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By Alan G. Fricker

Cyprus Gold NZ Ltd will be recovering residual free cyanide in barren gold pulp by air stripping. Laboratory investigations by DSIR have indicated additional advantages by recovering the cyanide from pregnant pulp. These are a lower leach pH, a greater cyanide recovery and less carbon consumption. They have a net economic advantage of $1.20/tonne over recovery from barren pulp. The realisation of these advantages is dependent on three crucial technical aspects -optimum pH for dissolution, the absolute loss of cyanide and the stability of the aurocyanide ion. The laboratory investigations described herein address these aspects. Earlier work had indicated that the rate of dissolution of freely revolving gold discs at constant cyanide ion concentration increased with decreasing pH from 11 to 8. Attempts to repeat the work in a more controlled manner by measuring the corrosion potential and current density have, to date, not been reproducible, but do not contradict the earlier observations. Cyanide recoveries and balances were obtained on leaches at pH 10.5 and 9 at the same cyanide ion concentration -the lower pH requiring three times as much total cyanide. Unaccounted-for losses, unfortunately, exceed the accounted-for losses, making interpretation of the balances difficult. Nevertheless, it appears that the additional amount of cyanide at the lower pH of 9 may not be fully recoverable. It may not, however, prove necessary in practice to use more cyanide at a lower pH. Both the gold and silver cyanide complexes remain available for carbon adsorption, as do mercury, copper and iron. Zinc, and probably cadmium, nickel and lead, may precipitate during stripping, which is an environmental advantage.

Jan 1, 1991

By H. N. McLeod, M. J. Thom

The use of cyanide in gold mining requires the careful handling and storage of cyanide rich tailings. Cyanide in groundwater can frequently be both persistent and mobile, so that tailings basins need to be designed to limit and collect seepage. Assessment of the potential environmental impact requires an understanding of the hydrogeologic regime, both before, during and after mining. Groundwater monitoring wells provide a basis for monitoring tailings pond behaviour and for assessing the impact of mitigative measures to reduce or control seepage. A case example of Cheni Gold Mines Lawyers Project in Canada is presented to illustrate the use of groundwater monitoring to determine the amount of cyanide degradation and attenuation between the tailings pond and the receiving environment.

Jan 1, 1991

By Des B. Bolton, Neil P. Boland

Typically, environmental work on mine sites in Northern Australia involves addressing an individual problem as it arises. However, individual mining companies are moving toward a more holistic approach to managing the interactions between the environment and the mining process and are thus pre-empting environmental problems. This paper presents a broad overview of this holistic approach and provides a few examples, drawn from our own experience, which illustrate some of the tangible benefits to be gained from Environmental Planning.

Jan 1, 1991

By Jacob D. Baker

Sulphur dioxide is a versatile gas which has many uses throughout Pulp & Paper, Chemical, specialty Chemical, Mining and other industries. During recent years, S0 2 consumption and distribution patterns have resulted in renewed interests for liquid S0 2 and on site gaseous S02 manufacturing facilities. one relatively new use for S0 2 in the Mining Industry is its use for cyanide detoxification. Our purpose in this paper is to describe the process steps, economics and general technical features of so 2 gas generation using a Jet Type sulphur Burning System.

Jan 1, 1991

By E. A. Devuyst, G. Robbins

A unique process for removing cyanide and base metal complexes from industrial waste streams was patented by G.J. Borberly et al. (1984). The process uses SO2 (liquid or gas, or solutions of sulfite salts, or from burning elemental sulfur), plus air that is dispersed in the effluent using a well agitated vessel. Acid produced in the oxidation reactions is neutralized with lime at a controlled pH generally in the range 7 to 10. The reaction requires the presence of soluble copper as a catalyst which can be supplemented by copper sulfate if necessary. The process can be applied to the detoxification of gold and silver mining waste streams, such as carbon-in-pulp (CIP) tailing pulps, barren solution bleeds, pond waters and heap leach rinse solutions and also to plating shops wastewaters. The SO.jAir process has substantial advantages over two of the main alternative methods of cyanide destruction, namely alkaline chlorination and hydrogen peroxide. Alkaline chlorination is highly penalized in terms of reagent consumption. Chlorine is a strong oxidant reacting with species other than cyanide present in the effluent such as thiocyanate and sulfides. Furthermore alkaline chlorination is an incomplete detoxification process. Iron cyanide is not removed and the potential for harmful by-products species exist. Consequently final effluents may be subject to additional treatment in order to comply with regulatory demands.

Jan 1, 1991

By Byron K. nelson, David Mathieson

Until quite recently concentration of free gold in gravity circuits ahead of froth flotation and/or chemical treatment was considered an uneconomical pursuit in many gold pi.ants in Australia. Over the past 10 yenrs since initial introduction of the Knelson Gold Concentrator, over 600 hnvc been surpl led world wide and they have been developed to the stage that Lhey can now be utilised in almost all instances where free gold appears in significant quantltles ln grinding circuits. They out perform and displace more conventional gravity sepnration equipment such as spirals, tables, sluices, jigs, drum separators etc.

