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By L. J. Vincze

The program of study of pellet binder materials was begun by the ORF in 1963 to examine various Canadian materials as substitutes for bentonite which is imported in large tonnages (199,270 tons in 1969) from the U.S.A. for Canadian pellet plant operations. Most of the raw bentonite used in Canada originates in Wyoming, North Dakota and more recently Greece, resulting in relatively high transportation costs to pellet producers. Some Canadian bentonites available in Western Canada (Alberta) can be beneficiated for uses as pellet binders but could not compete in cost with U.S. sources due to the cost of beneficiation and the higher rail transport charges to Eastern Canada. It is difficult to find a substitute for bentonite, and many materials have been investigated by research groups but, so far, no economic substitute is in use. However, some success is apparent in studies of low cost materials such as clays, sea weed, peat moss and low grade coal, The work done by the ORF over several years has covered systematic test¬ing of Ontario clays, lignite, some types of tree bark, waste sulphite liquors of various kinds, and peat moss as binders for iron ore pellets. The major effort has been concentrated on peat moss and has included a study of the influence of different additives. Since analysis of peat moss for humic acid is difficult and time consuming, a certain amount of time was devoted to development of improved methods, the most useful of which was a spectrophotometric method based on extraction of peat by sodium pyrophosphate for determination of humic substances. In the present paper, only the most recent work concerning the use of peat moss with suitable additives is discussed in detail, since it is the most conclusive and best documented portion of the program.

Jan 1, 1971

By Frederick J. McGarry, Fred Moavenzadeh

An experimental investigation of the thermal and mechanical responses of rock materials to laser radiation is described. Specifically, the following three topics have been studied in detail: 1. Temperature measurements on thin discs subjected to laser radiation. 2. Strain measurements on thin discs subjected to laser radiation. 3. Observation and evaluation of cracking and spalling phenomena in constrained and unconstrained thin discs respectively, subjected to laser radiation. In conjunction with the experimental work done, use was made of a heat flow analysis and a stress analysis program developed for this purpose. It was possible to theoretically predict the thermal and mechanical responses of a rock specimen to laser radiation and then compare them with experimental observations. Good correlations were obtained.

Jan 1, 1971

By N. Nemeth, L. L. Sirois

The role of the filter medium in continuous-vacuum filtration and the special circumstances which influence the resistance to flow through the porous cake and filter cloth are discussed. Due to negative pressure differential, gas bubbles evolve in the slurry, constrict passages in the filter cake and medium, and further restrict flow through the tortuous channels. Filtration is a liquid-solid separation process taking place at a porous medium under a pressure differential. The liquid passes through the medium; the solids are retained on the medium as a partially dewatered cake. Filtration is far from a simple process and has been described in terms ranging from "complex" to "subtle." Because of the many variables involved, no unified filtration theory has been developed, and the filtration process is still considered very much an art. In industrial filter design, basic relationships, whether derived for idealized conditions or developed empirically, are usually adapted to suit local conditions. In the mining industry where continuous-vacuum filtration is the main dewatering process, the physical state of the concentrates and the relatively low pressure differentials permit the assumption that the cakes are noncompressible, an assumption which leads to the use of theoretically sound rate equations. Notwithstanding this simplification, there are other problems, unique in the application of vacuum to dewatering, and until now completely ignored, which demand special attention. The basics of filtration involve the capture of solids on, while permitting the flow of liquid through, a porous layer of cake and cloth. Flow is determined by the structure of the solids which make up the cake and the particles permanently attached to the cloth. The problem of this structure, essentially one of solid geometry, has been considered insoluble by Hatscheckl as early as 1907 and by Freshwater as recently as 1967. Since cake structure is determined by the slurry parameters, that problem is far too large for inclusion in this study. For theoretical considerations, uniform buildup of the filter cake must be assumed; and for efficient practical operation, the resistance of the medium must be kept constant over long periods. The latter can be achieved by careful selection of the filter cloth, since the greatest part of the total filtration resistance will develop at the cake-cloth contact. This paper discusses the role of the filter medium in continuous vacuum filtration and the special circumstances which influence the resistance to flow through the porous cake and the filter cloth.

