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By Joyce A. Ober

Minerals for electronic and optical uses divide easily into two sections: 1) quartz and 2) minerals other than quartz. QUARTZ The properties of quartz crystal that make it useful for radio communications were discovered in 1918. Since that time, an in¬dustry for the mining and processing of natural quartz crystal has grown, matured, and been almost entirely replaced by new tech¬nology. The new technology still involves quartz crystal, but ma¬terial that is grown rather than mined. An economic summary of the commercial growing of quartz crystals has a place in a handbook directed to the mineral engi¬neering industry because quartz crystals have long been an impor¬tant commercial mineral, and the raw material for cultured quartz - ¬that is to say, quartz crystals grown through the ingenuity of man - is still natural quartz. Nearly all the natural crystals that have been used for elec¬tronics and optics came from Brazil. The larger pieces which met rigorous standards of quality were used for electronic and, to a lesser extent, optical components. Smaller pieces and fragments were used for vitreous silica. The need for high quality material in quantity led to US government sponsored research and exploration programs in the 1940s. No deposits meeting the very rigid requirements for electronic-grade quartz were found, but other projects resulted in the development of a process for the factory growth of beautiful crystals of prescribed shape, size, and quality. Domestic deposits of appropriate quality were identified to use as raw materials for the quartz culturing process. The development of the cultured quartz crystal illustrates the success that technology can have in adapting a product of the mine to increasingly sophisticated uses. A remarkable achievement per¬haps, but foreshadowed by experiments by Giorgio Spezia (1908), an Italian geologist studying the relative effects of temperature and alkaline environment on the solubility of quartz. Modem radio equipment is most often controlled as to fre¬quency by the presence in the circuit of a separately added crystal¬ - the 1918 discovery responsible for the existence and growth of the quartz industry. The crystal is quartz, but this component is a carefully oriented and prepared slice from a crystal, but not a crystal as recognized by a rock hound or seen in a museum. How quartz operates to control frequencies is not a proper subject for a handbook on industrial minerals, and references should be consulted (Cady, 1964, Mason, 1964). Quartz belongs to a class of materials called dielectrics: those that do not conduct an electric current but permit electric fields to exist and act across them. Quartz shows the piezoelectric effect, which means that when a quartz plate is mechanically deformed against its natural stiffness, one of its surfaces becomes negatively charged, the other positively charged. When the plate is released quickly from the stress, the charges disappear as the plate regains its original shape, but because of mechanical momentum the plate deforms in the opposite direction (to a lesser amount) and the surfaces correspondingly become charged in the opposite direction. By thinly coating the two surfaces with metal and attaching flexible wires, these charges can be brought into an electronic circuit. If the surfaces are suddenly electrically charged by movement of current through the wires, the converse piezoelectric effect occurs and the plate deforms. Carry the thought further and it is realized that an alternating current flowing through the wires responds to the mechanical oscillation. By controlling the thickness of the plate, its mechanical vibration frequency can be varied through a wide range. One type of quartz plate, the AT-cut, has a precisely defined orientation with respect to the crystallographic axes of the crystal and vibrates on a microscopic scale much as a book would deform when placed flat on a table and the top cover moved parallel back and forth with the hand. At least 17 other orientations have been studied, some of which have preferred uses in various applications (Cady, 1964). The quartz crystal industry is composed of three main segments (excluding fused quartz and quartz used for optical purposes): 1. Natural electronic-grade quartz crystals. Mined quartz suitable for fabrication into piezoelectric units. Zlobik (1981a) esti¬mated the waste to ore ratio at 1:1000 to 1000 000, depending upon the deposit. 2. Lasca. Mined quartz usable as feedstock in the production of cultured quartz. Approximately 0.63 kg of lasca are required to produce 0.45 kg of cultured quartz. 3. Cultured quartz. Cultured quartz is produced from lasca feed¬stock in a process of crystal growth in an autoclave under conditions of heat, pressure, and time. It is estimated that 0.45 kg of cultured quartz is equivalent to 1.4 to 4.5 kg of natural quartz crystal in yield of commercial quartz suitable for slicing into piezoelectric units. The chronology of the development of the quartz crystal industry both natural and cultured follows: Date Comment 1918 Discovery of the piezoelectric effects of quartz crystal 1921 Application of the piezoelectric effects of quartz crystal in the circuitry of radios 1948 Establishment of a quartz crystal commodity stockpile by the US Government 1952 US consumption of natural quartz crystal at an all time high of 228 t 1958 First commercial production of cultured quartz crystal 1970 Cultured quartz crystal production exceeds imports of nat¬ural quartz crystal 1971 Cultured quartz crystal consumption surpasses natural quartz crystal consumption