Jan 1, 1991

By A. Bruynesteyn

Most ores and coals contain sulphide minerals such as pyrite, FeS2, the sulphur portion of which is a ready substrate for a variety of sulphur oxidizing bacteria. Although there are several bacteria capable of oxidizing sulphide minerals, the most often discussed culprit is Thiobacillus ferrooxidans.. Oxygen from the air slowly oxidizes pyrite into sulphuric acid, but T- ferrooxidans can increase this reaction rate several 100,000 times.

Jan 1, 1991

By Jim V. Rouse

The decision to hold parallel conferences dealing with hazardous waste and mining waste grew out of the conviction that there were advantages to having personnel serving the two groups talk to each other, as both groups develop cost-effective and environmentally-protective solutions to present and future waste-disposal problems. There has been a certain amount of "reinventing the wheel" which could have been avoided by a better dialog between the two groups. The intent of holding the two parallel conferences is to allow for networking, to minimize future needless redundant effort. The opening session panel speakers represent expertise from both industries; I feel honored to speak as one with a history of serving both groups as a specialist in the subsurface behavior of heavy metals.

Jan 1, 1991

By Stephen D. Hill, C. R. Ferguson, T. H. Jeffers, P. G. Bennett

The U.S. Bureau of Mines' Salt Lake City Research Center has developed porous polymeric beads containing immobilized non-living biological materials for extracting metal contaminants from waste waters. Immobilized biological materials include peat moss, algae, biological polymers, and other materials that demonstrate high affinities for heavy metals. The beads, designated as BIO-FIX beads, have distinct advantages over traditional methods of utilizing biological materials in that they have excellent handling characteristics and can be used in conventional processing equipment or low-maintenance systems. Toxic metals such as copper, cadmium, zinc, lead, and mercury are several of the many heavy metals effectively removed from mine waste waters using BIO-FIX beads, Continuous cyclic testing indicated that the beads continued to produce treated effluents which met National Drinking Water Standards (NOWS) after 150 loading-elution cycles. Adsorbed metals were removed from the beads using dilute mineral acids. In many cases, the extracted metals were further concentrated to enable processors to reclaim the metals, thus minimizing the generation of a hazardous sludge, Tests indicated that use of the beads in a low­maintenance system was particularly effective for treating remote acid mine drainage waters and small toxic seeps from hard-rock mining districts.

Jan 1, 1991

By N/A

finally, but not least, the staff of Vaal Reefs Chemical Laboratory for their assistance and patience with the introduction of a new technology,

Jan 1, 1991

By Kurt O'Bryan

WaterFlush Technology has recently been implemented at a gold milling operation in the United states. This new technology offers maximum comminution performance bene­fits over today's more common comminution methods. These benefits will be presented via the discussion of performance results from existing installations, and the proj­ected performance gains for circuits sched­uled to begin operation in late 1991.

Jan 1, 1991

By Chris Joyce, Peter Ryan, Graeme Mcllveen

This paper briefly summarizes regulatory procedures and government agency roles and jurisdictions in each Australian State and Territory. The role of the Commonwealth of Australia and selected current trends in environmental regulation are also discussed. While the Commonwealth has played an active role in regulating specific commodities or mines through its powers over export licences, international heritage agreements and the Territories, such cases have largely been a result of response to specific public issues. This may change; the Commonwealth has established the Resources Assessment Commission and is canvassing the establishment of an Environmental Protection Act, aimed at the standardization of environmental standards through the creation of an Environmental Protection Authority. While the States, the Northern Territory and the Commonwealth lwve nominally different resource planning, environmental project approval and operational regulatory authoritit:s, the fundamental principles hinge on mining lease, planning and pollution control approvals.

Jan 1, 1991

By R. L. Murray-Smith, M. E. A. Robertson, M. J. Prosser

The AZTEC is an automated instrument, for the non-destructive analysis of gold ore samples, which uses energy dispersive X-ray fluorescence (XRF), This is achieved by X­ray tube excitation of gold K X-rays. The first production instrument was commissioned at Vaal Reefs Chemical Laboratory (VRCL) in November 1987, followed by two second generation instruments in 1989. AZTECs have also been installed at Western Deep Levels and at Anglo American Research Laboratories (AARL). A further unit is being assembled at Ashanti mine, Ghana. At VRCL the AZTECs are used primarily for the evaluation of mine (stope) samples. Each of the production instruments can routinely analyse 650-700 samples per day, with the aid of a robotic sample transfer system. Various techniques have been evaluated for increasing sample throughput. For example, higher value samples can be counted for a shorter time to obtain the necessary relative precision.

Jan 1, 1991

By Martin F. Grier, Nicholas H. Kempton

The Mt. Todd Gold Project in the Northern Territory is a joint venture between Billiton Australia Gold Pty. Limited, a wholly owned subsidiary of Shell Australia Limited, and Zapopan NL. As manager of the project, Billiton is guided by Shell's corporate policy that foremost consideration be given to protection of the environment from unacceptable impact and that sound environmental programmes are to be implemented effectively at all company operations. This policy on Health, Safety and the Environment helps operating companies in addressing environmental matters in a systematic way and gives guidance on the practical implementation of a range of controls to protect the environment. Most importantly, it seeks to do this in a co­ operative rather than adversarial manner. In developing the Mt. Todd Gold mine the joint venturers' environmental objectives have therefore been to plan and operate the project consistent with the highest industry standards and community expectations and in accordance with all Northern Territory government requirements. A development strategy has been designed which minimises environmental effects. Planning priorities have focused on the successful co-existence of the mine with an endangered species of bird, the Gouldian Finch, which breeds in the area; the mitigation of impacts on surface and ground. water qualities; and the protection of significant Aboriginal cultural and archaeological sites.

