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By L. B. Anderson, G. A. Carmody

We wish to comment on the paper by G.W. Heunisch (MINING ENGINEERING, January 1987), which raised several important points regarding treatment of acidic waste waters. This paper confirms, in part, tests carried out by Allyn Corp. Allyn is the manufacturer of the proprietary product Alka-Ment, one of the materials that Heunisch tested. The first point is the extreme sensitivity of the sedimentation rate on the nature of the treatment material used. This apparently results from differences in nucleation of the metal hydroxides, and is consistently higher for Alka-Ment. This decreased sludge volume is also observed when Alka-Ment is combined with flocculants, such as organic polymers (see Table 1). Our second point is to emphasize that Heunisch's work shows how dependent the sludge volume is on pH. It is common practice to overtreat AMD by raising pH to 9 or 10. This practice, in addition to being wasteful of material, actually decreases the density of the resulting sludge, probably by creating charged particles that do not readily coalesce. When treating with Alka-Ment, we recommend that the treatment be monitored by testing both pH and dissolved iron. For both tests, it is important to allow adequate time to elapse between treatment and measurement, so that dissolution of alkali, aerobic oxidation of iron, and precipitation of the metal hydroxides are nearly complete. Our tests have indicated that from 30 minutes to one hour is commonly required. Only in this way can a minimum pH be attained, with adequate treatment, denser sludge, and lower treatment rates achieved. Thirdly, Heunisch correctly recognizes that ASTM titration of Alka-Ment does not reflect the true treatment value available in a unit of Alka-Ment. Our work at Allyn indicates this is a most important consideration when evaluating various materials for the treatment of acidic waste waters. While we were unaware of Mr. Heunisch's work, we welcome comparisons between Alka-Ment and any competitive products readily available for field use. Allyn has hundreds of hours of laboratory and field data we are ready to share with interested parties treating acidic waste water.

Jan 1, 1988

By Y. Ye, J. D. Miller, E. Pacquet, S. Gopalakrishnan

From laboratory research activities during the past five years, it is now evident that effective flotation separations can be achieved with the high-capacity air-sparged hydrocyclone. The effectiveness of the equipment has been demonstrated on a pilot-scale basis (1 tph) for a number of mineral commodities including coal, copper, gold, and industrial minerals using a nominal 5-cm x 50-cm system with separation efficiencies equivalent to those achieved by conventional flotation machines. The high specific capacity of the air-sparged hydrocyclone (100 to 600 tpd per cubic foot of cell volume for a nominal 5 cm x 50 cm system compared to 1 to 2 tpd per cubic foot of cell volume for conventional columns and mechanical machines) makes it especially well-suited for the pro- cessing of low-grade ore. As a result of these pilot-scale successes, a number of plant-scale test programs are planned for larger-diameter units to establish wear characteristics and scale-up relationships for design purposes. The status of the air-sparged hydrocyclone technology is reviewed in the present paper, including a description of the system, fundamental considerations of flotation mechanisms, general discussion regarding the effect of control variables, and the significance of feed characteristics.

Jan 1, 1988

By Debra W. Struhsacker, Jean Kiel, Jeffrey Thatcher

3.1 INTRODUCTION As heap leach precious metal projects become increasingly common in the United States, federal, state and local regulatory agencies are beginning to take a closer look at the short- and long-term environmental consequences of this recovery technology. From an operator's point of view, there is seemingly a confusing regulatory maze to be navigated and a plethora of permits and approvals to be obtained prior to commissioning a heap leach operation. The degree of difficulty associated with obtaining permits for a heap leach project depends largely upon the state in which the project is located. Permit acquisition is generally easiest in those states most familiar with heap leaching technology. For example, heap leaching is well understood in Nevada, and heap leach operations are relatively easy to permit, although permitting conditions in Nevada have recently become more stringent. However, many states are just beginning to become familiar with heap leach operations. Many of these states such as Idaho, Colorado, South Dakota, Oregon, Montana, Washington and South Carolina are in the process of drafting regulations and establishing guidelines for heap leach projects. In most cases, these regulations specify design and operating criteria as well as reclamation and decommissioning procedures. This chapter provides an overview of the regulatory and permitting aspects of heap leach operations. Permitting requirements for projects developed on federal land are discussed in detail. 'The state and local regulatory atmosphere and permitting requirements for various states are also presented. The chapter concludes with a generic permitting strategy. 3.2 KEY ENVIRONMENTAL CONCERNS The primary concern of most local, state, and federal regulatory agencies is the use, storage and transport of sodium cyanide (NaCn), and potential cyanide contamination of surface and groundwater resources. The toxicity of cyanide to people, fish and wildlife is also an important issue. Unfortunately, in the public eye, cyanide heap leaching has some emotional impacts similar to those associated with radioactivity and uranium mining. This perception and the general lack of understanding of cyanide can lead to unnecessary concern about cyanide contamination, further complicating the regulatory environment.