Jan 1, 1994

By D. R. Nagaraj

Literally thousands of new flotation agents, both collectors and modifiers, have been proposed for sulfide and non-sulfide flotation over the past six decades since the beginning of the use of soluble surfactants in flotation. In stark contrast, the number of flotation agents used in practice is small. Xanthates and fatly acids, along with a few well-recognized modifiers, dominate the industry. Three major questions will then arise: a) are there truly specific needs in the industry that call for chemistries that are different from those used currently ? b) if yes, given the track record in the industry, what is the likelihood that such different chemistries will ever be used and to what extent ? and c) is more research into developing new chemistries necessary ? A critical assessment of flotation agents in general is made in this paper to provide answers to these questions and to identify the major factors that are responsible for the large disparity that exists between flotation reagent research and commercial usage.

Jan 1, 1994

By P. A. Hendricks

The surface coal mining industry in the United States employs over 50,000 people and is responsible for 60% of domestic coal production. This represents a very significant contribution to our national economy and an important source of highly skilled and well paying jobs. The U.S. Bureau of Mines (USBM) has targeted surface mining as an important research priority to reduce the social and economic costs associated with surface mining injuries and fatalities. USBM safety research focuses on the development of technologies that can enhance productivity and reduce mining costs through a reduction in the number and severity of mining accidents. This report summarizes a number of completed and ongoing research programs that address a broad range of surface mining safety problems. Research methods are described, and research products which are suitable for industry implementation are highlighted.

Jan 1, 1994

By G. V. R. Landman

In order to obtain a better understanding of the explosion risk at the coal face, anomalies in the ignition sensitivity for different modes of ignition of hybrid mixtures of dust, methane and air were studied. Results indicated that the explosible behaviour of the working environment is highly dependent upon the ignition source and the fuel composition. For example, depending on the ignition source, the same hybrid mixture can be inert or extremely explosible. In conclusion, it is stressed how the explosion risk can be expressed in terms of a safety factor which takes into account the influence of both the fuel and the ignition source.

Jan 1, 1994

By J. W. Devon

The coal mining industry is divided into two distinct economic segments based on Coal Supply Agreements. Coal supply agreements generally fall into two categories, spot or long-term, with the selected contract term being driven by the buyer's market expectations, security of supply considerations, fuel tonnage and quality requirements, and economics. Short-term or spot coal purchases are generally market driven and are highly competitive in today's marketplace. Long-term contracts, particularly those involving captive mines and mine-mouth power plants, are commonly driven by considerations other than economics. These other considerations, such as Reserve Conservation and Resource Recovery, Security of Supply, and Maintenance of Levelized Costs may increase the cost of coal, often needlessly and without benefit to the buyer or seller. The basic economic principles which guide the market driven metals industry and generally guide the spot coal sector of the coal industry should apply equally well to the long-term coal supply contract. The artificial constraints imposed as a result of regulated rates of return should be re-examined and in most cases, abandoned. There are many methods of surface and underground coal mining being used today such as, open-pit, contour, mountaintop, and area mining for surface mineable reserves; conventional, standard continuous and super-section continuous miners, and longwalls for deep reserves; and highwall miners, thin seam miners and augers in between. This discussion is primarily directed to surface mining, however the same principles of least cost mining on a Net Present Value basis must be considered in all cases.

