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By Standish N

The heterogeneous reactions of carbonaceous materials with oxidising gases are basic to all combustion phenomena and to many gasification processes. The carbon- carbon dioxide reaction at elevated temperatures (Reactivity) plays important roles in many metallurgical operations like iron blast furnace and ferro-alloys smeltings, zinc and lead smelting, alumina reduction, cupola operation and direct reduction processes. The stoichiometry but not the mechanism of the reaction between CO2 and carbon is represented by the equation (Boudouard reaction) CO2 + C 2CO (1) This reaction is more complex than that between carbon monoxide and metal oxides, which involves essentially a transfer of oxygen from the oxide to carbon monoxide to generate carbon dioxide without any change in gas volume, whereas the volume of the product gas of Equation (1) is twice that of the reactant gas. In the present paper an attempt has been made to review critically the reactivity measurements of various carbonaceous materials in carbon dioxide atmosphere. Steps in C-CO2 reactions, surface reaction mechanism, role of mass transfer on reaction kinetics, dynamic oxygen exchange reaction and rate equations and rate controlling steps are discussed. Various methods of reactivity measurements with their pros and cons are also presented. Effects of pertinent process variables on the reactivity of carbon are also described in detail.

Jan 1, 1986

By Hedge AS

Mt Whaleback is one of the largest open-cut iron ore mines in the world. Haulage cost is the single largest component of operating costs at the mine. Past studies towards alternatives to truck haulage have recognised the potential viability of an in-pit crushing and conveying system, dependent on the proportion of uphill haulage. After seventeen years of mining Mt Whaleback still contains more than 1,000 million tonnes of ore, needing 1,800 million tonnes of waste removal to extract it. What was once a quarry has now turned into a large open pit. The increasing proportion of uphill haulage, the need to replace ageing 120 ton and 200 ton trucks and the necessity of achieving and maintaining a higher stripping ratio prompted, in 1984, the initiation of a new feasibility study into the viability of alternative material handling systems. A semi-mobile in-pit crushing and conveying system was found to be most suited to Mt Whaleback conditions. The East Pit was selected as the best location based on the analysis of haulage profiles measured on long term incremental mine plans. A capacity of 22 million tonnes per year was considered achievable by the proven technology currently available. A detailed estimation of capital and operating costs of two systems - one with trucks only and another with trucks, crusher and conveyor - for the removal of 22 million tonnes per year of waste rock, showed substantial cost savings achievable by the proposed system. An economic evaluation of the two systems established the advantages of constructing the in-pit crushing and conveying system. This is now under construction and will be commissioned in early 1987. Experience gained in constructing and operating this installation is expected to influence decisions on similar installations in future.

Jan 1, 1986

By Yuanping H

There is a practical method of handling methane in a fully mechanized high output coal face when the methane outflow rate from the face is too high to be handled by ventilation alone, a combined method would be adopted. Before adopting this method, above all, the sources of methane outflow, which can be divided into methane in the intake airflow and methane emitted from the working seam and from the worked-out area, are determined by air-methane measure- ments in the tail gate and intake conveyor gate or by air-methane measurements in the working space of the coal face. Then, in

Jan 1, 1988

The narrow quartz vein deposits at Konongo and Ghana Main Reef gold mines in Ghana were emplaced during the plastic flow cross folding of pre-existing sub-isoclinally folded volcanic and perivolcanic deposits of Proterozoic age. The older fold structures tightened differentially according to their position in relation to the axes of the cross fold pattern giving complex outlines to the reefs in both plan and cross section.Some 4500 measurements of bedding plane linears were used in the resolution of the Boabedroo footwall structure at Konongo. The methodology developed at the Boabedroo mine was then successfully applied to other complex bodies at the Konongo and Ghana Main Reef mines.All mine development, especially stope preparation, of the folded quartz reefs at Konongo and Ghana Main Reef was controlled by the geologist to ensure that the veins were removed with as few geologically enduced hiccoughs as possible.

