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Improve the efficiency of stainless steel pickling (chemically cleaning) operations by providing the industry a quick and convenient method to estimate pickling solution behavior and to estimate recommended ranges of nitric and hydrofluoric acid concentrations for effective pickling of stainless steels. Background Iron, chromium, and nickel in stainless steels react with nitric and hydrofluoric acids during pickling. Ions of these dissolved metals complex or combine with the acid anions. When the total metal concentration reaches about, 50 grams per liter of pickling solution, the solution no longer serves its purpose and is considered spent. Knowledge of cation and anion species in these pickling solutions contributes an insight into pickling chemistry and allows estimates to be made of the most effective ranges of acid concentrations. The Bureau developed a computational model of the complex equilibrium chemistry occurring among iron, chromium, and nickel and the pickling solution. Total concentrations, in grams per liter, of nitrate, fluoride, iron, chromium, and nickel were used as input; output was 17 cation and anion molar concentrations. The model, in the form (if an equilibrium program on a mainframe computer, was used extensively to facilitate Bureau research by determining chemical complexes in numerous stainless steel pickling solutions. However, the program's availability to members of the stainless steel industry, its intended users, was limited because of lack of mainframe compatibility and the difficulty of program maintenance.

Jan 1, 1989

By George Machan

Bitumen coatings have been successfully used to significantly reduce downdrag on piles. Thicker coatings of "soft" bitumens can accommodate downdrag so well that very little downdrag load is transferred to the pile. Many of the case histories describe better than 80 percent downdrag load reduction. Bitumen coatings have been used on several projects in Oregon. On the Mocks Bottom Bridge project (see Reference 1), experimentation and instrumentation confirmed the viability of bitumen coatings and provided insights for design and construction. Subsequent bridge projects have used this information and have raised issues to be resolved.

Jan 1, 1989

By S. S. B Wang

Zirconia-based ceramic materials have potential applications in high temperature furnace insulation, hot extrusion and casting dies, pressure nozzles, cutting tools, engine parts and electronic materials. High purity and superfine powders of zirconium oxide (baddelyte) were synthesized from a solution containing zirconium oxychloride and urea under hydrothermal conditions. crystallization of the metastable tetragonal zirconia using magnesium oxide or yttrium oxide as stabilizing agents was successfully achieved. The mechanism of hydrothermal reaction to produce these powders are discussed.

Jan 1, 1989

By M. Jawed

Coking coal reserves in India are distributed geographically in Giridih, Raniganj, East Bokaro & Jharia Coalfields (J.C.F.). 97% of prime coking coal in JCF coming through underground mines is credited to Bord & Pillar mining systems inspite of the fact that it results in heavy mining losses. The cost of mining in B & P mines has been much higher due to various factors. In this paper, O.R. model has been discussed with case study for optimizing the cost of production in operational underground mines. Also, a computer algorithm has been discussed using a schematic flowchart, which provides the trend of mining-losses 'in different mining, systems with changing design parameters and finally selects, the optimum mining system for undeveloped seams based on economic appraisal criteria.

