Search Documents

By Sheldon P. Wimpfen, Nelson Severinghaus

13.2-1. Introduction. Man's first association with industrial minerals came at the dawn of history when a remote ancestor first put a few rocks together to protect a fire or selected colored clays to decorate his face. He was dealing with industrial minerals when he selected flint to tip his arrows or scrape a hide. From that inauspicious beginning shrouded in the mists of man's earliest history, industrial minerals have grown tremendously in importance to our civilization. The growth rate of the industrial minerals, or nonmetallic group, has been considerably greater than that of the metals group, as can be seen by the following Fig. 13.2-1: [ ] Industrial minerals produced in the five-year period of 1961-1965 had more than twice the dollar value of the metals produced:

Jan 1, 1968

By Keshavan Nair

In connection with Project Payette, which is concerned with the detection of underground nuclear explosions, it was necessary to determine the technical feasibility of constructing and maintaining a large (approximately 315 feet in diameter) unsupported underground cavity at a depth of approximately 2700 feet in the Tatum Salt Dome in Mississippi. The dimensions and the location of the cavity in the salt dome were governed by criteria laid down by the Atomic Energy Commission. Within the framework of the specified criteria, cavities of various shapes and dimensions could be utilized. One aspect of the feasibility study was to investigate the structural stability of various cavity shapes and to recommend a preferred shape. This paper summarizes the studies that were conducted to evaluate the structural stability of various proposed cavities.(l)

Jan 1, 1968

By D. R. Forshey

The recent occurrence of fatal accidents in copper mines, presumably due to premature ignition of loaded holes by the heat from reacting ammonium nitrate-fuel oil (AN-FO) and pyrite-bearing ores, has led to an examination of this reaction. The reactivity of prilled AN-FO mixtures with pyrite-bearing ores and the effects of water, dilute sulfuric acid, and potential inhibitors on reactivity of the mixtures were evaluated. Initiation of an exothermic reaction was observed as low as 150° F with acid in the absence of inhibitors. Low concentrations of urea, calcium carbonate, zinc oxide, and magnesium oxide were effective in inhibiting the reactivity of the mixtures. The temperatures produced during the reaction of mixtures of AN-FO and pyrite-bearing ores, in the absence of inhibitors, always exceeded the temperature at which electric blasting caps are thermally initiated.

Jan 1, 1968

By Lawrence Adler

The design of an underground opening involves the coincidence of two highly complex and poorly specified components. First, the structural or mechanical characteristics of a geologic rock mass are not only extremely variable but are also very difficult to evaluate. Second, the general lay¬out of mine workings contains a large degree of indeterminancy as to the structure itself as a result of the indefiniteness of the mining process, and also because of the inherent redundancies associated with bulky and weighty structures. Even for the relatively simple problem of tunneling this complexity is well recognized to be "without question that to which the study of geo¬logy (for the Engineer) can most fitly and usefully be applied".1 It can, therefore, be appreciated that the comprehensive opening design problem involves a complicated assemblage of component structures made up of a sketchily defined, or sometimes even an undefined material and acted upon by largely unknown tectonic forces.