Jan 1, 1994

By G. Pan

Although geostatistical techniques have been widely accepted as the standard methods for reserve calculations in the mining industry, the production data of many mines frequently differ from geostatistical estimations based on exploration and development drilling. The discrepancies in recovered metal amounts, commonly in the range between 10% and 30%, are related to different factors. Major causes vary from mine to mine. A common cause, however, is the ignorance of important geological constraints in reserve modeling. Three major factors appear to be related to such an unfortunate fact: 1) modelers are over-confident on geostatistical techniques, 2) it is difficult to establish geological models, and 3) mine schedules are too tight to allow detailed geological modeling work. Defining mineralization envelopes has been a major effort in geological modeling. Past experiences have showed that geological modeling is much mo~ demanding than the choice of sophisticated kriging estimators. Since building envelopes for complex ore bodies can be extremely tedious and time-consuming, computerized approaches are badly needed for mine modelers. A comprehensive procedure reported here is referred to as probability-assigned constrained kriging (PACK), which includes a built-in method for defining 3-d mineralization envelopes. The modeling technique is fast and accurate for complex precious metal deposits. The technique is demonstrated on a gold deposit. The estimation results are compared with blast-hole based production panels, showing that the estimated tonnage is 2.2% larger than the actual production and the average grade is 2.6% lower.

Jan 1, 1994

By J. Stachurski, N. A. Abdel-Khalek

The objective of this investigation was to compare the results of countercurrent, column cell flotation vs. conventional (mechanical) cell flotation for the cleaning of a sulfur ore (-0.5 mm, 27.43% S) and its discrete size fractions. The tests were carried out using diesel oil as a collector and alcohol as a frother. Generally, column flotation produced concentrates of higher grade. For example, column cell flotation produced a nonwashed concentrate of 65.3% S with a recovery of 84.1%. However, conventional cell flotation produced a rougher concentrate of lower grade (57.0% S) and higher recovery (92.5%). At a superficial-wash water velocity of 0.265 cm/sec, the column product grade increased to 76.4% S, with a slightly lower recovery (80.3%). However, a concentrate with a similar recovery but a lower grade (74% S) than that of the washed product was obtained after three cleaning stages with the conventional cell. The column gave superior results for the flotation of fine and ultrafine particles.

Jan 1, 1994

By K. S. E. Forssberg, J. A. Jirestig

Laboratory investigations on the possibility of using magnetic separation for the recovery of sulfide minerals have been reported. A survey of several sulfide ores and flotation concentrates indicated that, in most cases, magnetic separation is not a suitable primary beneficiation method. However, encouraging results have been obtained in concentrate purification. At the Boliden complex sulfide ore concentrator in Garpenberg, Sweden, an Allis-SALA Mark III carousel High Gradient Magnetic Separator (HGMS) is used with a small flotation circuit to recover sphalerite lost to the galena concentrate during lead flotation. After four years of refining the HGMS process, there has been an increase in zinc recovery and an enhancement in the quality of the lead concentrate.

Jan 1, 1994

By R. Flores V.

The Refugio Project is located in the Andes mountains of northern Chile, in the Maricunga Hineral Belt. The Verde, Pancho and Guanaco Au ore bodies have been recognized and are Early Miocene in age. Mineralization consists of fine-grained disseminated gold hosted by dacitic to dioritic subvolcanic porphyries. Alteration comprises massive to veinlet-controlled silicification overprinted on earlier potassic and propylitic alteration and surrounded by later argillic alteration. Geologic relationships suggest that the Refugio ore bodies occur within an Early Tertiary volcano overlying Paleozoic and Mesozoic basement rocks. Geologic reserves at Refugio are approximately 300 million grams (9.7 million ounces) of gold. The Verde deposit contains 185 million tonnes of mineable and leachable ore with an average grade of 0.90 glt Au and is currently in the pre-construction stage after a positive feasibility study. Proven and probable mining reserves at Verde deposit are 101 million tonnes at an average grade of 1.02 glt gold. Additional potential exists at to other deposits within the Refugio property (Pancho and Guanaco) but no reserves have yet been defined due to the limited drilling to date.

