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By Boontanjai C, Boyapati ER

Reagents used for batch flotation tests were Aeroxanthate-343 & 350, Dow Z-6, & reagent-4037 (from Benambra) as copper collectors; Na2SiO3 & Na2S2O3as gangue depressants; lime & HCl as pH regulators; and pine oil & MIBC (methyl isobutyl carbinol) as flotation frothers. A Denver Sub A flotation cell of capacity 250 gms was used for the batch flotation experiments. Atomic absorption spectrophotometer was used for copper assays and microscopy for selectivity and liberation studies. Melbourne tap water was used throughout the experiments. Unless otherwise stated, the following parameters apply to the flotation experiments: flotation impeller speed - 1300 rpm, pulp density during flotation- 22%, reagents addition - in 4 stages, total conditioning time for collectors - 8 minutes, total flotation time- 9 minutes. A variable quantity of copper mineral collector according to the test in question was added, then conditioned the pulp for 2 minutes. The froth was removed by hand, scraping the full length of the cell at constant depth every 10 seconds. No frother is required for this copper tailing flotation. Four concentrates were collected after addition of collector and conditioning at 2,4,6 and 9 minutes. The pulp volume was maintained at a constant level to yield a constant froth depth.

Jan 1, 1990

By S Roberston, G Batt, R Shanahan, B Shah, A Trench, H Bromfield

The geographic imperative of ore systems leaves mining, more so than virtually any other aspect of modern industry, heavily dependent on obtaining and maintaining social licence to operate. A prospective miner cannot arbitrarily walk away from a deposit in search of more favourable community perceptions – concentrations of mineral endowment represent highly specific and fixed elements of the landscape, and their development and extraction thus requires the acceptance and trust of a specific network of landholders and stakeholders, sometimes with diverse and even competing interests in the development and use of the local environment. Weakness or absence of such social licence can bring added costs and complexity to developing and operating a mine – and in extreme cases even result in project failure. Because it must be maintained throughout the life of a project, such social risk becomes a substantial part of overall project risk profile, particularly during routine operations once initial technical and development risks have been largely resolved.CITATION: Bromfield, H, Roberston, S, Shah, B, Shanahan, R, Trench, A and Batt, G, 2018. On equitable distribution of mining wealth and the social licence to operate imperative – an African case study, in Proceedings Complex Orebodies Conference 2018, pp 6–7 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 21, 2018

By S K. Michelic, N Preisser

For certain applications, steels have to feature a very distinct and well-defined level of cleanness in terms of the number and composition of non-metallic inclusions. Therefore, one crucial aspect of steelmaking is removing and controlling said non-metallic inclusions during the process. Particle removal during ladle refining comprises three stages, namely: 1. Flotation 2. Transport through the steel/slag interface 3. Dissolution of the particle in the slag. Only if all three stages are completed the particle can be considered as fully removed from the steel melt which, in turn, leads to the slag being one of the most influential parameters for inclusion removal and control. Depending on the composition of the particles and the slag, the dissolution can be controlled by different mechanisms. This study focuses on the diffusion-controlled dissolution of solid oxidic particles in slags. For this, a model of particle dissolution has been developed. For modelling diffusion, either the differential equation following Fick’s second law can be solved, or an analytical solution to this equation valid for stationary interfaces can be used. Both approaches allow for calculations of concentration profiles of the dissolving species in surrounding slag. From this, the mass flux can be derived, which finally leads to calculating the boundary layer velocity due to considerations of mass balance. In this work, both methods as well as results of dissolution experiments using High Temperature Confocal Scanning Laser Microscopy are compared. This research aims to provide a framework for diffusion-based dissolution modelling in further expanding the understanding of particle dissolution in secondary metallurgy.