Jan 1, 1993

By Coin CDA

From a study of coke samples obtained from the tuyere level of four Australian Blast Furnaces, the nature of in-furnace coke degradation has been investigated. At the periphery of the raceway is a concentration of fines and the lump coke appears dull and rounded. However coke from the deadman is angular and relatively undegraded. Cokes made from higher rank coal appear to suffer preferential attack of the reactive maceral derived component (binder). The coke from lower rank coal appears to be attacked non-preferentially by the solution-loss reaction. Initial attempts to simulate these phenomena have given results consistent with these findings. From chemical analysis of the tuyere probe samples there appears to be a relative increase in carbon and decrease in-.sulphur and phosphorous between stockline and tuyere level. An overall decrease in coke mineral matter derived material was noted and associated with this was a significant gasification of silicon. Consequent formation of silicon carbide was noted.

Jan 1, 1981

Iron and steelmaking slags have been utilised for a century. All dumps are now exhausted. Because of constraints in establishing new stock yards, all slags have to be utilised immediately. At present, this is being achieved. Only in a situation where there is an increase in pig iron and crude steel production, together with the impact of new residual materials competing from other industries can marketing problems be anticipated.

Jan 1, 1979

The Comstock Lode, a world-class precious metal vein district near Virginia City in western Nevada, U.S.A. (Fig. 1), produced 8.3 million ounces (0.28 X 106 kg) of gold and 193 million ounces (6.56 X 106 kg) of silver during the period 1859 to present (Bonham and Papke, 1969). More than 95% of production was from the Comstock fault, while the adjacent Silver City, Occidental and Flowery vein systems produced about $10 million (U.S.). Within the Comstock fault high-grade ore bodies, or bonanzas, were distributed over 2.3 miles (3.8 km) along strike and persisted to >3000 feet (>900 m) below the surface (Fig. 2). Bonanzas consisted of as much as 1.4 million tons (1.3 million tonnes) of ore grading up to 1.9 oz./ton (65 gm/ton) Au and 30 oz./ton (1020 gm/ton) Ag (Table 1). Some bonanzas occurred in the main Comstock fault plane while others, including the highest grade bonanzas, formed in hangingwall frac- tures. After 1880 most ore consisted of lower-grade vein material surrounding mined- out bonanzas and large volumes of mineralized vein and wall rock in the Comstock hanging- wall that were mined from open cuts. Deep mining was hindered by large quantities of hot water and bad ground which ultimately defined the limits of underground production. The widths and richness of Comstock bonanzas strongly influenced U.S. mining law, milling and underground mining methods, and securi- ties regulations that are in practice today. Within the district Mesozoic metasedimentary rocks, metavolcanic rocks, and granitic in- trusions are overlain by Miocene volcanic rocks (Thompson and White, 1964). Veins cut all lithologies. Miocene volcanic rocks and their K-Ar ages (Vikre, McKee and Silberman, 1987) include Santiago Canyon rhyolite (22

Jan 1, 1987

Operations at two open cut mines have so far commenced on two out of the five potentially mineable seams in the Fair Hill - German Creek Coal Measures. Due to seam splitting, up to seven mining units are present in the Dysart Seam interval at Peak Downs giving a total of 12 mining units in the section. The coal is low to medium volatile type and produces strong coke. Rank increases and fluidity decreases in the southern part of the area.

Jan 1, 1974

Australia is the Western world's largest producer of alumina, supplying one third of total needs. Western Australia's South-West has the greatest concentration of alumina production in the world, with a current annual production rate in the region of 6.8 million tonnes per annum, over 20 per cent of the total supplied to market economies. The value of this production in 1989-90 was 2.34 billion dollars, a very significant contribution to the economy of the State (1). This is despite the fact that the bauxite from the Darling Range is the lowest grade that has ever been commercially exploited, and despite the geographical isolation of the region. It is therefore of great importance to the National and State economies that this industry retain its competitive edge, particularly in the current times of economic downturn. One essential ingredient of this competetiveness is technology and innovation, which can be assured by the committment of the industry to an active program of Research and Development, with support from the public sector as Appropriate.