Jan 1, 1968

By Patrick E. Cavanagh

"A pilot shaft furnace was operated for one year at Steep Rock to produce special high-grade products from coarse ore, using lignite as fuel. The furnace is 10 ft in diameter and 60 ft high. When operated to heat coarse Steep Rock ore to drive off combined water and give a 64-per-cent-Fe product, the fuel consomption was 900,000 Btu's per long ton of product. The furnace was run in this way from September 1966 to January 1967 to establish the technique of feeding and discharging the furnace and controlling the gas composition and temperature. The furnace is similar in operation to a lignite water gas producer containing a large proportion of catalytic iron oxide. Steam injection is used to control the temperature. The product was tumbled in a rotary trommel to stabilize it. The resulting fines could be fed to the conventional pellet plant at Steep Rock. The furnace was next operated to make 77-per-cent-Fe metallized coarse ore. Several major modifications in de-sign were made and the furnace was successfully operated for short periods to maintain the required conditions to remove 75 per cent of the oxygen from the ore to give a 75-per-cent-reduced product at a grade of 77 per cent iron. The furnace cooling zone was operated under positive pressure, with internai alkaline water sprays to cool the charge. The product was discharged from the open bottom of the furnace without serions reoxidation. The metallized ore was magnetically separated from the discharge. Most of the charred lignite discharged along with the ore is re-cycled. Fuel requirement was 11,000,000 Btu's per long ton of product. This metallized coarse ore is intended for blast furnace feed. A short test run was carried out to establish the conditions for making a highly reduced melting stock for steel furnaces. To achieve 90 per cent reduction and over 90 per cent Fe, the furnace must be slowed down so that the production rate is about one-half the rate when making a 75-per-cent-reduced metallized product. Fuel requirement is 15,000,000 Btu's per long ton of product. The simple shaft furnace developed is similar to the top half of a blast furnace, with some major modifications to allow discharging into the open air. This Low Temperature Blast Furnace program has been technically successful and has resulted in making data available for the design of a commercial plant. Study of the commercial feasibility of large-scale production of metallized coarse ore at Steep Rock is still continuing."

Jan 1, 1968

By A. M. Laird

Endako Mines' molybdenum operation is located near the geographic center of the province of British Columbia, Canada. The property is six miles south of the Northern Transprovincial Highway and the northern main line of the Canadian National Railway. The area is broken by high hills covered with dense stands of spruce and pine with vast areas of the valley floors covered with aspen and poplar. The climate is moderate with precipitation averaging 22 inches per year. Approximately four feet of snow accumulates in the winter, and temperatures range from 900 F. in summer to -40° F. in winter. The orebody, a lowgrade porphyry type deposit, occurs in a widespread granitic intrusive which has been locally weakened at the intersection of two regional faults. In this vicinity the quartz monzonite has been further shattered to permit the entry of mineralizing solutions and local dykes. Two types of mineralization occur within the orebody. The most prom¬inent is the six inch to four foot wide continuous quartz veins with characteristic ribbons of molybdenite and frequently finely-divided grains of molybdenite within the quartz. The second type occurs as fine fractures filled with quartz molybdenite in the form of a stockwork halo radiating out from 20 to 200 feet from the quartz veins. Minor hematite, magnetite and chalcopyrite are also present. Mineralization is roughly proportional to the extent of kaolinization in the quartz monzonite, kaolinization being one of three distinct forms of hydrothermal alteration. Pyrite is commonly associated with molybdenum mineralization within the orebody and a pyrite halo is recognized on the south side of the orebody.

Jan 1, 1968

By H. K. Pelzer

Belt conveyor systems for long-distance haulage are nowadays in a competitive position with conventional methods of transportation such as railways, truck haulage, and also pipelines for solid materials. In a number of cases, the economical use of conveyors is obvious. This is in all those cases where typical features of a conveyor system are showing the outstanding economical position in the very first approach for a certain project. Regarding downhill conveyors, with today's level of belt conveyor techniques nobody would reasonably doubt the justified application of a conveyor system, - as for instance at the Marcona Mining Installation, or at the iron ore mine of Lamco in Liberia.

