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By Claudio Guarnaschelli

Alteration of the electronic distribution of mineral surfaces by light irradiation has been used to modify the adsorption characteristics of flotation reagents. Energy of a few electron volts is suficient to cause the necessary transitions that either enhance or retard the adsorption phenomenon. The adsorption characteristics of potassium ethyl xanthate on galena and marmatite are presented as functions of the energy of illumination, type of semiconductor, and surface oxidation. In dilute solutions, the adsorption differences are readily detected by controlled kinetic measurements. The correlation between the electronic distribution and the adsorption and desorption phenomena at the solid surface is gaining more attention and acceptance. These interrelations have found a practical application in mineral processing since all of the sulfide minerals display semiconducting properties. By varying the ratio of free electron to electron vacancies, the separation of ilmenite from rutilel and zircon from pyrochlore" has been executed successfully. Plaksin et al.' indicate three possible ways of utilizing the semiconductor properties of a mineral. The first one involves the control of the oxidation-reduction potential of the liquid phase, the second one consists of allowing selected additives to diffuse through the mineral surface, while the third one entails a change in the adsorption and chemical activity of minerals by irradiating their surface. The aim of the present work is to consider the effect of irradiation on the adsorption-desorption characteristics of natural minerals. Since the effect of irradiation is to change the electronic distribution at the surface:

Jan 1, 1971

By Bruce A. Kennedy

Lufthansa flight 497 roared down the runway and climbed rapidly through the early morning mist hanging over Pudahuel airport and the city of Santiago, Chile, into the brilliant sunlight above the clouds. As the plane banked onto course for Lima, Peru, we got what was possibly our last look at the beautiful snowclad mountains that ring Santiago. To the northeast was the massive hump of Aconcagua, the highest mountain in the Southern Hemisphere, wreathed in clouds and virtually looming over Rio Blanco, the new mine put into production by Cerro de Pasco just one short year before. Almost a thousand miles to the north lay the massive open pits of Chuquicamata and Exotica, and a little closer to Santiago the El Salvador mine. Behind to the southeast, clinging to the steep slopes of the Andes, was the large and awe-inspiring El Teniente mine at Braden. These mines, once the bastions of such companies as Anaconda and Kennecott, had a new owner-the Government of Chile. On the plane were a number of people who had spent a large part of their lives in Chile operating these mines and plants, and who now were suddenly faced with the necessity of starting new lives somewhere else. To them, this was their last look at the country which not too long ago was their home, a bittersweet moment of reminiscence and a time for questioning what the future held.

Jan 1, 1971

By Enrique Levy

The publication from which this paper was abstracted is the first at-tempt to correlate all the metallogenic deta compiled by the author for the preparation of the 1:2,000,000 Metallogenic Map of Central America. It is not a treaty of metallogenic theories but rather a careful effort to postulate metallogenic provinces and epochs with the intention to stimulate other geologists and mining companies familiar with the area to criticize and improve on the ideas proposed. The sole purpose being to find new mineral deposits for the betterment of our people.

Jan 1, 1971

By E. E. Remmenga

Often a collection of analytical data, which should reasonably be expected to follow the normal distribution, contains too many extreme values, which the experimenter is inclined to eliminate according to some arbitrary procedure. The stepwise computer procedure described for this purpose is similar to many other truncation procedures; however, because truncation of a basically normal distribution causes a downward bias in the estimated variance, this procedure provides a graphical method to compensate for the bias.

