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By J. P. Hoffman, A. S. M. de Jesus

Additions of boron have been found to increase the hot workability of stainless steels. Boron forms complex chromium-iron borides, primarily at grain boundaries but also on delta-ferite stringers. This paper describes how a nuclear technique based on the track-etch method was used to distinguish between borides and chromium carbides on grain boundaries and to investigate the distribution of boron in stainless steels. The method was found to be sensitive for boron, and made it possible for boron precipitates to be identified on grain boundaries and interphase boundaries.

Jan 1, 1989

By L. G. Austin

"This paper is based on the development of the Maza-Austin technique for characterizing thousands of coal particles by approximate analysis of the major inorganic constituents Ca, Al, Si, K, Na, Fe and S in each particle. The technique has sufficient sensitivity to work on small volumes, is fast enough to handle large number of particles within a reasonable period of time, and consists of scanning electron microscopy combined with energy dispersive x-ray spectrometry (SEK-EDS). A computerized SEK-EDS system that allows the automated analysis of hundreds of coal particles per hour' is described. The analysis is based on the location and tracing of coal particles embedded in a polished specimen, the selection of sampling points on the traced particles, the collection of an x-ray spectrum from each sampled point for a defined period of time, and the processing of the x-ray intensity to calculate point composition using ZAF corrections. Procedures for correcting for dead time, background, detector efficiency and spectrum overlap are described. These corrections are essential if reasonably accurate analyses are to be obtained from unknown complex mixtures of the elements in a coal or fly ash particle. Examples are given. INTRODUCTION Coal is a complex mixture of organic and inorganic materials. The inorganic fraction is referred to as mineral matter (Gluskoter, 1978) but can occur in three modes: (i) an observable mineral species; (ii) as cations held by ion exchange to carboxylic groups; and (iii) in chelate complexes. The mineral matter content normally represents a significant proportion of a coal, with an average value of about 15% for US coals (Gluskoter, 1975). The standard methods of analysis of the mineral matter in coals are performed on a sample selected to represent the whole coal as closely as possible, and give the overall inorganic composition in the coal. Such analyses are of limited use for solving problems originating from the behavior of individual coal particles, whose compositions vary widely from the average value. This is particularly true in pulverized coal combustion, where the current methods of predicting the slagging and ·fouling potential of a coal are based on the bulk ash composition, but the fly ash particles which create the deposits originate from coal particles with large differences in mineral compo1ition. Some examples can be found where, in a comparison between two coals, the one with the smaller slagging potential according to the mean ash composition was the one that behaved worst in the furnace (Moza et al., 1980; Koza and Austin, 1983). The u1e of gravity fractionation to assess the slagging potential of pulverized coals has shown that conventional ASTM analysis is not sensitive to differences in the distribution of mineral matter when comparing coals (Borio and Narciso, 1979). Bryer (1979) concluded that coals should be examined for fouling and slagging potential by analyzing gravimetric and size-fractionated coal, preferably pulverized· and ground to the size expected at the mill outlet."

Jan 1, 1989

By Larry J. Hughes

Ground-based electrical geophysical techniques have be valuable for three indirect exploration strategies: "tracer" sulfide mineralization, 2) mapping structure with or controlling mineralization, and 3) mapping proven to 1) mapping? associated alteration zones. When sulfide mineralization is associated with gold, it often can be mapped using induced polarization (IP). This technique can detect pyrite in amounts as small as 0.2% by volume, and in some cases can distinguish pyrite from anomalies due to graphite and clays. A case history illustrates mapping sulfides in a shear zone. Structure and alteration mapping are often the domain of controlled source audio-frequency magnetotellurics (CSAMT) due to the superior lateral resolution and depth penetration of this technique. Typical CSAMT targets include silicified sediments and volcanics, faults, brecciated zones, argillic alteration, clay and graphite horizons, and certain lithologies. Examples of mapping silicification and mapping epithermal alteration are presented in CSAMT case histories over Cannon mine in Washington and Hishikari mine in southern Japan. In our experience, four things are needed to use geophysics effectively in precious metals exploration. First, the explorationist must correctly identify the exploration stage at which the geophysics is most useful. Second, the explorationist must clearly define the types of "tracer" mineralization, host geology, or alteration which need to be defined by the geophysics. Third, the right electrical technique needs to be applied to the problem to provide the best chance of success. Fourth, the explorationist must be willing to commit adequate finances to do the geophysics properly. With careful adherence to these principles, geophysics can greatly enhance exploration success while reducing the total cost of exploration.

