Search Documents

By Larry A. Lien

Membrane technology has been available for about 30 years, but has been used very sparingly within the general mining industry. However, recent developments in polymer chemistry, spiral wound element construction, pretreatment equipment and element cleaning techniques have improved the reliability and robustness of membrane based systems. These improvements have expanded the potential to use this "new" technology to enhance critical recoveries of gold and silver in heap leaching operations or in the extraction circuit. Another opportunity for the mining industry will be to use membrane technology in new processes like controlling organic acids or ammonium thiosul­fate to enhance gold and silver extraction during leaching opera­tions. Finally, the most common use for membrane technology is for the control of mining water balance and acid mine drainage issues. Polymeric membranes, specifically thin-film composites, have been developed that will purify, fractionate or concentrate gold or silver. Recent applications have been developed for spi­ral wound modules that operate across the pH spectrum from 0 to 14. Systems using membranes have been constructed that operated on feed streams from 200° C to 3000 centipoise. Most recently, membrane based systems have been pilot tested suc­cessfully to purify solvents, like LIX. Opportunities exist to apply membrane technology to concen­trate gold and silver cyanide solutions with thin-film composite Reverse Osmosis (RO) membranes at elevated pH values above 10. Incorporating membrane technology could allow one to increase production without incurring additional expansion of the gold extraction side of the process. Furthermore, free cyanide is not rejected by the Reverse Osmosis membranes, but other inorganic salts are rejected 98+%, thereby, allowing an essentially ion free, except for the free cyanide, to be recirculat­ed back to the heap leach operation for enhanced extraction.

Jan 1, 1998

By M. Gordon, J. M. Tranquilla

Microwave power, used in conjunction with properly designed applicators, is an efficient and practical energy source for pre treating a wide range of mineral ores and concentrates. Novel processes which take advantage of the unique properties of rapid microwave excitation present many distinct advantages over other pretreatment methods. These include dramatically reduced costs and elimination of all or most of the toxic by-products. A capital and operating cost analysis is presented of EMR's microwave process for treatment of refractory gold ores and con­centrates based on the company's experience using both small and large scale pilot plants. Comparisons are presented between the microwave process and roasters, autoclaves and bio-oxidation.

Jan 1, 1998

By David Green

Outokumpu introduced Flash Flotation in the early l 980's for the recovery of floatable material from grinding circuits. The devel­opment came as a result of surveys made in the company's own concentrators, initiated to find ways of improving recoveries with increasingly complex and lower grade feeds. Hydrocyclones make a separation on the basis of particle size and mass, resulting in the "over collection" of fine grained, high S.G. particles. Minerals such as pentlandite, galena and gold are easily caught in the circulating load around the mill until they are overground and rendered more difficult to collect. In the case of downstream flotation this may simply involve a reduction in the rate coefficient due to the finer sizes or, as is commonly experienced in gold operations, the mate­rial is slimed and coated onto non-floating gangue and is eventual­ly lost to tails. At the time of Outokumpu's plant surveys, it was a relatively common practice, particularly in Pb operations, to have a flotation section fed directly from the secondaiy mill discharge. This is called unit flotation and certainly provided an improvement but very high wear rates and frequent sanding out of the cells was com­mon. The development of the SkimAir® Flash Flotation cell by Outokumpu provided a subtle but quite dramatic departure from the unit cell approach. Now it was possible to feed cyclone under­flow into a special purpose-built flotation machine and recover a final grade concentrate from the grinding circuit (see Figure I). The cell was designed to handle the coarse circulating load, per­mitting the coarsest fractions to be short-circuited back to the mill and retain the floatable sizes for a nominal time of 30 seconds to several minutes. The short retention time was possible largely due to the relatively clean content of the cyclone underflow stream. This means that the fine gangue is not present except in small quan­tities and most of the fine to mid-size paiiicles are higher S.G. and more likely represent valuable mineral. This condition provides for very high rate coefficients. Typical operations would recover 40-60% of the valuable mineral in this fashion and improvements in recovery were typically from 2-5% for sulphide minerals to the 5-20% range for gold and silver.