Jan 1, 1971

By Marcus M. Key

Silicosis among metal miners is an ancient disease, probably as old as mining itself.' However, the primitive forms of mining were not productive of much silica dust, and the short life span of slaves used in mining probably precluded the development of more than a few sporadic cases of silicosis. Early diagnostic terms of miners' asthma and miners' phthisis suggested an occupational relationship and a tubercular component, but little attention was given to silicbsis until the turn of this century when epidemics of silico-tuberculosis arose due to the great expansion of the mining industry in the United States, especially silver and gold mining. The expansion was accompanied by mechanization and the introduction of pneumatic tools, which generated increasing amounts of fine silica dust. Mining communities were crowded and hygiene was poor.' The tubercle bacillus would probably have flourished even without the predisposition of silicosis.' As is so often the case in occupational health, biostatistical analyses first called attention to the problem, and environmental-medical studies later confirmed its existence. The bio-statistical analyses were occupational mortality statistics compiled by the Prudential Life Insurance Company in 1907, showing evidence of excessive mortality from tuberculosis and relationship to dust exposure. I The

Jan 1, 1971

By Nathaniel Arbiter

There is a history in all men's lives, Figuring the nature of the times deceas'd, The which observ'd, a man may prophesy, With a near aim, of the main chance of things. W. Shakespeare, Henry IV; Part 2 Introduction This nation's first century embraced two stages of the Industrial Revolution. During one, what had been a colonial agricultural economy began to industrialize; water power, then steam after 1794, were the energy sources; coal and iron were the essential ingredients. The second stage started after 1850; aided by rich and diverse mineral resources, the country began its transition from the Iron Age to the Age of Metals. Early civilizations had been built on stone, and fairly high levels were sustained on iron. But the spectacular advances in the past century in communication, in construction, in transportation by sea, rail, land and air, and in much that characterizes modern civilization have depended increasingly on the use of the complete metallic and nonmetallic resources of the earth's crust. Thus it was appropriate to define the Industrial Revolution as “the period during which man's relationship to natural resources became utterly changed”, 1 with minerals playing a major and indispensable role. But we are now becoming aware that the relationship of man to natural resources must change again. On every hand the dangers inherent in the contamination of land, sea and air by the wastes of civilization are becoming apparent. And from the growing realization that mineral wealth is finite must eventually come other far reaching changes in mineral use and distribution. For on the scale of centuries we cannot continue to exploit mineral resources even at present rates, let alone at expanded rates, without eventual depletion of the more abundant resources, and early exhaustion of the less abundant. In the past our problems were relatively easily met by the development of new and improved machinery and processes. But the future will

Jan 1, 1971

By J. D. Vincent

During the history of man, the term concentration has had many meanings. Early in history, it may have been construed to mean sorting and smelting. Not many years ago, its definition included only the physical beneficiation processes. Today, and in this article, the term concentration is taking on the meaning of beneficiation and chemical processing, or either separately. An alternate definition could be: concentration is the process of recovering and upgrading an element or nonmetallic mineral so that the product can be used or refined for the needs of man. For the purpose of this article, concentration will have the same connotation as it does in the mineral industry, which has come to include processing methods such as leaching and chlorinization under this heading. Usually, smelting techniques and electrorefining are excluded and classified under the heading of refining. Using the broad definition of concentration, the areas of mining processing include not only the physical beneficiation processes and flotation but also hydrometallurgy and vapor-metallurgy. These methods include sorting, sizing, crushing and grinding, gravity concentrating, magnetic processing and flotation as well as hydrometallurgy and vapor- metallurgical processing.

Jan 1, 1971

By G. O. Crowell

This paper gives the history of the celestite deposit, now being mined by Kaiser Celestite Mining Ltd., near Sydney, Nova Scotia. Mining and milling procedures are covered, and the regional and local geology of the area are described, including the origin of the celestite.