Jan 1, 1989

By Kavetsky A

In surface mining operations, the ease with which a muckpile may be dug is a dominant factor in mining efficiency. Within broad limits, this is largely dependent on muckpile shape and looseness within a muckpile. Moreover, prediction of grade boundary movement and subsequent dilu- tion is of interest to most open cut mines. Such a predictive tool would enable blast design changes to be made to reduce mixing of certain grade regions. At the very least, a good knowledge of post-blast region bound- aries can reduce layout of the grade boundaries and decrease grade dis- crepancies between pit and plant. The model presented in this paper is able to consider various options for a production blast and predict consequent muckpile shapes and grade boundary movements in a three dimensional manner. The overburden geometry, hole patterns, hole inclination and charge distribution are all explicit model inputs. The model divides the rock mass into blocks and calculates a velocity for each block. Three controlling parameters are used in the model, which are related to the explosive energy per unit length of blast hole, energy attenuation of the rock mass and inter-row delay, respectively. The output of the model is a 3 dimensional muckpile shape (contour or any cross section) and a contour map of grade distribution within the muckpile. The model parameters are site specific, since their values depend on the rock condition and explosive-rock interaction which varies from site to site. In order to "tune" the model to a particular site, parameter values must be found which reproduce an observed muckpile profile shape from a given blast design. This calibration of the model requires at least one surveyed muckpile profile shape from a production blast. The model parameters which best reproduce that shape are found by a pattern search technique, and may then be used to predict the effect of changes in blast design on muckpile profile shape and grade boundary movement.

Jan 1, 1989

By David Seymour

Newmont Gold Company (NGC) located in Northeastern Nevada has been processing carbonaceous and sulfide refractory gold ores through a chlorination circuit prior to cyanidation. A "Flash Chlorination" pilot plant was installed in 1987 in an effort to obtain higher chlorine utilization efficiency and increase gold extraction. The Flash Chlorination process oxidizes organic carbon and sulfide sulfur. It also deactivates preg-robbing carbon, making the ore amenable to cyanidation. Significant recovery improvements were observed using this new process. This scheme has also been instrumental in the processing of higher than normal grade ores at economic chlorine levels. The Flash Chlorination pilot plant has been successfully treating carbonaceous ore on a production scale since April 1988. This paper summarizes laboratory and pilot plant optimization test work, using conventional and statistical methods.

Jan 1, 1989

By L. A. Vermeulen, D. D. Howat

Extensive work was done previously on the wear of grinding media and on the comminution processes operative in bal milling based on the determination of the number-size and mass-size distributions of samples of balls taken from bal mils by a specially designed device. Proof that a sample is as nearly representative as possible of the whole mass of material from which it is drawn is usually extremely difficult. This paper reports a special case in which a direct comparison was made between the number-size and mass-size distributions obtained from a sample drawn from a mil and those from the whole bal charge emptied from the mil. Exposure of the internal defects of the grinding balls caused them to develop irregular shapes after wear had reduced their diameters by about 50 per cent. As a result of the marked change in the morphology of the grinding components, an anomaly was observed between the proportion of small components collected by the sampler and that determined in the total charge. Except for this anomaly, a marked similarity was found in the data relating to the larger components in the sample and the total charge, indicating that the sample obtained by the procedure outlined is representative of the mass of the grinding charge in a mill.