Jan 1, 1998

By Ki Chun

Optimizing ore processing requires a thorough understanding of not only the process itself but the economic constraints which influence business decisions. No single modeling technique is able to model all the different processes running in today's mines. The solution then is to use a number of different model­ing techniques, each competing with the others to best correlate the data. Among these modeling techniques are: Neural Networks, Genetic Algorithms, Fuzzy Logic, Crisp Logic, Statistics, First Principal Models, and System Identification models. Once a model has captured the behavior of the process, a numerical optimization determines the optimal operating point and set point parameters. A single step is then taken in the direc­tion of the optimal location by changing all the process parame­ters to the setting recommended by the optimization system. As the process begins to re-stabilize, the models are updated, the new optimal determined and another step is taken in the direction of the optimum. Through the use of multiple competing models integrated into a numerical optimization the process can achieve the optimal running condition even if the ambient conditions fluctuate dynamically.

Jan 1, 1998

By Norman Haber

The Haber Gold Process (HGP) is a proprietary. hydrometallurgical extraction methodology that was developed in 1983-1984 by Norman Haber and Dr. John Lee of Haber, Inc., a small public company in Towaco, New Jersey specializing in hydrochemical process development for precious metals. It was pilot tested repeatedly in 1985 at our pilot plant in Tombstone, Arizona, with different types of gold bearing mineralization. Both Pincock, Allen and Holt (USA), and PA Technology (Australia) were involved with some of these pilot tests. The ores tested included easily cyanide-extractable oxide type gold ore from Australia, marginal heap-leach type ore from Cripple Creek, USA, and a hematite bearing ore from California. In all cases, extraction time was 6 hours or less yielding 90-99% recoveries of assayed gold values. The HGP operates as a lixivient which parts the gold from the rock matrix, yielding gold in solution in a fully recoverable form. Both precipitation methods, such as zinc participation or Carbon in Leach systems ( or Carbon in Pulp) have been shown to be feasible with this technology for the recovery of gold from the pregnant solution. Both batch vat leaching as well as continuous processing are realistic for use with the HGP. It has also been considered that the HGP might also benefit heap leaching due to several advantageous factors over cyanide. One such consideration is that the HGP can operate effectively with acidic ore types. The use of cyanide with such ores often requires attention to pH and neutralization with lime. This tends to reduce and even clog the permeability of the leach bed.

Jan 1, 1998

By Robert C. Dunne

Nearly one third of Australia's total gold product is produced in the Kambaloa - Kalgoorlie - Leonora Goldfields. There are presently some 25 gold mines in the area with the possibility of another six plants being constructed in the next year. Details of the gold extraction techniques used on these mines will be discussed and certain innovative technologies and problem areas will be highlighted.

Jan 1, 1998

By Tan Xiang-Kun, Liu Ming-dong, Yao Dun-Pu

Since the 1980s, heap leaching of gold and silver ores has been developing rapidly and experienced widespread use in China because of its lower capital and operating costs, less time consumed in construction and specific applicability to small-to-medium scale mining operations and low grade ores. Ores treated include ordinary oxidized ores, refractory sulfide ores and even those containing deleterious elements (such as arsenic or antimony) and/or carbonaceous substances. In addition to chemical leaching agents, some micro-organisms (e.g. T-ferrooxidians and T-thiooxixians) and their biochemistry mechanism have been equally emphasized. To overcome the adverse effect caused by excessive content of fines and slimes, research and pilot experiments of agglomeration-heap leaching are currently underway at two gold mines in South China and their encouraging preliminary achievements will be briefly described as illustrations in this paper. It could be expected that heap leaching of gold and silver ores holds promise and will play an increasingly important role in China's gold industry.

Jan 1, 1998

By Daniel W. Kappes

Until recently, the general expectation among mining compa­nies and financial analysts has been that the price of gold would remain on a generally upward slope. The recent drop in the price of gold has caused many people to re-think the issue. Of course, the price of gold is singularly difficult to predict, so it is difficult to tell which concept is correct. In the present financial situation, however, many junior gold companies are faced with the reality that money is hard to raise, and many senior gold companies find that they are facing a period of corporate losses even though they own solidly producing mines, As engineering consultants, Kappes, Cassiday has recently received several requests to review conventional milling projects to see if heap leaching is a more viable option. In regard to straight financial criteria such as return on investment and net present value, the question is usually fairly easy to answer. However, corporate decisions must often be based on less definable criteria. For instance, new stock issues tend to be more successful if they are larger, which tends to favor milling operations over heap leaches. The corporate issues are often subjective and difficult to generalize about, so I will con­centrate in this paper on a few financial concepts.