Jan 1, 1989

By A. R. MacPherson

"This paper considers four aspects of autogenous grinding. Part 1 discusses statements on power efficiency of autogenous grinding compared to conventional crushing and grinding systems. It also demonstrates how high-power efficiency can be obtained from autogenous grinding systems. Part 2 considers a simple method of testing ores to determine the type of autogenous plant which can treat these ores on a commercial basis. A comparison of testing for simple small plants vs large plants or complex ores is included. Part 3 considers important aspects which have to be considered in proper design of an autogenous grinding system. Part 4 discusses problem ores and how they can be treated in an autogenous system. INTRODUCTIONAfter about 35 years of using autogenous grinding plants in the mining industry, it is perhaps time to review where we are with this, by now, relatively old development. Autogenous grinding in this paper means grinding run-of-mine ore by fully autogenous means or by using a ball charge to assist the grinding (semi-autogenous). Also, autogenous grinding can be eitherby dry or wet.The use of autogenous grinding in the fifties was making its slow start, and it was not until the sixties that more of the mining industry would consider its use . By the seventies, most builders of new plants would have considered autogenous grinding, whether they used it or not, in the final design.In the eighties, most large plants use autogenous mills and to reduce over-all operating costs, many older conventional plants are now looking and actually retrofitting these old plants with autogenous grinding mills.It is evident that many misconceptions concerning autogenous grinding are still current. Some come from improperly designed plants which result from poor test work. There are many considerations in the proper design of autogenous plants. Some ores have been found to give problems even in a well designed plant. These ore types are beginning to be classified and recognition in the test stage allows steps to be taken in the design so that these ores can be efficiently handled in autogenous grinding plants.Therefore, this paper will address the following aspects of autogenous grinding:1. Misconceptions regarding autogenous grinding.2. Testing of ores to ensure a well designed commercial plant.3. Important considerations in mill design.4. Difficult ores, their recognition and types of design to handle such ores."

Jan 1, 1989

By Frank T. Duda

A U.S. Bureau of Mines interactive FORTRAN computer program can screen explosion-proof enclosures intended for underground service. The program incorporates important information and criteria to assist enclosure manufacturers and Mine Safety and Health Administration (MSHA) personnel by providing a first-order approximation of rectangular explosion-proof enclosure characteristics prior to actual certification testing. The program uses information and data that can be retrieved automatically during program execution. The program also performs the calculations for a series solution algorithm and various equations to evaluate the enclosure for both a static internal pressure and an internal explosion. The program writes the intermediate and final calculations and information concerning the status of the screening process to a summary file on a floppy disk. One data base contains MSHA certification requirements given in the Code of Federal Regulations (30 CFR 18). A second data base contains material properties of acceptable construction materials and weld joint efficiencies. A series algorithm determines bolt and cover stresses for a simply supported rectangular cover with arbitrary bolt locations. Limit and yield line analysis is used to calculate the strength of body panels.

Jan 1, 1989

By J. E. Gebhardt, S. Chander

Significant advances have occurred in the use of electrochemical techniques for sulfide mineral flotation research. The techniques have been used singly or jointly with other characterization methods. When used in combination with other methods, the electrochemical methods provide a means to control the state of oxidation of the surface. Various analytical methods are employed for characterization. The methods that have been used include wetting, x-ray photoelectron and fourier transform infrared spectroscopies. The electrochemical methods include voltammetry and transient electrochemical techniques of galvanostatic polarization and AC impedance spectroscopy. The challenge for the future lies in the utilization of this knowledge in plant operations so as to increase the overall efficiency of flotation separations.

Jan 1, 1989

By B. L. Seegmiller

Regular entry trusses are used in headgates, tailgates, roadways and intensely-faulted areas. These trusses have proven to give the required support and maintain roof stability even under major abutment loading conditions for both the re-treating and advancing longwalls. Areas previously requiring steel arches have been eliminated. A special Continuous Entry Truss? provides permanent support to adjacent tunnel/crosscut zone for more than 300 feet in each tunnel. The continuous nature of the tensioned truss allows sup-port forces to be placed on the roof in not just the two-dimensions of regular trusses, but in a full three-dimensions. A newly developed Roktruss? provides support in an arched 30-foot high rock zone. The Roktruss? allows truss support concepts to be used in an opening with a curved roof.

Jan 1, 1989

By Guoqi He

Common offset seismic data collected over two active longwall panels at different stages of mining reveal that significant arrival time delays are produced in reflections from different levels within the mine cover. Mining-induced arrival time delays are also observed beyond the edges of the mine over unmined areas. Reflection arrival time delays increase with reflector depth and are laterally variable. The arrival time delays are produced by reductions of seismic velocity within the overburden. Reflection arrival time delays from a major strong unit located neutrally within the cover are proportional to subsidence, however, delays in other events are not.

