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By B. Suresh, Kalyan K. Das, Pradip

A series of salicylaldoxime derivatives with alkyl group substitution in the main chain and the side chain were synthesized and evaluated for the flotation of malachite, cerussite and smithsonite. The effect of chain length and the position of the substituent group on the selectivity of separation amongst oxidized copper, lead and zinc minerals are discussed in this paper.

Jan 1, 1995

By N. O. Lotter

Studies investigating the evaluation errors in laboratory scale flotation tests for platinum-bearing Merensky Reef in the Bushveld Complex, South Africa, have constructed a quality control model to assure a 95% confidence in the attested data. Specialized knowledge of the mineralogy of the platinum-group elements (PGE), together with acquaintance of evaluation models, validate a systematic checking of the sub-processes of the testwork. These include determination of minimum mill feed sample size, assay head reference distribution, mass balance checks, and specialized sample preparation of flotation test products prior to analysis. A flow schematic of this quality control model is proposed, with an example of test data that produce an error in the metal balance of 0,2% after rejection of outlier data.

Jan 1, 1995

By G. P. Hand

Graphite usage in the United States during 1994 was fairly strong. The hearty showing of the domestic economy, along with sound performances from the major industries that use graphite, helped make 1994 a solid year for the graphite industry. Supply Virtually all natural graphite is imported into the United States, as there is no domestic production. The primary producers are Brazil, Canada, China, Madagascar, Mexico, Mozambique, Sri Lanka and Zimbabwe. Mozambique is a new producer. It is now supplying a high-carbon, large-crystallite flake in large quantities. Sri Lanka continues to experience problems with one of its two mines, closing operations in December 1994. The synthetic graphite used domestically was produced primarily in the United States as a byproduct of electrode production. Synthetic graphite was also imported from Switzerland for specialized applications. The purified graphites/carbons, such as Desulco and ThermoPURE materials, were also produced domestically. There was a sufficient supply of all types of graphite to meet domestic demand.

Jan 1, 1995

By J. F. McDonald

On December 8th of last year, the new St. Clair River tunnel was holed-through to Port Huron, Michigan. The tunnel, commissioned by the Canadian National Railway, was needed to replace an existing tunnel that had been built between 1889 and 1890, and had remained in continuous operation until the new tunnel was opened to traffic in April of this year. The original tunnel, after more than 100 years of service, was still structurally sound, but was too small to accommodate the double stacked container cars and other advances in the railroad's equipment that had developed over the years. Prior to the construction of the first tunnel, all freight was barged across the river. It was a slow, expensive process, which in winter was sometimes impossible. The nineteenth century tunnel was built in twenty months, utilizing two shields that mined to the middle from each end. The lining, which is still in excellent condition, consisted of bolted, cast iron segments, with an O.D. of 6.4 meters. It was the first sub-aqueous tunnel built in North American, and it's use of compressed air under the river and hydraulic power on the shields may also have been firsts. The digging was done by hand, and the muck hauled out by mule drawn wagons. Boulders and methane gas were reported to be a constant problem during the drive, and compressed air sickness was common, but when the two shields came together in August of 1890, it was reported that the alignment was within 6 mm. The new St. Clair River Tunnel was constructed for basically the same reason as the original. The larger equipment which the railroad is using today would not fit through the old tunnel, and once more they were forced to ferry the cars across the river.

Jan 1, 1995

The dissolution behavior of gold and silver from Au/Ag alloys in aerated cyanide solutions has been investigated using rotating disc electrodes. The variables studied included concentration of cyanide, oxygen partial pressure and rotating speed of the disc. The dissolution potential and the rate of dissolution were obtained in view of the anodic and cathodic current-potential relationships. The results were discussed in terms of a mixed potential theory. The results showed that the dissolution rate of gold and silver from the alloys was partially controlled by chemical reaction, but largely by transport of either oxygen or cyanide, depending on their relative concentration under the experimental conditions employed in this study.

Jan 1, 1995

By L. A. Arrington-Webb

Forty-four states produced clay products during 1994 for a total value of $1.6 billion. This was a 3% increase in total tonnage and a 7% increase in value from 1993. Kaolin Domestic production of kaolin during 1994 was estimated to be 9.3 Mt (10.2 million st), according to the US Bureau of Mines (USBM). Georgia remained the leading producer with 7.5 Mt (8.2 million st), followed by South Carolina with 535 kt (589,000 st). Kaolin used as a paper coating or filler pigment accounted for 51% of domestic consumption. Other uses included grogs (14%), fiberglass (5%) and plastics (4%). A reclassification by an Alabama producer of fire clay to kaolin accounts for the introduction of kaolin used in grogs. This also accounts for the apparent decrease in the use of kaolin in paper from 60% in 1993. However, the actual amount of kaolin used in paper was the same.

