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By Carlos Martins Viana

Neste trabalho, foram sintetizados e caracterizados nanofios de prata que posteriormente foram usados para produção de uma tinta condutora cuja, caracterização elétrica foi medida através de valores de tensão versus corrente. A primeira fase do trabalho consiste na obtenção dos nanofios pelo método poliol. Nesta fase, fez-se uma análise da estrutura dos fios, com o objetivo de verificar a uniformidade (forma e tamanho). Para estudos da estrutura utilizou-se a microscopia ótica (MO) e microscopia eletrônica de varredura (MEV). Também utilizou-se a espectroscopia de Ultravioleta-Visível (Uv-Vis) para identificação dos nanofios no produto obtido. A segunda fase, consiste no desenvolvimento da tinta condutora, onde nanofios foram redispersados em uma mistura de solventes e CTAB em banho de ultrassom, para obtenção de valores de tensão superficial e viscosidade. Por fim, medidas de corrente contínua da tinta, permitiram a construção da curva tensão versus corrente, da qual se obteve o valor da resistência elétrica. Através da curva foi possível comprovar o caráter condutor da tinta e pela linearidade da curva, verificou-se que a tinta produzida é considerada um material ôhmico.

Aug 16, 2017

By Pedro Jorge Walburga Keglevich de Buzin

The steel production in mini mills generates several process residues, among them the electric arc furnace dust (EAFD). This residue has as main elements Fe, O, and Zn, being classified as hazardous by the presence of Pb and Cd. In recent years, a rise in the chlorine content of this residue was observed, motivated by the increased use of scrap with impurities bearing this element. In this work, a qualitative assessment of the presence of chlorine in the electric steelmaking process is made. Complementing it, theoretical considerations based on the computational thermodynamics tool FactSage show the effects of the chlorine on the mineral species in EAFD and on gaseous species in the gas phase (HCl and Cl2). For this study, PVC polymer was used as the chlorine carrier substance which contaminates the EAF charge; presence of other minor elements in the system such as K, Na and Pb were also considered.

Aug 7, 2018

By Kátia Cristina Gouveia

O objetivo deste trabalho foi determinar a TTDF do aço ASTM A36 com diferentes graus de encruamento após ensaios de impacto Charpy, sob diversas metodologias. Não se notaram diferenças no comportamento do material quando se avaliam os valores de TTDF obtidos pela medição da expansão lateral dos corpos de prova, nem considerando o valor da TTDF na qual o material apresenta 50% de fratura frágil, usando as metodologias de avaliação visual das faces de fratura dos corpos de prova, embora os valores sejam divergentes dos valores obtidos pelos métodos analíticos. A avaliação das faces de fratura dos corpos de prova por microscopia eletrônica de varredura permitiu visualizar que nas regiões onde visualmente considerou-se que havia apenas fratura frágil, também haviam regiões típicas de fratura dúctil. Conclui-se que a metodologia mais indicada é aquela que considera a TTDF como a temperatura na qual a energia absorvida é a média dos patamares superior e inferior, pois é um método simples, de fácil reprodutibilidade e que melhor refletiu a tendência de comportamento do material nos diferentes graus de encruamento estudados.

Aug 7, 2018

By Masakazu Iida

In this article, technologies of unburned Al2O3-MgO (UAM) refractories are demonstrated in terms of microstructure evolution. During operation, Mg2+ diffuses from MgO to Al2O3 through the liquid phase to form spinel (MgAl2O4) network. Molten slag tends to penetrate along the voids in the spinel network structure and spinel dissolves in the penetrated slag. Therefore, maintaining a high degree of spinel saturation in the penetrated molten slag is important. In order to achieve the condition described above, suppression of overall mass transfer through penetrated slag is effective. This is achievable by evolution of complicated spinel network structure with small pore diameter, which increases the flow resistance of molten slag. Thus, optimization of refractory composition and fabricating conditions, with the aim of creating on improved spinel network, is essential. The effectiveness of spinel network improvement was validated by commercial applications. According to the investigation of UAM brick after use, further densification due to heating under restrained conditions was recognized. Hence, it was concluded that the evolution of the spinel network structure in UAM refractories is essential technology needed to improve durability.