Jan 1, 1971

By W. R. Davison, C. A. Brown, J. P. Carstens

INTRODUCTION The phenomenon of heat-weakening of rock with 10.6 micron radiation from a continuous-wave C02 gas laser has been investigated in detail at the Massachusetts Institute of Technology for over 5 years. The programs at MIT have explored the basic nature of the heat-weakening phenomena and rock fracture caused by heating (e.g., Refs. 1 and 2), and have resulted in quantitative estimates of the relationship between the amount and parer level of heating and the resulting decrease in the modulus of rupture of a rock beam in a three-point bend test (Ref. 3). Results of the tests reported in Ref. 3 indicate a greater than 90% reduction in the modulus of rupture for granite beams heat-weakened by a laser. These results prompted the U. S. Department of Transportation to seek an assessment of the expected feasibility of employing the heat- weakening concept in a full-scale tunnel boring operation. Present- day continuous rock-tunneling machines have demonstrated tunneling time and cost savings over drill-and-blast methods, when used in rock types that are easily broken by the cutters. However, cutter bits have not yet been developed which can easily penetrate very hard rock

Jan 1, 1971

By B. Ball, D. W. Fuerstenau, P. C. Kapur

A two-phase distributed-parameter model of the flotation process has been extended to allow consideration of the important process parameter, concentrate grade. A simple expression is presented for the grade of concentrate in terms of the zeroth and first moments of the concentrate distribution. An example is given for a binary ore containing two pure minerals each having nondistributed rate constants. For extend-ing the model to the distributed rate constant case, a cubic polynomial zoas utilized to simulate the feed distribution. One particular example is considered and grade-recovery curves are generated to show the dependence of such curves on the initial feed distribution. Operating flotation plant engineers have traditionally evaluated plant performance in terms of the recovery of valuable mineral and the grade of the concentrate. In both operation and research, grade-recovery relationships have been used as a guide for selecting flotation conditions. Weissl illustrated the use of grade-recovery curves in plant operation and considered the grade-recovery relationship to be a metallurgical one. The extensive experimental work of Chi" using standard batch flotation tests on iron ores shows that, even with extensive statistical correlation of data, little insight can be gained into the basic fundamentals of these relations. Such relations must depend on the kinetic behavior of the various mineral species in the flotation circuit. In his flotation text book, Gaudin3 considered the relationship of recovery and of product grade to flotation kinetic indices, but he did not extend his calculations to yield grade-recovery relations. Although Gaudin used a simplistic model for his analysis, he did recognize that variations in flotation rates must result from variations in locking, surface heterogeneity, particle size and shape, among other things. In a recent paper,' we presented a model of the flotation process that could be readily analyzed with an analog computer. This model combines the concept of a distributed set of rate constants"" with that of the two-phase flotation model,8" resulting in a model more powerful and flexible than previous ones. The purpose of the present paper is to show how this model can be used to generate grade-recovery curves and to determine the dependence of such curves on the various kinetic parameters. In this paper, the model will be limited to the semi-batch case, but extension to the continuous case is a straightforward step.

Jan 1, 1971

By C. G. Hunkin

In situ, or in-place leaching is concerned with the extraction of metals from natural mineral disseminations without removal from their geologic location which, in many cases, amounts to the reversal of the deposition process accompanied by a presumed increase in velocity of the processes, if the project is to be profitable. Solution mining processes involve removal of minerals such as sulfur, common salt, and potash, generally leaving cavernous voids, in contrast to in situ leaching which term is applied to the selective dissolution of a mineral from its gangue without sensible disturbance of the formation. Where such a process can be operated, the advantages are manifold and have been so recognized by miners from the earliest days of mining. Recent technological developments have encouraged a reassessment of the status of in situ leaching, and it now appears possible to extend the application of the method from a few isolated special situations to many uranium and copper deposits. Anaconda's interest in the techniques stems from long experience with vat and heap leaching, 'dump leaching, and natural leach activities associated with several established mines. Increasing activity through-out the industry has been noted, particularly in leaching low grade pillars and the peripheral zones of operating mines, often by the introduction of leach solutions via boreholes drilled from surface. Reactivation of dormant mines] using similar techniques has been successful. Over the long term, environmental improvement activity will lead to excess sulfuric acid production, even to a disposal problem. The cost of leach solutions and reagents must be reexamined in this light. The mineral industry now classifies as uneconomic deposits of readily soluole minerals whose potential value, on a per acre basis, may De several times that of many currently profitable oil field reser-