Jan 1, 1968

By R. G. Ward, D. R. Gaskell

Using the maximum bubble pressure technique, the densities of iron silicates at 1410°C have been measured blowing helium, nitrogen, and argon. By ensuring equilibrium between the melt and the blowing gas with respect to oxygen potential and by minimizing tempcrature cycling of the furnace, iron precipitation in the melt has been prevented. Thus the previously reported effect of blowing-gas composition on the densities of the melts has been eliminated. Consideration of the oxygen densities of the melts gives an indication of the structural changes accompanying composition change. The density-composition relationship of iron oxide-silica melts in contact with solid iron has been the subject of several investigations1-7 and considerable disparities exist among the various results obtained. Of these investigations, all except one5 have employed the maximum bubble pressure method. In the most recently reported of these investigations1 the density-composition relationship obtained blowing nitrogen differed from that obtained blowing argon. The measured densities obtained under nitrogen were greater than those obtained under argon, the difference being a maximum at the pure liquid iron oxide composition and decreasing with increasing silica content. This observation rationalized the disparities existing among the results of the earlier investigations, showing that two lines, one for nitrogen and the other for argon, could be drawn to fit all the earlier results. No explanation for this phenomenon could be offered. Chemical analysis of rapidly quenched samples of melt for dissolved nitrogen, and direct weighing measurements, excluded solution of nitrogen in the melt from being the cause of the increase in density. The range of blowing gases was extended by Ward and Hendersons who measured the density of liquid iron oxide bubbling helium, nitrogen, neon, argon, and krypton. The measured density was found to decrease smoothly with increasing atomic number of the bubbling gas. The work reported here is a continuation of the program initiated by Ward and Sachdev7 to study the densities in multicomponent melts in which the iron oxide-silica system is the solvent. As such it is necessary to explain or eliminate the anomalous densities of iron silicates under different atmospheres, and the present rede termination was carried out towards this end. EXPERIMENTAL The maximum bubble pressure method of density determination was again employed and the experimen- tal apparatus used was essentially the same as that used by Ward and Sachdev.7 A molybdenum-wound resistance furnace heated an ingot iron crucible of internal diameter 1 in. containing a 2-in. depth of melt. The bubbling gas was blown through a 1/4 -in.-diam mild steel tube onto the end of which was welded a 2-in. extension of 1/4 -in.-diam ingot iron rod, drilled out to 5/32 in., and chamfered to an angle of 45 deg. The blowing tube was introduced to the furnace through a sliding seal and its position was controlled by a vertically mounted micrometer screw which allowed the depth of immersion to be determined with an accuracy of ± 0.01 cm. A Pt/Pt-10 pct Rh thermocouple was located below the crucible and temperature control was effected initially by means of an on-off controller and later by a saturable core reactor. The bubble pressure was determined by measurement of a dibutyl phthalate manometer using a cathetometer. PREPARATION OF MATERIALS Iron oxide was produced by melting ferric oxide in an inductively heated iron crucible in air. The liquid was quenched by pouring onto an iron plate. Silica was prepared by dehydrating silicic acid at 650°C for 12 hr. RESULTS Before any measurements of the density of a melt were made, the density of distilled water at room temperature was measured bubbling helium and argon. Both gases gave the density as 1.00 ± 0.01 g per cu cm which showed that the density of the manometric fluid (dibutyl phthalate) was not affected by contact with the blowing gas. With the furnace controlled by an on-off temperature controller an attempt was made to measure the density of pure liquid iron oxide by bubbling argon. The furnace atmosphere gas and bubbling gas were dried over magnesium perchlorate and deoxidized over copper turnings at 600°C. It was found that the pressure required to blow a bubble at a given depth increased slowly with time, and thus it was impossible to obtain a unique value for the density of the melt. Inspection of the blowing tube after removal from the furnace showed that rings of dendritic iron had precipitated from the melt onto the immersed part of the tube. This is shown in Fig. l(a) where the various "steps" correspond to different depths of immersion. The precipitation of iron was considered to be due to one or both of two possible causes: i) The composition of the liquid iron oxide is that of the liquidus at the temperature under consideration and can be expressed by the equilibrium

Jan 1, 1968

By G. H. Gronhovd

The U.S. Geological Survey estimate of the total remaining reserves of lignite in this country as of Jan. 1, 1967 was about 448 billion tons. This represents 27 percent of the total coal reserves on a tonnage basis and about 17 percent on a thermal basis. Approximately 98 percent of these reserves are in a vast lignite field located in western North Dakota and eastern Montana. This field also extends north into the Canadian province of Saskatchewan. Despite these large reserves and relative ease of mining by stripping operations, lignite production historically has accounted for less than 1 percent of the national total. This is largely due to the fact that the lignite deposits are located in an area that has no large centers of population and the economical radius of transportation is limited by its relatively high moisture and low heating value. Commercial utilization of North Dakota lignite for power production became firmly established in the mid-1920's with the development of the first successful lignite-burning equipment. Most of the early lignite-fired boilers were equipped with spreader stokers, but as the size of the plants increased, pulverized-coal firing became the more popular method, and with few exceptions, the plants built during the past 15 years are pc-fired.