Oct 30, 2017

By Sebastien Flament

More and more Hot Strip Mills are facing defects on their products that lead to a rejection of complete product batches by their customers. Several of those defects are induced by excessive work roll degradation. This paper is focussed on the understanding of work roll corrosion and oxidation mechanisms in a hot strip mill. Several laboratory trials (Hot rolling simulator, cyclic oxidation) have highlighted important factors influencing corrosion of work rolls as well as helping the understandings of oxidation of a work roll in the roll bite and along the roll circumference in a stand. The attention is focussed on several elements present in water used in HSM for direct roll cooling (e.g. chloride, bactericides, sulphates, phosphates) and their effect on roll surface degradation. The second part of this paper is focused on the understanding of work roll oxidation along the roll circumference. The effects of roll composition, roll temperature, water composition and water temperature have been studied in order to understand the oxidation/corrosion mechanisms in a HSM.

Aug 16, 2017

By Breno Totti Maia

This work was a continuous and multidisciplinary development. Through studies of the blowing process and its parameters results, evolutions, improvements and adjustments were made on the lance’s hot face with Slagless® technology, as well in the process parameters and mitigating actions of the projection of materials out of the converter. The main results are the increase in the nozzle’s life with a “record mark” of 1785 heats, and water leakage occurrence in the cartridge decreased considerably reaching the mark of one year without any occurrence.

Oct 30, 2017

By Daniele Tolazzi

In today’s highly competitive market situation, it is of outmost importance for EAF steel makers to optimise their processes in order to reduce operating costs and to improve safety and reliability of the equipment. The laser based off-gas analysis technology, With laser units installed on the fix duct, downstream the combustion gap, uses the “Tuneable Diode Laser Absorption Spectroscopy” (TDLAS). The system performs real-time off-gas emissions measurements of CO, CO2, O2, H2O and temperature. A closed-loop operation is in place for dynamic control of the chemical energy package combustion/post-combustion of CO, H2 and CH4 gases into the EAF furnace shell. A statistical framework which builds on a data analysis engine, based on Danieli Automation Q3Intelligence technology, evaluates the “fingerprint” of the process represented by average and deviation trends of both gases and other process parameters. Process fingerprinting is conceived both for offline profile optimisation and on-line control of the refining process. This paper describes how the technology has been applied and the results achieved at ACCIAIERIE BERTOLI SAFAU (Italy) 100 t AC Electric Arc Furnace.

Aug 16, 2017

By Božidar Šarler, Umut Hanoglu

A rolling simulation system has been developed to calculate the macroscopic rate of deformation, stress, strain, and temperature fields by using a novel meshless method. The model is based on two-dimensional traveling slice assumption. The slices are aligned towards the rolling direction. The initial size of the billet, bloom or slab and the geometry of the grooves at each rolling stand, the distances between the rolling stands, and continuous or reverse rolling can be arbitrarily considered. The purpose of this paper is to complement these development by predicting and visualizing also the grain size of steel over the strand cross-section for each position in the rolling mill. The grain size models have been in one-way coupled to the macroscopic calculations. First the critical strain for dynamic recrystallization is being checked. If the calculated strain is higher than that, considering also the time for meta-dynamic recrystallization, dynamic or meta-dynamic grain size calculations are carried out. If the strain is too low then only the static recrystallization is considered together with its required time. Finally, austenite grain size and ferrite grain size are calculated respectively as the steel cools down. The listed physical models are based on collection of empirical relations found in literature. The user of the system is free to choose or create the model he wants with his own parameters. The simulation system has been coded as a user friendly computer application for an industrial use based on C# and .NET framework and runs on regular PCs. The computational time for a rolling simulation is usually less than one hour and can thus be straightforwardly used for optimization of the rolling mill design in a reasonable time.