Jan 1, 1995

By Rock M. Poulin, Bruce G. Moulton, Daniel E. Nowak, David T. Cass

The Yacambu Irrigation Tunnel Project of 34 km, 5 meter diameter circular and horseshoe section, has been under construction since the early 1970's. Notable among the excavation challenges is high ground cover of 3,000m creating large lithostatic pressures in the tunnel alignment with subsequent plastic flow of the ground in the tunnel walls. The tunnel may converge from small amounts to 1 or more meters of diameter over long sections. Several excavation techniques have been attempted but all without desired results. The paper proposes a new machine concept that uses the history of ground experience as its basis for design.

Jan 1, 1995

By Mark A. White

Surface mining of multiple seams by mountaintop removal and contour mining is complex in Appalachia. Arch of West Virginia, a division of Apogee Coal, has made its operations state-of-the-art to cope with this challenge. Arch of West Virginia moved into the heart of coal mining in Appalachia when Arch Mineral acquired coal reserves and coal operations in the southern West Virginia counties of Logan and Wyoming. These reserves were initially developed at the turn of the century as underground operations. Today, though, they are mined using mountaintop removal and contour mining. The steep slopes in the mountains of Appalachia generated a method of mining referred to as contour mining. During the late 1960s and early 1970s, contour mining was introduced at these operations using front-end loaders with bucket capacities of more than 7 m3 (10 cu yd) that could load 45-t (50-ton) end-dump trucks.

Jan 1, 1995

By Armando Alatorre

The Republic of México is the world's largest producer of celestite/strontium carbonate and natural sodium sulfate. It is also a significant producer of flourspar, barite, graphite, sulfur, feldspar, salt and gypsum. New production may be brought on stream for borates, wollastonite, garnet, calcium carbonate and others. The country covers a geographic area of approximately 2 million square kilometers (760,000 square miles), and is divided into seven geological/geomorphological provinces. Less than 20 percent has been explored in detail for either nonmetallic or metallic minerals. This leaves large areas available for the discovery of world-class industrial mineral deposits. In addition to new deposits of those minerals currently being produced, there is exploration and development potential for borates, magnesite, rare earths, nepheline syenite, heavy mineral sands and numerous others.

Jan 1, 1995

By S. Davis

It has been accepted almost as dogma that sampling contributes most of the error to fluctuations in gold fire assays. Differences in assay results on pulp material from the same sample interval are frequently regarded as evidence of the presence of the so called "nugget effect" or relatively coarse gold particles. It is true that if coarse gold particles are present they contribute to substantial sampling fluctuations, but while the process of sampling is probably the major source, the analytical process cannot -be completely ignored as a possible contributor to erratic assay results. In order to maintain a stable assay process, the analytic part of the system must be kept in control as well as the sampling and preparation part. One way of monitoring the performance of the analytic system is to systematically assay standard material whose sampling characteristics are carefully controlled. Gold assay standards are not prepared nor can they be prepared to account for both sampling and analytical errors. It is not possible to send coarse material to a lab for preparation (which includes both the processes of comminution and splitting) followed by fire assay, to make inferences only about the fire assay process. Because most gold ores are very heterogeneous, sampling errors would in most cases completely mask the contribution of the analytical errors. Assay standard material is prepared only to assess the accuracy and variability in the fire assay process.

Jan 1, 1995

By Kenneth N. Han, Yichang Guan

The dissolution behavior of metals from Au/Ag/Cu-alloys has been studied using rotating disc electrodes in solutions containing acids, cyanide, and ammonia. Electrochemical methods as well as leaching tests were adopted in this study. The results showed that there was no galvanic effect on the dissolution of metals from homogeneous alloys. In aerated cyanide solutions, the dissolution of gold, silver, and copper from their alloys was partly controlled by surface chemical reaction, but largely by mass transfer. On the other hand, the galvanic coupling effect played a very important role in heterogeneous alloy systems.

Jan 1, 1995

By Alan A. Campoli, Michael D. Zuber, Frank E. McCall, Gerald L. Finfinger

Injecting water under pressure to wet the coalbed in advance of mining reduces mining-generated respirable dust. Owing to economic and geological barriers, water infusion for longwall dust control in the United States is currently limited to the Pocahontas No. 3 Coalbed in Virginia. Water is pumped into the coalbed through underground boreholes drilled horizontally from the headgate toward the tailgate side of retreat longwall panels. This paper theorizes that the barriers to widespread utilization of water infusion for longwall dust control could be overcome by long-duration, low-pressure water infusion through vertical gob gas boreholes. Currently, 43% of the 72 longwall mines in the United States employ vertical gob gas boreholes. Computer coalbed reservoir simulation suggests that one vertical surface borehole could infuse the same longwall panel area as four horizontal boreholes in the current water infusion system for longwall dust control in the Pocahontas No. 3 Coalbed.