Aug 21, 2024

By B, G Strobos, J P. Maree, N Smit

In mining and processing operations where minerals, high in pyrite and low in calcite/dolomite are processed, acid is generated, which needs to be neutralised. Ticor at Empangeni in South Africa (SA) produces rutile (TiO2), leucoxene (TiO2 plus iron compounds), titanium (Ti), zircon (Zi) and ilmenite (TiO2 plus iron compounds). Neutralisation is required in the processing plant where acid is leached into the wash water. This water needs to be treated to a quality suitable for re-use in the metallurgical process or to a higher quality to make it suitable for discharge into the Empangeni sewage system (SA). For re-use the water needs to be neutral and under-saturated with respect to gypsum while for discharge into the sewage system the sulfate concentration needs to be reduced to less than 500 mg/L (as SO4). Acid mine water is generally neutralised with lime. Disadvantages associated with lime are the costs and maintenance of the slaking equipment as well as hazards, associated with handling of the alkali. The cost of powdered limestone (CaCO3) in South Africa, a by-product, is 50 - 60 per cent cheaper than lime. A technology has been developed where limestone is used for neutralisation of acid mine water instead of lime. This development includes: Limestone handling and dosing system. A novel, robust system has been developed where waste CaCO3 from the paper industry is slurried to a constant density. A full-scale plant was constructed to evaluate its performance (Figure 4). The dosing system consists of an inclined slab onto which the limestone is stored and from where it is slurried into a make-up tank. The density of the slurry in the make-up tank is controlled via a loadcell that measures the weight of the tank (operated at constant volume) and activates/deactivates the spray of the recycle slurry onto the slab. Integrated limestone neutralisation/lime treatment process. In this process powdered CaCO3 is used for neutralisation and partial sulfate removal of acid leached from the coal washing plant. The sulfate concentration can be further reduced to below the saturation level of gypsum (ie 1200 mg/L) through gypsum crystallisation by means of lime treatment, resulting in metal precipitation (eg Fe3+ and Al3+). CO2- treatment for CaCO3 precipitation. The pH of the lime treated water can be adjusted to pH levels of 8.5 and lower using CO2. The CO2, generated during limestone neutralisation (Equation 2), can be captured and used in this stage of the process. The first two stages (limestone- and lime neutralisation) of this technology have been implemented on full-scale at Ticor to treat the effluent of the process. The constructed plant is 80 m3/hr and differs from coal processing plants by way of not containing Fe(II) and Fe(III) in the water. The CO2-treatment stage (Stage 3) will soon be implemented at IHM as part of a program to optimise the technology for maximum benefits.

Jan 1, 2003

By B Newcombe

From many years practical industrial experience the author has drawn together a list of the key points to consider when embarking on a large-scale geometallurgical project. Fundamental aspects which must be considered include (but are not limited to):understanding the variability of the orebody both laterally and with depth;comminution properties and variability;flotation properties, requirements and variability – differing ore zones may have substantially different requirements for optimal performance;the role of texture – the consequences of both grain size and distribution and how the circuit will handle these;realistic expectation in terms of the financial requirements and time frame results are required within; andintegration of, and communication between key personnel within the various departments of the site (mining, geology and processing) is a fundamental aspect of any geometallurgically based processing system. An example of a highly complex nickel sulfide ore will be used as the basis of discussion.

Sep 5, 2011

By B Godel, E R. Ramanaidou, M Verrall

Fortescue Metals Group Ltd Iron Bridge (IB) operation is a magnetite deposit located in the Pilbara region of Western Australia situated around 145 km south of Port Hedland. This Mesoarchean deposit belongs to the 3230 Ma Pincunah banded-iron formations (BIF), a member of the Kangaroo Caves Formation, Sulfur Springs Group (van Kranendonk, 2000).

Sep 18, 2023

By R F. Sandenbergh

Due to environmental considerations, mineral processing plants are increasingly recycling water to decrease the impacts of wastewater on environment and the depletion of fresh water resources. Industrial experience has shown that increasing recycling water in flotation typically negatively impacts the recovery and selectivity, especially in the selective flotation of minerals from complex sulfide ores. The major reason for the reduced selectivity is typically the inadvertent activation of sphalerite or pyrite by the heavy metal ions (HMI) in solution. These HMI are often produced during milling and flotation and absorbed by other minerals. In the normal flotation pH value range (8 - 10), these HMI are often in the form of precipitates or complex ions that may re-appear in solution or become active should conditions favour this. In this paper, microflotation, batch flotation and XPS surface measurement were used to investigate the use of HMI absorbents additions to the pulp to improve flotation selectivity of a complex sulfide ore. It has been demonstrated that HMI removal does improve flotation selectivity by facilitating more effective depression of the sphalerite. Microflotation and XPS surface measurements have shown that HMI absorbents compete with sphalerite to absorb HMI, and thus reduce the surface concentration of HMI on those sulfides. The practical use of HMI absorbents in complex sulfide ore flotation is also discussed.

