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By I. Longson

Maintaining control over underground environmental conditions in the United Kingdom is increasingly dependent on the contribution of underground booster fans. Given the recent trends of higher rates of production from a fewer number of coal faces with higher levels of mechanization and higher power consumption, the effect has been to place a greater load on the mine ventilation system. This has increased the scale of potential problems that may arise should any of the main ventilation control devices not perform at the required full duty. This is particularly true for underground booster fans. Major changes occur in the main ventilation parameters on the stoppage or restart of a booster fan which results in a temporary loss of environmental control. This paper analyzes the impact of such events and details a mathematical model thar has been developed for a single-mesh circuit containing a main and a booster fan. Predictions based on this simple model are presented and discussed with particular reference to the energy changes occurring within the ventilation system immediately following a booster fan stop or restart

Jan 1, 1995

By Arthur P. Chaves, Lauro S. Norbert Costa, Adão B. Da Luz

A series of bench-scale bleaching tests have been carried out on kaolin samples from the Rio Capim area( northern Brazil) at CETEM/CNPq. The whole sample has been homogenized and submitted to particle size separation, when the + 44 µm fraction has been discarded, prior to being bleached. The main objective of this series of tests has been to evaluate the possible effects of interactions among variables which are believed to play important roles in the bleaching operation on the efficiency of the process itself in terms of the brightness achieved in the final product The tests have been planned according to a classical four-variable, two-level factorial technique. The chosen variables have been the pH, sodium dithionite addition, aluminium sulphate addition and bleaching time. The study has shown that, apart of time, all other three variables are significant. None of the interactions among them have shown to be of significance. Brightness numbers close to 88 have been obtained in the products, which represents an improvement, since brightness for the non-bleached - 44 µm Rio Capim kaolin sample averages 83.

Jan 1, 1995

By D. S. McAllister, P. M. Rice, M. E. Fowler

The Westside Light Rail Project, a major 19.3-km (12-mile) extension of Portland, Oregon's light rail system, includes 4.6 km (2.8 miles) of twin 5.8-m (19-ft) diameter running tunnels, a binocular type station which, at 80 m (260 ft) below the ground surface, will be the deepest mass transit station in North America, two 9.4-m (31-ft) diameter station access shafts, and a 5.2-m (17¬ft) diameter ventilation shaft. The tunnels are being excavated by TBM and conventional rock, soft ground, and mixed-face methods. Geologic conditions, alignment, underground opening design, excavation method selection, and payment provisions for excavation and initial ground support are discussed.

Jan 1, 1995

By Y. Wang, E. Forssberg, R. J. Pugh

The coagulation of dispersed ultrafine weakly-magnetic oxide mineral particles (e.g., natural hematite and chromite) in an external magnetic field can be described by interparticle forces. Essentially, coagulation occurs when the short-range London-van der Waals interactions and the long-range magnetic forces outweigh the stabilizing electrical double-layer repulsion. Using the classical colloid chemistry theory, the various components of the potential energy for different-sized particles at a series of ionic strengths and magnetic field intensities were calculated. The results of this theoretical analysis were then related to the results obtained from experimental studies in which the magnetic field-induced coagulation of the ultrafines of natural hematite and chromite in aqueous suspensions were investigated using a laboratory-scale electromagnetic solenoid. The experimental results relate the coagulation process (as determined by magneto-sedimentation analysis) to the particle size, the slurry pH and the external magnetic field. In the magnetic fields, the maximum coagulation occurred near the pH of zero-point-of-charge (pHzpc) of the minerals (where the electrostatic double layer repulsion was reduced to a minimum) enabling the particles to enter the "primary minimum" energy sink. On the other hand, in cases where the electrostatic repulsion was not suppressed, the long-range magnetic forces enabled coagulation to occur in the "secondary minimum." This caused the formation of chains that appeared to be relatively stable during sedimentation.