Jan 1, 1971

By James M. Neilson

In contrast to the rather generalized title of this paper, the subject of discussion will deal with two specific cases of sliding in glacial lake clays in northern Michigan. The slides in question occurred on lands owned by the Upper Peninsula Power Company a short distance south of Lake Superior. Slope failure problems have plagued the Company's operations for many years. It is hoped that this paper may provide some insight into the causes and possible mechanisms of clay slides in general as well as providing details of the two slides specifically cited. LOCATION The Upper Peninsula Power Company's Victoria facilities lie in section 29, T. 50 N., R. 39 W., in Ontonagon County, Michigan. The power site is situated on the West Branch of the Ontonagon River, approximately five miles southwest of the town of Rockland and only one mile to the southeast of the old mining location of Victoria. The area lies wholly within the Precambrian Shield and it is geologically similar to adjacent parts of Wisconsin, Minn¬esota, and Ontario. (Figure 1). THE VICTORIA HYDROELECTRIC SITE The Victoria hydroelectric power facilities were constructed in 1930 on a portion of the West Branch where meanders are conspicuously developed. The generating station is actually sited on an abandoned meander at a place where valley widening has occurred. Water is conducted from Victoria Dam through a 6000-foot, 10-foot diameter wood stove pipe - through a surge tank - and into the powerhouse where

Jan 1, 1971

By Maurice Allais

El presente texto señala la importancia de la ciencia económica en la formación del ingeniero. La ciencia de la economía es vital para un ingeniero -en tanto enseña eficiencia en su propia especialidad, así como los organiza. De otro lado, se revisa la teoría de los óptimos económicos, su metodología y las necesidades efectivas para un ingeniero.

Jan 1, 1971

By R. Hogg

Based on a simplified model for the motion of particulate materials in horizontal, rotating cylinders, approximate expressions have been derived relating the power consumption of a tumbling mill to its dimensions and speed of rotation and to the amount and nature of the charge. The basic assumptions underlying the model are that there is no slip between the charge and the mill shell, that the free surface of the charge remains essentially planar during rotation and that there is no transfer of momentum from the material flowing down the free surface back to the mill shell. The relationships formulated from this model have been shown to be in excellent agreement with experimental results taken from the literature. While the requirements of the model are most closer met at low speeds of rotation, the results appear to be valid even for speeds up to 70-80 percent of the critical speed. Poorer agreement between theory and experiment is found when the charge consists of relatively large particles (balls) and when the filling of the mill exceeds 50 percent of the available volume. Qualitative explanations of these deviations have been offered.