Jan 1, 1991

By L Huang

"Successful rehabilitation of tailings landforms of tens to thousands of hectares in size at base metal mines is critical to mining companies’ ‘social licence to operate’. Rehabilitation technology used is closely related to both the economic sustainability of the mining company and the ecological sustainability of the mined environment. Conventional technology to rehabilitate mine waste landforms is costly and constrained by the availability of soil (to reconstruct root zones) and clay materials (to reconstruct compressed layer). Depending on mine waste properties and site-specific resource availability, it is not uncommon to cost A$0.1–0.5 M/ha for the establishment of conventional cover systems over mine waste domains, which often accounts for large proportion of the total closure costs. This can lead to costs approaching several hundred millions dollars for rehabilitating larger tailings and acidic waste rock using conventional cover systems.The present extended abstract proposes a suite of new technologies to tackle the problems outlined above and discusses critical factors in successful rehabilitation from substrate levels to the whole landform performance, in two key aspects:in situ engineering of tailings soil to offset/reduce materials requiredin situ chemical engineering of massive hardpan layer through alkali-activation and mineral gel cross-linking network mechanisms to encapsulate reactive tailings and achieving sustainable hydro-geochemical stability in root zones.This aims at functionally replacing the roles of the compressed clay layer and capillary breaks in conventional covers. These technologies would improve both the economic and ecological sustainability of mine waste rehabilitation, thus addressing the triple-bottom line of mining and mineral processing industries not only in Australia but other countries.CITATION:Huang, L, 2016. Emerging technology for economic and ecological sustainability in the rehabilitation of metal mine tailings, in Proceedings Life-of-Mine 2016 Conference, pp 128–131 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Jun 28, 2016

By Nguyen V. V

The development of structural defects in the overburden material immediately behind a production blast was studied using surface and subsurface techniques. A significant increase in vertical and horizontal fracture intensity was recorded. The extent of fracturing into the highwall appeared to be dependent on the structural and petrologic characteristics of the various lithological units and the relative position of the explosive charges. A shallow zone of disruption to a depth of 10 m and extending to around 30 m from the newly formed highwall crest was recorded. Horizontal fractures in lower units of the overburden sequence were recorded at distances up to 50 m from the new highwall Face.

Jan 1, 1981

The Hunter Fracture Zone can be traced into the Fiji group, and onshore SE Viti Levu in the form of NE-trending morphostructures. NW- trending morphostructures offset the NE elements. Structural mapping of Suva Harbour indicates that the NE elements are grabens bordered by faulted monoclines. Faulting is characterised by block-rotations and dip-slip displacements. The NW morphostructures are faults displaying elements of both dip-slip and strike-slip movement. Structural overprinting suggests that the NW faults represent the youngest phase of deformation, and current seismic activity occurs on this trend. A conceptual, geomechanical model of the deformation invokes toppling and wedge failure at the edge of the Fiji platform, translating material downslope into the Hunter Fracture Zone. The interference pattern produced by the superposition of the NW on the NE structures consists of a series of circular features bearing superficial resemblance to volcanic centres. Known mineral deposits in SE Viti Levu correspond closely to these features. The formation of the circular features postdates mineral genesis, suggesting that the features provide a focus for the enhanced exposure of mineral deposits rather than a source of mineralisation. There is a close association between mineralised exposures and interference patterns in extensional structures in SE Viti Levu, and a correlation between these structures onshore, and the Hunter Fracture Zone cum South New Hebrides Trench offshore. Future mineral exploration in the SW Pacific will benefit by closer consideration of the geologic structure of Pacific islands bordering the extensional regimes of deep oceanic trenches.

Jan 1, 1987

By Giannini L. M

Optimisation techniques, based on the block model, for solving the optimum pit limit problem were discussed in an earlier paper. Of the available techniques the one based on graph theory proved to be the most attractive. In the graph theory model the vertices represent blocks and the arcs represent the mining restrictions. For large ore-bodies direct application of the graph theory method poses considerable computational and storage problems. Techniques for easing the computational effort by reducingthe problem size were introduced in an earlier paper. Further, significant computational savings can be made by exploiting the structure of the graph. This is done by building the graph up level by level and successively applying the graph theory algorithm to reduce the number of blocks. In building up the graph in this way one needs what is called a "search pattern" to indicate which arcs are to be added as new vertices are introduced. Moreover, as it is essential to keep the number of arcs to a minimum it is necessary to establish a "minimum search pattern".The problem of determining minimum search patterns for any block model and for any wall slope restrictions has not been considered in the literature.The objective of this paper is to present a complete solution to this problem and to discuss, through typical case studies, the application of the associated software developed.

