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By H. D. B. Wilson

"IntroductionRECENT ADVANCES in geo-chemistry and in •our knowledge •of crystal structure provide a key which enables us to create a systematic picture of the genesis of many ore deposits. This genetic scheme may be used with confidence in assessing certain types of orebodies and may be of some aid in actual exploration, since it affords a rational explanation of the dependence of the composition •of the ore minerals on that of the rock type in which they occur with which they -are •associated. For purposes of the present paper, .the elements chosen are •chromium, vanadium, iron, and titanium. The oxides of all these metals occur in deposits of similar or related type, and it is proposed to show that, for each, the composition of the •ore mineral is related to •the composition of the enclosing :rock, and that one of the principal factors controlling the composition of the ore is the ionic size of its constituent elements.Geochemical PrinciplesThe crystals of the rock-forming silicates and of the magmatic oxide minerals are essentially ionic types. This means that they are composed •of oppositely charged ions such as Mg²+ and 0²-, which are held together by electrostatic attraction. The ions of each element are spherical, with characteristic size known as the ionic radius. Crystals are built up by the packing of these spheres in the most stable arrangement compatible with the size and the size and valence of the ions• involved.Many of the principles governing the formation of ionic crystals are •simple ,and logical."

Jan 1, 1953

By Tassos Grammatikopoulos, Sarah Prout, William Mercer, C. Gunning

"The Nechalacho rare metal deposit is located in NWT, Canada. Avalon Rare Metals Inc. is now evaluating processing techniques for recovery of REE to be used in the industry. QEMSCANTM analysis coupled with whole rock, REE, Zr and Nb, and electron microprobe analyses were utilized to identify and quantify the mineralogy of the deposit, and define the REE distribution among minerals. QEMSCANTM mineralogy was performed on fifty intact drill samples using EXPLOMINTM that provided textural information for the mineralization; crushed samples were used to determine the variability of the ore and define REE domains, and composite samples to determine the liberation and association of the REE minerals. The sample matrix predominantly consists of biotite, feldspars, quartz, muscovite/clays, minor chlorite and amphibole, magnetite and hematite and carbonates. REE include in decreasing order of abundance allanite (3.6%), monazite (1.5%), synchysite (0.9%), columbite (0.9%), fergusonite (0.6%), bastnaesite (0.4%), and zircon 11.0%. The majority of the HREE are carried by fergusonite and zircon, and the LREE by monazite, allanite, synchysite and bastnaesite. QEMSCANTM mineralogical data is extremely valuable in assessing the mineralogy of the ore. The data have been implemented in defining the mineralogy of the ore body, support metallurgical test work, predict recoveries and grades, and finally calculate reserves of the deposit.INTRODUCTIONAvalon is in the unique position of owning and developing one of the world’s largest rare earth deposits in the Northwest Territories of Canada.The term Rare Earth Elements (REE) is used to describe the 15 lanthanide elements or metals and, more recently, the metals yttrium and scandium, which display similar physical and chemical properties. REE are not particularly rare and have a similar abundance in the earth’s crust to nickel, tin or tungsten. Unlike these better known metals however, the rare earths have little tendency to become concentrated into commercial ore deposits. When they do become concentrated, deposits of REEs usually display enrichment in one of two groups. The most commonly occurring deposits of REEs contain a sub-group of elements referred to as the “light rare earth elements” (LREEs), which include lanthanum, cerium, praseodymium, neodymium, and samarium. Less commonly, deposits of REEs contain the much more valuable sub-group of elements referred to as the “heavy rare earth elements” (HREEs), which include europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, ytterbium and lutetium. Yttrium and scandium most commonly occur in association with this second HREE sub-group. Generally, LREEs are produced from the mineral bastnaesite, and the HREEs have been produced from the minerals xenotime and monazite. LREEs continue to be produced from bastnaesite, however in the 1980s, China started production of HREEs from unique laterite clay deposits. China now produces approximately 95% of the world’s rare earths."