Jan 1, 1968

The reactions between molten aluminium and cryoIite have been determined from a material balance of all components involved in the process. The interpretation of results were supported by x-ray diffraction studies of the evolved vapours, quenched electrolyte samples, and side-reaction products.The most important reaction involves the formation of both Na2F (sodium subfluoride) and chiolite in the fused electrolyte. The Na2F accelerates vaporization of the melt. Some AIF (aluminium monofluoride) may also be formed but the proportion of this is much less than for the former subvalent compound.

Jan 1, 1968

By N. Christensen, B. Augland, T. H. Johansen

Samples of an Fe-Nb alloy were brought to equilibriurtr with hydrogen-methane mixtures in the temperature range from 950° to 1050°C, and subsequently analyzed on their carbon contents. The solubility pvoduct L = [%Nb] [%C] may be represented by the equation Approximate solubilities indirectly assessed through hardness measurements have been included from a previous report. These data are shown to be in a fair agreement with the present solubility measurements. IN an investigation based on hardness measurements by de Kazinczy, Ms, and pachleitnerl the molal heat of solution of NbC was estimated to 11.5 kcal per mole. This value was considered rather small, and an investigation using a similar technique was carried out. The results indicated a heat of solution about 35 kcal per mole.2 At this stage it was decided to determine the solubility under conditions of true equilibrium . During the course of this work a similar investigation was published by Smith. 3 His heat of solution, 41.6 kcal per mole, is not very different from the value resulting from the present work (42.5 kcal per mole). Our solubility product, on the other hand, is at considerable variance with that reported by Smith. Possible reasons for these differences are discussed below. Mori, Tokizane, and saheki 7 have studied the behavior of niobium in commercial steels, with special attention to the formation of niobium carbide, nitride, and sulfide. Assuming a carbide composition Nbco.87 based on X-ray diffraction and chemical analysis of residues extracted from Fe-Nb-C-S alloys, the molal heat of solution of niobium carbide was estimated to 35.2 kcal per mole. MATERIALS AND EQUIPMENT The chemical analysis of the materials is given in Table I. Electrolytic iron* was used in the preparation of