Jan 1, 1971

By D. S. Choi, R. Stefanko

There are a number of complex factors that influence the effectiveness of anchorage to maintain tension in rock bolts. However, a plastic analysis of the anchorage site employing certain simplifying assumptions with application of the Mohr-Coulomb criterion appears to explain the observed phenomena. Such an analysis has been made and a correlation sought with field and laboratory tests. Field tests were made in an anthracite mine in eastern Pennsylvania and included pull tests and long-term tests of a variety of anchorage devices in two basic lengths, 30 and 42 in. in two widely differing seams. Performance is reviewed for wedge, expansion shell, and resin anchorage. Laboratory tests duplicated many of the field conditions but in addition compared the performance of shells with normal and reversed serrations. This performance was compared with the predicted results from the plastic analysis. One of the major problems in conducting long-term underground tests is the selection of suitable instrumentation. All installed bolts were fitted with spherical and hardened washers to insure the best possible torque wrench readings. In addition, commercially available load cells were used. Finally, the performance of a specially developed strain-gage-equipped ring cell is viewed. Rock bolting as a method of support continues to increase with applications in many other industries in addition to mining. Nevertheless, with nearly 55,000,000 roof bolts installed in coal mines alone last year, this remains as the single greatest use. While bolts have frequently supported ground where conventional timbering could not, there are relatively few design criteria; and trial-and-error procedures prevail. Furthermore, there has been a lag in development of suitable instrumentation that is simple to install and read out, sensitive, durable, reliable, safe, and economical in evaluating the effectiveness of a bolt over long periods of time. Therefore, the pull test continues to be the most popular method of evaluating the applicability of a certain type of roof bolt under specific installation conditions. At The Pennsylvania State University in the Dept. of Mining, research has been conducted for a number of years to measure bleed off in carefully controlled laboratory experiments as well as in underground investigations."-' Unfortunately, most of the instrumentation developed has been primarily suitable only for research purposes, not possessing all of the aforementioned characteristics desirable for routine underground use. Other groups also have met with restricted success. Therefore, while relatively crude, the torque wrench continues to remain as the most widely used load measuring device. While both field and laboratory tests continue to be con- ducted, analytical analyses are attempted to discover the more important design parameters in order that more efficient anchorage might be devised. Bolts are being used for a greater variety of purposes in mining. Suspending wire sideframe belt conveyors from roof bolts is a common application. The suspension of a monorail transportation system presents yet another. One such system has just been installed in a recently reopened anthracite mine and is presently being evaluated under production conditions. Preliminary studies revealed that a considerable cost reduction was possible by suspending the monorail on bolts anchored in the top. The monorail was to be installed under two widely differing conditions—a competent sandstone above the Buck Mountain seam and a softer shale top above the Skidmore. The type of anchorage device, length of bolt, and long-term performance, consistent with economy and safety, had to be established for the installation once the decision was made to suspend the system on rock bolts. This paper describes some of the testing procedures leading to a final selection. Theoretical Analysis of Expansion Shell Anchorage A detailed look at an expansion shell assembly might shed some light on the factors involved in the design of a suitable shell, Fig. 1. When a bolt is rotated, the tapered plug is forced downward, expanding the leaves laterally to grip the sides of the hole. Two friction surfaces are present: (1) the interface of the plug and leaf and (2) the interface between leaf and rock. The relationships of these friction planes, geometry of expansion shell, and properties of the rock are important in the design of an expansion shell. Therefore, an analysis assuming the rock to behave as a rigid plastic material with its yield governed by the Mohr-Coulomb criterion was made." Furthermore, the effect of friction between the leaf and rock produced by serrations was analyzed.

Jan 1, 1971

In order to see the sand mining industry in the context of the coastal plain environment, the following points are noted. The coastal plain comprises several different geomorphological and ecological entities, some or all of which may be profoundly different from their condition before European colonisation, Sand mining is only one of a number of competing land uses which modify the environment of a given area. The frontal dune system in particular has undergone considerable deterioration and with the pressures of an ever increasing population, this deterioration will accelerate until an adequate control policy is Implemented.

Jan 1, 1971

By C. Kenneth Eilerts

A method is described for controlling instability in finite-difference computations of liquid saturation near the borehole of a recovery well. Differences of pressure-and saturation-dependent variables are indexed offcenter, upstream and downstream alternately, to provide a stabilizing average. It was found that size of the time step could be increased by a factor of 4 without loss of numerical stability. Finite differences of the variables occur in a variety of relative numerical sizes and combinations. Those relationships of the differences that contribute to instability may be identified by the computing program in which they occur and modified to assist convergence of the computations and execution of the partial differential equations of liquid and gas flow.

Jan 1, 1971

By James H. Barks

Exploration for ore deposits in southeastern Missouri in the 1950's resulted in the important discovery of lead, zinc, copper and silver in 1955. Further discoveries in the area led to the naming of the Viburnum trend. It has sometimes been referred to as the "New Lead belt" to distinguish it from older lead-producing areas to the east. As presently developed, the "trend" is 35 miles long, running north and south about 50 miles west of the Lead belt. Galena (lead) is the principal ore mined, with lesser quantities of sphalerite (zinc), chalcopyrite (copper) and silver recovered as economic by-products. The ore body is as much as 140 feet thick and 1,200 feet wide, and is found in the Bonneterre Dolomite (Upper Cambrian) at depths ranging from 700 to 1,200 feet. Since its discovery many companies have engaged in exploration and several major companies have developed new mines and constructed mills and a smelter in the area. The first mine in the Viburnum trend came on stream in 1960, but as more mines came on stream and others reached capacity, lead production increased to the point that the Southeast Missouri Lead district produced 432,576 tons of lead in 1970 to become the world's largest lead-producing region (Missouri Geological Survey and Water Resources, 1971). The Viburnum trend area with its rolling, heavily forested hills and numerous clear running streams is in the Clark National Forest of the Missouri Ozarks. Until the recent development of its mineral resources, the area was sparsely populated and nearly unmarked by the activities of man. Industrial development is almost certain to be accompanied by environmental changes. In a day of growing awareness of the need to preserve the quality of the

