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By J. K. Whyatt

The Bureau of Mines, under a cooperative agreement with Callahan Mining Corp., measured rock displacement at the 4,7S0-ft level of the 5,100-ft-deep rectangular, timbered Caladay Shaft in northern Idaho. Displacements were measured with multiple-position borehole exten-someters (MPBX) installed 4 ft above the face and timber extensometers (TE) installed with the timber sets. This report presents the displacement data along with preliminary, qualitative observations of rock behavior. The measured displacements showed an instantaneous response to shaft sinking and significant time dependency. The relative magnitudes of displacement measured at the shaft walls were heavily influenced by local geologic structure and distance from the shaft bottom.

Jan 1, 1987

By K. D. Hester

"1.0 INTRODUCTIONThe uranium industry started in Canada with the reopening of the gravity concentrator at Eldorado's Port Radium mine in the North West Territories in 1942. In 1948, uranium exploration and processing was opened to the private sector, and the Federal government offered special pricing incentives to the industry. Eldorado explored the Lake Athabaska deposits in northern Saskatchewan, and in 1953 opened the Beaverlodge mine. Other mines in the area soon followed. In 1953 also, the deposits in the Blind River - Elliot Lake area and in the Bancroft area of Ontario were discovered. Mines and mills were quickly developed in these areas.Canadian uranium production peaked at 15,900 short tons of U3O8 in 1959. In that year, uranium exports at $300,000,000 exceeded those of all other minerals in value. On October 1, 1959, Canadian uranium operations employed 13,900 people.Up to 1956, it was a seller's market. By 1958, world production of uranium was far ahead of requirements. Accordingly, in November of 1959, the USAEC announced it would not renew it's options for continued delivery of uranium from Canadian mines. This led to the ""stretchout"" of existing uranium contracts, and many mines were shut down (see Table 1) .In the early 1970's, a commercial uranium market seemed to be developing. In Ontario, at Elliot Lake and Bancroft, mines reopened. But competition was coming from the Athabaska basin of Saskatchewan. Currently it is these high grade, open pit deposits of northern Saskatchewan which are in the forefront of Canadian uranium developments. Canadian developments since 1942 reflect the political and market forces, as well as metallurgical progress and changes in environmental standards. This paper attempts to show these process changes in broad perspective."

Jan 1, 1987

By G. M. Wilemon

The Bureau of Mines conducted preliminary investigations on the use of an acid-alcohol leaching technique for recovering phosphate values from phosphate matrices. H2S04 and methanol were used as the leaching agents. Starting-matrix particle size and acid-apatite ratio were found to significantly affect the efficiency of phosphate leaching. Phosphate extractions of more than 80 pct were obtained when minus 200-mesh ore was used and the acid-apatite ratio was 8:1 or more. The iron and aluminum oxide impurities (R203) present in the crude acid products were monitored, and R203-P205 ratios are reported. Phosphate extractions in excess of 80 pct also were obtained when phosphatic clay wastes were leached. Typically, leach slurries filtered using test leaf filters ex-hibited filtration rates of 100 lb/(h·ft2) or more.

Jan 1, 1987

By J. A. Hrabik

The feasibility of mining deep phosphate deposits by a borehole mining system was compared with mining by proven conventional techniques. An economic comparison of the borehole mining system with conventional dragline and bucket wheel excavator mining systems was completed at various mining depths and production rates. Hypothetical phosphate deposits, with various overburden thicknesses and reserve tonnages, were defined. Geologic conditions necessary for the application of the borehole system were identified. Discounted cash flow analyses based on derived capital and operating costs were used to generate rates of return and product prices. Borehole mining was found to be more economical where overburden thickness was 46 m (150 ft) or greater. However, at 15- and 30-m (50- and 100-ft) thicknesses, conventional surface mining was more economical. Overburden thickness has a great effect on the economic feasibility of the conventional mining systems but less effect on the economics of borehole mining. Economies of scale are only realized in conventional mining, since larger equipment is used to achieve greater production, whereas increased production from borehole mining is achieved using additional equipment units. A comparison of the environmental effects of borehole and conventional surface mining systems showed that borehole mining is environmentally more desirable.