Jan 1, 1988

By D. Olsen

The paper discusses the legislative and practical approach adopted to problems of management of environment in relation to coal mining in a very sensitive area of the south coast of New South Wales. The environmental problems are complicated in this area due to multiple and very often conflicting land usages. The environmental approach in relation to water quality maintenance, noise control and air quality is discussed and methods adopted meet stringent requirements. Requirements of New South Wales Regulations on Environmental Impact Statements (EIS) are described.

Jan 1, 1988

By J. D. McKendrick

Alaska's Arctic Slope lies between the Brooks Range and Beaufort Sea and is a region about the size of Nebraska. It has some of Alaska's richest hydrocarbon deposits. In addition to containing petroleum and natural gas. Much of the area west from the Colville River has low-sulfur coal deposits which are shallow enough for surface mining. Developing those resources will require a firm and realistic' commitment to protecting and rehabilitating the natural habitats. Balancing such a commitment with economic constraints in a practical sense requires knowledge of the environment and its associated biological components, i.e. the soil/water-plant-animal relationships.

Jan 1, 1988

By W. J. Halvorsen

Means for minimizing the disadvantages of thermal drying are suggested. The other ap¬proach of substituting other techniques in place of thermal drying is also discussed. Recent devel¬opments in fine coal screening dry down to 3.2 mm (0.125 in.) and 2.0 mm (10 mesh) offer an econom¬ical means in certain cases.

Jan 1, 1988

By D. C. Moore

The decision to proceed on a "fast track" construction project is not" without risks as well as rewards. An understanding of some of the risks prior to start of the project will maximize the rewards. This paper describes the research, development, procurement, engineering and construction of the Asamera Minerals cannon Mine concentrator. This fast track project was accomplished in 20 months. Special attention is paid to the risks encountered and the steps taken to ameliorate them.

Jan 1, 1988

By J. M. Keane, C. K. Chase

Critical to successful dump and heap leaching of copper is an adequate evaluation of applicable parameters. This paper deals with methods to establish optimum conditions for dump and heap leaching copper so that commercial operations can proceed. Discussion is also offered of ore occurrences and preparations for dump or heap leaching.

Jan 1, 1988

By John B. Sabey, Vernon R. Degner

The industrial coal processing trend toward greater fines production, due to mining techniques and customer requirements for reduced ash and sulphur content in the fine coal product, is the basis for ongoing efforts to improve the performance of the flotation machine. WCO has successfully adapted the principles of the beds Column to a full size machine prototype. Recent plant evaluation tests confirmed the initial promise of this concept by achieving a considerably lower ash product while maintaining the combustible recovery level of conventional flotation machinery. The paper will include a review of the fundamental principles of the beds Column concept, together with a summary of the WEMCO R&D Program from concept evaluation and laboratory testing, through pilot, to full size machine tests. The performance of the WEMCO/Leeds flotation column will be compared to conventional flotation concepts using a flotation "kinetics" approach, which quantifies the floatable and non-floatable specie recovery performance using the Klimpel model as the basis for analysis. The variety of distinct features unique to this concept include a series of barrier rods which are used to advantage, often together with countercurrent reflux water flow, to achieve a significant improvement in product grade. The hydrodynamics associated with the mechanics of "gangue stripping" from the rising "air bubble-floatable specie" matrix will be briefly reviewed.