Jan 1, 2005

By M-E Boucher

While the haematite concentrates produced in Eastern Canada and the magnetite concentrates that Australia will soon be producing are different feed materials, the pellets they produce have similar physical and metallurgical properties. This paper will examine the similarities and differences in the evolution of pellet microstructure for pellets produced from magnetite and haematite. The molten slag phase generated at high temperatures has a lower melting point when in contact with magnetite compared with haematite due to the higher divalent iron content. The presence of some slag is beneficial for bonding but too much can inhibit oxidation of magnetite, although slag generation at lower temperatures reduces energy usage. In pellets produced from haematite, magnetite is generated artificially from the combustion of the carbon particles added to the pellet feed as a source of energy. Maintaining the optimum production level and mineralogy of such æsecondaryÆ magnetite, allowing for its subsequent reoxidation, is important for the quality of haematite pellets. In both magnetite and haematite pellets, balancing the slag formation and oxidation (re-oxidation for haematite pellets) of the magnetite (secondary magnetite for haematite pellets) is necessary.

Jan 1, 2007

By E Nettleton, A Melkumyan

Identification of geology and mineralogy in situ on the mine face is essential if mining processes are to be automated for tasks such as exploration, grading and reconciliation. Hyperspectral data acquired from field based platforms are ideally suited to these tasks, and are set to revolutionise the automated mining industry. Changing conditions of solar illumination introduces variation into the hyperspectral signal, which is unrelated to geology, complicating analysis of data. Thus, algorithms must be able to deal with changing illumination conditions and operate in a consistent and probabilistic framework, which is a prerequisite for data fusion with other sensors. To produce accurate classification maps of geology, algorithms must be developed that are effective under different conditions of illumination.The efficacy of three algorithms to classify hyperspectral data for geology mapping on vertical mine faces was assessed. These algorithms are the spectral angle mapper (SAM), and two machine learning methods operating within a fully probabilistic Gaussian process (GP) framework û the squared exponential (SE) and the observation angle dependent (OAD) covariance functions (kernel). Two experiments were done to assess the classification performances. The first determined the performance of the algorithms by classifying hyperspectral data of known rock samples acquired using a field spectrometer. The GP-based methods had a similar performance, with average accuracies and F-scores of 97 and 88 per cent (GP-OAD) and 95 and 81 per cent (GP-SE), respectively. Average accuracies and F-scores for SAM were significantly smaller (80 and 40 per cent respectively). The algorithms were then applied to hyperspectral imagery acquired from a vertical mine face at different times of the day, under very different conditions of illumination. In contrast with experiment 1, SAM and GP-OAD gave results which were superior to GP-SE and were entirely consistent with geology mapped in the field. Compared with SAM, GP-OAD was less sensitive to the effects of shadow and produced classified images that were less noisy. The GP-SE method failed to delineate even gross changes in geology on the mine face. These results show conclusively that in order to use independent training data (spectral library) to classify imagery acquired under a different set of conditions, algorithms must take into account variability in incident illumination. Measures based on spectral distance are inferior to those based on spectral angle.The OAD kernel within the GP framework (GP-OAD) is superior to the other two methods because:it provides a probabilistic framework;it is insensitive to variability in illumination within and between imagery acquired under different conditions; andit can identify and map geological zones on a vertical mine face using an independent spectral library, without a priori knowledge.

Sep 26, 2011

By Y Wei, P Soole

This paper gives a brief description of VirtuoBlast technology ù a new, automated and highly interactive stereo vision technology which has been developed in CSIRO Exploration and Mining. VirtuoBlast technology is an integration of three advanced technologies - close-range digital terrestrial photogrammetry, oblique stereo imaging or high-speed stereo imaging, and temporal-spatial image matching technique. VirtuoBlast has been developed for the automated 3D measurement of blasting through rapid collection, processing, analysis and visualisation of 3D data related to blasting. A major field trial has been undertaken in August 1998 at the KCGM super pit. The field trial involved three applications of the technology, namely, pre-blast 3D surface mapping; post-blast 3D performance measurement; and temporal-spatial modelling of dynamic blasting process. This paper presents some results from this trial with emphasis on the application of VirtuoBlast technology to pre-blast 3D surface mapping and post-blast 3D performance measurement. Application to the temporal-spatial 3D modelling of dynamic blasting process will be presented in a separate paper. Pre- and post-blast surface models derived using both VirtuoBlast technology and conventional field survey method are presented. The differences in results using the two mapping methods clearly show that the digital photogrammetric technique has many advantages over conventional survey methods. Results of pre- and post-blast from the field trial have demonstrated the potential of VirtuoBlast technology to efficiently perform pre-blast 3D surface mapping and post-blast 3D performance measurement of production blasts. Demonstrated applications of VirtuoBlast technology to automated 3D measurement of blasting are showing an exciting future in advancing blasting science and modern blast design. The basic technologies are in place, however, continued improvements to the functionality, robustness and outputs are needed. The challenge is to build on the current state-of-the-art, by developing techniques and hardware which can be easily transferred to and implemented by the mining community. Current and future research and development will see improvements in imaging systems, automatic image processing and 3D data analysis.