Jan 1, 1994

By G. Bonifazi

The study of minero-petrographical characteristics and the subsequent textural and structural characterization of an ore mineral represents the first step of each industrial processing whose aim is the beneficiation of each valuable mineral phase present inside the ore. Analytical, mineralogical and petrographical, chemical and multispectral image analyses based investigations, applied to eclogitic ore samples deriving form "in situ" sampling campaigns, were applied. These procedures enabled to point out some textural and structural aspects characteristics of ore litotypes belonging to eclogitic-amphibolitic dikes. Such dikes are characterized by a paragenesis constituted mainly by siliceous gangue and accessory "useful titanium minerals" as rutile [TiO2], "pseudolilmenite", ilmenite [FeTiO3] and sphene [CaTiSiO5]. In the beneficiation process applied to ore s is of preliminary importance to establish a strategy in order to obtain a recovery of high quality "mono-minerals concentrates" as rutile, "pseudolimenite", ilmenite and phene. To reach this goal is thus necessary to develop a preliminary study of the textural, structural, petrochemical and minerochemical characteristics of the samples. Different ore samples (eclogitic rocks), resulting from sampling campaigns carried out in the Piampaludo area (Sassello district: Savona, Northern Italy), are examined.

Jan 1, 1994

By G. Plenge, M. Diaz

Silver-bearing, bulk sulfide concentrates from several Peruvian mines were autoclaved in a l9-L (5gal) laboratory autoclave in Lima, Peru. Cyanidation of autoclaved concentrates, following a hot lime jarosite destruction step, extracted more than 98% of the silver and more than 95% of the gold. Autoclave operating parameters, such as time, temperature, pulp density and autoclaved solids recycle, were investigated and reaction rates determined. The problems of excessive heat generation, silver solubility during autoclaving and formation of pellets containing unreacted sulfides were addressed. The data presented will be used to design a continuous autoclave pilot plant to provide reliable scale-up data for a 50 to 100 t/d (55 to 110 stpd) facility.

Jan 1, 1994

By J. A. Porter

This paper uses project examples, primarily associated with large iron ore mines in Brazil, to demonstrate opportunities for the mining industry to go beyond traditional compliance and impact mitigation to proactively operate within the ethics of environmental and economic sustainability.

Jan 1, 1994

By J. Pang, S. Chander, A. Briceno

The mechanism of sulfur oxidation in pyrite is a function of the rate and driving force for oxidation. New evidence is presented to show that, at moderate potentials, a sulfur-rich hydrophobic layer is formed. Under ordinary conditions, the sulfur layer is covered with a layer of iron oxides, hydroxides, sulfate or oxy-sulfide ions. Pyrite is hydrophilic under these conditions. In the presence of iron-chelating agents or iron sequestering ions, an iron layer might not form. Under these conditions, the sulfur layer is exposed, and the pyrite might become hydrophobic. Stronger oxidizing conditions decompose the sulfur layer, thereby making the surface hydrophilic.

Jan 1, 1994

By Betty L. Gibbs

What does the information age mean to mining companies? The perception of greatly increased access to information is based on modern communications through ‘smart’ fax machines and computer networks. Computer media allow us to `talk' to the President or to a sister in Australia. If we need data to help put together a mining permit, we can find that data somewhere on computer media. The vast amount of easily accessible information quickly overwhelms us. To avoid `information burnout,' we must learn to target searches and be able to discriminate between dross and information that is useful to our goals. If you watch commercial TV, you have learned to screen out most product commercials. A similar screening process must be applied to computerized information sources. You may need to sort through a lot of irrelevant information before finding the pearls you are looking for. ‘Smart’ fax machines can send information with no direct human intervention. MINES FaxBac, for example, from the US Bureau of Mines instructs you to enter four-digit numbers to have particular reports sent directly to your fax machine. Software vendors use a similar system to supply information about their products. You select an item by number, and the related brochure is faxed to your machine. To compete, the industry must maintain access to as many information sources as possible. The availability of computers and software for almost every conceivable application allows us to accomplish work faster than we ever thought possible, even as recently as 10 years ago. Most mining companies have become aware that doing geology, reserves, mine planning and other technical tasks completely by hand is much too slow. The world moves faster, drilling happens faster, mining happens faster, all related activities happen faster. We no longer have the manpower or time to keep all maps. calculations and records up to date.

Jan 1, 1994

By W. C. Lacy

It is the responsibility of educators to look ahead and prepare young engineers and scientists to cope with industrial and social problems of the future. We are faced with a review of history as well as prophesy of the future. The mining industry exists in a "bubble" with little interaction or communication with the outside. This isolation must be broken down if the industry is to survive in the U.S. and Canada. The ability to communicate with the general public and public officials is essential. Many changes are occurring that will require readjustments in technology and staffing. Aging population will result in raising retirement and increasing available workforce. This may force shorter working weeks to supply additional jobs. Environmental concerns will likely direct more attention not only to these concerns during mining, but to planning for post-mining land usage. Retraining and up-dating educational programs are required to cope with these changes.