Jan 1, 1995

By Leszek W. Lunarzewski, Adam L. Lunarzewski, Raymond C. Pilcher

The Floorgas and Roofgas simulation programs are used to identify strata relaxation zones and their boundaries, to assess active gas sources from coal seams and gas¬bearing rocks and to determine relevant gassiness prediction coefficients for any local longwall. The paper shows that by use of the print-outs from the Floorgas and Roofgas programs the following benefits are achievable: • identification of the shear and gas discharge zone positions in the floor, strata relaxation angles and various gas discharge zone positions in the roof, which are both relevant to local geological and mining conditions • optimisation of cross-measure drainage hole length, location, number and angle of inclination calculation and definition of gas make prediction coefficients such as the release ratio from adjacent coal seams, specific gas emission during longwall extraction and the relationships between gas make, longwall width and coal production levels.

Jan 1, 1995

By Yongping Hu, Dianchen Cai, Congya Zhang

China is a rich in stromite mineral resource. Unfortunately, the resource is very difficult to separate by using conventional flotation method because stromite and gangue minerals are very fine disseminated, the average size of them is about 10 µm or below, and the content of clay minerals such as illite is 19% or even more. In this paper, the aggregation floatation behavior of ultrafine (-10 µm) stromite, illite, ablbite and quartz using anion collector were studied. The result show that, Oxidized paraffin (O.P) is a good collector and has better selectivity for stromite particles flotation. The salted sodium silicate depressed illite gangues minerals effectively. The separation of mineral mixtures was carried on successfully at one stage flotation by the technique. The mechanism of O.P. and salted sodium silicate were studied and discussed by using IR and Zeta- potential measurements.

Jan 1, 1995

By D. W. Jahn

Road construction in the near future will require contractors to guarantee that a project will remain trouble free for years after the project has been completed. These guarantees will challenge aggregate producers to become technically proficient in judging performance of their products. Testing procedures are described that may be used to predict performance of concrete and asphalt pavements before being committed into a construction project, and may also be used as quality assurance tools during construction to monitor performance as construction proceeds.

Jan 1, 1995

By S. K. Kawatra, H. L. Dilley, W. W. Wen, T. C. Eisele

To improve the sulfur-rejection capability of a coal-cleaning plant, it is first necessary to evaluate the performance of the existing circuit. This information can then be used to decide whether there would be significant benefits from improving the operation and control of the existing circuit, or whether further improvements would require more radical process changes. This paper describes a simple model for evaluating heavy-media separation circuits, and presents a case-study of such an analysis of an operating heavy-media coal cleaning plant. Efficiency curves were calculated and modelled using Lynch's method, and a simplified expression was derived for calculating the Ecart Probability value from the model parameters.

Jan 1, 1995

By Robert A. Haney

During the last ten years, longwall mining systems have undergone many changes. Panel widths and lengths have increased. Longwall faces have become more automated. Average production from individual longwall panels has increased from 1,000 to 3,600 tons per shift. To control the dust generation resulting from the higher production, longwall dust control systems have integrated various dust control techniques. Systems designed to control dust generated at the crusher/stageloader, shearer, and supports are common to most longwall faces. A survey was made of the dust controls that are currently in place on all the longwalls in the U.S. This survey addressed the types of controls used to reduce dust generated at the crusher/stageloader, shearer and roof support movement. Additionally, information on face ventilation rates, cutting cycle and level of automation was obtained. The purpose of this paper is to review the dust control practices that have been implemented throughout the United States and to identify those controls that are being used on high production longwall faces. Additionally, a model is used to demonstrate how ventilation and automation affect occupational exposure. Automation of roof support movement can offer some of the greatest reductions in occupational dust exposures. While technically feasible, its full benefit has not been fully realized by the industry. Until technology to fully automate longwall mining systems becomes more reliable, future dust control systems must rely on increased ventilation, application of headgate dust collectors, improved shearer dust controls and improved shield dust suppression systems.