Jan 1, 1987

By J. P. Landriault, F. W. Harrison

"Zinc-iron alloy coatings can be produced by either thermally alloying hot-dipped galvanized steel or by electro deposition. Stelco Inc. produces a thermally alloyed Zn-Fe alloy-coated steel, which is mechanically wiped to remove free zinc.A more extensive use of Zn-Fe alloy-coated steel has been predicted for unexposed autobody and structural part applications, since this material is characterized by good spot weldability and formability, and provides superior corrosion resistance under automotive primers.This investigation has examined the coating composition, corrosion resistance, spot weldability and formability of Stelco's Zn-Fe alloy-coated steel and found its properties to be similar to those of Zn-Fe alloy-coated steel produced by post coating annealing.IntroductionRecently, there has been increased automotive interest in galvanneal, which is characterized by good spot weldability, good paintabilityt and good corrosion resistance when primed. Stelco produces a thermally alloyed zinc-iron coated sheet product similar to galvanneal. However, this product is produced by mechanically wiping the free zinc from the surface of hotdip galvanize to expose the underlying zinc-iron alloy.The surface of Stelco zinc-iron alloy-coated sheet is matte gray and has longitudinal streaks which result from contact with Kevlar wipers during production (Fig. I). This paper describes the coating composition, corrosion resistance, weldability, formability and surface appearance of Stelco zinc iron alloy coatings and, wherever possible, compares these properties to those of galvanneal."

Jan 1, 1987

The Hunter Fracture Zone can be traced into the Fiji group, and onshore SE Viti Levu in the form of NE-trending morphostructures. NW- trending morphostructures offset the NE elements. Structural mapping of Suva Harbour indicates that the NE elements are grabens bordered by faulted monoclines. Faulting is characterised by block-rotations and dip-slip displacements. The NW morphostructures are faults displaying elements of both dip-slip and strike-slip movement. Structural overprinting suggests that the NW faults represent the youngest phase of deformation, and current seismic activity occurs on this trend. A conceptual, geomechanical model of the deformation invokes toppling and wedge failure at the edge of the Fiji platform, translating material downslope into the Hunter Fracture Zone. The interference pattern produced by the superposition of the NW on the NE structures consists of a series of circular features bearing superficial resemblance to volcanic centres. Known mineral deposits in SE Viti Levu correspond closely to these features. The formation of the circular features postdates mineral genesis, suggesting that the features provide a focus for the enhanced exposure of mineral deposits rather than a source of mineralisation. There is a close association between mineralised exposures and interference patterns in extensional structures in SE Viti Levu, and a correlation between these structures onshore, and the Hunter Fracture Zone cum South New Hebrides Trench offshore. Future mineral exploration in the SW Pacific will benefit by closer consideration of the geologic structure of Pacific islands bordering the extensional regimes of deep oceanic trenches.

Jan 1, 1987

By Fletcher A. E W

Ever since it made its debut in 1962, in the form of a Robbins 31R, the raiseborer has become an accepted tool in the mining and civil construction industries. The first raiseborer to be used in the Witwatersrand goldfields made its appearance in 1968. This was a Robbins 42R which could raisebore 185m deep holes to 1,22m diameter. From 1968 to 1973 capability increased with the introduction of first the 61R, then the 71R and finally the 83R, which could raisebore 610m deep holes to 3,66m diameter. This created a demand for larger holes but the cost of bigger, more powerful machines requiring larger, stronger drill pipe, cutters and other accessories was prohibitive. To avoid replacing existing models such as the 71R, and in order to increase their capability, the concept of reaming in two stages sequentially was developed jointly by a German drilling equipment manufacturer, Wirth, their South African subsidiary, Transbor, and a local contractor, Rocbor Raiseboring and Mining Contractors. The result, the Sequential Reaming Head, proved most successful and existing machines, normally limited to 2,44m diameter holes, could now ream to 3,66m diameter. This created a demand for even larger holes. In order to maximise the use of the sequential reaming head to meet this demand the HG330, and subsequently the HG330SP raiseborer were developed. Using a 4,26m/6,02m cutting head, these machines have raisebored holes 1000m deep in hard rock. The raise- boring of the first major hole to be excavated by this combination, the 484m deep x 6,02m diameter surface shaft at Premier Mine is described. Reference is also made to six other shafts which have been completed or are under construction.