Jan 1, 1991

By J. W. C. Wong, T. A. Songberg, S. D. Miller, J. J. Jeffery

Natural degradation of cyanide has been widely used by the gold mining industry for removal of CN from cyanidation processing wastes. However, little documented study has addressed the decay and fate of cyanide within residue storage ponds. 'fhis paper describes a study on the cyanide behaviour in a residue storage pond at the Boddington Gold Mine in Western Australia. Depth profile samples were collected from the active residue storage to determine the distribution of CN forms and complexing metals throughout the settled residue.

Jan 1, 1991

By Hans von Michaelis

It is appropriate that this opening session of HAZPAC '91 and Randol Gold Forum CAIRNS '91 should address the question of what the two industries can learn from each other. The panel is made up of members with experience in both industry. Several are experts on managing both hazardous waste and the mine/mineral processing environment. There is a marked difference in the regulatory needs with respect to treating and disposing of mining and mineral processing wastes, and "hazardous" or industrial waste materials. The topic of this paper is on the things that the two industries have in common: Many of the processes and technologies that are being used or are currently being developed for treatment of hazardous waste are the same or similar to the processes that have been used for decades or k,nger in the mineral processing industry. Hazardous waste treatment and remediation of contaminated solid and/or groundwater is a relatively new industry. Many of the practitioners in this new industry are relatively inexperienced in most of the "new" technologies that are being applied or developed.

Jan 1, 1991

By P. Richardson, B. Sceresini

The carbon-in-pulp and the carbon-in leach process for the recovery of gold and silver from cyanide leaching of ores is now widespread in the precious metals mining industry. However the presence of various base metals can have a detrimental effect on the efficiency and the economics of the process due to high cyani,:••? consumption and a reduction in leaching and adsorption rates resulting in poor recovery of the precious metals. Furthermore the presence of fast leaching and adsorbing metals such as copper can significantly reduce carbon loading capacity for the precious metais thereby necessitating a higher carbon inventory, more frequent stripping and poor bullion quality resulting in higher production costs. This paper describes the development and application of a process for the recovery of copper and and the recovery and re-use of the associated cyanide from the leach circuit at the Mt. Gibson Gold Project in the Murchison Goldfield in Western Australia. The process provides a means to counter-act the detrimental effects of the copper which occurs in the ore as various oxide and sulphide minerals including an extremely fine chalcopyrite powder. It has the added benefit of recovering the base metals in this instance copper, in a saleable form. The process is subject to a patent application by Reynolds Australia Metals, Forsayth N.L. and the author.

Jan 1, 1991

By D. K. Gibson, A. I. M. Ritchie

The phenomenon of acid drainage is likely to occur whenever pyritic rock is broken up, permitting access of air and water. The basic chemistry of the oxidation process is described by the equations below:- FeS 2 +1120 + 7 02 ➔FeS04 +112S04 +1440k.J This reaction proceeds rather slowly, although believed to be bacterially catalysed to some extent. Once sufficient ferrous ions and acidity have been established the following two reactions take over, yielding the same net result but at a much greater rate. First, ferrous ions are oxidised to ferric; this is an extremely slow reaction unless bacterially catalysed.

Jan 1, 1991

By J. M. Carter, Rodney H. Sergent, L. E. Kun, J. T. Pressly

Underground mine service water in South Africa is used for dust suppression and cooling the environment as well as the pneumatic rock drills. Although the chilled water is not intended for potable use, it is often used as drinking water by mining personnel. Furthermore, droplets sprayed are liable to be inhaled. The water is recirculated on a continuous basis and is a potential source of infection by intestinal microorganisms or water-borne diseases such as cholera or typhoid. In order to protect the health of the underground workforce it is customary to disinfect the chilled service water, The bacteriological quality of the water is monitored by enumerating total aerobic bacteria (TAB), total coliforms (C C) and Escherichia coli (E Coli). E coli is an indicator of human faeca_l __ - -- contamination, The bacteriological standard specified by the Anglo American Corporation for mine service water is less than 3000 TA B per 100ml, less than 2 CC per ml and the total absence of E Coli. There are several disinfecting agents available for use. Among these are UV irradiation, ozone, chlorine dioxide and compounds that produce hypobromous and hypochlorous acids. Historically, the methods of treatment have been chlorine based and include the use of gaseous chlorine (surface installations only), calcium hypochlorite granules or tablets, chlorinated cyanurate tablets, sodium hypochlorite solutions and hypochlorite produced by electrolysis.

Jan 1, 1991

By David Martin Menne

Introduction

Jan 1, 1991