Jan 1, 2011

By C. M. Anson

Introduction The prosperity of any country today is dependent upon the efficiency and growth of its primary steel industry. The ?march of the United States of America to its present commanding position in world affairs parallels the growth of its steel industry. The remarkable growth of that industry was possible only because bountiful providence endowed that country with adequate supplies of the raw materials necessary for steel making -coal and iron ore. If we accept this hypothesis, and surely we must, then to what extent can we envisage the future of our own country? This symposium deals with the most important of the raw materials required for steel making -iron ore. If we are blessed with a bountiful supply of iron ore, then surely a glorious future awaits only our taking advantage of that blessing. It is becoming increasingly evident that Canada has immense iron ore deposits. It is my privilege to make you acquainted with one of these, one that can only be classified as among the more important ore reserves in the world. I refer to the Wabana ore deposits in Newfoundland. Location These deposits lie under the floor? of Conception bay, off the east coast of Newfoundland. They consist of a series of beds which outcropped for a distance of about three miles on the northeastern shore of Bell Island, dipping at approximately 8° toward the northwest. This three-mile outcrop is the only key to the occurrence.

Jan 1, 1951

By G. Grassmück

The question of whether the air curtain principle could be used under conditions prevailing in Canadian metal mines was investigated. A vertical, portable BERRY air curtain was tested, at first in a wind tunnel built at Ecole Polytechnique at full scale (8-by 8-ft cross section) to simulate a drift and its lateral connections, and then in the haulage ways of a metal mine under actual conditions. The results permit us to predict under what conditions this type of air curtain is capable of acting as an air stopping or flow regulator and how it could be further developed.

Jan 1, 1969

By J. C. Roy, S. Couture, C. Barbeau

The chemical composition of the asbestos tailings from different mines in the Eastern Townships of Quebec are fairly uniform in composition. The serpentine minerals antigorite and chrysotile form about 85 to 90 per cent of the total. Iron oxides add another 7 to 10 per cent; magnetite represents about 70 per cent of the oxides. Chromite is present in amounts of about 0.5 per cent. The average contents of elemental magnesium, iron and nickel are 23, 6 and 0.25 per cent respectively.

Jan 1, 1972

By D. Bois, P. Poirier, B. Bussière

Environmental desulphurization is an attractive alternative for the management of acid generating tailings. Bulk sulphide flotation is the most commonly used method to produce desulphurized tailings, as shown from many previous works. This process can reduce the volume of problematic tailings to manage by making a sulphide fraction concentrate. The desulphurized tailings can then be used as construction material for an engineered cover to prevent acid mine drainage. In this paper, the results from different laboratory and pilot scale flotation tests are presented. These results confirm that low sulphide non-acid generating tailings can be produced by froth flotation. It is also demonstrated that sulphide concentrates obtained from desulphurization mixed with the appropriate binders can be used as feed material for paste backfill. From previous work on the evaluation of operating and capital costs of the desulphurization process for different ore types, the use of desulphurization as a tailings management approach was studied for several scenarios. The desulphurization process was then compared with other technologies (underwater disposal, engineered soil cover) currently used to prevent acidic drainage (AD) for a new mining operation. Results show that partial or total desulphurization are technically and economically viable options to manage tailings during mine operation. Mine waste managers should consider desulphurization as an efficient technology.

Jan 1, 2005

By L H. Warren

The types of equipment available for generating a plasma have been reviewed. The efficiency and potential of the plasma generating equipment used in performing extractive metallurgical reactions have been determined. A general classification of the reactions that might be per-formed in a plasma has been proposed. Experimental work done on extractive metallurgical plasma reactions, heat transfer between the plasma and solids, and the quench of the products of plasma reaction has been summarized. From the preliminary results it appears that the high-intensity are or the transpiration-cooled anode plasma torch offer the most promising areas for further research. C ONSIDERABLE world-wide research effort is currently being devoted to the development of processing technologies which employ the new high-temperature generating devices that have appeared over the past few years. The plasma flames produced by these devices offer the potential for subjecting materials to any single gas or mixture of gases at temperatures up to 20,000°K. With these conditions available, many reactions in extractive metallurgy,

Jan 1, 1965

By C. G. Harris, R. Sluyter

The purpose of an undercut is to undermine a block of ore which will then proceed to cave into draw holes just below the undercut. Undercut-ting is the final and most vital phase in the development of an ore block. Since its purpose is to undermine and induce caving into a block of ore, great care must be exercised to avoid premature caving by removing only enough rock to permit undercut development to proceed. Several undercutting methods, used over a twenty-year period, are re-viewed and their suitability is com-pared with ideal requirements.

