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By G. A. Brooks

The problem of treating concentrates with increasingly higher levels of arsenic and antimony is compounded by the trend to stricter environmental guidelines regarding the disposal of smelter wastes. Much of the arsenic and antimony from non-ferrous processes is recovered as oxide fume. The options for handling these fumes include recycling them to the smelter, stabilising and disposing of them, and recovering values from them. Whilst arsenic oxide has little value, there is a market for antimony oxide and this provides an incentive for devising techniques for separating antimony oxide from arsenic oxide before disposal of the arsenic oxide. Arsenic can be separated from antimony oxide by selectively volatilising the more volatile arsenic trioxide from a mixed oxide sample or by selectively condensing the less volatile antimony tetroxide at high temperatures, leaving arsenic trioxide to condense out at lower temperatures. The results of selective volatilisation experiments at 379 to 587 °C indicate that it is difficult to achieve an arsenic content below 5.0 wt.% using air or nitrogen as carrier gas due to the formation of solid solutions between the two oxides. Injection of oxygen into a mixed vapor stream improved separation by selective condensation and antimony tetroxide containing as low as 0.23 wt.% was obtained in laboratory experiments.

Jan 1, 1994

By C. G. Anderson

Throughout the world, there are many orebodies or materials which have significant value but also contain arsenic. As regulations on the transport, exposure, disposition and emission of arsenic have become more stringent; it has become increasingly more difficult to derive the values from these resources. This paper will outline the fundamentals of alkaline sulfide hydrometallurgy and its successful application to arsenic bearing ores, concentrates and materials.

Jan 1, 2005

By Corby G. Anderson

Today, with a stringent economic and environmental climate prevailing in the copper business, there is increased interest in evaluating new processing alternatives for production. Hydrometallurgical pressure oxidation of copper concentrates is one of the more viable approaches and several technological candidates have emerged. Of these, an overlooked but, ironically the first industrially proven methodology, utilized nitrogen species catalyzation in the oxidizing pressure leach system to produce copper via SX!EW. Given its many inherent process advantages, this may prove to be a feasible process alternative for the future. In this paper, the history of the system and its application to chalcopyrite concentrates will be outlined. In particular, a novel methodology for effective recovery of precious metals from chalcopyrite concentrates will be discussed. Finally, the perceived economics of this unique industrially proven process will be delineated.

Jan 1, 2000

By Corby G. Anderson

Today, with a stringent economic and environmental climate prevailing in the copper business, there is increased interest in evaluating new processing alternatives for production. Hydrometallurgical pressure oxidation of copper concentrates is one of the more viable approaches and several technological candidates have emerged. Of these, an overlooked but industrially proven methodology utilizing nitrogen species catalyzation in the oxidizing pressure leach system may prove to be a feasible process alternative for the future. In this paper, the history of the system and its application to chalcopyrite concentrates will be outlined. In particular, a methodology for effective treatment of precious metals bearing chalcopyrite concentrates via partial oxidation at low temperatures and pressures will be discussed. Finally, the perceived economics of this unique industrially proven process will be delineated.

Jan 1, 1999

By M. Nishikawa

The Hachinohe Smelter employs the Imperial Smelting Furnace (ISF) for production of zinc and lead and handles a large number of concentrates and recycled materials. In recent years, recycled materials such as zinc-bearing materials, lead sludge and Waelz oxide have provided up to 30% of the feed materials at the plant. To allow for a satisfactory operation using such a wide range of recycled materials, the Hot Briquetting Plant was built in 1986 and started its operation in January 1987. In April 1988 the zinc production capacity of the ISP was increased from 81,000 to 101,000 tonnes per year. The additional production in the ISP has been attributed to the utilization of the hot briquetting process. This paper describes the various facts of the smelter, concentrating on hot briquetting operations and treatment of hot briquettes in the ISF.

Jan 1, 1991

By N. A. Barcza

DC plasma-arc technology using a hollow graphite electrode (cathode) has been successfully implemented in the primary metallurgical industry in South Africa up to the 30 MW scale. Mintek has applied its expertise base, established over the past fifteen years, to testing the treatment of metallurgical wastes such as carbon- and stainless-steel plant dusts, lead- and zinc-containing slags, and residues from the base-metal industry. Favourable results have been achieved, and disposable products were produced. The evaluation of numerous wastes indicates that recovery of zinc as metal gives the best economic return from these sources. Direct recovery via a splash condenser or electrolytic zinc extraction from fume are the two preferred alternatives under review. In both instances dehalogenation is an important issue, but can be achieved by suitable treatment processes. The Enviroplas technology provides a flexible, commercially viable approach to the treatment of a wide variety of wastes. Mintek, together with its associate Pyromet CC, are installing a plasma- arc pilot-plant facility with both an ISP lead-splash condenser of about 5 t/d condensed zinc capacity and a combustion chamber to burn zinc vapour to zinc oxide. This will demonstrate the suitability of the Enviroplas technology for treating specific metallurgical wastes, so that customized industrial plants can be engineered based on large-scale testwork.

