain industries.

By Mustapha A. Raji, Alafara A. Baba, Christianah O. Adeyemi, Aishat Y. Abdulkareem, Rafiu B. Bale, Malay K. Ghosh

The increasing demand for pure aluminum and aluminum compounds of industrial quality from kaolinite ore cannot be overemphasized. Nigeria is one of the African countries endowed with abundant solid mineral resources that have not been sufficiently exploited to assist its indigenous industries. A wide array of applications of pure aluminum and its compounds are available, such as paper filling, refractories, adsorbent, catalysis, and paint additives. In this study, the upgrading of a Nigerian biotite-rich kaolinite ore by a hydrometallurgical route was investigated in oxalic acid media. During leaching studies, the effects of parameters including reaction temperature, lixiviant concentration and particle size on the extent of ore dissolution were examined. At optimal conditions (1.0 mol/L C2H2O4, 75 °C), 92.0% of the initial 10 g/L ore was reacted within 120 min. The dissolution curves from the shrinking core model were analyzed and found to conform to the assumption of surface diffusion reaction, and the calculated activation energy of 33.2 kJ/mol supported the proposed model. The unreacted product (~8.0%) analyzed by XRD was found to contain siliceous impurities and could serve as a valuable by-product for certain industries.

By H. Y. Yang, L. L. Tong

For gold recovery, a Chinese refractory, high-sulfur gold concentrate was subjected to biooxidation with high pulp density in a single stirred-tank reactor. The flotation concentrate contained 36.9 percent sulfur (S) and 33.9 percent iron (Fe). Different experimental regimes for biooxidation were applied. With a mixed culture and by controlling the amount of addition of the gold ores and the pH of the biooxidation system, maximum iron oxidation of 82.6 percent and sulfur oxidation of 79.3 percent were achieved. The experimental results indicate that the pH control was beneficial to the biooxidation of this concentrate. Approximately 28.4 percent of elemental sulfur (S8) was found in the oxidizing slags. Two dissolution mechanisms of elemental sulfur are proposed: (1) FeS2 → S80 → S2O32− → SO42− and (2) FeS2 → S80 → SO42−. The high pH had a positive effect on the reduction of the S8. The results of thermodynamic analysis indicate that as an oxidant the dissolved oxygen can effectively reduce the Gibbs free energy of the pyrite oxidation process and, compared with the reaction of ferric iron as the single oxidant, the oxidation of pyrite is easier. The efficiency of the gold recovery was related to the iron oxidation as well as the sulfur oxidation. Gold and silver recoveries of 92.4 percent and 66.4 percent, respectively, were achieved.

By Mandira Madhuchhanda, N. B. Devi, P. C. Rath, R. K. Paramguru, K. Srinivasa Rao

An experimental investigation of the dissolution of three base-metal sulfide minerals, namely, CuFeS2, ZnS and PbS, in hydrochloric acid medium in the presence of manganese dioxide is reported. Polarization measurements and leaching studies were employed in the study. Dissolution occurred in the following three ways: by the cyclic action of the Fe3+/Fe2+ redox couple, by galvanic interaction between Mn02 and the sulfide minerals, and because of chlorine evolution from the system. The later two routes were found more effective at higher HCI levels. PbS appeared to be oxidized easily, whereas CuFeS2 was the most difficult to dissolve. ZnS dissolution fell in between PbS and CuFeS2.

Jan 1, 2002

By VÍCTOR VÁZQUEZ-VÁZQUEZ, GUILLERMO TIBURCIO-MUNIVE, María M. Salazar-Campoy, JESÚS L. VALENZUELA-GARCÍA, OFELIA HERNÁNDEZ-NEGRETE

The present study examined a process for precious metal recovery (silver and gold) from difficult minerals which exhibit refractory characteristics to cyanidation and ammonium thiosulfate leaching (low extraction and high consumption of leaching agent). It is well known that mangano-argentiferous minerals are mainly composed of manganese, silver, gold, and iron. In this research, a mineral sample from Monte del Favor mine, located in Hostotipaquillo, Jalisco, Mexico, was physically and chemically characterized by X-ray powder diffraction (XRPD), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), fire assay, and atomic absorption spectroscopy (AAS). Two-stage leaching was carried out: first to eliminate manganese from the sample using sodium sulfite (Na2SO3) as a reductive reagent and sulfuric acid (H2SO4) and a second stage to dissolve silver and gold with sodium hypochlorite (NaClO) and hydrochloric acid (HCl); the results show extraction around 96% for Mn and 98.73% and 83%of Ag and Au, respectively. The usefulness of high acidity and Na2SO3 to obtain good results in Mn and Ag leaching is discussed along with the roles that HCl and NaClO play in the dissolution of Ag and Au values.

Apr 15, 2020

By VÍCTOR VÁZQUEZ-VÁZQUEZ, GUILLERMO TIBURCIO-MUNIVE, María M. Salazar-Campoy, JESÚS L. VALENZUELA-GARCÍA, OFELIA HERNÁNDEZ-NEGRETE

This study examines a process for the recovery of precious metals from difficult minerals that exhibit refractory characteristics to cyanidation: low extraction of metals and high consumption of leaching reagent. A mineral sample from Monte del Favor Mine, located in Hostotipaquillo, Jalisco, Mexico, was physically and chemically characterized by X-ray powder diffraction (XRPD), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), fire assay and atomic absorption spectroscopy (AAS). Two stages of leaching were carried out, first to eliminate manganese from the sample using sodium sulfite (Na2SO3) as a reductive reagent along with sulfuric acid (H2SO4), and second to dissolve gold and silver with hydrochloric acid (HCl) and sodium hypochlorite (NaClO). The results show extractions of around 96 percent for manganese (Mn), 98.73 percent for silver (Ag) and 83 percent for gold (Au). The usefulness of high acidity and Na2SO3 to obtain better results in Mn and Ag leaching are discussed along with the roles that HCl and NaClO play in Ag and Au dissolution values.