Jan 1, 1960

By B. Dubé, R. Friedman, J. Oliver, R. Aubertin, M. Burson, G. Panneton, M. Hamilton, J. Ayer

"Abstract — The Detour Lake gold deposit is located within the northwestern limit of the Archean Abitibi Subprovince of the Superior Province. Mineralized zones are hosted by a sequence of pillowed and massive flows, hyaloclastite units, and altered ultramafic rocks, and are commonly oriented parallel to a series of high-strain zones that are co-planar to the regional-scale Sunday Lake Deformation Zone. Early in its kinematic history, the Sunday Lake Deformation Zone placed older (2.72 Ga) volcanic rocks of the Detour Lake Formation over younger (2.70 Ga) sedimentary rocks of the Caopatina assemblage. Gold mineralization is also parallel to the position of a laterally persistent siliceous rock unit, the 2.725 Ga ‘Chert Marker Horizon.’ The Chert Marker Horizon coincides with the boundary between the mafic-dominated upper Detour Lake Formation and the ultramafic-dominated lower Detour Lake Formation. Stratigraphic and geochronological data suggest that the Chert Marker Horizon is a deformed felsic volcaniclastic unit. At a cut-off of 0.6 g/t Au, the Detour Lake deposit contains 17.26 million ounces of Au within 445.9 million tonnes of rock grading 1.20 g/t Au. Gold occurs in shear-hosted and extensional vein arrays within rocks of the upper and lower Detour Lake Formation and within the Chert Marker Horizon. The Detour Lake deposit has many of the characteristics of a greenstone-hosted, quartz-carbonate vein deposit; its very large size may be attributed to large-scale rheological controls resulting in the formation of dilatant sites in permissive rock units. © 2012 Canadian Institute of Mining, Metallurgy and Petroleum. All rights reserved."

Jan 1, 2012

By R. M. Graves, C. B. McKenzie, D. Barbour, D. W. Desnoyers

"Abstract -The prospective Tulks volcanic belt hosts five significant massive sulfide deposits, Tulks Prospect, Tulks East, Jack's Pond, Daniel's Pond and Victoria Mine, as well as numerous showings and indications throughout its 70 km outcrop length. Regionally, the 498 Ma sequence consists dominantly of felsic pyroclastic rocks and flows with interbedded mafic volcanic units and fine­ grained sediments, commonly graphitic. Contemporaneous granitoid rocks occur in the south half of the belt. Rocks usually display a strong NE-SW, steeply dipping, penetrative foliation and other shear-related high-strain fabrics. Facing directions are normally northwest, although there is local evidence of folding. Sulfide bodies and their alteration systems are deformed and shape-modified in the style of ambient strain.The Tulks, Tulks East and Jack's Pond prospects appear to occupy a similar stratigraphic level, on or near the contact between a thick felsic pile and an overlying broad, conductive package of graphitic sedimentary rocks. AU are pyritic deposits with well-developed footwall alteration systems. The Tulks prospect comprises four polymetallic lenses totalling 750 000 t. Three lenses constituting more than 6 000 000 t of sulfide mineralization are indicated at Tulks East but only the 210 000 t ""B"" lens contains significant base metals. Jack's Pond consists of a very extensive, zoned alteration complex in which four lenses of massive to semi-rnassive pyrite + chalcopyrite are known.The central part of the system, characterized by Mg chlorite and carbonate, is enveloped by pervasive sericitization and capped by intensely silicified and pyritized volcanics. The sulfide lenses are interpreted as part of the footwall zone and are beneath that part of the system most likely to host polymetallic massive sulfides.Daniel's Pond differs from the other prospects in such fundamental ways as metal content, associated alteration and structural setting. The deposit comprises strongly tectonized, Ag-rich, Zn-Pb mineralization distinguished by a pronounced Ba-As-Sb signature. Mineralization is confined to a narrow, north-south high-strain zone which separates unstrained mafic volcanic rocks to the east from well-foliated felsic rocks. The deposit Jacks an extensive alteration halo and at its north end is associated with a lens of barren, undeformed massive pyrite.The Victoria Mine deposit, the most cupriferous of the five, is related to a moderately dipping structure that separates well-foliated Tulks volcanic rocks from an overlying, Jess deformed volcanic­ sedimentary sequence that may be as young as 462 Ma. The structure is also the locus of black chlorite, dolomite and quartz alteration. Structurally remobilized precursor sulfide mineralization is one possible source for the deposit."