Jan 1, 1994

By L. M. Pruett

The Arizona Legislature is currently in the process of considering mined land reclamation legislation in the 1994 legislative session. A bipartisan legislative study committee has drafted proposed mined land legislation. The committee has attempted to craft legislation that is appropriate for the unique conditions in Arizona. Existing Arizona and federal laws and regulations extensively regulate the environmental performance of mines in the state to protect public health, safety and the environment. The proposed mined land reclamation legislation does not replace or duplicate these statutory provisions relating to environmental protection. Instead, the purpose of the proposed legislation is to provide for the reclamation of land that is being mined and to fill the gap in existing laws by requiring the reclamation of land that currently is being mined or that has been mined since 1986 to provide for future land use. The legislation would require an operator to submit a reclamation plan describing the exploration operations, mining operations, post-mining land use and the proposed reclamation measures for review by a state agency. Financial assurance also would be required in an amount such that a third party could complete the approved reclamation measures. Arizona's mined land reclamation legislation would recognize Arizona's leading role in hard rock mining and emphasize the mining industry's economic importance to Arizona and the nation. Because mining operations necessarily require disturbing the surface of the earth to extract valuable minerals, reclamation requirements would be adapted to different conditions and would vary depending on site-specific conditions and on the commodity being mined. The current proposal does not identify the state agency that will administer the mined land reclamation program and approve reclamation plans, substantial changes to plans, and transfers of reclamation plans to other operators.

Jan 1, 1994

By T. P. Meloy

Like our wives, the comminution of brittle solids is easy to recognize but difficult to describe. However, describing it we must. Describing the fracture mechanism of brittle solids permits the eventual mathematical quantification of the results, process optimization and control strategies. This paper presents a physical model of brittle solid comminution that explains why the slope of the log-log size distribution curves have a slope of one or less in the smaller particle sizes. To develop the hypothesis, modifications of the Gaudin Meloy physical model are made. In brittle solids, comminution takes place by cracks propagating through the material. These cracks may bifurcate as they move. Cracks may terminate either on the original surface of the material, or on a secondary crack within the material formed earlier in the comminution process.

Jan 1, 1994

By Haydn H. Murray

Common clay includes a wide variety of clay and other fine- grained rocks that are used in many ways. These clays are some- times classified as miscellaneous clay and shale. Most products made from them are fired and include such things as structural and face brick, drain tile, vitrified pipe, quarry tile, flue tile, conduit, pottery, stoneware, and roofing tile. Very large tonnages of these materials are bloated by firing to form lightweight aggregate, and large quantities are used in making portland cement (see the specific chapters in this volume). Uses not requiring firing of a finished product include filler for paint and other products and shale and clay used for packing dynamite in blastholes and for plugging oil and gas wells that are no longer in use.

Jan 1, 1994

The initiation of a panel cave is an extremely important and infrequent event in the life of a large underground caving operation. A new cave was initiated at the Henderson Mine in 1991, 15 years after its first cave had been developed in 1976. The original cave was started after a half billion dollars had been invested in the development of the mine, mill and 23 km haulage system. Many things had changed since 1976, the most significant of these being much lower realizations for molybdenum. In 1976 the high demand for molybdenum and uncertainty of caving characteristics, formed the basis for a very conservative cave initiation sequence with miles of boundary weakening and inspection drifting. In 1991 the highly competitive molybdenum market in conjunction with 15 years of caving experience made for a very different mining climate.