Jan 1, 1995

By M. R. Yalamanchili, J. D. Miller

Discussion by M.R. Yalamanchili and J.D. Miller The authors, M. S. Celik et al., should be recognized for their efforts to describe the flotation behavior of boron minerals. In the case of borax and other soluble salt minerals, analysis of the flotation chemistry has been difficult because of the high ionic strengths associated with these soluble salt systems. However, considerable progress has been made in this area, and recently a surface charge/collector colloid adsorption model was proposed by Miller and his coworkers to explain the collector adsorption phenomena observed in soluble salt flotation systems (Milleret al, 1992; Yalamanchili et al., 1993; Miller and Yalamanchili, 1994; Yalamanchili and Miller, 1994a: Yalamanchili and Miller, 1994b). In this work, the sign of the surface charge of alkali halides in their saturated brines was established on the basis of nonequilibrium electrophoretic mobility measurements by laser-Doppler electrophoresis (Miller et al., 1992). Generally, these results are what would be expected from the simplified lattice-ionhydration theory. This electrokinetic information coupled with the stability and prevalence of collector colloids in such soluble salt flotation systems indicates that the selective flotation of alkali halides is due to the adsorption of oppositely charged collector colloids by heterocoagulation. Experimental flotation/bubble attachment results for 21 different alkali halides (Yalamanchili et al., 1993; Yalamanchili and Miller, I994b) confirmed that the flotation response of soluble salt minerals with weak electrolyte collectors can best be explained by the adsorption of oppositely charged collector colloids rather than by the adsorption collector ions and/or neutral molecular dipoles as originally suggested by many researchers (Fuerstenau and Fuerstenau, 1957; Schubert, 1967; Roman et al., 1968). In addition, the flotation of certain alkali oxyanions (Pizarro et al., 1993) and double salts such as schoenite and kainite can be explained by the same collector colloid adsorption mechanism (Miller and Yalamanchili, 1994). The borax flotation results reported by Celik et al. need to be examined in terms of the above mentioned surface charge/ collector colloid adsorption model. Unfortunately, the authors seem to be unaware of this recent work that nicely describes soluble salt flotation with weak electrolyte type collectors such as amines and carboxylates. In view of our past work, the flotation characteristics of borax were of particular interest, and, in this regard, the results of dodecyl amine flotation of borax reported by Celik et al. have been examined in further detail in the light of experimental results from our laboratory. In our research, a vacuum flotation technique was used to study the flotation response of borax (Na2B407.10H20), which has a solubility of 39 g/L at 25 °C) with dodecyl amine hydrochloride as collector. These chemicals were purchased from Eastman Kodak and used as received. Saturated solutions of borax at desired pH values were prepared by continuously stirring the salt solutions over a period of about 10 hrs. It should be mentioned that the conditioning time to achieve equilibrium is an important variable and can significantly change the flotation response of some soluble salts (Yalamanchili et al., 1993). Collector was added to the saturated borax solutions containing about one gram of 100x 150 mesh borax particles, and conditioning was done for about 20 minutes prior to flotation. The borax flotation recoveries from saturated brine are presented in Fig. 1 as a function of collector addition at the natural pH of 9.3, as reported both by Celik et al. and as measured in our laboratory. In addition, the region of precipitation for the dodecyl amine hydroborate is included in Fig. 1. It can be seen in Fig. 1 that the flotation response curves are separated by about one order of magnitude in R12NH3CI collector addition. The flotation results of Celik et al. show that the maximum borax recoveries can be obtained below the solubility limit of the dodecyl amine hydroborate collector. However, in our experiments borax flotation seems to occur only after the precipitation of the dodecyl amine hydroborate collector as might be expected from the collector colloid adsorption model (Yalamanchili et al., 1993) if borax were negatively charged. Further analysis by nonequilibrium and equilibrium electrophoretic mobility measurements for borax indicates that borax is negatively charged at the natural pH of 9.3, as discussed below. The reliability of the nonequilibrium electrophoretic measurements has been demonstrated previously for alkali halides and alkali oxyanions (Miller et al., 1992; Miller and Yalamanchili, 1994). The equilibrium and nonequlibrium electrophoretic measurements for borax were found to be consistent and are presented in Table 1. These results provide clear evidence that borax carries a negative surface charge in its saturated brine (pH 9.3), and the sign of the surface charge of borax reverses and becomes positive if the pH is reduced to 8.6. The equilibrium between borax and its saturated brine can be described by the following reaction: [2Na2B407.1OH2O-4Na++B407=+HB4O7 +OH+19H20] It appears that the oxyanions of the borax lattice provide

Jan 1, 1995

By F. Dingwu

The demand of manufacturing high-purity magnetite concentrate leads to the advent of various magnetic separators. A novel magnetic drum separator has been developed with an optimal permanent magnet system and a complex-forces field is adopted, involving magnetic force, gravitation, fluid resistance, friction, inertial centrifugal force, etc. Proper ultrasonic probes are inserted into the bottom tank to break up the magnetic floes. The performance of magnetite in the complex-forces field is described and the optimal operation conditions are suggested.

Jan 1, 1995

By O. V. Bush

Most governments recognize that energy efficiency represents a partial solution to reducing global capital shortages and environmental crises that threaten to seriously impede economic growth. Much of the United States and many foreign countries are embracing the concept of Integrated Resource Planning (IRP) which incorporates Supply Side Management (SSM) and Demand Side Management (DSM). Since SSM comes at twice to three times the cost of DSM, it makes economic sense to employ the energy conservation techniques of DSM. This paper will explain these concepts and some of the incentives being put forward by governments and utilities to promote DSM.

Jan 1, 1995