Jan 1, 1999

By Morgan B. D

Since the mid 1950s, limonite deposits of a new type have been found in the northwest of Western Australia. The deposits consist of extensive fossil valley fillings up to several hundred feet in depth, of medium to high grade limonite, frequently containing limonitized fossil wood, and of Mesozoic or Tertiary age. The distribution of the deposits is closely linked with hilly outcrops of Archaean and Proterozoic jaspilite in the headwaters of the old valleys, from which the iron has been derived by leaching, and presumably re-precipitated by a process not unlike that which operates in forming bog iron deposits. Due to the relative resistance of tlie limonite to erosion, the rejuvenation of streams in the area in recent times has left limonitic remnants as mesas up to· several hundred feet above the levels of the present creeks, the courses of which generally are adjacent to or within a few miles of those of the old limonite filled valleys.The Robe River limonite deposits are the largest of this type known and can be traced for approximately 130 miles along the old stream, over 30 sq. miles of limonite remnants remaining at the present time.The present quantity of limonite in this system alone is probably in excess of 5,000,000,000 tons, and the original quantity must have exceeded four times this tonnage when allowance is made for erosion.Some thousands of millions of tons of this material contain in excess of 54 per cent Fe, with approximately 10 per cent combined water. The chief impurities are SiO2 and Al2O3, and minor elements are not present in objectionable amounts. A portion of these deposits was extensively tested by The Broken Hill Proprietary Company Limited (the B.H.P. Co. Ltd.) during 1962-1964. Most of the data presented in this paper are based on the work done on these deposits which are typical of those discussed. The overall problem of the origin of the limonite is discussed. It is apparent that the limonite originates from the jaspilitesof Archaean and Proterozoic age which form the highlands at the upstream ends of the deposits. The iron oxide has been chemically and/or mechanically derived from these jaspilites and deposited by one or more of the following mechanisms.A.-Chemical-sedimentary mainly by biological agenciesB.-Replacement of fluviatile sediments by iron-charged watersC.-Clastic sedimentary processesD.-Lateritization of fluviatile sediments.These various mechanisms are discussed; the authors favour machanismA.Manuscript received' at The Institute, 14th July, 1964.

Jan 1, 1964

By A Melkumyan, M Balamurali

Geological domains describe the mineralisation state and stratigraphic location of different geological regions of mines. They play a very important role at the geological modelling stage as weight percentage of chemical elements information within each geological domain is assumed to be correlated while information coming from different geological domains is considered uncorrelated. Having correct domain assignments to both the chemical assays and the 3D space of modelling is critical for building a reliable geological model of the mine.As standard practice significant effort is invested into the interpretation of the deposit and identification of the geological domains for the chemical assays and the 3D geological space. Despite these efforts, there are some chemical assays with ambiguous geological domain where the exploration assay domain and the block domain do not match. Incorrectly including a sample in the wrong domain can cause a large change in the predicted weight percentage of chemical elements estimation for that block. Therefore, the major challenge of grouping the spatially correlating weight percentage of chemical elements is how to determine which of these domains best fits these misclassified samples.This work proposes machine learning based autonomous technique for identifying to which geological domain (the exploration assay domain or the block domain) the misclassified sample belongs. The proposed methodology is based on Gaussian Process (GP) classification. The GP machine learning approach consists of training and inference stages. At the training stage the GP automatically learns the properties of different geological domains using the chemical assays with unambiguous domain assignment. Then, at the inference stage the GP makes predictions for the geological domains of the assays with ambiguous initial domain assignment.We tested the proposed technique by conducting a case study for an iron ore deposit located in Western Australia. The results demonstrate that the application of the proposed GP technique removes statistically significant deviations in the assay values in many regions: mineralised ore region, unmineralised region, highly weathered region and intrusive material that is highly variable. In this case study the proposed methodology autonomously identified the geological domains for more than 50 per cent of samples which are initially ambiguously classified. For the majority of the assays the GP predicted domain agrees with the geological domain assigned by the exploration assay.CITATION:Balamurali, M and Melkumyan, A, 2014. Automated identification of geological domains for exploration assays with ambiguous initial domain assignment in an iron ore deposit, in Proceedings Ninth International Mining Geology Conference 2014 , pp 99–106 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 18, 2014