Jan 1, 1971

By David P. Lindroth

The heat content above 25.0° C up to 1,000° C was measured for six rock types: St. Cloud Gray Granodiorite, Holston Limestone, Sioux Quartzite, Rockville Quartz Monzonite, Salem Limestone, and the basalt at Dresser, Wis. The calorimetric data were obtained with an isothermal jacket-copper block calorimeter. The experimental heat content data for each rock type are presented, along with specific heat data obtained from the temperature derivative of the heat content. For the six rock types the maximum deviations of the specific heats at a given temperature were within 10 percent below 575° C and within 34 percent above 5750°C. The increase in the values of specific heat range from a minimum of 13 percent for the basalt at Dresser, Wis. (temperature range, 100° to 1,000° C) to a maximum of 46 percent for Holston Limestone (temperature range, 100° to 870° C).

Jan 1, 1971

By Malcolm T. Wane

The subject matter of this paper, "Applied Rock Mechanics?," has its genesis in a recent field trip taken by the author. A more or less standard question asked at the mines visited was "How are you using the principles of Rock Mechanics to assist you in maintaining an efficient, safe, and competitive mining operation?" The question was couched in a number of different forms, but the intent was to determine whether or not a general theory based on reason and the scientific method was applied or whether the alternatives of tradition, intuition, ?common sense', revelation, ?shotgun methods' or authoritarianism were invoked. Perhaps two responses to this query will be illustrative of the general nature of the replies. At operation XYZ an extension to the known ore body has been found. The extension is of large enough size and grade that a mining scheme using load-haul-damp techniques is envisaged. Since this represents a departure from the present mining scheme, questions have arisen regarding pillar sizes, room and entry sizes and possible support requirements. A task force has been set up to expeditiously plan for these things and write the necessary specifications and requirements. The fundamental question was posed to members of this group.

Jan 1, 1971

By I. H. Warren

Hydrometallurgy has a well-known and established role in the production of manganese metal (1) and manganese compounds, including battery grade manganese dioxide (2). Also, several leaching processes have been developed and applied at various times for the recovery of manganese from low grade ores (3). Recently, interest in the hydrometallurgy of manganese has been stimulated by the problems presented in the processing of sea nodules (4). Fumes and dusts from the ferro-manganese furnaces also offer a potential field for the application of manganese leaching techniques (5). In treating low grade manganese ores a major requirement of the leaching process is that it should dissolve manganese from a mixture of manganese and iron oxides. The most selective reagent for this purpose is ammonium carbamate applied after preliminary pyrometallurgical reduction of the ore (6). Since soluble carbamate complexes of the postulated type (7) are formed by both manganous and ferrous, but by neither manganic nor ferric, ions, selectivety of manganese leaching is achieved by control of the reduction operation to yield, essentially MnO and Fe304? A potential improvement to this two step process would be to simultaneously reduce and selectively leach the manganese in one hydrometallurgical operation. This possibility has been experimentally studied and the results are described below. During the preliminary study of the stability of solutions of ammonium, ferrous and manganous carbamates at elevated temperatures, it was observed, contrary to the observation of Welsh (8) at lower temperatures, that