Jan 1, 1989

By B. W. Jong

The U.S. Bureau of Mines investigated anhydrous chlorination and caustic-acid leaching processes to recover Ni, Co, Mo, and W from waste hydroprocessing catalysts. In batch laboratory-scale equipment, the chlorination process extracted 61 to 99 pet of the metals. Final recovery was 65 to 99 pct. The caustic-acid leaching process extracted 81 to 98 pct of the metals. Final recovery was 36 to 99 pct. Chlorination processing included roasting, chlorination, hydrolysis of metal chlorides for recovering Mo or W, water leaching of Ni or Co from the spent charge, purification, and solvent extraction or precipitation of Ni or Co from the purified solutions. Caustic-acid leach processing included NaOH leaching, solvent extraction of Mo or W from the NaOH leach liquor, H2S04 leaching of the NaOH leach residue, purification, and solvent extraction or precipitation of Ni or Co from the purified solution. The estimated fixed capital cost for a commercial-scale plant processing 39,000 Ibid of waste Ni-Mo-AI catalyst was $8 million for the chlorination process and $9.6 million for the caustic-acid leaching process. The estimated operating cost was about $0.20 and $0.40 per pound of the waste catalyst, respectively, for the two processes.

Jan 1, 1989

By Dennis Ofiara, Paul Zick

Two 8.2 m diameter flood control tunnels are being constructed in the Taylor Shale Formation beneath San Antonio, Texas. These tunnels use precast concrete segments as final lining. This paper describes the features of the segments chosen for this project. The tunnels are being excavated with a hybrid Tunnel Boring Machine. This paper also describes the features of the TBM which make the machine compatible to the type of segments chosen.

Jan 1, 1989

By A. Singh, R. R. Maclachlan

SYNOPSIS A back-analysis procedure based upon 35 mm photography was developed on a laboratory scale for the pur¬pose of determining the percentage of oversize particles known to be present in heaps of fragmented rock. Eight simple blends of crushed stone containing varying percentages of oversize on a 1:40 modelled scale were examined. Simulated test conditions for the following were subjected to the photographic study: (1) a bench heap, (2) the surface exposure of a partially excavated heap, (3) a gravity-sorted surface as occurs on an apron dump, and (4) four quadrant views of an incrementally built conical heap of rock fragments. The best back-analysis determinations were obtained from (4), the cone, over all eight blends of fragments. The mean error was within -0,16 per cent of the true value, with a range of ± 1,872. This was for oversize contents of 5 to 20 per cent where a minimum 25 per cent of the photograph area was processed by digitizer. The worst results were from the apron dump at - 1,462 per cent for a mean error of ± 4,174 per cent. The intermediate results were from the undisturbed bench at -0,186 per cent with a mean error of ±2,862 per cent.

Jan 1, 1989

An improved technique for the quick and accurate measurement of the weight and centre of mass in the horizontal plane of large machines has been developed. On-site weighing of large plant such as bucket wheel dredgers is an important part of the commissioning procedure. The results from the weighing assist in determining the stability of the machine and also enable confirmation of the structural weight distribution used for stress analysis at the design stage. In this paper the techniques previously used for weighing are reviewed and the sources of error using these methods examined. A full descrip- tion of the current technique and procedure is given explaining how the measurement system comprising strain gauge load cells, displacement transducers, wind speed and direction sensors, data logger, computer and software was developed to enable quick and accurate measurements to be made. Proposed modifications to software necessitated by the replace- ment of current measuring instrumentation and computer are discussed. A typical example of measurements from the weighing of a large dredger, illustrating the accuracy of the new technique is given and the calibration technique used to check the accuracy of the force and moment measurements is explained. An outline of how the results are used to certify the machine for operation is given.