Jan 1, 1987

By A. D. Agate

In developing nations, novel mineral processing methods like bacterial leaching are gaining prominence. The principles and practices for isolation and preservation of cultures used in bacterial leaching are discussed with special reference to cultures used in leaching copper from Indian ores. In all, 145 potentially useful microorganisms such as iron- and sulfur-oxidizing bacteria were isolated from various ecosystems of the copper mining areas in the country. The major organisms isolated by enrichment culture technique belonged to T. ferrooxidans and T. thiooxidans species. In addition, thermophilic cultures like Sulfolobus sp. and thermophilic thiobacilli were also isolated. The process of copper leaching was scaled up to the 300-kg level in PVC columns. Since the preservation of efficient cultures in active state was vitally important, a new method was devised that preserved the activity of thiobacilli for a period of more than two years. The novel method of storage in sterile chalcopyrite ore at 8°C can be considered an important advance.

Jan 1, 1987

The distribution of p(~rphyt1 copper deposits, in time as well as place, is used to propose an occurrence model based on the genesis models of Sillitoe and Rona. A magmatic source of the metals is accepted. The characteristic metallogenic epoch and the migration of the mineralization event along an elongate metal province are explained as the result of subduction of an obliquely- oriented strip of mineral-enriched material on the oceanic plate. Two mineral-enriched trails emanate from a hot-spot source of high-intensity hydrothermal activity in an oceanic rift. Because the whole plate system moves relative to hot spots, the hydrothermal source appears to migrate along the rift, and the two trails are not parallel to transform faults, but form a broad "V" centred on the hotspot. Source loci are spaced at intervals of about 3000 km, resulting in the possible repetition of metallogenic epochs, in a subduction zone province, at about 100 m.y. intervals. The position of the mineral-enriched strip can be found graphically, given ages of a series of deposits in a province, and the plate convergence vectors. This knowledge provides an exploration tool at regional scale and, by reflection across the rift, the potential for exploration is extended across oceans. The model has implications for commodities and deposit types other than porphyry coppers.

Jan 1, 1987

By P. C. Kapur

The hierarchical relationship between three broad kinds of grinding models for a spatially homogeneous, linear, time-invariant batch grinding system are first established. Limiting and asymptotic arguments for arriving at approximate but simpler models are employed in all three cases. These parsimonious models -provide alternate and, in some respects, more incisive and convenient tools for the analyses of grinding processes and simulation of comminution circuits. In the discrete-size, discrete- time class of models, a reduced mill matrix is derived, which is seemingly adequate for those grinding circuits whose identification otherwise is difficult because of limitations on the quantity of data and its quality. In discrete-size, continuous-time types of models, parameter lumping has been employed for obtaining a G-H solution which is quite accurate and exceptionally useful for graphical display of data, model verification, and parameter estimation and simulation. In continuous-size, continuous-time models, a similarity transformation is used for solving the integrodifferential equation of grinding. This solution provides a unified framework for a number of apparently diverse empirical grinding phenomena such as self-preserving behavior of ground particle size distributions and energy laws.

Jan 1, 1987

By Collins AR, Meares RMD, Graham JM

Exploration programs for both alluvial (placer) and hardrock platinum group metal deposits are being conducted in Papua New Guinea by a joint venture between Degussa AG and Pancontinental Mining Limited. Prospective areas were defined on the basis of ultramafic/ophiolitic source rocks shedding detrital platinoid grains. Field sampling techniques including churn drilling, together with appropriate laboratory analytical and mineralogical techniques, were developed and are contributing to the success of the exploration programs.

