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By B. K. Parekh, R. H. Mehta

Handling of fine coal is an importance issue for coal as well as the utility industry. Reconstitution in form of pellet or briquet would be desirable if it could be done economically. This paper evaluates the effectiveness of three binders e.g., asphalt- emulsion, corn starch and Brewex, in forming pellets of ultra-fine clean coal. It was found that asphalt emulsion and corn starch were not effective binders for ultra-fine clean coal, however, Brewex provided excellent quality of pellets, which exceeded all the minimum quasi requirements of coal pellets. INTRODUCTION Advanced coal preparation techniques (physical or chemical) are designed to process ultra-fine (minus 200 mesh or 74 pm) coal. The average particle size of the clean coal product is about 25 pm. Currently available dewatering techniques are effective in providing a 25 to 30 percent moisture product of this size coal slurry (Parekh et al. 1989). Handling and utilization of this dewatered ultra-fine size coal is difficult. Reconstitution, which includes pelletization, briquetting, extrusion, etc., of the dewatered coal product provides an ideal answer to handling and transportation problems. However, reconstitution of fines in the coal industry has not been successful due to various reasons. The most important criterion for its unsuccessful application in the coal industry is the cost of the binder (Capes et al. 1965). Various methods of reconstitution, such as briquetting, disk pelletization, extrusion pelletization and roller and die-pelletization, have been tested for fine coal agglomeration (Conkle et al., 1991) (Richards, 1990). Conkle et al., (1992) have provided a detail analysis of each technique in terms of moisture and operating cost requirements. According to Conkle, briquetting requires a product containing very low moisture, whereas pelletization can be done with coal containing up to 30 percent moisture. Currently available dewatering technique provides about 25 percent moisture product, thus, pelletization appears to be an ideal route for reconstitution. In this paper, results are presented on the comparison of three different binders i.e., asphalt-emulsion, corn starch and Brewers condensed solids (BCS or Brewex), for fine coal pelletization.

Jan 1, 1995

By R. R. Klimpel

Over the last six years, several new commercial families of sulfide mineral collectors have been developed. This paper summarizes some plant data and use experiences gained with each of these product families. The first is a series of products (F-series) based on a chelation mechanism of attachment. The second of these families is a series of products (S-series) based on an electrochemically controlled mechanism of attachment. The major advantage of the F-series collectors is the very high metal recovery capability in complex ores involving Au, Pt, Zn, Ni, and mixed Cu minerals. The major advantages of the S-series collectors are the very high pyrite rejection capability along with reduced lime requirements in Cu/Mo plants.

Jan 1, 1995

By E. H. Cho, P. K. Dai

An acid mine drainage sludge sample, containing 3.6% Mn, 0.18% Ni, 0.15% Co and 0.39% Zn, was obtained from central West Virginia. The sample was leached at room temperature with a pH 3 sulfuric acid solution. Air was then bubbled through the leach solution at pH 4.5 to precipitate the iron. The leach solution contained 258 ppm Zn, 105 ppm Ni, 90 ppm Co and 2050 ppm Mn. Three solvent extraction studies were performed to selectively extract these metal ions in a sequential operation with DEHPA. Cyanex 272 and Lix 84. The A/O ratio was one, and the extractants were diluted ten times with kerosene. A study of solvent extraction with DEHPA showed that Zn could be extracted without Ni or Co up to a pH of 2.75. A pH of 2.75 is considered to be the optimum pH to maximize the selective separation of Zn from Mn. The separation factor of Co over manganese suggests that the two metal ions should be extracted together by Cyanex 272. The separation factor of Co over Ni indicates that these two metal ions can be separated most effectively around pH 5.3. Also, Ni can be effectively extracted by Lix 84 above pH 5.5.

Jan 1, 1995

By J. A. Cole

Santa Fe Pacific Gold's Lone Tree mine is located in Humboldt County, NV, 45 km (28 miles) east of Winnemucca. The mine currently operates a 1.74-Mt/a (1.92-million stpy) run-of-mine heap-leach operation and a 2.27-kt/d (2500 stpd) refractory gold¬ore-processing plant. Most of the mill-grade ore reserves are refractory, mainly due to pyrite and arsenopyrite encapsulation of the gold. The autoclave pressure-oxidation circuit was commissioned in February 1994 to process the refractory ore. Mineralogy unique to the Lone Tree deposit allowed for the design of a partial-oxidation process. It takes advantage of the heterogeneous nature of the pyrite morphology. Partial oxidation has resulted in an autoclave plant that is able to achieve low operating-unit costs (Figs. 1 and 2).