Jan 1, 1988

IA )W cli',hla cn1cnt fault 7011(-s 0 11Cn cOrnprise a nrc,II of inrcIIinkc(I faults, cvtcnqonal shear and In]rck cxtcnsir>nal vein- fractures. Hydrothermal mineralisation localised around such structures testifies to their importance as conduits for fluid flow. Mesh structures are most commonly developed in situations approximating bulk pure shear but predominantly simple shear meshes also occur. They appear to develop through the infiltration of pressurised fluids into a heterogeneous rock mass with varying material properties. In some circumstances, mesh formation appears to be a precursor to the development of major throughgoing faults. Mesh formation generally involves hydrofracturing (Pf> a3, at least locally) and the condition Pf - 63 to be maintained for the mesh to remain a high permeability conduit, requiring fluid overpressuring at other than shallow depths in extensional-transtensional regimes. The volumetric character of earthquake swarm activity appears to result from the passage of hydrothermal fluids through mesh structures, representing a form of distributed fault-valve action along suprahydrostatic hydraulic gradients arising from magmatic intrusion, compaction overpressuring, metamorphic dewatering, etc.

Jan 1, 1995

By Hinton A. T

Three, and possibly four, distinct types of quartz-vein associated gold mineralisation are recognised in New Zealand. They are: epithermal, schist-hosted, metagreywacke-hosted and metamorphic core complex associated types. Each has a unique geological environment and structural regime which has provided the gold source, scavenging mechanism, emplacing mechanism and geometry. Each has a characteristic suite of associated metals and trace elements. The first three types form economically important gold deposits while the fourth type have been historically worked for gold and base metals. Intense exploration is currently being focussed on all four types.The epithermal type is typified by the extensive vein systems of Martha Hill, Karangahake and Golden Cross and numerous smaller examples. The veins were deposited in a near surface active volcanic environment from deeply circulating hot water. Their structure is tensional, veins are vertical-to sub-vertical and have limited depth. Their geochemistry is identical to that in active felsic hydrothermal centres in the central North Island. Major minerals are gold, pyrite, arsenopyrite, galena, chalcopyrite, sphalerite and argentite.

Jan 1, 1990

The far reaching consequences of designing pillars for coal mines, while retaining concern for safety and economics, are cause for the search for refinement of the existing engineering methods to continue. Coal pillars, while having various functions within the overall mine plan, are the basic structural elements that assure the stability of a mine. Reliable coal pillar design methods take into account criteria which the pillars should meet in specific applications. These applications include typical mining situations such as the partial extraction room and pillar method with and without subsidence considerations, high extraction rate room and pillar, longwall mining chain pillars, and barrier pillars. However coal pillars are onlyu one element of a three element roof-pillar-floor system, weakest element of which system usually determines the stability of the excavations; however, the mining engineer can ony change dimensions of a pillar, properties of the surrounding strata remain beyond his control. The state of the art approach in pillar design places emphasis on recent developments in research. A widely encountered problem in certain coal fields is where pillars are underlain by weak floor strata. The resultant pillar design constantly maintains the perspective of the reliability of the design.

Jan 1, 1991

By Jaczkowski B. M, Cox T. J, Domfeh I. A, Stalker I

Mining and treatment of gold ore in the Ashanti region at Obuasi, Ghana has been continuous for more than 100 years. Earlier production from this world class deposit can be traced far into the history of West Africa's gold trade. As part of a general development and expansion program, Ashanti Goldfields Corporation (Ghana) recently undertook a program to heap leach oxidized near surface ore. Kappes, Cassiday & Associates was given a major role in the design, equipment supply, installation and start-up management of the 3000 tonne/day heap leach. Unusual conditions included a high annual rainfall and an ore which could be characterized as a soft, decomposed, water saturated schist. Production began in March 1990. Startup problems and their solutions are discussed.