Jan 1, 1994

By Carole Read

Hydrogen is under consideration by several countries for its potential as an energy carrier for transportation applications. In order to compete with vehicles in use today, hydrogen-powered vehicles will require a driving range of greater than 300-miles in order to meet customer needs and expectations. For the overall vehicular light-duty fleet, this dictates that a range of 5 to 13 kg of hydrogen be stored on-board (assuming a fuel cell power plant) within stringent system weight, volume, and cost constraints. Vehicular hydrogen storage thus constitutes a major scientific and technological challenge. To meet this challenge, the U.S. Department of Energy (DOE) initiated a ?National Hydrogen Storage Project? with roughly 40 universities, 15 companies and 10 federal laboratories, actively engaged in hydrogen storage research. Centers of Excellence in metal hydrides, chemical hydrides, and carbon-based materials have been established, as well as independent university and industry projects in the areas of new concepts/materials, hydrogen storage testing, and storage system analysis. Recent technical progress in each of these areas is discussed, as well as collaborative hydrogen storage activities under the recently established International Partnership for the Hydrogen Economy (IPHE).

Jan 1, 2006

By Chao Zhang, Kexin Jiao, Yi Qian, Jianliang Zhang

Now low-grade iron ore were widely used. However, one prominent problem is that the content of trace elements is higher than that in high quality iron ore. For the requirement of the content of Mn, Cr, Ni, Cu, and Ti in hot-rolled steel sheet and strip, the upper limits of these elements in sinter will be studied in this paper. Using the activity model of aggregation of electronic phased slag composition, the distribution ratio of each element in converter is analyzed and the content of each element in hot metal is calculated. Furthermore, through the thermodynamics method, the distribution ratio of each element in BF is analyzed and the content of each element in raw material is calculated. The upper limits of Mn, Cr, Ni, Cu, and Ti in sinter can be determined by calculating, the values are as follows: Mn 0.767%; Cr 0.552%; Ni 0.055%; Cu 0.159%; Ti 0.108%.

Jan 1, 2015

Copper and gangue mineralogy constitute the most critical parameters for the hydrometallurgical processing and cost-efficient extraction of copper. Minor changes in copper-, rock-, or alteration mineralogy can severely impact the comminution efficiency, curing, agglomeration, acid consumption, copper extraction and PLS impurity loading. Further, copper leach operations, particularly in the southwestern United States, are increasingly challenged by a combination of low grades and semi-refractory copper. This paper discusses the metallurgical and economical benefits of continuous mineralogical analyses in order to establish and operate a mineralogical data base in copper leach operations. Troubleshooting for copper extraction, integration of process mineralogy into production forecasting, and process optimization will be illustrated with operational experiences from Chile and the United States.

Jan 1, 1999

By K. R. Robilliard

The Peru based tin mining company, Minsur S.A., commissioned Ausmelt Limited to design, supervise construction and commission a tin smelter and refinery for production of refined tin metal. The plant is located 240km south of Lima, near Pisco, Peru and is operated by Funsur S.A., the wholly owned subsidiary of Minsur S.A.. Selection of the Ausmelt Technology followed a series of crucible scale test work and pilot plant trials conducted at Ausmelt's facility in Dandenong, Australia and two feasibility studies undertaken by Ausmelt in 1991 and 1993. Ausrnelt began the plant design in 1994 with the construction phase following in 1995. Commissioning of the plant commenced early in 1996 with a target throughput of 30,000 tonnes per annum of concentrates. In mid 1998 oxygen enrichment of the Ausmelt lance air was introduced to expand the capacity to the throughput of 40,000 tonnes per annum of concentrates. The process route involves the use of an Ausmelt furnace for primary concentrate smelting, followed by a conventional tin pyro-refining circuit to produce high grade tin suitable for sale. Further work continues between Ausmelt and Funsur to investigate the use of an alternative, more economical, fuel source and the installation of a second Ausmelt furnace. The paper reviews the project to date with details of ongoing operations and developments at the Minsur Tin Smelter.

Jan 1, 2000

By Roberto Javier Santiago

The diferent applications of the Calcium Carbide in the steel plants are described in this paper, trying to give advantages in their use.