By Manca PP, Lassandro R, Caranassios A, Massacci G, Ciccu R

The paper discusses the state of the progress reached in the development of the diamond wire tool for cutting hard rocks. To the advances of this relatively new technology a substantial contribution has been provided by the research being carried out at the University of Cagliari on samples of granite rocks from different Sardinian stone quarries. On the basis of field experiments and laboratory test data, the mechanism of diamond wire cutting has been assessed. In particular the influence of the rock features and operational variables on tool performance (cutting rate and bead wear) has been Elucidated.

Jan 1, 1992

By J Zhang, O Ostrovski, C Zhang D Cai, Q Wang

The conventional CaO-SiO2-based mould fluxes are not suitable for high-Al steel casting because of the strong reaction between silica in the flux and aluminium in the steel strand. In the process of casting of high-Al steel, flux composition changes; with the decrease of the silica concentration and increase of alumina. Knowledge and understanding of the effect of the Al2O3/SiO2 ratio on flux structure and properties are useful for flux design for the high Al-steel continuous casting. This paper investigated the effect of the Al2O3/SiO2 ratio on structure, viscosity, phase composition of fluxes quenched at different temperatures and heat transfer of CaO-Al2O3-SiO2-B2O3-Na2O-Li2OMgO- F fluxes. It was found that flux melting temperature increased with the increase in Al2O3/SiO2 ratio. Viscosity of the flux melts increased significantly with the increase of the Al2O3/SiO2 ratio from 0.7 to 1.2, reaching the maximum value, and then decreased with further increase of the Al2O3/SiO2 ratio. Raman spectroscopy analysis revealed that the change of the Al2O3/SiO2 ratio led to the change of aluminate and silicate structural units. The turning point for viscosity was attributed to the change in the degree of flux polymerisation. X-ray diffraction (XRD) analysis showed that increasing Al2O3/SiO2 ratio increased crystallisation tendency of the fluxes. Heat transfer measurement by infrared emitter technique (IET) revealed that increasing Al2O3/SiO2 ratio led to the decrease in heat flux which is correlated well with the increased crystallinity of the flux. The results suggested that the flux with Al2O3/SiO2 ratio 4.3 is the best candidate among the studied CaO-Al2O3-based mould fluxes for casting of high-Al steel.

Aug 21, 2024

By J Rock, K Bambrook

"Hanwha Mining Services was approached by Glencore Coal to provide a series of (trial) demonstration blasts at its Clermont coalmine. The intent of the project was to trial a bulk explosive product that would be able to provide sufficient energy for the ground type encountered without production of post-blast fume. Three blasts were loaded using the patented XLOAD bulk explosives with a density of 1.00 g/cc. XLOAD bulk products are water resistant explosives that can be loaded at densities much lower than traditional (generic) water resistant heavy ammonium nitrate – fuel oil (ANFO) or pumped blends with significantly reduced risk of fume. In addition, these products have detonation characteristics that generally deliver a higher heave partition than conventional bulk products and hence improve muck pile looseness and digability.The priority key performance measures included the absence of fume from blasting, being at least cost neutral and providing similar if not improved shovel dig rates. The design for the initial blast took a conservative approach to ensure the key blast outcomes of fume control and fragmentation were achieved.The second blast used the same pattern dimensions as the benchmark bulk product used in this area to provide a cost neutral comparison with the benchmark products that had been used over the prior six months. This resulted in a 20 per cent lower powder factor than would have otherwise been used. To test the suitability of XLOAD, this shot was slept for over two weeks between loading and firing in geology where the sleep time is typically kept to a few days to minimise the fume risk.The third blast utilised a slightly larger drill pattern to push the capabilities of XLOAD and provide a cost neutral comparison between the trial product and the traditional benchmark products. All three blasts were fired with no fume observed, no recordable incidents and good fragmentation. Shovel productivity from all three of the trial blasts was excellent with higher average instantaneous dig rates being recorded (average six per cent improvement against the instantaneous dig rates recorded for the benchmark blasts).Citation:Rock, J and Bambrook, K, 2016. Controlling Blast Related Fumes with Unconventional Explosives, in Proceedings Ninth AusIMM Open Pit Operators' Conference 2016, pp 39–49 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Nov 15, 2016