Jan 1, 1971

By Thomas V. Falkie, Robert Stefanko

Previous articles in this column have defined the manpower situation as it. applies to the coal industry. There is at present a shortage of experienced managers, mining engineers, technicians and skilled workers. The extent of this shortage is controversial, but it is sufficiently important to have received the serious attention of coal industry people at all levels. It has also been discussed by union officials, educators, government agencies and trade publications as well as other communications media. Discussion is not enough, however. A plan of action is needed. Some suggestions for such a plan are presented here. First, the coal industry must interest itself in government training programs. The U.S. Government (primarily the Bureau of Mines and HEW) is planning to spend or is spending millions of dollars to educate and train technicians, inspectors, engineers and miners. The new Federal Health and Safety Academy at Beckley, W. Va., for example, will involve an expenditure of $20-30 million for the physical plant alone. There are encouraging signs that the present hierarchy in the Bureau of Mines intends to seek the advice of mining educators on some of these projects, but industry should also demand a voice in the policy to be followed in making these expenditures.

Jan 1, 1971

By Norman F. Schulz

The technical excellence of separation achieved in a mineral concentration process, or any other process where two constituents of any kind are physically separated from each other, is expressed uniquely and quantitatively by the separation efficiency (E,): E. = (R - R,), where R is the percentage of the valuable constituent and R, the percentage of the waste appearing in the concentrate. The separation efficiency meets all the usual requirements of a true efficiency and is independent of the nature of the process used. It can be visualized as the percentage of the feed material that, in effect, actually undergoes complete separation while the rest of the feed is distributed randomly and unchanged into the two separation products. The problem of quantitatively assessing the results of a mineral concentration process recurs whenever one tries to decide which of two similar test results is more desirable. Although economic factors may greatly influence the eventual choice of process, they usually have very little to do with the technical excellence of a separation and are, therefore, not a consideration at this point. Concentrate grade and recovery, used simultaneously are the most widely accepted measures of performance, and if both the grade and the recovery are greater for one case than for another, the choice is simple. However, when the results of closely competitive operations are compared, it often occurs that one set of test results shows a higher grade and a lower recovery than another and the choice is no longer obvious. Laboratory investigations of a mineral concentration process applied to a given feed material can often be designed to yield successive paired values of concentrate grade and recovery over the practical range of the course of a separation process.' These results may be plotted as some combination of the cumulative values of grade, weight recovery, or unit recovery in the concentrate. The resulting correlations for two slightly different sets of conditions can then be compared qualitatively, or even quantitatively in particular cases.2 Such comparisons are not applicable, however, to individual concentration test results. The reduction of a separation test result to a single efficiency figure, preferably as a percentage of ideality, would afford the simplest and most precise means for comparing the results of competitive tests. The effective proportion of feed material that undergoes complete separation in any real concentration process, hereafter referred to as "separation efficiency," is such a figure. It is essily calculated from the usual feed and product data and can even be evaluated, in many cases, from data in publications describing various concentration processes. Mineral Concentration Processes and Their Evaluation Mineral Concentration Processes: The overall concentration process may be subdivided into a liberation process which severs the bonds between unlike mineral species, and a separation process, which sorts the resulting liberated particles into two products—a concentrate rich in mineral A and a tailing lean in mineral A. A perfect mineral concentration process is represented by the idealized scheme shown in Fig. 1 in which liberation and separation are not differentiated. The feed mixture consists of two mineral types which are completely liberated early in the process and then sorted by type. All the mineral particles of type A which respond uniquely to the selection forces acting in the ideal separator, report to the concentrate, while all the mineral particles of type non-A report to the tail-

Jan 1, 1971

Recent work on decoppering lead is reviewed CUS is formed rapidly even from dilute solutions of copper in lead. The mechanism of decoppering is discussed and an explanation for the retention of metals such as silver in lead is advanced. As decoppering tin appears to be an analogous process, the, Cu-Sn-S system is studied at 300°C.. CuS, which is not an equilibrium product, is found m decoppermg drosses. In the removal of nickel from lead, Ni3Pb2S2 is formed; preliminary measurements show the equilibrium nickel content to be greater than that obtained by stirring in sulphur. Decoppering bIsmuth IS thermodynamically favoured, but is complicated by the occurrence of CuBiS2 The Cu-Pb-S system IS the only one of the four studied where the equilibrium can be calculated simply, as the presence of ternary sulphIde or other phases invalidates calculations based on binary data.