Jan 1, 1995

By G. P. Dvoichenkova, E. A. Trofimova, M. V. Zaskevich, V. A. Chanturiya

The paper presents theoretical and practical aspects of directed adjustment of physicochemical properties (pH,Eh) and ion composition of recycle and mine water by electrochemical treatment. Treatment is run in the conditioners of diaphragm-type with production of alkaline catholyte of pH value up to 12 and acidic anolyte of pH up to 2. In process of water electrolysis the directed motion of Mg2+ and Ca2+ ions is observed from anode volume to cathode one, were they precipitate as hydroxides and carbonates; it leads to decrease of salt content in anolyte and catholyte. The anolyte has been concentrating anions, it is being saturated with oxygen, which reaches 20-35 mg/L. The results of experimental and industrial testing of electrochemical technique for mine and recycle water in flotation of diamond-containing and sulphide-scheelite, hematite, phosporite, apatite-nephelite, bauxite ores indicated the increase of recovery up to 2-1 5% and grade up to 0,5-2%, concurrent with decrease of reagent consumption from 15 to 50 %. Modules of industrial conditioners of different type capacity have been developed.

Jan 1, 1995

By Hugo J. Garcia, M. C. Fuerstenau, D. M. Lupan, J. L. Hendrix

Biodegradation of cyanide by microorganisms isolated from solids previously exposed to cyanide has been investigated. The anaerobic cyanide biodegradation showed good, short-term removal of cyanide in the presence of nutrients (medium A). This system retained metabolic activity at cyanide concentrations up to 300 ppm at pH 10.5. Microscopic examination of stained specimens revealed that the bacteria were Gram-negative, rod-shaped bacilli. Strains capable of cyanide decomposition were identified as Pseudomonas and Alcaligenes. The kinetics of biodegradation were found to be first order with respect to cyanide concentration, and the overall reaction rate constant is k = 0.102 day-1. Studies with Na14CN showed that 17 % of 14C transformation went into the cells, 18 % into carbonate and 47 % into bicarbonate.

Jan 1, 1995

By Robert J. Timko, Lincoln Derick

This work is a follow-up to previous research that attempted to predict the location of spontaneous heating episodes in underground coal mine pillars. The objective of the original work was to see if the data obtained by commonly used detection methods could accurately predict spontaneous combustion episodes in coal pillars. Data accumulation during the study was enhanced when a spontaneously generated fire occurred within one of the pillars being examined. The fire provided researchers with realistic data that could be used to determine if fire prediction was possible. Results from the initial study found that the atmospheric status equations that were used provided little advance notice that combustion would occur where it did. This study reevaluated the accumulated data by applying it to recently developed equations and compared these results with previously obtained information to determine if a combination of these techniques could more effectively predict impending combustion.

Jan 1, 1995

By K. N. Han

The dissolution kinetics of cobalt in iodine/ iodide solutions were investigated using a rotating-disc technique. Variables studied included temperature, rotating speed, concentration of lixiviants and the pH of the solution. The overall dissolution reaction appeared to be limited by the mass transfer of tri-iodide through the diffusion boundary layer with an Arrhenius activation energy of <16.2 kJ/mol (4 kcal/mol) over the temperature range of 2 to 42ºC. The pH of the solution had little effect, as long as the pH of the solution was <8. However, when the pH of the solution became >8, the dissolution rate decreased dramatically, due to passivation. The rate of dissolution was in good agreement with the dissolution model developed by the authors earlier.

Jan 1, 1995

By Silvia H. M. Grimaldi, Afonso H. Martins

The scope of this experimental work was to study the yttrium extraction and stripping behaviour in a solvent extraction system with mono(2-ethylhexyl)2-ethylhexylphosphonic acid (IONQUEST 801) in a chloride system The study was performed for only one contact between organic and aqueous phases The experiments were carried out according to a factorial design. Due to the statistical analysis and its experimental proof, the optimum conditions for maximum yttrium loading into the organic phase of the extraction stage were 16 minutes for time of contact between phases, 980 rpm of stirring intensity and pH=2.3 for the aqueous phase of the sovent extraction system. The optimized experimental conditions by the statistical approach for the stripping stage were: time of contact between phases equal to 20 minutes, 1050 rpm of stirring intensity and 1.75 M HCI into the stripping aqueous solution.