Jan 1, 1988

By O. Olajide, E. H. Cho

A laboratory study of the jigging process with Pittsburgh seam coal has been conducted. The laboratory-scale Baum jig used in this study was a McNally-Norton LO30X Right Hand Model Baum jig with an effective screen area of 0.186 m2 Feed material was prepared by selecting a size range from 6 mesh to 1.91 cm. Solid feed rates were 27.2 kg/min and 32.7 kg/min. Water flow rates were varied from 37.9 to 94.6 L/min. It has been found that smaller particles give higher values of density of separation and lower efficiency of separation. Increasing water flow rate increases the discharge rate of clean coal at a constant solid feed rate. It appears that the efficiency of separation increases by increasing water flow rate up to a certain value, and then levels off upon increasing the flow rate further.

Jan 1, 1988

By Daniel J. Brunner

The U. S. Department of Energy (D.O.E.) requires that the prospective nuclear waste repository in Basalt at Hanford, Washington, comply with State of California mine and tunnel safety orders. These regulations require that all main fans be installed in such a manner as to permit prompt reversal of airflow. This paper evaluates the requirement of air reversal and the appropriateness of imposing such regulations on the proposed nuclear waste repository in Basalt.

Jan 1, 1988

By Guoming Liu, Weibai Hu

The designing aspects of column profile, cross-section and height, types of aerator or air sparger, and feeding and discharging devices have been designed and tested. In operating aspects, the flotation column: has beer, compared with the conventional mechanical flotation machine in large- scale plant practice. It has been found that the reagent conditioning time and the slurry residence time required in the column are longer than those in the mechanical flotation machine. The general opinion is that the flotation column can show some effectiveness in specific cases as long as it is properly designed and carefully controlled.

Jan 1, 1988

By Ralph E. Weeks

Utilization of true in situ technologies for mining copper in Arizona will involve a complex environmental permitting process. This process is a key factor in determining the feasibility, costs, and implementing time frames required for development of this innovative mining method. The regulatory structure in Arizona is presently changing due to enactment of the Environmental Quality Act (EQA) of 1986 and development of new aquifer protection rules and regulations. The Bureau of Mines has reviewed the comprehensive hydrogeologic characterization, ground water monitoring, mechanical integrity testing, well construction, contingency planning, and other regulatory elements that will serve as mechanisms to assure protection of ground water resources. The purpose of this paper is to inform the domestic copper industry of the significance of the new Arizona regulatory structure and its implications for prospective in situ operators.

Jan 1, 1988

By M. S. Bickers

Prior to 1970, the environmental liabilities associated with mine construction and management were few. Mostly, they were aimed at health and safety matters. At that time less than two dozen codes were incorporated into the engineering design and they were somewhat static and well known by the engineering designers and managers. These codes issued by governmental agencies and professional associations are listed in Table 1

Jan 1, 1988

By R. V. Huff

An in-situ leaching technology was developed for copper oxide minerals at the Van Dyke deposit at Miami, Arizona. This paper discusses the process developed and the activities that occurred. Specifically, the activities of well installation, deposit data acquisition, leach testing and equipment development are reviewed. Installation and operation of the test facility are described.

Jan 1, 1988

By W. K. Fletcher

As part of an ongoing programme on behaviour of heavy minerals In streams, the dispersion of Au as free gold (Day and Fletcher, 1987), Sn in cassiterite (Fletcher et al, 1987) and W in scheelite (Saxby and Fletcher, 1987) have been investigated downstream of mineralization. The studies of Au and W were undertaken, in British Columbia and the Yukon Territory, respectively, in streams that are strongly influenced by spring snowmelt floods. Sn was investigated under tropical rainforest conditions in Peninnsular Malaysia.

Jan 1, 1988

By R. D. Schmidt, S. E. Follin

Introduction Mineral recovery from an in situ leaching operation is determined by the often complex interaction of hydrology, mass transport, and chemical kinetics. The operating conditions of many pilot and production scale uranium leaching operations involve heterogeneities in aquifer permeability. Differences in permeability may be naturally occurring, the result of differences in main size or cementation, or they may be induced by leaching activity. Variations in permeability directly affect the fluid flow streamline pattern, fluid flux, and so also leaching geochemistry and uranium recovery. An in situ leaching hydrology model (ISL) and a mass transport-oxidation rate model (ISLGC) have been developed for use in making site specific predictions of the leachability and productive potential of heterogeneous ore deposits, and for the optimal design of leachant injection and recovery operations. The two models are linked by output and input requirements. The ISL hydrology model generates a leachant flow streamline pattern between injection and recovery points in a flow domain incorporating regions of arbitrary permeability. The ISLGC transport model describes the changing solution concentrations of uranium and oxygen and the changing mineral concentrations of uranium and pyrite resulting from convection, longitudinal dispersion, and oxidation reactions. ISL hydrology model Basic equations The differential equation for steady-state two- dimensional flow in an isotropic porous medium is