Jan 1, 2006

By Markus A. Reuter

In this paper various hybrid modelling architectures are proposed for the modelling and metallurgical control of pyrometallurgical reactors. Discussed are architectures in which data reconciliation is combined by thermochemical, neural net and dynamic modelling to improve the models. At the same time the data reconciliation models can act as soft-sensors for estimating unmeasurable data. Cases that are discussed are (i) the modelling of a submerged arc furnace for the production of thermal phosphorous, (ii) the processing of Sn-Pb-Zn flue dust (originating from secondary copper) in a hearth furnace, (iii) modelling of a steel converter, and (iv) dynamic modelling of a flash smelter.

Jan 1, 2001

By Kymberley Worrell

The Cripple Creek and Victor Gold Mine was acquired by Newmont in August 2015. The high grade flotation mill project was commissioned in February 2014. The mill to date has been throughput limited due to mechanical and design issues. In order to create the most value from a throughput limited plant a campaign to provide timely ore characterization was undertaken. A diagnostic leach methodology was developed to determine gold associations by ore type. The resulting associations were then used to characterize feed blend; gold losses and optimize gold production. The diagnostic methodology is presented along with discussion on flotation implications.

By Alan M. Peel

"Over the past years there has been an increasing demand by aluminium cast -house operations to obtain a greater return from their existing installed plant. This has included increasing existing furnace production capacity to match new and higher downstream production requirements, reducing melt losses and more efficient alloying.The paper discusses how Electromagnetic Pumping, which was developed for the combined purpose of;1. Melting light gauge aluminium scrap with a reduced melt loss and; 2. Effective circulation of the aluminium melt,has established its self in recent years, as an effective means of satisfying many of these industry requirements, but how it has also provided many other additional operational benefits to the aluminium cast house.The paper will discuss operational performance of the system with a particular emphasis on its effect on the metal bath quality (alloying, chemical and temperature homogeneity), metal recovery and increased production due to the high circulation.The technology having now been adopted by a variety of industry leaders has a number of prominent references and the paper will discuss the operational benefits and experiences from some of these."

Jan 1, 2000

By L. Cifuentes

Electrodialysis (ED), i.e. a technique based on the effects of electrically charged membranes on ions in solution in an electric field, has been applied to Cu-Fe-As-Sb- H2SO4 electrolytes similar to those used in copper electrorefining and electrowinning operations. The effects of current density, time and species concentration have been studied in a batch ED cell. The technique has shown to be effective in concentrating and separating a range of ions and points to possible new methods of treating copper electrometallurgy effluents.

Jan 1, 1999

By M. Drozd

Multi-use pad operators require an efficient and economic method to destroy cyanide in their process residues so new material can be stored on the pad and leached. Operators of the dedicated or single-use pads require an effective cyanide destruction method for pad closure. Cyanide destruction can be accomplished by utilizing oxidants such as hydrogen peroxide or calcium hypochlorite, or by utilizing ferrous sulfate which sequesters the cyanide in strong acid dissociable complex. Ferrous sulfate can be the preferred method of cyanide destruction because it is a less costly chemical, reaction rates are almost immediate and unlike oxidants, it can penetrate the total depth of a pile without being destroyed by side reactions. Literature indicates that the (Fe(CN)6)-4 com~lex is produced slowly but it appears that complexes such as Fe(CN)4(H20)2-or Fe(CN)4(OH)2)-4, are formed quickly and should have no U.V. sensitifity, unlike (Fe(CN)6)-4. Stoichiometry of the testwork indicates that Fe«CN)4(OH)2)-4 complex may be the species formed. The usage of ferrous sulfate has the advantage of being able to bring ~ level down that divalent metal ions such as Cu++, Cd++, Hg++, Pb++ and Zn will form insoluble complexes and precipitate from solutions does not destroy weak acid dissolvable complexes and can leave a heavy metal problem behind after cyanide destruction.