Jan 1, 1989

By M. A. Ackerson, R. E. Griffin, W. H. Pomroy

Two automated fire detection system configurations have been used successfully in underground mines: the pneumatic "tube bundle" approach and the electronic telemetry approach. The electronic telemetry approach is more widely used, owing to its greater speed, flexibility, and capacity to both monitor other underground conditions, and remotely control underground equipment. However, depending on specific mine conditions and layouts, pneumatic detection, or a combined pneumatic/telemetered system may offer significant advantages over the telemetered approach alone. This paper describes research by the U.S. Bureau of Mines to design and in- mine test a rapid response pneumatic fire detection system tailored to the unique requirements of multilevel metal mines. The relative merits of pneumatic detection are discussed in the context of typical multilevel mine layouts and environments. A Bureau developed proto- type system is described with emphasis on design features which counter commonly perceived and/or experienced pneumatic detection system operating problems. Finally, the results of a 3-yr in-mine performance evaluation of the prototype hardware are discussed. Included are descriptions of system layout and coverage, response time, tube leakage, sample dilution, elimination of accumulated water from sample lines, and system maintenance and reliability.

Jan 1, 1989

By G. S. Brierley, R. D. Drake, J. E. Kelley, J. C. Kellogg

This case study embodies the problems of an underground project under current contracting practices. It will provide a realistic framework for a structured examination of the anatomy of a major complex underground project. Just as it will illustrate the frustrations of the parties to an underground contract, it will also provide a means to examine potential opportunities to provide a better way to develop underground space. Urban Transit Authority (UTA) had planned to expand their heavy rail underground transit system through an extension to an existing line. UTA lacked sufficient funding to guarantee the construction and operation of this planned extension. Venture Partner Associates (VPA) in conjunction with four major department stores entered into an agreement to create a major underground space for a commercial/recreational facility. The concept was to locate the facility adjacent to a planned station and beneath existing aboveground office facilities. This group was known as Commercial Development Corporation (CDC). UTA had reached an agreement with UMTA to provide 20 percent of the line and station costs. UTA then entered into an agreement with CDC to provide the needed additional funding for the station work in return for locating the station adjacent to the planned underground commercial/recreational complex. The agreement called for CDC to contribute 20 percent to the station cost to a maximum of $25 million plus a one percent contribution from commercial/recreational revenues for operating costs.

Jan 1, 1989

By Brian W. Hester

All gold occurrences in Tanzania are of Precambrian age and in geological settings similar to gold deposits in other parts the world. The three main areas of interest are perhaps the least prospected of areas of gold mineralization in Precambrian rocks in non- aligned, or market economy nations. Historic production exceeds 77.660 kg (2.5 million oz). Current results by small scale workers go unreported, but have been estimated to be as high as 11.000 kg (350.000 oz) annually. Gold occurs in both lower and upper Precambrian rocks. In the older. gold is associated with greenstones and iron formations typical of many cratonic areas of Precambrian age. The Tanzanian Craton lies in the north west quarter of the country where it is flanked on both east and west sides by mobile belts involving upper Precambrian rocks of high metamorphic grade. Gold occurs in fractures in the western belt within two distinct areas.

Jan 1, 1989

By Reno M. Tonsi, Bill Raley

Supervisory Control and Data Acquisition (SCADA) systems are important tools in providing more efficient and profitable operations for the mining industry. This paper touches on the different types of equipment used in SCADA applications and discusses the benefits obtained in using Programmable Logic Controllers in this application.

Jan 1, 1989

By D. R. Tesarik

An instrumentation and numeric modeling study was conducted by the Bureau of Mines at the Magmont Mine in Bixby, MO. An isolated section of this room-and-pillar mine was monitored with borehole and closure extensometers during a pillar recovery program to determine stress redistribution. In situ stress measurements were taken in the rib before pillar extraction began. Sample cores from the boreholes were taken for analysis of the properties of the host rock in the laboratory. The extensometers recorded no measurable displacements during most of the operation. Two-dimensional, finite-element; three-dimensional, finite-element; and three-dimensional displace-ment discontinuity codes were used to model the area of study. The finite-element models were run with two initial stress conditions, i.e., stress due to gravity only and stress obtained by in situ measurements. Horizontal stresses in the models reduced the calculated factor-of-safety in the mine back by up to a factor of 10, but did not have a significant effect on calculated pillar stability.