By W Potma, C Brauhart, S Halley, S Urbisinov, A Scogings

Truly integrated, quantitative, 3D GEOmetallurgical (or mineral system) characterisation, classification and 3D modelling should provide a cradle to grave unifying link across the exploration and mining value chain. All too often, spatially representative (quantitative) characterisation and modelling of a mineral system is delayed until feasibility stage, incurring a significant opportunity cost. The application of robust GEOmet characterisation methods early in the project lifecycle (at exploration stage) improves ground selection, exploration, and Mineral Resource estimation outcomes, long before there is a need for metallurgical test work. The value of this early provision of quantitative 3D mineralogy models is compounded at project feasibility stage, and continues to accrue over the entire project lifecycle, delivering cost savings, improved decision making and early warning of issues and opportunities.CITATION: Potma, W, Halley, S, Scogings, A, Urbisinov, S and Brauhart, C, 2018. Putting the ‘GEO’ back in front of GEOmetallurgy: importance of early implementation of quantitative mineral system characterisation, classification and modelling, in Proceedings Complex Orebodies Conference 2018, pp 55–57 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 21, 2018

Slide presentation at conference

Jan 1, 1996

By M Berry

Many mining companies routinely use benchmarking to review their operational activities and associated costs. The aim is to measure operational performance against industry norms, and identify areas where a company is performing better or worse than industry best practice. The goal is continuous improvement.In general, mine technical services, including mining geology activities, are not routinely benchmarked. There are exceptions, such as the cost of drilling per metre and the average discovery cost per unit of metal, but generally mining geology activities are only included indirectly in mining benchmarking studies.Aspects of benchmarking can play a critical role in assisting mining geologists to improve the efficiency and effectiveness of the services they provide. Industry norms for many generic mining geology functions have not been developed and measured, and therefore it is impossible to use external benchmarking to assess performance against other mines. But when used in parallel with quantifying the value of mining geology functions and establishing strategic goals for the team, key components of benchmarking methodology can provide essential feedback on how a team is performing against these strategic goals.CITATION:Berry, M, 2014. Benchmarking – does it have a role in improving the performance of mining geology?, in Proceedings Ninth International Mining Geology Conference 2014 , pp 361–366 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 18, 2014

By M Ziemski

The provision and management of energy in both fuel and electricity forms is an increasingly important consideration for mines. Pressures from communities, governments and markets are increasing towards more transparent and improved energy management. Combined with the energy-water nexus, where water and energy are closely related in the operation of a mine, this emerging business climate means a more thorough and responsible approach is required for the acquisition and use of energy, as well as the release of emissions. Many of the complexities in potential new ore bodies are borne in remote locations, high altitudes, low grades, arid climates and deep deposits. Each of these challenges affects the successful provision of energy. In combination, such challenges can leave an operation seemingly unviable from an energy perspective, especially when approached from a traditional mining energy feasibility lens. This paper discusses some of the energy alternatives currently available and emerging in the mining industry. Both energy supply and demand options are considered, which can provide a very different energy footprint with the flexibility to address, and potentially overcome, major energy challenges for a mine. CITATION: Ziemski, M, 2018. Energy complexities in complex orebodies, in Proceedings Complex Orebodies Conference 2018, pp 106–111 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 21, 2018

By I H. Jung, W O. Choe

Gallium (Ga)-containing compounds such as Gallium Arsenide (GaAs) and Gallium Nitride (GaN) are widely used in electronic devices due to their superior electro-optical properties and their usages increase rapidly. For the sustainable supply of Ga to electronic industry, therefore, the recycling of Gallium becomes essential. Pyrometallurgical Ga recycling process involves the complex chemical reactions between slag, matte, liquid metal, gas, refractories, etc. Therefore, the accurate thermodynamic information and phase diagram data for the oxide system containing Ga2O3 is important. In the present study, new phase diagram experiments for binary SiO2-Ga2O3 and ternary CaO-SiO2-Ga2O3 system are carried out using Differential Thermal Analysis (DTA) and quenching experiments followed by Electron Probe Micro-Analyser (EPMA) and X-Ray Diffraction (XRD) phase analysis. Based on new phase diagram data and available literature data, the thermodynamic modelling of the entire CaO-SiO2-Ga2O3 system is performed for the first time.

Jun 19, 2024