Jan 1, 1995

By F. Gray

Diamond tool fabricators expect strong growth in most applications for 1995 and 1996. Overall growth projects range from 8% to 10%. Diamond grinding is forecast to grow between 5% and 8%, while cubic boron nitride grinding should grow between 10% and 12%. A strong automotive industry is a major factor in this projected growth, as is continuing demand for other durables

Jan 1, 1995

By Shelley M. Burg, Dennis K. Poulton, Robert B. Gordon

This project includes the excavation and concrete lining of approximately 18 900 m (62 000 ft) of 5.5 m (18 ft) finished diameter subway tunnel for the Los Angeles MTA. The project required that four soft ground headings be excavated from a single shaft located near the mid point of the tunnels. The tunnels were classified "gassy" during the excavation phase. Because of the contract schedule requirements and the limited urban work site available, many logistical problems had to be overcome during the project while excavation was accomplished at a record setting pace. Some unique project features include the muck handling system and an access shaft using a high strength tieback support system. In order to accomplish the work, an extensive effort to plan and construct the main work site was required.

Jan 1, 1995

By S. Kmet, A. Nguyen-Van, H. J. Schulze

The P/B collision and attachment interactions in fine particle flotation have been quantitatively analyzed. New models for attachment probability and kinetics of ‘true flotation’ have been developed. The results are given for both a single bubble and a bubble swarm. The mechanism of the attachment event is also examined. It is shown that (i) impact collision mechanism and rolling mechanism can be ignored in actual fine particle flotation and sliding mechanism is of importance for attachment of particle onto the bubble surface (ii) the attachment probability of fine particles is independent of bubble size and determined by the kinetic measure induction time of hydrophobicity. The theoretical predictions are also compared with the experimental data.

Jan 1, 1995

By Ching Wu, David A. Sutter, Peter Frobenius

The MUNI Metro Turnback (MMT) Project includes a 256 m (840 ft) twin tunnel section, which connects to the Embarcadero Station, and runs under Market Street in San Francisco. The tunnels go through a mixed face condition of fill at top and Bay Mud at bottom, and a significant number of buried timber piles. This paper presents the selection of tunneling equipment, excavation methods, excavation support and chemical grouting; specification of timber pile cutting methods; and steel lining analysis and design. This paper also reports on the initial phase of the tunnel construction.

Jan 1, 1995

By G. D. Hood, B. E. Davis

A fundamental study of the mechanisms involved in the conditioning of coarse Florida phosphate has led to some interesting discoveries. Studies by the US Bureau of Mines have shown that conditioning time and mixing intensity greatly affect the grades and recoveries of the phosphate minerals and quartz in the rougher concentrate. In particular, as the conditioning time or mixing intensity increased, the phosphate recovery remained constant while the amount of quartz floated decreased. This phenomenon is contrary to conventional wisdom and could lead to a more efficient coarse flotation circuit.