Jan 1, 1968

By B. R. Hollebone

The chemical action of molten anhydrous pyridinium chloride (pyridine hydrochloride) on oxy salts and ores of some Group IV and V metals are discussed-in particular zirconium, hafnium, niobium (columbium) , and tantalum. Laboratory-scale experiments are described whose results suggest that this reaction might provide a practicable means of converting ores of these metals to the anhydrous metal chlorides. Experimental results are given which provide some insight into the nature of the reactions and some of the compounds which could be present at intermediate stages. The treatment of ores of the more refractory metals is difficult and expensive and often demands the use of gaseous chlorine, hydrogen fluoride, or other reagents which are, if nothing else, expensive and dangerous to use. This situation is, of course, due to the strong metal-oxygen affinity resulting from the high charge and the small size of the metal ion which combine to produce such high lattice energy in the metal oxide as to defeat standard reduction methods. Thus, the characteristic of these metals which leads to one of their most important properties—corrosion resistance—is the main hurdle in obtaining the metal. Many common methods' for treating ores of zirconium and niobium (columbium), for example, proceed as directly as possible to the preparation of anhydrous halides. These halides are purified by now standard processes of solvent extraction, fractional distillation, and so on. This paper reports on preliminary stages in the development of a method of treating these ores—particularly of niobium—so as to prepare the anhydrous, volatile halides by the use of chemical reagents which are much more easily handled than those used at present. CHEMICAL PRINCIPLES The solvent action of aminium halides has been referred to periodically in the literature over several decades. The chemistry of pyridinium chloride has been discussed particularly by Audreith2 and Starke.3 However, since this is not familiar chemistry in its nonaqueous setting, it is perhaps well to point out some general metallurgical principles and applications. One can use, as point of departure, the fact that HC1 dissolved in pyridine is an acid very much the same as aqueous HC1. It thus gives essentially all the reactions of the HC1 with which we are familiar. However, when the ratio of HC1:pyridine reaches 1:l (a ratio far higher than is possible with H2O) the solution becomes solid C5F5NHC1, pyridinium chloride.* Inter- estingly, the acidic properties of HC1 persist in this medium, although they are manifest only in the molten state of the compound. Some typical reactions of divalent metal compounds which we have carried out in our laboratories are the following: 2PyHCl + Zn — (ZnCl2) + H2 + 2Py 2PyHCl + MnO — (MnCl2) + H2O + 2Py 2PyHCl + CuS — (CuCl2) + H2S + 2Py 2PyHCl + CaCO3 — (CaCl2) + H2O + CO2 + 2Py In these equations, the parentheses indicate a solvated compound which in water would be predominantly a hydra ted cation but which in molten PyHCl will more likely be a complex chloro-anion of the type MC14-. Some important physical properties of pyridinium chloride (PyHCl) are given in Table I. One sees from the data in Table I that at the temperature of molten pyridinium chloride both water and pyridine will boil away. Thus the system will be kept anhydrous. For this reason the reaction 2NbCl5 + 5H2O— Nb2O5 + 10HC1 has no counterpart in molten PyHCl. Instead, the chloride is made even more stable by the formation of a hexachloro complex: Nb2O5 + 12PyHC1 — 2PyHNbC16 + 5H2O + 10Py One interesting property of these complexes is their thermal instability which for the case of niobium can be illustrated as PyHNbCl6 — PyHCl + NbCl5 With a view to possible use of this chemistry in ore treatment, we have attempted to dissolve Pyrochlore (essentially FeO - Nb2O5) and recover the NbC15 from it.

Jan 1, 1968

By C. O. Brawner

Approximately 7 billion tons of soil, rock and ore are currently being excavated in open pit mines and quarries on the North American continent at the present time. As the depth of excavation increases and the grade of ore being mined reduces, the safety and economy of the stability of the pit slopes becomes increasingly important. The magnitude of the potential influence on economics can be appreciated from the results of recent full scale field studies by Kennecott Copper Corporation at the Kimbley pit near Ely Nevada (Merrill, 1968). This pit was originally excavated with an average wall slope of 45°. Based on detailed studies it appeared that a slope of 610 would be stable. Subsequent excavation to this slope proved the original pit could have been steepened by 16° during production.

Jan 1, 1968

By L. Valentik

Many attempts have been made during the last forty years to evaluate the performance of gravity separation equipment, that is, the effectiveness with which light and heavy particles are separated. The most comprehensive treatment of the subject was made at the 1st International Conference on Coal Preparation held in Paris (1950) by Cerchar. The methods suggested by the Conference were accepted and very widely used in the last 25 years. This paper discusses an improved method of evaluation in the light of the now accepted standard presentation. The float and sink analysis of the product is presented on a Gaussian distribution curve, resulting in an easier visualization of the inherent difficulties of separation. The ogives of the distribution curve are then plotted, giving a quantitative measure of the deviation from perfect separation as an error distance instead of an error area. Illustrations of the new method are given both for gravel and for coal preparation, but the concept is valid and applicable to other types of minerals which are separated by gravity methods.