Jan 1, 1989

By M. C. Roberts

The success of any industrial mineral project requires an accurate forecast of the demand for the material. This paper develops a general method of evaluating these needs and applies it to the case of graphite. The basic method is to explain graphite consumption in each of its major uses by the output and manufacturing technology of the using industry. Once these underlying factors are determined, they can be projected to establish future requirements. This demand forecast is critical to the evaluation of a new source of supply, such as the graphite resources of upper Michigan.

Jan 1, 1989

By K. Hansson, A. Jedborn

Background In the mining industry, conversion of fine particles into a slurry is often part of the normal processing of the ore. Therefore, from a system's point of view, slurry transporta¬tion would be considered as a natural alternative, all the way from the working face to the final processing. In underground mines, there is sometimes a considerable inflow of ground water that has to be pumped out. When the mine dewatering installations are integrated with a hydraulic hoisting system, the cost of power needed to pump out the ground water can be excluded from the cost of hoisting, compared with other modes of transporting the solids to the surface. The chief advantage of hydraulic hoisting is that the hoisting capacity can be increased at comparatively low total cost without necessitating the sinking of new shafts. Alterna¬tive examples include deepening of the existing mechanical hoisting system, truck, or conveyor belts transport in ramps to the present level. These often become very expensive. The economic effectiveness of hydraulic hoisting and hydraulic design considerations have been discussed by Kostuik (1965) and Sellgren (1985, 1986) for both small shallow mines and large deep underground mines. Objective and scope The objective of this study was to demonstrate the feasi¬biliy of hydraulic hoisting in hypothetical examples of mine deepening. Underground grinding to a maximum particle size of about 700 um (about 25 mesh) is considered. The pumping of ground ore products with positive displacement plunger or membrane type of pumps at working pressures of up to 15 MPa (2200 psi) is a thoroughly tested technique (Venton, 1986). Hydraulic hoisting system A hydraulic hoisting system is described schematically in Fig. l . The ore is mined, handled, and crushed conventionally. It is then ground wet underground. The slurry is then tempo¬rarily stored in an agitated tank and pumped to an agitated receiving tank on the surface. The ore is then further processed in the concentrator. The capacity of a pipeline is very high. For example, an annual production of 500 Kt (550,000 st) of ore can be handled in a 100-mm-diam (4-in.-diam) pipeline. Systems layout - economic effectiveness Schematic mine layouts are presented that represent situ¬ations where hydraulic hoisting often is the most economical alternative. A situation where the ore is trucked to the level of the existing hoisting system is shown in Fig. 2 (following page). With hydraulic hoisting, only a shaft for ventilation, pipe¬line, and personnel are needed. In a first phase (Fig. 2), a hydraulic hoisting installation with crushing and grinding units, storage facilities, and pumps has been located at a level of about 400 to 600 m (1310 to 1970 ft) below the surface. With further development of the mine, the hydraulic hoisting

Jan 1, 1989

By Norman A. Jull

"IntroductionThe scope of this paper is intended to deal mainly with cyclones in grinding circuits. However, the section on Cyclone Equipment, contains more general descriptions, to cover most of the cyclones used in mineral separation plants.Cyclones as heavy media separation vessels are discussed by Mark Freberg (this volume). Their use in tailings deslirning is discussed by P.C. Lighthall, eta/. (this volume).Cyclone EquipmentCyclone TerminologyApexObviously, the apex of a cone is the smallest end. However, with cyclones the term is usually used for the fitting which is attached there to control discharge of the underflow stream.Note that the cyclone need not be so mounted that the apex is the lowest point, although that is the most common method. Keeping the apex below the rest of the cyclone helps avoid plugging when the underflow contains very large particles and the tonnage of underflow solids can fluctuate.Various devices for adjusting apex diameter or otherwise controlling the underflow are discussed later under ""Cyclone Construction"".BypassingThe transport of a portion of feed slurry directly to underflow so that classification is bypassed by that portion of feed.This action is fundamental in any hydraulic classification, whether gravity or centrifugal, because the large particles going to underflow have some void volume between them, which remains filled with feed slurry.D50By definition, D50 is that particle size which has an equal probability of going to overflow or to underflow.It is calculated by drawing a curve of recovery vs particle size and noting the size at which 500Jo recovery occurs.This may be done equally with corrected or with gross recovery (see below) and the resulting value should therefore be identified as d50c (corrected d50) or as d500 (gross d50).Note also that it is common in industry practice to plot size analysis data on the retained size rather than on the average of passing and retained (the middle of the size band). To portray sizing alone it makes no difference, but to read a D50 value off a curve of corrected or gross recoveries, it is essential to plot those values on the average size of each band."