Jan 1, 1995

By N. Piret, B. Shoukry, S. Buntenbach

Traditional or artisanal goldmining, also known as small scale goldmining, has a strong and probably a negative environmental impact. The processing methods applied are very frequently a source of severe pollution due to the emissions of mercury by the extraction of gold by means of amalgamation as well as the emissions of cyanide through cyanide leaching of gold bearing ores. The emissions find their way into the environment and contaminate soils, sediments, water and atmosphere. Abnormal concentrations of mercury and cyanides in waterways are known to occur year after year destroying irreplaceable regions of the world. Mercury and cyanide compounds are highly toxic and may directly create permanent damage to the whole ecosystem. Existing methods for recycling of mercury and for decontamination of mercury and cyanide contaminated tailings are not customary applied in small scale mining and are ineffective as well. Based on investigations of traditional and small size goldmining, this paper presents: -processing methods of gold and discarded tailings under consideration of environmental protection; -figures on actual situation; -recommendations for equipment; -some decontamination methods for mercury and residual cyanide. Mineral Processing methods in traditional gold mining Gold is usually existing in its ores as the metal alloyed with metallic silver and perhaps copper. The element may occur in the form of: -native gold -inclusions also of microns or submicroscopic size metal sulfides (auriferous) such as pyrite, pyrrhotite, stibnite, arsenopyrite and galena -combined as telluride or sulphotelluride. The separation process selected depends on whether the gold can be freed from its unfavorable associations (e.g. gangue) at a sufficiently coarse grain-size, or whether it is carried in a heavy sulfide which can be freed similarly. The usual practice is to concentrate the goldbearing mineral at a relatively coarse grain-size and to regrind the ore if necessary. The gold content is concentrated by secondary or tertiary gravital methods or is extracted by chemical methods (amalgamation, cyanidation etc.) Gold, even when of fine grain-size, settle readily due to its high specific gravity from pulps in which the main gangue mineral is quartz or silicates. Amalgamation is the process of separating gold and silver from their associated minerals by binding (entrapping) them into a mixture with mercury. The cyanide process is applied to separate gold or gold-bearing compounds by dissolution from the finely ground ore (CIP, CIL, RIP), or as heap leaching. The dissolved gold is separated from the solids and the metal-rich or pregnant solution is then treated to recover its gold. Gold is also recovered by flotation methods. This process is widely used in treating base metal ores and in separating various sulfide components of ores, as well as in removing the barren gangue. The gold usually associates with a specific product in a sequence of flotation operations and is recovered subsequently in the smelting of the sulfide concentrates and refining of the metallic products, or by cyanidation of the roasted concentrates. Froth-flotation can be applied to separate gold and sulfide minerals from a finely ground pulp. The Amalgamation Process Amalgamation is the main method for the recovery of gold in traditional mining and is applied for the extraction of gold from placers as well as primary ores. The mineral technology used depends on the nature of ore deposits. In winning gold from solid ore, the matrix of minerals and rocks must be crushed and ground to sufficient fineness to liberate the gold. The liberated gold could be treated similar as free gold from placers. Gold is mainly separated from the valueless gangue (barren rock) by utilizing the difference between the density of the impure native metal (density about 16-19) and the gangue (density about 2.5). In simple operations the material is carried by a stream of water down a sluice generally equipped with small transverse barriers (riffles) against which the gold collects. The riffled sluice is the principal device used by artisanal gold miners. Nowadays, spirals as well as centrifuges, such as Knelson separator or Falcon separator, are occasionally applied for gold recovery. Gold may also be recovered from the pulp, by passing it over corduroycovered tables that catch the heavier particles - a method maybe as ancient as gold mining itself. In history, sheep skins were used to catch gold particles in this manner. Furtheron, gravity separation of gold is practiced on jigs, hydraulic traps, shaking tables and

Jan 1, 1995

By Daniel Hodouin, Claude Bazin, Sami Makni

A method is proposed to perform on-line data adjustment and inference of unmeasured variables, using measured flowrates and on-stream assays in mineral processing plants. The algorithm minimizes a weighted sum of squared residuals of the measured variables and squared species imbalances around the flowsheet nodes. The method is based on a trade-off between the material transient accumulation, evaluated by the imbalances, and the data inaccuracies, evaluated by the residuals (i.e. the adjustments brought to the measured values). A recursive algorithm is developed for on-line implementation of the method. It is a real-time extension of the hierarchical method for balancing steady-state data for bilinear mass conservation constraints. An illustration for a simulated flotation circuit is provided.

Jan 1, 1995

By K. N. Han

The adsorption of gold onto activated carbon in iodide solutions was studied. The adsorption rates were determined as a function of temperature, salt concentration and pH, as well as activated carbon concentration. A kinetic model was developed for the adsorption. The adsorption rate was believed to be controlled by a combined mechanism of film diffusion and pore diffusion with the film diffusion having the most significant effect. Experimental findings were in good agreement with the model developed. The apparent activation energy was found to be 14.9 kJ/mol.