Jan 1, 1971

A predicted increase in aluminium production and the possibility of a diminishing supply of petroleum coke for anode electrodes in alumina reduction cells makes it desirable to find alternative electrode materials. Browncoal char, with a lower ash content and with an elemental purity similar to petroleum coke, was produced by leaching in hydrochloric acid, washing with water, and charring at 1,150°C. The cost of processing is estimated tobe competitive with petroleum coke.Without further processing the bulk density and real density were undesirably low, but by briquetting the coal before charring and crushing, the bulk density was improved to 92 per cent of the petroleum coke value andthe particle density was improved to 92 per cent of the density of petroleum coke by water displacement or 75 per cent by mercury displacement.Pre-baked electrodes were prepared from the char alone, mixtures of petroleum coke and char, and from petroleum coke alone, all bonded with coal tar pitch.The electrodes were tested for the usual physical properties and were evaluated for performance in a laboratory size alumina reduction cell.Electrodes based on brown coal char alone were found to be inferior in physical properties and performance, but mixtures of the char and petroleum coke, despite poorer density, electrical resistivity, and carbon consumptionon a theoretical basis, in performance tests gave up to 17 per cent better carbon consumption per weight of aluminium produced and 21 per cent better electrical current efficiency than the electrodes based on petroleum,coke alone.It is suggested that larger scale tests are warranted.

Jan 1, 1971

By G. A. Frame, J. G. Patterson

The 24,000-tpd Frood-Stobie mill grinding circuit operation and control are described. Changes implemented during the past three years to improve grinding efficiency and capacity are discussed.

Jan 1, 1971

By C K. Bell, L. S. Collett

An AFMAG survey was flown in 1968 over the Upper Nelson River area, Manitoba. The flight direction was northwest-southeast and flight spacing was 2 miles. In the Cross Lake Subprovince, AFMAG showed that an isolated peridotite outcrop was part of a dike that extended over 80 miles. Diabase dikes are not always marked by an anomaly, but isolated cross-overs, when used in conjunction with geological and magnetic data, permit their extrapolation. Anomalies coincide with areas of sulphide mineralization. In the Flin Fion Subprovince, known and unknown northeast-trending faults are detected. The Berry Creek fault was extended south through Tramping lake, then under the Paleozoic cover. Conductors were detected at, or near, the axes of major synclines within Amisk and Snow Group sediments. Granitic terranes have low conductivity and, because they are characterized by smooth AFMAG profiles, they can be delimited. AF.MAG is being recognized as a geophysical method that can aid geological mapping and interpretation. Its most important contribution to the geologist will be in regions where out-crops are sparse.

Jan 1, 1971

Esso-BHP have installed a production supervisory control system that is presently controlling the offshore oil and gas facilities on the Barracouta and Marlin platforms from an onshore master station. This control is achieved with a computerized master station onshore which uses a UHF radio system for telemetry and control.The system is designed to control, monitor, and gather data from a large number of oil and gas production platforms and has flexibility to handle future variations in operating conditions.The system will be extended to the Halibut platform late in 1970 and to the Kirlgfish platforms during 1971.

Jan 1, 1971

By Wilfred Walker

Much is known of the geography of the Alpine orogeny because it has now ended and all geosynclines are in their terminal, cordilleran form. The principle of sea floor spreading, continental drift, and mantle cells has gained general acceptance, but the number and position of the cells, even during the Alpine orogeny, is controversial. The oceanographers have demonstrated the uprises and in this paper it is suggested that downflows are marked by island arcs in the oceans and geosynclines (now cordillera) in the continents, for a total of about a dozen cells. Major mineral deposits associated-with the Alpine downflows are porphyry copper, molybdenum, nickel, chrome, lead-zinc-silver, gold, mercury, tungsten, and tin. Amore precise environment is known for some of these metals, for example, nickel, chrome, and mercury in flysch (which flanks mantle downturns), Ten major orogenies have taken place from 3500 m.y. to the present, Their re¬construction and metallogenesis is the subject of a continuing study.