Jan 1, 1990

By Selvin Yesilay, Munevver Caki, Canbora Bayraktar, Bekir Karasu, Rahmi Imrak

"In this study, the utilization capability of the solid wastes taken from a commercial roof tile and brick factory in Eskisehir of Turkiye has been investigated in the production of stoneware bodies which can be formed by slip casting. At the first stage, X-ray fluorescent (XRF) and X-ray difractometer (XRD) analyses of the wastes were performed. Depending upon the results, a body recipe with an optimum casting concentration was adjusted. The bodies obtained from prepared slips were fired at 1160 oC as glazed and unglazed forms. Then, they were undergone certain tests in order to determine their firing shrinkage values, water absorption levels and optical parameters. To establish what kind of phase formations occurred after firing as a result of waste incorporations into bodies XRD analysis was conducted. Additionally, effects of such a compositional modification on the microstructure of the bodies were examined by a scanning electron microscope (SEM). Consequently, it was concluded that fired roof tile and brick wastes could be evaluated in both glazed and unglazed stoneware bodies. Introduction Stoneware is the general name applied to many wares fired between 1150 and 1300 °C. It has a different and denser structure than those of ceramics produced at lower temperatures. Fired stoneware possesses a lower water absorption value. When matured at a high temperature, it gives a possibility for the use of feldspar as a main ingredient [1-2]. Colors of stoneware can be brown, red, white and most of the times beige. Firing usually takes place in oxidation atmosphere but also reduction can be rarely used. This naturally has an effect on the body colors [3]. Earth, which contains clay minerals, becomes plastic mud when mixed with water, has a capability to be easily shaped and can be hardened without cracking if fired at 900-1000 °C, is referred as one of the brick and tile raw materials [4]. Natural and aesthetic appearances of buildings obtained with brick and tile products, which make them preferable especially for construction sector, are of importance. Because clays being main raw material of that type of productions generally do not exist as pure materials in nature, their usability depends on their mineralogy and impurities they contain [5]."

Jan 1, 2008

By G. Johnston, J. Greenly, R. G. Buchheit, D. C. McIntyre, R. Muenchausen, D. J. Rej, R W. Stinnett

"Rapid thermal treatment of materials using high energy, high flux, pulsed ion beams can produce modified surface layers with unique microstrutures and properties. High energy ions loose their energy during the slowing down process in the workpiece and thus deposit their energy continuously over a depth of a few microns. The deposition of energy can lead to melting and in some causes ablation of the heated layer. Because the pulse duration of the ion beams is typically only 50-200 ns, steep thermal gradients generated during heating facilitate rapid cooling (107K/sec-108K/sec) of the treated layer by thermal diffusion into the underlying material. Rapid heating and cooling of materials can generate surface layers with non-equilibrium amorphous or nano-crystalline microstructures that exhibit increased hardness, wear resistance, and corrosion resistance. Pulsed ion beam treatment can also lead to surface smoothening or can be used to mix thin « 1 11m thick) coatings into underlying substrates. Pulsed ion beams can be generated using existing ""flashover"" ion source technology which is capable of producing single shot, mixed C, H, and O ion beams with beam cross sections of approximately 100 cm2 and energy fluxes up to 100 J/ cm2. Recent advances in repetitive high energy pulsed power technology and development of magnetically confined anode plasma ion sources have facilitated the development of ion beam systems that generate single species beams that pulse continuously at 120 shots/second. These capabilities will allow rapid treatment of large surface area workpieces at low cost.IntroductionThe rapid solidification of liquid materials can create unique materials and material microstructures that often have properties that can lead to enhanced performance. Rapid solidification processing of the surfaces of materials using continuous and pulsed laser beams (laser glazing) has been explored for over 20 years (1-5). Advances in high energy, pulsed electron and ion beam technologies over the past decade have provided rapid thermal treatment techniques that may be less expensive to impliment than laser surface treatment for many surface modification applications (6). High energy pulsed ion beams have recently been used to harden aluminum(7), copper(8) and tool steel surfaces (6,9), increase corrosion resistance of Al alloys (6), mix coatings into underlying substrates (10), and create amorphous films (11,12)."

Jan 1, 1994

By Luis M. González, Guzmánm Guillermo D., Davis Juan C.

"The Teniente converter (CT) of the Ventanas Smelter and Refinery of Codelco-Chile has two tuyeres for dry concentrate injection directly into the melt.The diluted phase injection system can feed 15 to 20 kg of concentrate for 1 kg of air, which creates a very abrasive solid/gas phase. The tuyeres commonly used lasted for about 3.5 days due to the accelerated decay of the shell, and 1.5 hours were necessary for the replacement of new ones in the reactor.Tests were carried out with common shell tuyeres with a tungsten based welding cover, and a life span of 28 days was reached, increasing the Teniente converter operational continuity between 1.5 to 2 %."

Jan 1, 2009

By S. P. Ball

A major limitation to maximising the rate of gold extraction in commercial operations occurs as a consequence of the limited solubility of oxygen in cyanide liquors. The use of additions of solid inorganic peroxides as an in-situ supply of oxygen to the lixiviant has been studied, in particular in its application to heap leaching. Experimental studies showed-that the release of oxygen into solution from these peroxides is very sensitive to solution pH. Agitated leaching tests showed that, when either Ba, Ca or Sr peroxides were used as the-sole source of oxygen, both the rate and extent of gold extraccion was enhanced. Column leach tests were used to simulate heap leach conditions. These showed that significant increases in the rate of gold extraction could be achieved by additions of calcium peroxide, made to the ore, prior to it being loaded into the columns.

Jan 1, 1989