Jan 1, 1989

By Wenbin Zhang, George W. Poling

"Prior or simultaneous addition of ammonium sulphate can, not only enhance the activating effect of hydrosulphide ions on xanthate flotation of malachite but it can also eliminate possible detrimental or depressing effects of excess residual hydrosulphide . Use of relatively inexpensive ammonium sulphate appears to reduce the consumption of the much more expensive sulphidizing agent for optimal flotation recovery INTRODUCTIONOxidized copper minerals float poorly with conventional thiol-type collectors. This is believed to be due to the nonadherent character of the collector coating, which is readily re- moved by particle abrasion. Rosas and Polingr reported emulsion flotation seemed capable of resisting abrasion during the flotation of non-sulphide copper ores. It appears that the most common flotation technique for oxidized copper minerals comprises sulphidization with Na .S and subsequent treatment by sulphydryl collector. The principles of this method are available . Malghan recently reviewed the studies on the role of sodium sulphide in the flotation of oxidized copper, lead and zinc minerals.It is well known that in the sulphidized flotation of malachite, the activation process depends strongly on the concentration of the sulphidizing agent, i.e., insufficient sulphide gives poor recoveries because of inadequate sulphidization; excessive sulphide also causes poor recoveries due to the depressive effect of the residual hydro-sulphide ions in solution. A major difficulty in sulphidization, especially with a varying feed nature, is to establish and maintain the optimum sulphide concentration in solution. In plant practice, vigorous control of sodium sulphide is required and stepwise addition of the reagent is recommended to improve the efficiency of the process. Soto and Laskowskim have found that malachite, depressed by an excess of sulphide ions, can restore its floatability if air or oxygen is introduced to the pulp. They attributed this to the oxidation of the HS - ions on the surface of the mineral. Jones and Woodcockuvi showed that a sulphide ion selective electrode could be used to optimize the conditions (e.g . amount of hydrosulphide, sulphidization time, flotation time) more readily and precisely than existing methods in the flotation of oxidized copper ores."

Jan 1, 1989

By J. L. Gent

Compressed air distribution networks are essential for powering equipment in many mines even though some mines are replacing them with electrical power for hydraulic drills. Compressed air can be costly especially if the system is poorly designed and maintained. This paper outlines a technique for proper compressed air system design that will help mine managers reduce compressed air power costs; an important topic in today's highly competitive international minerals market. Compressed air system design is complex. It requires specifying: 1) air quantity and pressure in all branches of a large network, 2) proper location and types of valves and fittings, 3) the network solution that determines compressor requirements, 4) optimal hose and pipe, diameters, 5) receiver and compressor accessories, and 6) required capital and operating costs.

Jan 1, 1989

Working in thick coal seams presents many problems, included in these is obtaining the maximum recovery of coal under safe working conditions. In order to obtain maximum extraction it is important to understand the behaviour of pillars left for support purposes. However it is not always the practice to maintain pillar stability it is often required to design for pillar failure. The greatest hazard of pillar mining is uncontrolled pillar collapse. Many major and relatively minor collapses of pillar workings have been recorded in the history of mining. Notable among the collapses was that at Coalbrook Colliery in South Africa in 1960 (Bryan et al 1964). This led to recommendations on the design of bard and pillar workings in South Africa. (Salamon 1967) These design recommendations were based on the statistical analysis of stable and unstable pillar workings and introduced the concept of probability of pillar failure and safety factor. On the basis of this study a safety factor of 1.6 was prescribed for production panels in South Africa. A general review of pillar design procedures, reveals that a new phase of reinterpretation and modification is in progress. This takes into account for instance the effect method of working, whether by conventional drilling and blasting or continuous miner, has on coal pillar strength, and the necessity to review the methods for increasing depth of working. Also, as more is being understood about overall rock mass properties and advanced computer modelling techniques become more readily available, the mine planning engineer is faced with numerous approaches to pillar design.