Jan 1, 1995

By M. M. Foss

Geophysical methods are gaining acceptance in the evaluation of coal mine ground control condition. The use of in-seam seismic investigations has contributed significantly to the body of information concerning ground control feature identification and analysis. Seismic methods have been used successfully in locating voids, faults, fracture zones, roof and floor rock interfaces, and more recently in characterizing in-seam stress distribution. Seismic tomography is an effective tool in data interpretation for several of these applications, but as is the case with other engineering application of geophysical techniques, there are limits as to how much substantive information can be interpreted from a given data set. This paper discusses some of the applications of in-seam seismic geophysical tomography, and the limits to which the transformation from raw data to information should be taken.

Jan 1, 1995

By J. A. Pontius

The Cresson Deposit is located in central Colorado within the historic Cripple Creek Mining District. The deposit has moved from its initial discovery in 1990 to full production in less than five years (current reserve nearly two million ounces). This accomplishment required a great deal of cooperative teamwork between the exploration, development, permitting and corporate groups. Nowhere was this cooperation more evident than in the construction of the geologic block model. The detailed modeling of gold and its metallurgical characteristics formed the foundation upon which critical financial and design decisions were based.

Jan 1, 1995

By Jorge Rubio, Luis Valderrama, Carlos Pérez

This work describes the effect of the degree of energy transferred to the pulp, during the conditioning stage, on gold flotation fines recovery, grade and kinetics, with three types of frother (Dowfroth 250, pine oil and MIBC) and amyl xanthate as collector. Best results show an increase in 24% recovery and 50% in concentrate grade, depending on the intensity of conditioning and type of frother (better with Dowfroth 250). For low or intermediate energies (0.5-1.5 kWhlm3 pulp), the fine particles adhere to larger ones, increasing the recovery due to a mixture of carrier (pyrite, in this case) and autogeneous carrier flotation and at higher shear (2-3 kWhlm3 pulp), gold fine particles aggregate themselves. These phenomena are demonstrated by measurements of flotation rate, true flotation (flotation by actual particle-bubble adhesion), and by the amount of entrained particles. Alternatives for this type of pulp conditioning and mechanisms involved are discussed.

Jan 1, 1995

By J. Y. Kim

Lead ions originating from galena during processing of complex sulphide ores migrate to "cover" the surface of sphalerite and iron sulphide mineral particles, and cause poor selectivity in differential flotation. Generally in sulphide ore processing, the lead-activated minerals float in the Cu/Pb rougher circuit. Subsequently, surface lead complicates the zinc flotation circuit by lowering the concentrate grade due to the co-flotation of lead-activated iron sulphide minerals. The effect of lead in the differential flotation of sphalerite from Cu-Pb-Zn and Pb-Zn ores is discussed. Plant and laboratory test data are interpreted by determining the surface composition of individual grains of sphalerite and iron sulphide particles using two surface analytical techniques, Laser Ionization Mass Spectrometer (LIMS) and Time of Flight-Secondary Ion Mass Spectrometer (TOF-SIMS). Cationic and anionic species on the surface were analyzed to elucidate the phenomena.

Jan 1, 1995

By P. Bevilacqua, G. Ferrara, M. C. Williams, T. P. Meloy

Tabling is an old environmentally friendly separation unit operation. This paper models shaking tables and explores the action and design of riffles on shaking tables. By reassessing riffle shape and riffle patterns, significant improvements in tabling performance appear feasible. While table sales appear at their nadir, a high-tech environmentally friendly table may have a significant market in the coming decade. Riffles on a shaking table impact particle separation. Particles are affected by riffles and their exit position on the table is dramatically changed, Riffle shape determines how much the riffle will influence a given material. Moreover, riffle patterns influence the concentration of a given material and its exit points on a table. This effect of riffle placement and design is modeled in a spreadsheet. Major performance and separation improvements may he expected by improved table design. Two physical laws of tabling have been derived. These laws aid in the design of sophisticated high-tech tables.