Jan 1, 1987

By K. O. Bennington

The thermodynamic properties of two manganese silicates, pyroxmangite and fowlerite (zincian rhodonite), were experimentally determined by the Bureau of Mines. The standard enthalpies of formation were determined by hydrofluoric acid (HF) solution calorimetry, the low-temperature heat capacities by adiabatic calorimetry, and the high-temperature heat capacities by differential scanning calorimetry over the range 322 to 1,372 K. Data for the standard enthalpy of formation (AH298), the derived standard entropy (S298), and the standard Gibbs energy of formation (AGf 298) are as follows: Pyroxmangite [(Mn0.9554Cao,0446)(Si03)J- AHf298 319.668±0.46 kcal/mol AH298 (from oxides)... -7.215±0.11 kcal/mol 5295 23.785±0.048 cal/(mol'K) AGf298 -301.190±7.96 kcal/mol Fowlerite [(Mno.7o3Zno.0884Ca0.2086)(Sio3)]--AHf298 ?... -329.914±0.419 kcal/mol AH298 (from oxides)... -8.400±0.104 kcal/mol 5598 21.949±0.059 cal/(mol-K) AGf298 -310.716±7.99 kcal/mol These experimentally determined values were combined with data from the literature to calculate the Gibbs energies and equilibrium constants of formation over the temperature range of the measurements. Standard enthalpies, Gibbs energies, and equilibrium constants of formation are given as a function of temperature from both the elements and the constituent oxides.

Jan 1, 1987

By Hargraves A. J, Smith J. W

Experiments conducted at Tahmoor Colliery, Sydney Basin, have demonstrated the variability in chemical and isotopic composition of seam gases issuing from boreholes in the Bulli seam and desorbing from lump coal from the same source.From this work it appears that an immediate preferential release of methane accompanies the physical disturbance of the coal seam by penetration with development or drilling or by detachment. In addition, both early released methane and carbon dioxide are depleted in 13C relative to later desorbed gases, therefore the analyses of gas samples taken after such events may not reflect the true bulk composition of the undisturbed seam gas in situ. A method for overcoming this problem by taking gas samples at depth in the "steady state" is proposed.

Jan 1, 1987

By O. Fernandez, M. Vesely

Abrasive grinding, leading to ultrafine product and "critical size" material buildup inside the mill, is proposed as the cause of high power consumption and low capacity in many fully autogenous grinding processes. Addition of steel balls (hence, semiautogenous grinding) or pebble removal and separate crushing have been used, with different efficiencies, to overcome the problem. Information and data for the conceptual analysis, basic design, and operation of a pebble crusher at the Los Bronces semiautogenous grinding plant is presented along with data showing a production increase of 1000 t/d (1100 stpd) and significant operating costs savings.

Jan 1, 1987

By Jesse L. Hoyer

A Bureau of Mines turbomill was evaluated for use in the production of high-purity, ultrafine x-Sic powders suitable for advanced ceramics that could substitute for high-temperature alloys containing critical materials such as chromium, cobalt, and nickel. The effect of milling param-eters, such as type of dispersant, temperature, pH, and gas environment, on the milling of x-SiC was studied. The addition of dispersants improved the grindability of x-SiC. Of the six dispersants studied, the best results were obtained with Mara-sperse N-22. Grinding efficiency was also increased when the x-SiC was milled in a basic slurry and at elevated temperature. Gas environments did not appear to affect grinding of x-SiC. Optimum grinding efficiency was obtained at 50° C in a slurry at pH 9.5 with Marasperse N-22 as the dispersant. Under these conditions, minus 100-plus 200-mesh x-SiC was ground to 80 pct less than 1 um in 4 h.