Jan 1, 1998

By David C. Sanders, Rodney H. Sergent, Victor C. Storhok, Batric Pesic

In the past, considerable work has been done on the applica­bility of bromine chemistry in the extractive metallurgy of gold. While the research in this area spanned from the understanding of fundamental dissolution chemistry to the demonstration on a pilot plant scale, no work was done on the fate of discarded leach residues with respect to the stability of accompanied heavy met­als. Because the leach residues were the discharge products of halide/halogen systems, the general perception was that the con­tained heavy metals would be more susceptible to dissolution than in typical sulfate systems, thus causing increased environ­mental problems. A long-term study was performed to obtain the information on the stability of heavy metals contained in the leaching residues after bromination. The study involved the leach residues of three different ores, as well the precipitates prepared from the synthetic solutions (not presented here). The conclusion of this study is that the stability of solid residues produced by bromination leaching was same as the sta­bility of leach residues produced by leaching in the sulfate sys­tems. Also, contrary to the past expectations, the presence of bromide ions in the test solutions (up to 1 g/L NaBr) did not enhance the solubility of heavy metals (Cu, Zn, Pb, As) beyond the solubilities found in the sulfate systems.

Jan 1, 1998

By Richard J. Frechette

Very few facilities containing hydraulically deposited tailings have been completely reclaimed and capped at this time. Design of a closure cap for a tailings impoundment has relied heavily on consolidation theory in order to achieve a cap that maintains sur­face drainage. Obtaining data for the consolidation evaluation can be difficult and costly. The author reviews the performance of two tailings impoundment closure caps that have been suc­cessfully installed and presents the experience gained from these projects with an emphasis on the ability to optimize cap design through post-operational monitoring prior to initiating cap con­struction. Using the optimization approach, a significant earth­work quantities reduction may be realized for the ultimate cap.

Jan 1, 1998

By Rob Dorey

The disposal of mine waste continues to be one of the main controlling factors in the economics and feasibility of project development. Particular to gold and precious metal mining, waste disposal is further complicated by the environmental and political implications of the use of cyanide. Regulatory compliance criteria have partially dictated and can be anticipated to further dictate the approach and methods of tailings disposal. To develop practical, economic, and environmentally acceptable tailings disposal systems within these criteria requires the use of common sense approaches and the application of available technology. Waste disposal is typically considered during the pre-feasibility stages of project evaluation. At this time, the main emphasis is on the economics and practicality of extracting the metal values from the ore. Frequently, the result of this is that the nature of the tailings and the ability to dispose of the tailings is prejudged. It is also frequently the case, however, that during the feasibility stage and project permitting, the requirements for tailings disposal become paramount.

Jan 1, 1998

By C. S. Caldwell, L. C. Thompson

Mine closure and reclamation issues have evolved over the past several years becoming further complicated by stricter standards and by the cmrent economic climate and price of gold. Many mine permits are calling for more stringent remediation of spent ore heaps and tailings. Leachate solution water quality must meet strict discharge criteria for multiple parameters besides cyanide at mine closure. Closure standards are more difficult to meet and most mines do not have an increased budget at the end of mine life to deal with the falling standards. These issues make additional gold recove1y at the end of mine life a critical problem in financing some closure operations. Another issue is the length of time that must be budgeted for heap rinsing operations. Innovative biological processes developed and applied by Pintail Systems, Inc. at numerous mine closures have indicated that bio-processes can significantly enhance gold recovery dur­ing heap cyanide bio-detox over the recoveries expected from rinse operations. If heap rinsing can be eliminated or reduced and if gold recovery can be improved at the end of mine life, many mine closures may be possible with processes that pay for themselves or generate profit. Additional advantages of the bio­detox technology is that it can be engineered to treat multiple contaminants besides Weak Acid Dissociable (WAD) cyanide. Other contaminants treated in heap process solutions include nitrates, ammonia, heavy metals, thiocyanate and total cyanide. At the Cripple Creek and Victor Mining Company Ironclad Mine near Victor, CO, 5 million tons ofrinsed, heap leached spent ore were biologically detoxified to reduce cyanide content, enhance gold recovery during bio-detox and to reduce dissolved metals in heap leachate solutions. During the bio-detox treatment period a substantial improvement in gold recovery allowed the detox oper­ation to operate as a profit center. Final gold recovery was at least twice what was expected from a normal rinse operation.