Jan 1, 1991

The iron ore mining operations carried out by Goldsworthy Mining Limited at Golds- worthy, Shay Gap and Sunrise Hill, in the Pilbara region of the North-West of Western Australia, are unusual insofar as the ore reserves occur in a number of widely separated and relatively small deposits, requiring deep mining below the water table, and even below sea level at the Goldsworthy pit. This paper has been prepared to describe some of the problems associated with these deep open cut mines, and the technology employed to overcome them, in order to provide an efficient and economical operation. The problems discussed are: 1. Development of the Dewatering System for the Goldsworthy Mine. 2. The Stability of Pit Slopes at the Goldsworthy and Shay Gap Mines. 3. Development of Diesel Electric Trucks for Lonq Uphill Hauls.

Jan 1, 1979

High-sulphidation (HS) gold, silver and/or copper deposits are generated in both the epithermal and the upper parts of the underlying porphyry environments over vertical intervals of up to 2 km. The HS deposits are generated in advanced argillic lithocaps, which are products of the absorption of acidic magmatic volatiles by voluminous groundwater systems. Mineralisation styles in HS systems reflect depth of formation as well as the interplay between structural, lithological and hydrothermal parameters. The deep parts of HS systems, at depths of >1000 m, are typified by disseminated copper¦gold mineralisation comprising digenite, chalcocite and covellite in pervasive advanced argillic as well as underlying sericitic alteration. In highly telescoped systems, suchmineralisation may overprint porphyry stocks and associatedquartz-veinlet stockworks. Intermediate levels of HS systems commonlycontain fault-controlled copper-gold mineralisation, typically as enargite in bodies of vuggy residual quartz, silicification and/or massive pyritic sulphide. The shallow parts of HS systems, at depths of The exploration focus is on four principal HS mineralisation styles: 1. copper (eg Chuquicamata, Monywa) or copper-gold (Wafi) in thedeep porphyry-hosted parts of systems preferably, in the case of thelatter, where supergene oxidation is limited and, hence, flotationmay be used for metal recovery,2. copper¦gold-bearing replacement mantos and pipes hosted bycarbonate wallrocks in the deep parts of systems (eg Bisbee),3. high-grade gold in late-stage veins or hydrothermal breccias thatoverprint the intermediate to shallow levels of systems (eg El Indio,Goldfield), and4. large, bulk-mineable gold deposits in the shallow parts of systemsthat were subjected to supergene oxidation, thereby permittingheap-leach treatment (eg Yanacocha, Pierina).To these preferred HS styles may be added the low-sulphidation veinor disseminated gold¦silver mineralisation that is commonplacealongside many HS systems (eg Victoria at Lepanto). * Originally published in the Proceedings of PACRIM æ99,published by The AusIMM.

Jan 1, 2000

By T Kon, K Ohno

Slag foaming is an important control item in the process of refining molten steel. This study aims to investigate the factors controlling slag foaming by observing the bubble formation behaviour resulting from the chemical reaction between iron oxide and Fe-C alloy in the slag. In this study, 0.06 g of Fe- C alloy was introduced at the bottom of a BN crucible, and 6.0 g of slag (SiO2:CaO:Fe2O3 = 40:40:30) was placed on top of it. The crucible was positioned inside an infrared image heating furnace, where the temperature was rapidly raised to 1370°C at a rate of 1000°C/min in a nitrogen stream, and then held at that temperature for a predetermined time before rapid cooling. Following rapid cooling, the internal structure of the sample was examined using a high-resolution X-ray CT device. The spherical equivalent volume was calculated based on the number of observed bubbles and their equivalent circle diameter. Additionally, the relationship between the volume ratio of small bubbles in the slag volume and the distance from the bottom of the crucible was determined, along with the calculation of bubble density and volume ratio. Under various experimental conditions, numerous bubbles with equivalent circular diameters ranging from 200 to 300 μm were consistently observed. The density and volume fraction of bubbles with circular equivalent diameters between 200 and 500 μm showed a tendency to increase as the distance from the bottom of the crucible increased. Bubbles with equivalent circular diameters of 500 μm or more consistently exhibited lower bubble densities, regardless of their height within the crucible. The formation of larger bubbles is attributed to a decrease in iron oxide concentration within the slag as the reaction progresses. However, this is believed to be due to their higher buoyancy, resulting in shorter residence times within the slag and a reduction in the number of encapsulated bubbles.

Aug 21, 2024