Jan 1, 1993

By J. S. Moretzsohn, D. F. Graham

"Airborne Synthetic Aperture Radar (SAR)was acquired over the Carajás Mineral Province, within the rainforests of the Amazon, which hosts the world’s largest Fe-ore deposit(Santos, 1986). Significant chemical weathering exists in this humid environment. PrevalentAu mineralization is thought to be generally associated with deformation zones in Archean schists.Radar data have proven to be very useful as an aid to geological mapping in the tropical rainforests of the Amazon Basin in Brazil. In these densely vegetated areas, a sense of regional structural trends is obtained as a con-sequence of the sensor/terrain geometry. The top forest canopy is the main terrain reflector of X-band radar energy, and consequently is the main terrain surface feature expressed in processed radar imagery. Radar is important for extending t,he continuity of mapped structural lineaments. Differential weathering is related to variations in radar image texture which is used to infer gross lithologic variations and relative age relationships of major rock units. Specifically, quartzites and banded iron formation are highlighted in the radar imagery due to their unique tonal and textural appearance, in contrast to schists, gneisses and metavolcanic rocks. As tropical areas are typically enveloped in cloud or mist, radar data are invaluable in providing information for logistical planning of field mapping activities."

Jan 1, 1997

By J-F. Turgeon, Y. Pépin, G. Hudon

The high temperature hydrochloric acid leaching of titanium slag in the QIT upgraded slag process (UGS) creates a harsh environment for materials of construction. Because of their excellent chemical and heat resistance, furan mortars are a key component in the lining system of the UGS pressure leach reactors. Similar products coming from different manufacturers have however shown unequal performances in service. In some cases, cracking of the brick lining has occurred during curing of the mortar. This study was initiated to investigate the impact of the curing conditions on the properties of carbon filled furan mortars. Laboratory tests were conducted to assess the effects of temperature and exposure to water and HCl solutions on mortar shrinkage and mechanical properties (tensile, compressive and bond strength). Three commercial furan mortars that have been used in the UGS leach reactors were thus characterized. Mortar properties were found to vary significantly among the products tested. Moreover, the curing conditions were shown to have a significant impact on mortar shrinkage and mechanical strength. The experimental findings provide explanations for the unequal performances of the mortars in service and for the problems of brick lining cracking that occurred in the UGS leach reactors. This study demonstrates that excessive mortar shrinkage compromises the integrity of a brick lining system.

Jan 1, 2004

By K. J. Heale, G. G. Richards, D. J. Rioux, R. L. Stephens

Slag fuming has remained a key process for the recovery of Zn, Pb, and minor elements in the integrated flow sheet at Teck Cominco's Trail Operations for more than 75 years. Since the start-up of the KIVCETTM process and the #3 slag fuming furnace in 1997, a range of process intensification projects have been completed to improve metals recoveries and throughput based on improved process control, mechanical modifications, and, most recently, the implementation of oxygen enrichment of the blast air. This latter project, initially named 'nitrogen depletion' and now 'nitrogen oxygen performance enhancement' (NOPE), is the primary focus of this paper. NOPE reduces the amount of heat required to heat the inert nitrogen gas, and therefore more of the energy input can be used for reduction. It also frees up boiler capacity because the inert nitrogen gas does not then have to be cooled down. A dynamic METSIMTM model was developed to determine the opportunities to improve the process capacity and heat balance to both assist with justifying the project and to verify the observed furnace behaviour. Several process safety management issues were also addressed and a few key minor mechanical modifications were made to allow the project to proceed to commercial implementation at 25% blast air oxygen enrichment. Short term plant trials have confirmed the model predictions. The first three months of a long term, continuous trial showed a 6% increase in zinc fuming rate from average furnace performance despite the implementation of a KIVCETTM fluxing change to assist with minor element recovery that was expected to negatively impact the zinc fuming rate by 3 to 5%. This encouraging result is also in line with the model predictions.