Jan 1, 1989

By Tom Plouf, Deepak Malhotra

INTRODUCTION The U. S. mining industry experienced a severe recession in the early 1980's. This resulted in the realization that the domestic mining industry had to compete on a global basis and only the strong or the low-cost producers would survive. The economic viability of a mining company not only depended on maximizing mineral recovery but also on its ability to do so at minimum cost. Companies had to become more productive not only by cutting costs, but also by developing and/or evaluating new technologies in existing or new plants. Several innovative concepts, including in-pit crushing and conveying, fine crushing, improved classification equipment, flotation, column flotation, pressure filtration, etc., have been developed in recent years. This paper addresses the impact of new flotation concepts and equipment on mill design. MILL DESIGN PHILOSOPHY Modern mill design, especially for large capacity plants, has its foundation in minimizing capital and operating costs. Capital costs can be minimized by minimizing the various components of the capital cost: infrastructure, equipment, instrumentation, structural, initial spare parts costs, etc. All these costs are minimized by simplifying the mill design and/or process flowsheet. The simplified process flowsheet, where applicable, consists of a single stage primary crusher followed by a semiautogeneous - ball mill grinding circuit to produce feed for a flotation circuit. Multiple flotation circuits have been eliminated in most cases. These concepts minimize the cost and encourage the use of large capacity equipment while maintaining optimum metallurgical recovery. The philosophy of mill modernization/modification is generally driven by the desire to increase the mill capacity within the limits of the existing mill building. This need is facilitated by using large size flotation equipment and eliminating multiple parallel flotation circuits in order to minimize capital and operating costs. Conventional flotation machine development has paralleled this mill design philosophy. FLOTATION CELL DESIGN Since froth flotation has been the most widely used separation process for over half a century, one would expect that it would be possible to design and select flotation machines for specific applications based on scientific principles. But this has not been the case. Best judgment, experience and personal prejudice have played a key role in equipment selection. These factors, along with the difficulty of evaluating new concepts in commercial plants, has slowed progress in implementation and commercialization of innovative ideas and/or equipment. Conventional Flotation There have been no major technological advances in conventional flotation cell design in recent years. A recent flotation cell survey indicates that 'larger flotation cells are still the order of the day.”(1) A comprehensive review of design of flotation machines indicate that they have been mechanically redesigned and are generally simpler and easier to maintain and less expensive to manufacture. (2,3) The approximate chronological development of conventional cells from the 25 cubic foot cells to the 3000 cubic foot cells, which were recently installed at the Copperton concentrator of Utah Copper, is given in Table 1. Larger flotation cells are the obvious choice for new plants or plants looking for expansion because of the following reasons: • They have lower capital cost per unit volume • Installation costs are generally lower because fewer units require less space • Maintenance costs are lower because of fewer mechanisms • Power requirements (HP/ton dry feed) are generally lower • with increased flotation cell size as illustrated in Table 2 [Table 1. Conventional Flotation Cell Size Development Year Individual Cubic Cell Size, Feet 1925 25 1935 50 1960 100 1965 300 1970 500 1975 1,000 1980 1,500 1985 3,000]

Jan 1, 1989

By J. E. Allison

As part of a Bureau of Mines research program to conserve critical and strategic metals, an aqueous electrodeposition method for preparing stainless-steel-type coatings was studied. Chromium powder (averaging 3 J1.m diam) was suspended in a ferrous-nickelous sulfate electroplating bath and occluded in the electrodeposited Fe-Ni alloy matrix. Subsequent heat treatment of the resulting composite coating formed the ternary alloy. The occlusion process was affected by the quantity of Cr powder suspended in the electrolyte and by the microstructure and composition of the electrodeposited matrix. Coatings containing up to 21 wt pct Cr were deposited from an electrolyte containing 20 vol pct suspended Cr powder. Heat treatment at 1,100° C for 8 h homogenized the composite coating. Deposition of 44Fe36Ni20Cr alloy coatings (250 J1.m thick) on AISI 1020 carbon steel rods, followed by heat treatment, provided complete protection of the carbon steel during exposure to a boiling 65-pct-HN03 solution. Corrosion rates of 0.6±OA mm/yr for the coating in the boiling HN03 approximate that of 304 stainless steel. Practically shaped electroforms have been prepared by the coating method.