Jan 1, 1989

By N. C. Joughin, H. Wagner

Research is a business activity, and is as different from other business activities as banking is from mining. attempting to use research to solve their problems, managers do not always recognize its unique features, are frequently disillusioned with the outcome. With a view to enabling managers to use research more effectively, an outline is given of the features of research as applied to mining. Types of research are distinguished, and stages in the research-and-development process are identified. The time-scales and resource requirements of the various types and phases of research are explained. Examples of research that have reached implementation in gold mining are given to illustrate the features mentioned. Practical and economic considerations are discussed, and pitfals and recommendations in the use of research are highlighted.

Jan 1, 1989

Provide guidance on the selection of millisecond initiator delays between blastholes in surface mine blasting to provide a desired degree of rock fragmentation consistent with safety and vibration considerations. The Problem Blasting remains the primary means of fragmenting, rock for all kinds of mining, quarrying, construction, and excavation activities, and it is the only practical and economic method of breaking up and moving large amounts of material such as coal overburden and stone aggregate. Because of the large amount of blasting done, typically using 4 billion pounds of explosive to break about 8 billion tons of rock annually in the United States, a small improvement in blasting performance will have a significant productivity impact. Standard blasting practices involve the selection of time delays in a blast for at [cast three purposes: (1) to control energy flow to minimize adverse vibrations, (2) to provide sufficient time relief for good rock displacement, appropriate muck pile shape for digging, and the prevention of collar violence, misfires, and flyrock, and (3) to provide an appropriate amount of interhole stress wave and gas pressure action for a desired fragmentation size distribution. Timing guidelines that exist are based on subjective observations rather than measurements, even for the relatively new casting methods. Until this Bureau study, no definitive analysis had been done to quantify the fragmentation and productivity of full-scale blast rounds as functions of precision delay timing.

Jan 1, 1989

By Denholm W. T

The SMELT-2 package is specifically designed to perform on-line simulation of smelting processes. This paper describes its application to the simulation of continuous matte converting followed by reductive slag cleaning in SIROSMELT reactors. The matte, containing 50% Cu is assumed to be produced at the rate of 20 tph in a continuous matte smelting furnace such as an Outokumpu Flash Furnace, Noranda or Sirosmelt reactor. Two alternative fluxing strategies in the converter are examined, namely: ò conventional silicate slags, ò calcium ferrite slags, and the flow sheets associated with each strategy are discussed. A regular solution model is used in the present study to account for the variations in the activity coefficients of components in the slag.

Jan 1, 1989

By Jai Ghosh, Aprad E. Torma, Roger Guay

The catalytic effect of ferrous ion in the industrial biohydrometallurgical heap and dump leaching processes is explained. During the bacterial leaching of metal sulfides, ferric ion will partly be hydrolyzed and a variety of sols, gels, amorphous and/ or crystalline mono- and polynuc- lear hydroxo- and sulfato complex species formed, especially by olation and aggregation reactions. There are many problems associated with these iron precipitates especially in the purification of leach solutions. The present study will discuss the iron precipitation reactions; gives kinetic and thermodynamic evaluations of the effect of temperature on pyrite and ferrous iron oxidation; and reports on the tolerance of heavy metal ion concentrations by Thiobacillus ferrooxidans.

Jan 1, 1989