Jan 1, 1971

By Robert W. Greene

Next month, American Commercial Barge Line Company will begin moving coal from mines on the old Camp Breckinridge property in Western Kentucky to TVA's new 2600 MW steam plant at Cumberland City, Tennessee. By April of 1973, this movement will reach a level of 7,000,000 tons per year. TVA bought the coal rights to this property from the General Services Administration in 1965 for approximately $7 million. The reserve contains about 120 million tons of recoverable No.9 coal, and about the same recover-able amount of No. 11 coal. TVA then contracted through competitive bidding with Peabody Coal Company to mine the No.9 seam through two slope shafts. The mines are about 300 feet deep and are separated by the one major fault on this property. The mine portals are approximately 3-1/2 miles apart, with the northern portal being over nine miles distant from the Ohio River (see Figure No.1). In 1969 TV A took bids on alternate methods for transporting 120 million tons of coal to Cumberland City at seven million tons per year. These alter-natives included overland transportation to the Ohio River by rail or conveyor, water transportation from Union County, Kentucky to Cumberland City, and total transportation packages from Camp Breckinridge to Cumberland City. The latter could be a joint land/water package, or all land (rail). Ultimately American Commercial Barge Line was awarded an $88 million package transportation contract to convey the coal from Camp Breckinridge to Uniontown, Kentucky; to store it at Uniontown in a quantity sufficient to allow ratable delivery to the steam plant; and to barge from Uniontown to Cumberland City via the Ohio and Cumberland Rivers.

Jan 1, 1971

By Donald P. Schlick

This Information Circular presents a brief historical digest of the early attempts of the Bureau of Nines and the U.S. Public Health Service to establish coal mine dust exposure standards. It reviews current, accepted standards of the United States as well as available standards of other countries.

Jan 1, 1971

By Irven A. Jacobson

The thermal reactions of l-methylindole were studied in the temperature range of 525° to 627° C in a flow reactor. The major products consisted of 2-methylindole, 3-methylindole, indole, quinoline, hydrogen, and methane. 2-Methylindole is formed from 1-methylindole by an irreversible isomerization reaction. The 2-methylindole isomerizes in a reversible manner to 3-methyl-indole, the equilibrium favoring the 3-methyl isomer. Indole is formed directly from 1-methylindole. Quinoline is formed from l-methylindole, 2-methylindole, and 3-methylindole.

Jan 1, 1971

By George H. Davis

The Caribou sulfide deposit near Bathurst, New Brunswick (Figure 1) is illustrative of one variety of strata-bound sulfide deposits. It consists of numerous near-vertical sulfide lenses which are concordant to the foliation and lithologic layering of low-grade metamorphic host rocks. Pyrite is the chief mineral in these lenses, but appreciable quantities of sphalerite, chalcopyrite, and galena are also present. Rocks in the Caribou mine area belong to the Tetagouche Group of Ordovician age. They consist chiefly of (1) quartz-sericite and quartz- sericite- feldspar schists, (2) greenschists, and (3) slate and phyllite. The trends of these steeply dipping rocks define the trace of a tight, steeply plunging fold structure, the Caribou fold (Figure 2). This fold plunges approximately 750 to the north-northwest; its axial plane strikes N.20°E. and dips steeply westward. Sulfide lenses of the Caribou deposit are associated spatially with the Caribou fold. The deposit is located in the fold along the contact between quartz-sericite and quartz-sericite-feldspar schists on the hanging wall and quartz-chlorite-sericite phyllites and graphitic schist on the footwall (Figure 3). Genesis of the Caribou deposit is ambiguous because its strata-bound form suggests syngenetic sulfide deposition, whereas its location within a fold suggests structurally controlled epigenetic mineralization. Acceptability of a particular genetic model rests on establishing the time of mineralization relative to deposition, deformation, and metamorphism of the associated rocks. To establish the timing for Caribou mineralization, the deformational histories of rock and sulfide, respectively, were compared. Epigenetic and syngenetic models can be tested against this interpreted structural history of the Caribou deposit.

Jan 1, 1971