Jan 1, 1968

By E. E. Malouf

With the continued development of low-grade porphyry copper deposits by open pit mining, substantial amounts of copper-bearing strip material have been accumulated in waste dumps adjacent to the many large mines. Since the end of World War II, the production of copper from leaching these copper-bearing wastes increased from approximately 4% of the total copper production to 10% by the early 1960's. Projected increases will probably raise this figure to 20 to 30% by the early 1970's. Furthermore, a gradual recognition of the economic feasibility of leaching mined-out areas is evident and will undoubtedly contribute additional production. Waste dumps in canyons and gulches on the periphery of open pit mines, mine stopes, caved areas, and abandoned open pits often contain substantial quantities of leachable rock ranging in concentration from 0.1 to 0.4% copper. Recent developments in the leaching of copper, mainly the recognition of bacterial oxidation of sulfide minerals combined with better under- standing of the control of the salt content of the leach solutions, both by adjusting the pH and/or by hydrolysis, are resulting in a greatly expanded recovery of copper from these hitherto uneconomic mine rejects. 11.5-1. Mechanism of Leaching. Leaching processes for the extraction of metal values from mine ore or waste may be classified for convenience as either chemical leaching or bacterial leaching. Chemical leaching is considered to be the extraction of soluble salts by metathesis in acidic, basic, or neutral water solutions. The reactions involved may be evaluated by chemical thermodynamics. Bacterial leaching, although a chemical process, is dependent on biological catalysis and this is generally a much more complex process. This justifies its separate treatment in the application to leaching. Acid ferric sulfate solutions are commonly employed in the mining industry to leach valuable metals from metal sulfide ores. The leaching mechanism is a reduction-oxidation reaction in which minerals are oxidized at the expense of ferric sulfate. Such chemical leaching is profitable when

Jan 1, 1968

By E. J. Fasiska, L. Zwell

PREVIOUS investigations 1,2 of Fe3P described by pearson3 and schubert4 show that Fe3P has a bct unit cell having four Fe3P tetrahedra centered around each lattice point. The space group is 14, No. 82, and all atoms occupy general positions 8(g). The cell dimensions3 are: a = 9.090, c = 4.446 kX, with an axial ratio of c/o = 0.4891. We have measured the lattice parameters of Fe3P, using a Fe as an internal temperature standard, at 23°, 414°, and 678°C and computed the thermal expansion over this temperature range. The Fe,P was prepared by melting under vacuum (after flushing with argon) a commercially pure iron and "ferrophosphor" in a high-frequency induction furnace. Part of the ingot was crushed for X-ray examination and for chemical analysis. X-ray diffraction and light microscopy indicated iron phosphide (Fe3P) present as the major constituent and a small amount (about 5 pct) of a Fe. Chemical analysis showed 0.05 wt pct Si, 0.008 wt pct N, 0.018 wt pet C, and less than 0.02 wt pct each of other metallic elements. X-ray diffraction powder patterns were obtained from a mixture of iron and Fe3P sealed in an evacuated quartz capsule using a Unicam high-temperature

Jan 1, 1968

By E. J. Kloos

Two self-contained breathing apparatus of the closed-circuit compressed-oxygen type were evaluated for performance at 32° to -25° F. Low-temperature effects of oxygen and carbon dioxide concentration, visual properties of the facepiece, and mechanical operation of the apparatus were studied. Although operation varied with the wearer, his breathing rate, the apparatus precooling time, and the temperature, results suggest that general use of currently approved compressed-oxygen closed-circuit breathing apparatus be limited to temperatures above 32° F.

Jan 1, 1968

Jan 1, 1968

By Allan F. Lawrence

"I AM SURE you do not expect from me any learned dissertation on the problems and opportunities of the mining industry. Y our program committee must have recognized my limitations when issuing the invitation to speak to you, because they very thoughtfully left the subject wide open.With the leeway thus granted, I hope that you will bear with me for a few minutes while I try to clarify the impressions of the mining industry that I have gained in the very short time I have held the Mines portfolio and some of the parts that government bas or should have in furthering its development.As I see it, it is the duty of the Mines Department, as an arm of the provincial government, to balance the proprietary rights of all the people against the interests to whom the privilege of developing our resources are, in a s e n s e, leased. To strike a fair balance is not always easy, nor is it possible always to satisfy both sides. Still, under the free enterprise democratie form of government to which I think we al! subscribe, no better way of handling the problem has yet been discovered."