Jan 1, 1998

By Donald R. East

For many years there has been increasing pressure on mining companies, not without some justification, to design tailings storage facilities which guarantee some degree of protection against process solutions entering local groundwater and surface water flows. A fairly straightforward approach to achieving this has been to design conventional water-retaining type structures, and this has often been reinforced by the need to store large volumes of process water and seasonal run-off within the tailings facility. The conventional design uses naturally occurring geological barriers and a conventional embankment with possibly a grout curtain, or artificial barriers around the entire facility, using either imported low permeability soils, admixtures, or synthetic liners. While these approaches may achieve the primary objective of minimizing seepage, various other factors should be considered. Firstly, by depositing the tailings slurry in a sub-aqueous manner, the tailings, especially if relatively fine grained, will settle to very low densities and little or no on-going consolidation may occur over the operating life of the mine, There have been many cases where measured pore pressures within the tailings mass equal the total overburden stress, i.e., no consolidation and no strength, many years after decommissioning.

Jan 1, 1998

By Jody Kelso, Thomas R. Clark, Gregory J. Olson

Refractory, sulfidic gold ore from the Metates deposit in Mexico was tested to determine if it could be heap biooxidized to improve gold extraction. Small column tests were conducted in a manner consistent with anticipated process conditions: increased tempera­ture due to oxidation of the high sulfide content ofMetates ore and full recycle application of leach solutions containing high concen­trations of dissolved solids. Biooxidation by thermophilic (heat­loving) microorganisms was tested to determine: 1. the extent of sulfide oxidation and bottle roll precious metal recovery, 2. reagent consumption, and 3. potential solution flow problems due to mineral precipitation.

Jan 1, 1998

By David Lunt, Paul Messenger, Peter Allen

The Rawas Gold Project in Indonesia has a high silver ore with a ratio of approximately 25:1 Ag/Au. Four process flow­sheets were considered during the development phase, ie. full Merrill Crowe, CIP, CIP with zinc cementation of eluate and a hybrid Merrill Crowe - CIP circuit. The process plant was constructed using a CIP circuit with zinc cementation of eluate. Unusual aspects of the design include an elution circuit designed to strip three batches of car­bon per day and an elution column designed to operate with either upward or downward solution flow. Significant improvements implemented since starting up the plant include the use of local materials and labour for relining the mill, a change from lime to caustic soda for pH modification and the elimination of caustic soda dosing to the elution pre-soak step.

Jan 1, 1998

By Peter W. Willcocks

The Cyanide Regeneration Process (CRP) was developed by Golconda Engineering and Mining Services and installed at Golconda's Beaconsfield Gold Tailings Retreatment Project situated in Tasmania, Australia. The Tailings Project is a 1000 ton per day carbon-in-pulp treatment plant, feed for which consists of tailings material which is dredged from the Tamar River. The pulp is screened to remove debris, then cycloned to form two products. Underflow pulp is stored in a 350 ton bin and cyclone overflow passes to a thickener. The coarse pulp material is fed to the grinding circuit then rejoins the thickened slimes in the cyanide leach circuit. Gold is extracted by carbon-in-pulp techniques. The plant is sited in rolling, hilly country approximately 200 meters from the Tamar River. The residue disposal area is quite small consisting of four dams, totalling 42 acres. The regional climate is cool and wet with little evaporation; therefore, we anticipated a net increase in contained liquor, and subsequent storage problems. Our plan was to remove cyanide from the liquor prior to returning the detoxified solution to the river system. Such treatment was not required until midway through the second year of the project. Initial testwork on sample material indicated that destruction of cyanide by chlorine was the simple solution. Subsequent follow-up on actual plant liquor indicated a huge chlorine requirement due, we believe, to the substantial degradation of vegetable matter plus organic content from the marine environment. The cost of cyanide destruction could not be justified.