Jan 1, 1988

By J. E. Gebhardt, P. E. Richardson

External control of the electrochemical potential of a bed of mineral particles was investigated by the US Bureau of Mines as a method for controlling particle interaction with organic collectors and, thus, flotation response. A cylindrically shaped, 200- to 300-g bed of sulfide mineral particles was used as the working electrode in an electrochemical-flotation cell. In a pH 9.2 sodium tetraborate buffer, chalcocite floated with ethylxanthate at applied potentials [=] - 0.25 V (versus the standard hydrogen electrode) ; pyrite floated at potentials [=] 0.15 V. Differential separation of a chalcocite-pyrite mineral mixture was obtained by controlling the potential, but the flotation response of the mixture did not follow the behavior predicted from measurements on the individual mineral beds. Chalcocite dissolution products had a deleterious effect on chalcocite-pyrite separation by activating pyrite so that it floated below the potential (~ 0.13 V) at which xanthate is oxidized to dixanthogen. A pyrite bed activated with a copper(II) sulfate solution exhibited a flotation response with a potential dependence between that of chalcocite and pyrite. Pyrite dissolution products had no effect on chalcocite flotation.

Jan 1, 1988

By Jean E. Kiel, Rob Dorey, Dirk J. A. van Zyl

1.1 INTRODUCTION This chapter seeks to provide an overview of important factors involved in the implementation of heap leach technology as a vehicle for gold extraction from its ores. Toward this end, brief discussions of the various elements important to this process are presented here. Topics covered in this chapter include a brief history of the process; basic chemical reactions responsible for the process ; characteristics of ores amenable to heap leaching; location of the greatest concentration of heap leach projects in the U.S.; heap leach components, methods, regulatory/permitting considerations; and economic considerations. Most of these subjects are treated at much greater length in subsequent chapters. Thus, this chapter serves as a summary for those which follow, in addition to providing the reader with a feeling for those topics which may be of most immediate interest. 1.1.1 History of the Process Modern Day Precious metal heap leaching technology has developed over the past decade, although the principles of heap leaching per se, as well as those of gold extraction through cyanidation have a long history (see discussion below). However, it is in the past 10 years that heap leaching has developed into an efficient method of treating oxidized gold and silver ores. It has proven to be both an efficient way to extract precious metals from small, shallow deposits, as well as an attractive way to treat large, low- grade, disseminated deposits. Heap leaching has several advantages compared to conventional milling (i .e., crushing, grinding, and agitation leaching). In general, these advantages include simplicity, lower capital and operating costs, shorter start-up times, and less intensive environmental regulatory concerns. A possible disadvantage of currently existing heap leach technology is a potentially lower percentage of metal extraction being obtained from the ore than would be the case with conventional milling (Potter, 1981; Hiskey, 1985; and Thorstad, 1987) The actual principle of heap leaching has a long history as inferred previously. For example, mines in Hungary recycled copper-bearing solutions through waste heaps in the mid-sixteenth century (Hiskey, 1985), and Spanish miners percolated acid solutions through large heaps of oxide copper ore on the banks of the Rio Tinto around 1752. By 1900, leaching operations were employing such techniques as leach/rest cycles to maximize copper recovery (Taylor and Whelan, 1942; Thorstad, 1987). Copper dump leaching is currently

Jan 1, 1988

By M. Murphy

The multibillion dollar cost of cleaning up thousands of environmentally contaminated sites across the country created by decades of inadequate disposal of hazardous waste has led to a search for "deep-pocket" sources of cleanup funds. The resul1:: is the emergence of a growing body of law that could have a profound impact on commercial financing transactions and other investment activities when present or past owners of contaminated property are involved.

Jan 1, 1988