Jan 1, 1995

By R. L. Andrew

The southwest Pacific has produced at least four of the world’s premier porphyry copper-gold deposits, and the current level of exploration is likely to produce even more. An appreciable amount of gold is being produced with this copper, with obvious economic advantages. Gold content, in addition to their large size, makes the southwest Pacific’s porphyrycopper-gold deposits very attractive exploration targets. The recognition of telescoping and overprinting of porphyry systems has produced a greater awareness of the likely surface expressions, in particular the significance of advanced argillic lithocaps in porphyry exploration. The recognition of the spatial and genetic association of porphyry copper and epithermal gold systems (Sillitoe, 1972), as in other parts of the world, has had important implications for exploration in the Asia Pacific region.

Jan 1, 1995

By F. M. Doyle, S. Duyvesteyn, K. Sreenivasarao

Toxic metals entering surface or ground water from sources such as metal finishing shop spills and abandoned mines can pose a significant threat to public health and the environment. Ion flotation and similar foam separation techniques show great promise for treating dilute, metal-contaminated solutions, and could also be used to treat effluents from many minerals and metallurgical processing operations prior to discharge. In ion flotation, an appropriate collector is added to the solution to form hydrophobic complexes with the metal ions. These metal-bearing species are then removed by flotation, usually with trace addition of a frother to stabilize the foam. In an effort to better understand the underlying scientific and engineering principles that determine the performance of ion flotation, the removal of Cu(II), Pb(II), Cd(II), Cr(II) and Cr(VI) has been studied using laboratory scale flotation columns in batch mode. The effects of the superficial air velocity, solution and froth height, nature of the collector, collector: metal-ion ratio, ionic strength and several frothers at low concentrations on the flotation kinetics are reported. Finally, results are presented on methods that might allow regeneration of collector and recovery of by-product metal from the foam product.

Jan 1, 1995

By Viacheslav Lyakhov, Cornelis H. Iestra, Victor I. Beloborodov, Vitaliy Bogdanovich

The results of a study and effective use of flotation for processing of ores with complex mineral composition containing fine-disseminated minerals with high specific density are presented in the paper. The object of research was complex baddeleyite-containing ore from Kovdor deposit (The Kola peninsula, Russia). Baddeleyite is a valuable, rare mineral, natural Zirconium dioxide with 5.8 - 6.0g / cm density, grade content 0.15 - 0.17 and dissemination less than 0.2 mm. The authors carried out a thorough investigation of baddeleyite- containing products selected in different sites of gravity flowsheet. It was determined that due to similar specific weight some sulphide minerals (pyrite, pyrrhotite) come into concentrate together with baddeleyite and, also, minerals of pyrochlores group (hatchettolite). The results obtained revealed the possibility of use the flotation for retreating rough baddeleyite concentrate. he given gravity concentrate has a number of specific features, e. g. high density of its minerals which, in its turn, provides for high speed of sedimentation of solid phase in pulp, and for the presence of large amount of sulphide minerals (up to 10%) having good flotability. With these features being taken into account a technology for flotation of baddeleyite-containing products after their preliminary gravity concentration has been developed (up to 5 - 10% Zirconium dioxide). The technology has three flotation stages. At the first one the reverse flotation of baddeleyite is carried out during which "light" minerals (forsterite. apatite and carbonites) come into froth product and at the second one flotation of sulphide minerals and at the third one direct flotation of baddeleyite is performed from the underflow product. The following reagents were used for flotation: of phosphate type (sodium tripolyphosphate, mono and diethers of alkylphosphpric acid) and sodium xanthate as collector for sulphides. The given set reagents provides for high effectiveness of flotation due to selective of collectors and presence of froth layer with high carrying ability. New flotation technology of recovering of baddeleyite from complex ore was developed and applied at the Kovdor Mining Plant, using AKER flotation machines.

Jan 1, 1995