Jan 1, 1994

By Gregory R. Wessel

Sulfur is a nonmetallic element widely distributed in nature and of great physical and economic importance. It is the 14th most abundant element in the Earth's crust (0.06%) and an important constituent of animal and plant life. Sulfur has been known and used since ancient times for a number of medicinal and industrial uses. At present, most sulfur is used to generate sulfuric acid that is used in a wide variety of industrial processes, particularly the production of fertilizer. Because of this, sulfuric acid (and hence sulfur) consumption is often regarded as a good index of a nation's industrial development. In the past, sulfur was mined from surface occurrences in several geologic environments, and was used in relatively small amounts. With time, the uses of sulfur and sulfuric acid expanded, as has the need for larger quantities of these commodities. Sulfur is now mined from both surface and underground deposits, and is recovered as a byproduct from a number of industrial processes. Despite valiant efforts and years of work by sulfur explorationists and others, many aspects of sulfur mineralization remain controversial. Almost as controversial is the spelling of the word sulfur. The English spelling sulphur commonly is used outside America and in the American sulfur mining industry, but sulfur is the correct American spelling as approved by the American Chemical Society, the American Geological Institute, and many others. Those new to the American sulfur industry often find it puzzling to be reprimanded for using the correct American spelling. Sulfur resources are abundant and widespread, but the extent to which they can be classified as reserves is constrained by pre- vailing prices and extraction technologies. At present, sulfur can be economically mined from very few deposits. The sulfur industry is roughly divisible into two sectors: voluntary (or discretionary) and involuntary (or nondiscretionary). In voluntary production, the mining of sulfur or pyrites is the sole objective, and the recovery of the resource is as complete as economic conditions will allow. During involuntary production, sulfur or sulfuric acid (termed recovered sulfur) are produced as byproducts, and the quantity of the output is dictated by the demand for the primary product. Voluntary sulfur now accounts for only about 35% of the elemental sulfur produced worldwide, and most inves- tigators believe that voluntary sulfur will be less important in the future. Sulfur sources and products are described as follows (after Barker, 1983): Sulfur Sources: Combined sulfur-sulfur that occurs in nature combined with other elements, commonly referring to sulfides and sulfates. Cupriferous pyrites-pyrite containing minor amounts of cop- per sulfides. Hydrogen sulfide-a toxic gas that occurs in petroleum and natural gas. Involuntary sulfur-sulfur produced as a byproduct in response to legislative or process mandates. Native sulfur-naturally occurring elemental sulfur. Nonferrous metal sulfides-opper, lead, zinc, nickel, and molybdenum sulfides that are processed for their metal content. Organic sulfur complex organic sulfur compounds that occur in petroleum, coal, oil shale, and tar sands. Pyrites-iron sulfide minerals that include pyrite, marcasite, and pyrrhotite. Sulfate sulfur-sulfur contained in anhydrite and gypsum. Voluntary sulfur-sulfur produced in response to market demand. Basic Sulfur Products: Acid sludge-contaminated sulfuric acid usually returned to acid plants for reconstitution. Brimstone-synonymous with crude sulfur. Bright sulfur-crude sulfur free of discoloring impurities and bright yellow in color. Broken sulfur-solid crude sulfur crushed to -8 in. Byproduct sulfuric acid-sulfuric acid produced as a byproduct of a metallurgical or industrial process, generally relating to combined sulfur sources. Crude sulfur-commercial nomenclature for elemental sulfur. Dark sulfur-crude sulfur discolored by minor quantities of hydrocarbons, ranging up to 0.3% carbon content. Elemental sulfur-processed sulfur in the elemental form produced from native sulfur or combined sulfur sources, generally with a minimum sulfur content of 99.5%. Formed sulfur-elemental sulfur cast or pressed into particular shapes to enhance handling and to suppress dust generation and moisture retention. Frasch sulfur-elemental sulfur produced from native sulfur sources by the Frasch mining process. Liquid sulfur-synonymous with molten sulfur. Liquid sulfur dioxide-purified sulfur dioxide compressed to the liquid phase. Molten sulfur-crude sulfur in the molten state. Prilled sulfur-solid crude sulfur in the form of pellets produced by cooling molten sulfur in air or water. Recovered sulfur-elemental sulfur produced from combined sulfur sources (including byproduct hydrogen sulfide, but sometimes referring only to sulfur from fossil fuels) by any method. Slated sulfur-solid crude sulfur in the form of slate-like lumps, produced by allowing molten sulfur to solidify on a moving belt. Specialty sulfur-prepared or refined grades of elemental sulfur that include amorphous, colloidal, flowers, precipitated, wettable, flour, and paste sulfur. Sulfur ore-unprocessed ore containing native sulfur.

Jan 1, 1994