Oct 1, 2019

By Jörg Busch

The essential pre-requisite for attaining the high quality of product required from high-speed continuous production processes is the use of new measurement and control technologies. High availability and reproducible measuring results ensure the high level of process stability necessary for full continuous operation. The requirements for the optimisation of quality across the complete production process and for quality analysis systems will be discussed. This report will present examples of basic and new measurement technologies in Cold Rolling Mills and Processing Lines. The following gauging systems will be discussed in detail: Strip tension meter, roll force measurements, weighing systems and shapemeter rolls. The measuring and control systems in this presentation must be seen as high-tech solutions in the field of processing technology. The measuring methods and technologies described are, together with optimised process models and precision control loops and actuators, the main pre-requisites for achieving the quality of product required from high-speed continuous production processes. Interconnected quality management systems enable optimisation across the complete production process.

Jul 30, 2018

By Zou Zhongpping

Under the new normal state, blast furnace outputneeds to be adapted to the market demand, however the limitation in blast furnace output has significant impact on blast furnace operation and is prone to cause inactive furnace hearth and higher fuel ratio. To address such problems, some practices to maintain stable and smooth operation of blast furnace in case of output limitation are proposed based on data analysis philosophy, which allows the blast flow and hence the top pressure to be determined based on the hot metal output, and adequate kinetic energy of blast supply can be assured by adjusting the tuyeres. Matching between the oxygen enrichment and the pulverized coal injection is also proposed based on theoretical flametemperature, and burden distribution cycle calculation method is proposed, whichoffersnew approach for analyzing the change in burden distribution pattern.

Oct 30, 2017

By Elton Douglas Heriger Pereira

Refratários de alta alumina apresentam boa refratariedade, elevada resistência mecânica em altas temperaturas, boa resistência à variação bruscas de temperatura sem se romper sendo utilizados em revestimento de panelas e válvulas siderúrgicas devido sua propriedade anfótero e ter aplicações sobre à ação de escórias básicas. Neste trabalho procurou-se avaliar o efeito de adições de 1,5; 3,0 e 4,5%p. de Nb2O5 em refratário de alta alumina, estes obtidos a partir de uma mistura de diversos tipos de alumina, 5,0 %p. ZrO2 nanométrica (TZ-8Y) e agregado de mulita, sinterizados em temperaturas de 1400 e 1600 °C. Como nestes refratários a ZrO2 não surte o efeito de microtrincamento, a formação de fase vítrea a partir de Nb2O5 e a incorporação de agregados ao refratário foram fundamentais nas propriedades obtidas. Foram avaliadas propriedades tecnológicas como densidade e porosidade aparente pelo método de Arquimedes, formação de fases por difração de raios-X e análise microestrutural por microscopia eletrônica de varredura e resistência ao choque térmico.

Oct 30, 2017

By Andreas Jungbauer

Two Arvedi ESP plants going into operation in 2015 will allow a Chinese steel producer to better serve the extremely attractive local and export markets for high-quality, thin-gauge strip products. The energy consumption and the related costs are reduced by up to 45% compared to conventional casting and rolling processes. This also means a major reduction in CO2 emissions. The new plants are designed for an annual production capacity of 2 x 2.55 million tons of high-quality, ultra-thin, hot-rolled strip products with widths of up to 1,600 mm and thicknesses down to 0.8 mm. The project scope also features a comprehensive training and assistance package for plant start-up and operations by personnel from the existing ESP plant at Acciaieria Arvedi SpA, Italy. The plant setup, the trainings and assistance program as well as latest results from the ESP plant in Italy will be presented. While this project is under execution three further ESP lines have been ordered by the same customer summing up now to five ESP lines at the same location.