Jan 1, 1971

By William G. Pariseau

A plasticity theory for anisotropic geologic media has been applied to the problem of quasi-static wedge penetration of rock under confining pressure. Numerical evaluation of the governing system of stress equations in the transversely isotropic and orthotropic cases using representative material properties shows that the consequences of initial anisotropy for the penetration process are by no means trivial. In the transversely isotropic case, a threefold increase in the vertical force required for penetration to a unit depth occurs as the inclination of the axes of anisotropy are rotated through 90° with respect to the penetration path. The horizontal force required varies from zero to a maximum at approximately 60° then back to zero as the axes of anisotropy are rotated. The maximum is of the order of magnitude of the force required in the isotropic case. Similar results are observed in the orthotropic case. Practical aspects of the post-elastic phenomena associated with anisotropic rock indentation within the context of drilling problems include: bit yaw, hole deviation and bending stresses in the drill rod, all of which vary with strata dip but which can be quantitatively evaluated given the bit geometry, interface friction and rock properties. In a broader context, the analysis reveals the necessity for well conceived experimental work and sound theoretical research concerning post-elastic behavior of geologic media as a function of confining pressure, the effects of induced anisotropy, and the variation of strength parameters with loading path changes in the post-elastic range.

Jan 1, 1971

By John V. Beall

Dear J. B.: The recent cable I sent you for a transfer of $200,000 was the outcome of the diligence and perspicacity of our group which, as you know, is laboring under severe hardships here in Rondônia. I only mention the latter difficulties in passing because no reply has been received to our urgent appeal for money. As much as I detest appearing to plead for more attention than you feel called upon to pay to our forgotten mission, I can assure you that it would be in the best interest of the company for you to do so. The fact is, we have been able to outmaneuver the competition and have succeeded in securing pesquizas on some of the most promising cassiterite gravels. We have not been able, up to now, to do much bulk sampling (for lack of funds) but our preliminary panning shows great promise as you can see from the enclosed assay sheets.

Jan 1, 1971

By John A. C. Fortescue

Details of the interactions between the environment and the growth of terrestrial plants may be complex and difficult to study. This paper focusses attention on some of these complexities by means of six examples, each of which provides information on an aspect of the interaction between the growth rate of plants and the chemistry of the environment. The relationships which exist between the information obtained from these examples and the concepts of "holism" and "transfer rate problems" are pointed out and the importance of long-term biog•eochemical studies in Canadian environments is stressed.

Jan 1, 1971

Broken Hill South Limited's discovery of phosphate deposits in the northwest of Queensland in 1966 prompted intensive exploration which has proved phosphate rock in excess of 2,000 million tons at ten separate deposits.Systematic exploration for phosphate in Australia was initiated by the company in 1964. Early in 1966, an investigation of oil wells in the Georgina Basin in the Northern Territory and Queensland revealed widespread anomalous phosphate in early Middle Cambrian Beetle Creek Formation and Thorntonia Limestone. Phosphorites recognized in oil wells in the southeastern part of the Basin, Queensland, led to the discovery of the Duchess deposits. Exploration of the Beetle Creek Formation since 1966 has disclosed nine other sizeable deposits north of Duchess around the eastern margin of the Basin. The Lady Annie and the adjoining Lady Jane deposits, by reason of their location, 160 miles south of the Gulf of Carpentaria, are expected to be the first to be brought into production.Beneficiation testing and engineering investigations commenced in 1967. Transport between the deposits and various port sites in the Gulf of Carpentaria has been extensively studied and a slurry pipeline as a means of transport to a deep water island port, is now being investigated.

Jan 1, 1971