Jan 1, 1968

By A. M. Johnson, M. M. Singh

The mechanism of failure under a drill bit is still improperly understood in spite of several investigations of the subject. Generally, the cratering process under static loading conditions is considered to be similar to that achieved dynamically by impact. This paper attempts to indicate that, although the sequence of fracturing in the two cases appear to be identical, at least some dissimilarities exist. For example, the width-to-depth ratios of the craters vary to some extent, and the amount of energy consumed per unit of volume of craters is unequal for the two different loading conditions. Prevalent rock penetration processes are dominated by methods utilizing mechanical attack on rock. It is, therefore, generally accepted that a better comprehension of the mechanism of rock failure under a wedge would prove beneficial towards improving present drilling techniques. Several attempts have been made in recent years to explain how craters are formed under a drill bit, but the mechanism of failure beneath a bit is still improperly understood. 1-11 Most investigators, to date, have inferred the sequence of events occurring during crater formation from analyses of force-time diagrams,1"6 from theoretical considerations,7 or from a study of the configurations of final craters.8-l0 These analyses have led to the presentation of widely divergent models for rock failure beneath a drill bit, ranging from brittle to viscoelastic. The cratering process under dynamic loading commonly is regarded as being similar to that obtained under gradually applied, or 'static', loads. But the effect of rate of loading on the action of a bit is still disputed. Some investigators11-12 maintain that there should be no such effects, whereas others have demonstrated experimentally that these exist.13-17' The purpose of the investigation reported in this paper was to examine petrographically the damage done to rock under the action of a chisel-shaped wedge, both with 'static' and dynamic loading, and to determine if rate-of-loading effects could be detected. Significant quantitative differences in crater volumes and depths were found to exist for a given consumption of energy. On the basis of this data, an attempt was made to indicate some of the rheological properties that a proposed model should possess. All the work reported herein was conducted at atmospheric pressures. EXPERIMENTAL APPARATUS AND PROCEDURE Two types of rocks were employed for most of the experiments reported in this paper, viz. Bedford (Indiana) limestone and Vermont marble. The mechanical properties of these rocks are given in Appendix A. Actually two types of Vermont marble were used, but since no marked difference could be discerned between the two varieties (as seen in Fig. 10) the data was used collectively for the analysis. Stronger rocks were not employed owing to difficulty in generation of observable craters without damage to the equipment. Six-in. diam cores were drilled from the rock samples and embedded in 8-in, diam steel pipe with 3/8-in. wall thickness, using hydrostone to fill the annulus between the core and the pipe. This procedure was adopted to confine the rock specimen so that fractures would not propagate to the edges of the cores. This goal was achieved satisfactorily for these tests because no cracks were observed to extend into the medium surrounding the rock, even when craters were formed only 1 in. from the rock core periphery. Three to four craters were formed on a core face, because the rock damage from any one crater generally did not appear to extend into the others. Whenever, interference between damaged areas around adjacent craters was suspected, the data was rejected for purposes of the analysis. The limestone and marble samples were tested with a 60-degree, wedge-shaped bit, 1 5/8-in. in length, made of tool steel. The bit shank had two SR-4 type electrical resistance strain gages, mounted axially, to record the force-time history during the loading operation. The static indentation tests were conducted using a 50-ton capacity press fitted with an adapter for drill bit attachment. See Fig. 1. The force exerted by the bit at any instant was measured with strain gages affixed to the bit shank. An aluminum cantilever, with two SR-4 strain gages mounted near its clamped end, was employed to measure bit displacement. Both sets of gages were included in Wheatstone bridge circuits,

Jan 1, 1968