Jul 30, 2018

By Dagoberto Brandão Santos, Kairo de Barros Guimarães, Túlio Magno Füzessy de Melo

The effect of the cooling conditions on the microstructure and hardness of a Dual Phase hot-rolled steel 800 MPa strength was investigated. Simulations of the cooling conditions using a dilatometer were carried out from samples of a hot rolled coil with variations of the intermediary temperature from 620 to 740°C, isothermal holding time between 1 and 10 s and coiling temperature between 50 and 400°C. In addition, two CCT (Continuous Cooling Transformation) diagrams were developed to evaluate the effect of the isothermal holding time on the phase transformations of the remaining austenite. It was observed that the intermediary temperature has a strong influence on the kinetics of the phase transformation, as well as the isothermal holding time influences the amount of ferrite formed and, consequently, the final microstructure and hardness of the material. The coiling temperature did not cause significant changes in the amount and morphology of the ferrite, but a gradual replacement of martensite with bainite was observed, which, in addition to the self-tempering effect, contributed to the hardness reduction.

Oct 1, 2019

By Liao Jianfeng

The Baosteel Zhanjiang 5,050m3 blast furnaces have been built with highly independent integration and innovation technologies and represented the state of the art of the world’s huge BFs. The proper of BF1 and BF2 is designed with long-campaign technology; both BFs share the same set of stockhouse, water and PCI systems; the BCQS serial-hopper no-bell top, TRT and blower are all local equipment as applied; four top-combustion stoves systems are matched; the BFG is cleaned by fully dry process; and the automation control system for the main process is self integrated. The BFs have been started up and performing with sound indicators. Their smooth proceedings symbolize China’s huge blast furnace ironmaking technology ascending a new high.

Oct 30, 2017

By Juergen Meisel

The paper will explain how to successfully implement a robotic solution from the initial idea to a working industrial solution. Primetals Technologies can call upon 10 years of experience in installation of Robot solutions in the harsh environment of steelmaking plants - the so-called LiquiRob. To enhance an existing shroud manipulation system, the idea to connect the shroud with a bayonet mechanism to the ladle nozzle was born in accordance with the requirements of a well-known steel producer. The paper will describe the development steps from the first simulations and prototype testing in the laboratory, it will show the intensive system testing under workshop conditions and will finally depict the successful integration into the plant. Furthermore, operational experience will be shown as well as the advantages of such an installation compared to other shroud manipulation systems.

Oct 30, 2017

By Raúl Daniel López

Un objetivo de seguridad y calidad en los moldes de la colada continua de Siderar fue la de tener un menisco estable y controlado. A lo largo de los distintos periodos de inversiones y mejoras, el control de nivel de Siderar logro como objetivo contener su variación de nivel de acero en el molde en un rango de variación menor a +/-2 mm y con una velocidad de cambio inferior a 1,5 m/segundos. Esta etapa trajo una relativa mejora en los aspectos mencionados (calidad y continuidad operativa) pero el hecho de tener como sistema de medición de nivel un sistema radiactivo (fuente Co60 y contador de centelleo) mantenía serias limitaciones en ambos rubros dado que este sistema no diferencia la interface escoria /polvo colador con el menisco de acero. Este trabajo tratará de mostrar y contar las tareas de desarrollo y aplicación de esta nueva tecnología, hoy vigente en la nueva Colada Continua N° 2 (CCD2) y en etapa de puesta en marcha de la CCD1.

Aug 15, 2017

By J. Bas A. F. Smeulders

Traditional laboratory lubrication tests, including those for cold rolling lubricants often involve measurement of neat oils. To achieve increased levels of test severity, such tests are often carried out at high temperatures and prolonged durations. However, we found that the levels of lubricant degradation and wear in these tests can be much higher than in the field. Moreover, steel rolling is not done with neat oils, but with emulsions, where the presence of water influences film formation, surface chemistry and oil composition in the roll bite. To better approach the situation in the field, and thus to be able to develop rolling oils with improved lubrication performance, several lubrication tests were developed for emulsions: direct measurement of film formation and measurement of Stribeck curves, in which the emulsions can be assessed in terms of their boundary lubrication and elastohydrodynamic behaviour. The key innovation is that also another test method was developed, which focuses on boundary lubrication and wear, and the role of extreme pressure and anti-wear additives. Realistic levels of test severity are achieved in the tribometer by mimicking frictional power intensities and flash temperatures for typical cold rolling or tinplate mills. Test conditions can be adapted according to the mill stand or pass number and other cold rolling process parameters. The emulsions are kept at normal operational temperature. Clear differences could be observed between emulsions of various concentration and composition. The viability of the method is illustrated by a number of field cases, in which a good correlation is demonstrated between the laboratory tests and the performance in a pilot or production mill.