Jan 1, 1995

By J. C. Norman

The United States was the world's largest producer and consumer of boron compounds during 1994. According to US Bureau of Mines (USBM) estimates, boron mineral concentrate and chemical production in the United States totaled about 1.05 Mt (1.15 million st), yielding 560 kt (617,000 st) of B203, for a total estimated value of $370 million. This production level was about 2% less than 1993 revised figures. The United States continued to provide nearly all of its own boron supply while maintaining a strong position as a source of sodium borate products and boric acid for export. Domestic employment in the mining and beneficiation of boron products during 1994 was 900 people, about the same as in 1993. USBM estimated total world production of boron of about 2.3 Mt (2.5 million st), yielding 1.1 Mt (1.2 million st) of B203. World production during 1994 was about the same as during 1993. USBM estimates US reserves to be about 210 Mt (231 million st) of ore and world reserves to be about 630 Mt (694 million st) of ore.

Jan 1, 1995

By R. J. Gochin, G. D. Schena

Mineral processing options and technical innovations should be financially assessed. Indeed technical feasibility alone does not offer an adequate process selection criterion. An appraisal by the use of engineering economics principles leads to a more efficient evaluation and selection of feasible mineral processing solutions. Financial consequences of different options synthesised by profitability indices allow better decision making. Selected examples derived from real world problems are used to illustrate the potential of engineering-economics methods applied to mineral processing.

Jan 1, 1995

By Bruce McKinstry

INTRODUCTION In June of 1992, the Bureau of Reclamation, United States Department of the Interior, awarded the contract for construction of the Sixth Water Aqueduct to the Fedrick-Redpath Joint Venture. This aqueduct, a segment of the Diamond Fork Power System, Central Utah Project, diverts water from Strawberry Reservoir into Sixth Water Creek and, when complete, will replace the old Strawberry Tunnel which was driven in the early 1900's. The new aqueduct is being built primarily as a result of deterioration of the old tunnel, but will also have a higher capacity and more positive control than the old tunnel as well as the capability to incorporate a turbine into the system at a later date. The Fedrick-Redpath Joint Venture is comprised of C.R. Fedrick, Inc. of Novato, California and J.S. Redpath Corporation of Tempe, Arizona. Fedrick, with its experience in pipelines and heavy construction, will construct the 4200 ft surface pipeline and flow control structure; Redpath, the managing partner, performed the underground work consisting of a 600 ft vertical shaft and 3300 ft tunnel. The project is located in the Uintah National Forest, approximately 20 miles east of Provo, Utah at a mean elevation of 7000 feet above sea level.

Jan 1, 1995

By R. M. Damodaran

The flotation performance of Florida phosphate rock was evaluated in terms of the mixing behavior of reagents with particulates during anionic conditioning of phosphate slurries. The various conditioning variables that influence mixing, namely, solids loading, agitation speed and the conditioning time were investigated to determine their effect on reagent coating on the particles. The phosphate recovery was used to monitor the conditioning efficiency. The mixing characteristics of the phosphate feed were evaluated in terms of the ratio of the mixing power P, to the minimum power Pm' required to keep the slurry in suspension. It was found that mixing conditions govern the conditioning time required to obtain high recovery. Reagentization was slower at lower P /P m ratios. At higher P /P m ratios, the flotation recovery was optimized and the agitation speed was found to have no significant effect on it. Optimum mixing conditions were obtained for a 74 wt% slurry at an agitation speed of 450 (47 rad/s) rpm. Under the optimum conditions of mixing, recovery was improved at low collector dosages and short conditioning times.

Jan 1, 1995

By Alfredo Romero Quispe, Carlos Hoffman Sampaio

This work presents a study of characterization of activated carbons for the adsorption of Au(CN)2- complex. A comparative study of six samples of activated carbons, three Brazilian and three produced out of Brazil was made in order to determine their qualification for a performance in adsorption circuits in the extractive metallurgy of gold. The adsorptive capacity and the kinetics of adsorption were compared to the physical and chemical properties of each one. The influence of poluant ions on the kinetics and loading capacity of aurocianyde anion was also determined.

Jan 1, 1995

By J. C. Stankus

In this paper, an innovative concept in longwall tailgate support is discussed. This new concept utilizes a new high capacity roof truss system in lieu of conventional wooden crib block. The first field test was conducted at Bailey Mine and was very successful. Similar tests have been installed in other mines and seams. An extensive instrumentation plan was designed and implemented in the truss test area. The test data has shown that the dynamic roof truss system effectively controls the various abutment pressures caused by longwall mining thus maintaining a stable tailgate entry.