Jan 1, 1998

By A. Giblett, J. Shuttleworth, R. Dunne

In a previous paper (Dunne, Martins, Goulsbra, Chittenden 1997), the new gravity circuits at Telfer Gold Mine, which incor­porate Knelson centrifugal separators in both the sulphide and oxides, are described. The advantages of the new circuits over the replaced spiral ( oxide circuit) and jig (sulphide circuit) were discussed, as were the improvements in gravity gold recovety. It is of note that the installation of the centrifugal separators in themselves did not result in increased gold recovery. The realisa­tion that changes in gold room practices are required to take advan­tage of the increased fine gold recovery from the Knelson concen­trator was an important step towards improved gravity gold recov­ery. This was achieved by increasing the time taken to treat the Knelson concentrate on the shaking table in the gold room. Although this increased gold recove1y, it was found that the table tailings, especially from the sulphide circuit, still contained high values of gold. In an effort to ascertain ways in which gravity gold recovery could be fu1iher improved, a sample of the sulphide table tailings was sent to the Oretest Laboratory in Perth for testwork. The results from this program are discussed in this paper.

Jan 1, 1998

By Dewey W. Marino

Conventional remote sensing applications for the exploration of natural resources has largely been the domain of low resolu­tion Earth orbiting systems such as Landsat™ which can sample a broad range of the spectrum. As the classic application of remote sensing, it has proven its worth through the discovery of numerous mineral deposits worldwide. Often this technique relies more on the spectral content of the imagery for narrowing potential sites on the ground, but often cannot reveal the detailed context of the observed response. As the dawn of the new era in remote sensing grows closer, high-resolution imagery is proving its worth for the definition of mineral potential and its cost sav­ing advantages for mine management.

Jan 1, 1998

By Morris Beattie

Arseno Processing Ltd. has developed process technology for the extraction of gold from refractory ores and concentrates. These ores, which do not respond to conventional extraction processes, are rapidly becoming the primary targets for mining companies wishing to become significant gold producers. It has recently been estimated that by the mid 1990's, the annual gold production from the Pacific Basin Epithermal Arc in southeast Asia could be as high as 550 tonnes. Within this area the Porgera deposit under development by Placer, Renison and MIM, and the Lihir Island deposit under development by Kennecott have been shown to be refractory and require pretreatment before the gold can be extracted. The additional deposits which are now starting to be developed in this area are also expected to require such pretreatment. The Arseno process promises to be an economical pretreatment for these ores and to result in the maximum achievable gold recovery. Numerous refractory deposits are also known in Australia, North America, China and other parts of the world. Samples from many deposits throughout the world have been tested using the Arseno process conditions and the consistently successful results have demonstrated its widespread application. The samples which have been tested include ores in which the gold is locked in pyrite, marcasite or arsenopyrite. The process is insensitive to the sulphur content of the feed. Feed materials containing from 1 % to 50% sulphur have been tested successfully with the process. In the Arseno refractory gold process, sulphide minerals are dissolved so that the contained gold becomes accessible for subs7qu7nt gold recovery. This gold recovery is achieved by cyamdat1on of the process residue. For many of the materials which have been tested, gold extractions in excess of 95% have been achieved.

Jan 1, 1998

By Stefan Norgaard

In today's modern gold mining industry in Australia, and the world, more and more companies are recognising the competi­tive advantages gained by implementing an effective training program for operations (processing plant) personnel. Plant operators, or process technicians, are unique amongst all other gold mine employees. They are at work in shifts cov­ering 24 hours a day and their actions can have a profound effect on the operation's economic performance. To a large degree, the minute to minute decisions and actions of an operator can deter­mine whether gold is extracted to bullion in the goldroom or is discharged into the tailings dam. Experience has suggested that most small to medium sized gold operations in Australia, and even some large ones, have not implemented an effective training program. This is not attrib­uted to deliberate negligence or "anti" attitudes against training, moreover mill superintendents and metallurgy managers are technical people not oriented to human resource techniques. Usually the demands of designing, constructing and commis­sioning a gold plant overshadow the need for training in the first instance, In fact some well designed plants treating friendly oxide friable ore have little need for a dynamic well trained oper­ating staff. However, many plants do require a thinking team to optimise production and changing ore conditions towards the end of a mine's life can expose poor competence levels at large expense. Few managers will argue that training is a necessity and results in a win-win situation. The operators win by increased job skills, job satisfaction, clear career development and possibly better pay conditions. Trained personnel usually reciprocate with increased effmt and work ethic. The company wins also by having a thinking team which will maximise gold production and reduce operating costs.

Jan 1, 1998