Jul 30, 2018

By Baoliang Xiao, Hui Pan, Yajun Hui, Kun Liu

The microstructure, properties, strengthening mechanism and work hardening mechanism of 600MPa grade high ductility hot-rolled sheet steel for automotive square tube were investigated by utilizing optical microscopy, scanning electron microscopy and transmission electron microscopy. The results show that the microstructures of low C-low Mn-Nb and Ti microalloyed steel (Steel A) and high C-high Mn-Nb microalloyed steel (Steel B) are composed of ferrite and a small amount of pearlite. Compared with steel B, the size of ferrite and pearlite of steel A is finer, while the size of the second phase precipitates is larger. The mechanical properties of the two tested steels are similar before tube forming, except that the yield ratio of steel A is higher. Steel A has/exhibits significant work hardening after tube forming; the yield strength and tensile strength increase by 45 MPa and 26 MPa, respectively, while the elongation decrease by 6.0 percent. The yield strength and tensile strength of steel B increase by 22 MPa and 10 MPa, respectively, and the elongation decrease by 4.0 percent. The grain refinement strengthening is the dominant strengthening mechanism, accounting for 52.9 to 61.8 percent of the total yield strength; the solid solution strengthening is the second strengthening mechanism, accounting for 17.2 to 25.3 percent, while the precipitation strengthening and dislocation strengthening contribute little to the yield strength. The dislocation strengthening increase by 82 MPa of steel A after tube forming, which is higher than that of steel B. Therefore, steel B has a low work hardening rate that is more suitable for manufacturing automotive square tube for secondary tube forming.

Oct 1, 2019

By Diego José Inforzato

Hot tensile data were correlated with creep data, in Aluminum Alloy AL7475-T7351, as part of a broader research program, aiming at the validation of a methodology that proposes an equivalence between the two kind of results, for metallic materials in general. The methodology is based on a criterion that establishes correlation among the following parameters from each test: the strain rate, ultimate tensile stress, and time to reach the ultimate tensile stress, in tensile tests, are equivalent respectively to the: minimum strain rate, applied stress and rupture time, in creep tests, for a given test temperature. The present material was tested at 3 temperatures: 133,166 and 193ºC, using 3 nominal tensile strain rates in the hot tensile tests: 3.2x10-6, 1.6x10-4 and 6.4x10-3 s-1 and 9 applied stress levels in the creep tests, varying from 140 to 400 MPa. The conversion of the hot tensile data to creep-like data allowed performing the analysis of all the results together according to the traditional creep relations proposed by different authors, namely: Norton, Arrhenius, Zener-Hollomon and Monkman-Grant, with the determination of the corresponding parameters in each case. The equivalence between hot tensile and creep data is also confirmed for this aluminum alloy.

Aug 8, 2018

By Francisco Morganti

In order to support hot rolling mill managers in improving the utilization of their plants, SMS group offers well defined Performance Modules. These are technologies, components, automation solutions or services, which can be implemented in existing plants to increase competitiveness in categories of efficiency, productivity, quality and process and product control referred to as “Industry 4.0”. Except the Performance Modules dedicated to the last category, targeting overall process controls, Performance Modules are characterized by quantifiable benefits. Performance Modules related to hot rolling mills are e.g. camber free rolling, modular laminar strip cooling system, new edge masking and intelligent components.

Oct 30, 2017