Jan 1, 1989

By Ron Robinson

Booster fans have been in regular use in British coal mines since the first half of this century, but a large increase in their use did not take place until after the Nationalization of coal mines in 1947. From that time the need was identified to improve standards of ventilation in general and mining engineers specializing in ventilation were appointed at all levels in the mining industry. A comprehensive approach to ventilation surveys and planning, together with the realisation of the benefits of booster fans, led to their more rapid introduction. Many coal mines in the U.K. are at moderate depth and have virgin strata temperatures of 30°C or less. The ability to control climatic conditions by increased ventilation rather than resort to cooling systems has led to the introduction of booster fans and recirculation systems in these mines. Large makes of methane and high levels of coal dust production due to increased mechanization have also required enhanced ventilation standards. This paper deals with the reasons for selecting booster fans and the specific safety considerations involved in their use. Numbers, types and sizes of booster fans in the U.K. are outlined, together with notes on installation and performance. Remote monitoring and control from the surface is dealt with, and current legislation. The evolution of controlled recirculation is also covered starting with auxiliary fan systems in 1970 and leading to very large district schemes in the late 1980s. The research at Newcastle upon Tyne University and other establishments in the climatic conditions associated with recirculation is summarised and its use in assisting existing and proposed conventional and recirculation systems is indicated.

Jan 1, 1989

By K. V. S. Sastry, K. D. Lofftus

Mathematical modeling and computer simulation are two valuable quantitative tools that are being effectively applied to mineral process- systems. This paper presents an up-to-date assessment of process modeling and simulation, identifies a number of associated challenges and opportunities and discusses in detail sane of the aspects of applying the current state-the art modeling and computational tools.

Jan 1, 1989

The U.S. Bureau of Mines conducted a laboratory study to determine what effect use of water-jet-assisted cutting has on frictional-ignition suppression. A single bit with a steel tip, installed on a rotating drum, repeatedly made 22-in-long cuts in a block of Berea sandstone. The drum was operated in an enclosure that contained an explosive methane-air mixture. High-pressure front-mounted water jets operating at 2,000 to 5,000 psig and low-pressure rear-mounted sprays operating at 80 psig were used; the number of ignitions that occurred with each type of spray was compared. The rear-mounted spray was more effective for preventing frictional ignitions than the front-mounted water jet.

Jan 1, 1989

By Wright S

Single pellets of mixed lead-zinc concentrate containing up to 20 % lead were roasted in the temperature range of 800-1100¦C. Variables studied included pellet size (from 9-8 to 3-2 mm diameter), gas flowrate past the pellet (from 0.05 to 5 ms t), composition of the atmosphere and the effect of additives such as zinc oxide and silica. After defined periods of time, the pellets were removed from the furnace, quenched and submitted for chemical, XRD, SEM and microprobe analysis. The oxidation of the zinc sulphide followed a shrinking core model. Temperature measurements showed that very high pellet temperatures were experienced at the start of an experiment but after 5-10 minutes these approached a constant temperature. The lead loss from the pellets was then constant with time. Thermodynamics predicted the presence of two bands of lead material in the reacted layer of the pellet. These were found in practice. The lead loss from the pellet occurred from the outer oxysulphate layer via the vaporization of lead oxide polymers. The vapour pressure of PbO, and the loss of lead, was dependent on temperature and bulk gas concentrations of SO2 and 02. At 1100¦C the addition of silica greatly reduced the loss of lead from the pellet. Physical factors such as pellet diameter and gas flowrate past the pellet affected the particle dynamics. These results were found to vary in accordance with the predictions of the Froessling equation.

Jan 1, 1989