Jan 1, 1987

By Edward L. McHugh

In 1984, at the request of the Bureau of Land Management, the U.S. Bureau of Mines studied an 84,165-acre portion of the 84,935-acre Clover Mountains Wilderness Study Area (NV-050-139) in order to evaluates its identified mineral resources. The area studied is in Lincoln County, NV, about 90 miles north of Las Vegas, NV. No mineral resources were identified in the study area. Volcanic rocks are the most common in the study area, consisting mainly of a thick sequence of ignimbrites in a cauldron complex. Cambrian to Triassic marine sedimentary rocks and Cretaceous to Oligocene clastic rocks are along and partly inside the west and south sides of the study area. No mineral production ha s come from the study area, but gold, silver, copper, and fluorspar have been mined nearby. Eleven mines and prospects in or adjacent to the study area were examined. Workings inside the study area include two shafts, 10 and 60 ft deep, and eleven shallow prospect pits at four sites along the west edge.

Jan 1, 1987

By Howard C. Pettibone

Mine safety personnel reported occurrences of excessive "glove-fingering" and other problems with resin-grouted roof bolt installa tions. To study these problems, the Bureau of Mines designed a test plan to (1) obtain baseline information on several resin cartridges and (2) investigate the variables involved in the installation of a resin bolt. Three brands of resin representative of the industry in January 1983 were selected for cartridge evaluation. The installation variables selected for study were the method of installation, the hole depth, and the hole annulus. These variables were studied by installing a series of bolts in concrete blocks using different values for each variable. Results of the research show overspinning the resin may cause problems, but they can be avoided by using the spin times recommended by manufac-turers. Excessive glove-fingering is not a problem if the manufacturer-recommended installation procedures are followed.

Jan 1, 1987

By D. A. Knight, V. G. Medina

Kidston's 14 000 t/d mine and mill complex in Queensland, Australia, started operation in January 1985. During its first 18 months of operation, the mine produced over 7000 kg (225,000 oz) of gold, making it the largest gold producer in Australia. This paper describes the planning, logistics, flowsheet, and process for the Kidston project, and some of the problems encountered during startup and the measures taken to correct these problems.

Jan 1, 1987

By A. J. Neale, B. C. Flintoff

A relatively inexpensive and reliable method of using liquid phase tracers to aid in the solution of material balance problems is introduced. The method is of value in situations where one is required to calculate a material balance around a process that has the operating appearance of a "blender" or "splitter" with respect to the available slurry sample data. The paper briefly reviews material balance development and tracer applications in mineral processing, introduces the problem to he addressed, and provides both theoretical and industrial evidence establishing the potential of the method.

Jan 1, 1987

By Parfitt RL

A quarter of the North Island, New Zealand is covered by weathered volcanic tephras of mainly andesitic and rhyolitic compositions. Rapid weathering of basic volcanic glass and slower weathering of acidic glass have produced short-range order alumino-silicate clays such as allophane. Although amorphous to x-rays they have a high degree of local structure. Allophane comprises hollo spheres of approximately 40 diameter and 7 X wall thickness. This small particle size and morphology gives a very high surface area (up to 800 m2/g). Ferrihydrite is another short-range order clay of similar small size and high surface area; it has ò formed from the rapid oxidation of water containing ferrous iron derived from volcanic rocks. The quantity of allophane present in tephra depends upon the climate, the nature of the volcanic glass and the time it has weathered. In New Zealand highest amounts (-50%) occur in beds of andesitic ash deposited on old ignimbrite surfaces with mean annual rainfalls >1600 mm. Both allophane and ferrihydrite will react with oxyanions, such as phosphate, arsenate or borate, and remove them from solution. Other anions such as fluoride also react with aluminium sites on the mineral surface. At NZ Soil Bureau, Department of Scientific and Industrial Research (DSIR), New Zealand, techniques have been developed for granulating allophane to enable it to be used to remove pollutants from solution without dispersion into the liquid phase. This granulated allophane can be used to remove phosphate from sewage effluent or fluoride from tap water without having a sedimentation stage to remove the clay.

Jan 1, 1987