Jan 1, 1995

By A. M. Johnson, M. A. Cornachione

The west central Upper Peninsula of Michigan contains a large resource of graphitic slate. The slate has potential industrial use as a substitute for shale currently used in the production of portland cement. Some of the unweathered slate, however, has a high concentration of pyritic sulfur that can create emission problems when processed in a kiln. A low-cost method to reduce the sulfur content of the slate through the optimization of pyrite oxidation in a bio-heap leaching operation was investigated. In this study, optimal conditions for the bacterium Thiobacillus ferrooxidans were created to promote pyrite oxidation and, therefore, sulfur removal from the slate. Preliminary lab scale flask tests using crushed and sized slate (-40 + 100 mesh) and T. ferrooxidans bacteria in a sulfuric acid medium resulted in 70% oxidation of pyrite over a one-month period. Subsequent column leaching tests on coarser materials (-3/8+1/4 in.) operated for six months resulted in a maximum reduction of total sum of 75%. These data suggest that bio-heap leaching to remove sulfur from the slate for use as a kiln feed material is viable.

Jan 1, 1995

By James A. Pappas, Francis L. Fong, Tracy K. Lundin

The impact of environmental regulations on the quality of tunnel groundwater discharges is examined in this paper. Tunnel contractors usually depend on specialty contractors or outside consultants to deal with this issue without carefully examining their activities to minimize the production of contaminants. This approach may not be adequate given increasingly more restrictive environmental requirements. This paper surveys the general practice of the tunneling industry and attempts to identify sources of contaminants which may affect the total suspended solids, oil and grease content, and pH of the discharges. Strategies for treating the discharges are included. Field data and observations from several tunneling projects are also presented.

Jan 1, 1995

By John Brett

BHP Australia Coal Pty. Ltd. (BHPAC) manages and, through its parent company BHP, partly owns seven large opencut mines in the Bowen Basin of Central Queensland, Australia. In terms of developments in surface mining in Australia, the operations of BHPAC are as representative as any. The seven mines managed by BHPAC produce a combined total of about 40 Mt/a (44 million stpy) of mostly high quality coking coal. They also produce small but increasing amounts of thermal and PCI coal. Virtually all of the coal produced is sold on the export market. In 1993, Australia exported 133 Mt (146 million st) of coal. Salable production was 172 Mt (189 million st) in New South Wales and Queensland and 180 Mt (198 million st) nationwide. Mining systems Surface coal mines in Queensland can be typified as large, long-strike-length, shallow-dipping and sometimes multi-seam dragline operations. There are exceptions. Blair Athol, for instance, works a 30- to 40-m (100- to 130-ft) seam beneath shallow cover but is still a dragline operation. Moura is truly multi-seam and steeper dipping but also is still a dragline operation. Mines in the Ipswich area are small shovel-truck operations.

Jan 1, 1995

By P. M. Solozhenkin

The proposed technology of antimony calcine processing includes ferrochloride leaching of calcine, reducing solutions, hydrolysis of hydrochloride solutions with antimony oxochloride isolation, synthesis of antimony trioxide by SbOCl neutralization and its drying, regeneration of hydrolysis solutions. The optimum parameters of separate stage of process has been determined and the chemical character of process has been given. During the leaching of calcine we succeeded to transfer 92.16- 95.66% antimony to solution. On the worked out sheme we attained recovery of antimony to antimony trioxide near 90 .5% Antimony triozide contains 99.5% Sb2O3. The composition of sinter burdens for pigments preparation "Naples Yellow" different colours from brightly-yellow, yellow and lightly yellow has been proposed. Three-sulfuretted antimony-antimonic cinnabar have been prepared by precipitation of antimony solutions by potassium sulfur-bearing solution. The prepared compounds correspond to inorganic pigments for artistic paint. The amorphous antimony-ferrous black we prepared by aluminium cementation of hydrochloric antimony solutions. The ferrous black were used as artistic paints and for coating of metals by antimony.

Jan 1, 1995

By Anthony G. Fonseca

About 45% to 50% of the coal mined in the United States passes through coal preparation plants. East of the Mississippi River, this number increases to about 75% to 80%. Although the cost for coal preparation is worthwhile to some, the coal industry faces the challenges of continuing downward pressure on the price of coal and the impact of new environmental regulations. Coal preparation is an effective process that achieves 75% to 80% ash reduction, 15% to 80% trace element reduction and 85% to 90% Btu recovery. It is less effective for pyrite reduction (35% to 70%) and on-line operating time (40% to 60%). It also suffers from obsolete control systems. In coal preparation, raw coal is modified to a more preferred form to enable its use. The methods used to achieve this modification must be cost-effective and appropriate to the raw coal, the scale of production and the end-user requirements.

Jan 1, 1995