Jan 1, 2008

"Conveyed coal flows have been diverted on the basis of real time ash analysis since the 1980s. Many coarse particle separation methods are available through screens, jigs, heavy media separation, particle sorters, to name a few, however bulk diversion requires a representative, continuous analysis to ensure diversion decisions can be made with confidence. Sensors also need to be able to provide measurements at useful time increments so that small tonnages can be diverted for maximum selectivity. Particle separation typically requires high capital costs and there are limitations either in throughput tonnage or particle size or both. Few techniques are able to provide robust and representative analysis of conveyed flows in a useful time basis. Prompt Gamma Neutron Activation Analysis provides multi-elemental analysis of conveyed bulk materials and has been proven in the minerals industry since 2003. This paper outlines the success of this technology in minerals applications in iron ore, phosphate rock and most recently in copper-gold ores, including its use in bulk diversion.INTRODUCTION Naturally occurring quality variability, or heterogeneity, in mineral deposits enables separation and recovery of the valuable components through mining and processing operations. There are distinct advantages in processing the minimum quantity of material to achieve the highest possible yield. Unfortunately, declining ore grades has resulted in larger scale operations and a subsequent loss in selectivity for mining operations. As limits are approached on the practical size of equipment, there is more motivation to investigate alternative solutions. Mining companies are subject to increasing social resistance to growing waste disposal requirements in addition to higher energy and transport costs. Major savings are available by reducing the quantities of material processed where pre-concentration can be effectively applied at early stages in the process. One of the simplest ways to pre-concentrate is to measure the bulk material and reject waste soon after mining so that minimal expense is incurred and that only higher quality material is sent to processing operations. This bulk sorting can occur within the mining operations and has major benefits through energy and other consumables savings. This paper discusses the application of real time analysis technologies suitable for bulk sorting within the minerals industry. Technology that has proven representative for conveyed material bulk analysis and its successful applications to date is explained. Analysis using a sensing technique is only one component of a successful bulk sorting process; the importance of effective diversion systems and a bulk sorting strategy are also discussed. The bulk sorting stage may be one component of a system that could include additional downstream technologies such as particle based sorting systems on a diverted stream."

Jan 1, 2018

By Gerry Doeksen

The paper deals with three case studies: (a) the handling of wet concentrates (5 to 8 per cent moisture) through feed bins; (b) the handling of the same product in rail cars; and (c) the handling of dry concentrates (less than 0.5 per cent moisture) through feed bins. In each case, the paper discusses the problems of rat-holing. In each of cases (a) and (c), there is a discussion on the consequent extreme variations of feed rates coming from the feeders, making automation of process control difficult to impossible. Currently available bin-flow theory and flow property tests are used as aids in redesigning the bins. The paper concludes with illustrations of the final results after the redesigned hoppers were installed and tested. There is also a discussion on the advantages of the new mass-flow bins on adjacent feeder performance.

Jan 1, 1970

By A. Brown

IN INTRODUCING the subject of rock pressures, it may safely be assumed that mining men are only too familiar with the physical effects of strata stresses that accompany the extraction of minerals. It may be further assumed that they have, as individuals, arrived at certain conclusions regarding their nature, based upon years spent in observing such phenomena and in learning how to continue mining in spite of them. Such hardly won experience forms the core of what is often referred to as 'pit sense'. This essential type of knowledge is not ?based on theoretical considerations, nor can it be found in text books. It is highly individualistic in nature and almost impossible to pass on from one generation to another in terms of precise rules for guidance. It is this aspect of individual judgment based on practical experience that has led to the significant phrase The Art of Mining.

Jan 1, 1956

By Mehmet F. Tauer, Pierre Trudel

"The metamorphosed mineralized Archean Bourlamaque batholith, dated at 2710 +-54 Ma, is a homogeneous body, composed mainly of quartz diorite; it is cut by late dioritic, mafic and aplitic dykes, and contains metasomatized ultramafic xenoliths. A geochemical investigation confirms the calc-alkaline affinity of the batholith, and the REE profiles are similar (Lal Yb = 3.9 to 8.1) to those of the intermediate to felsic metavolcanic rocks at Val d'Or into which the batholith was intruded and to those of the calc-alkaline members of the Blake River Group at Rouyn.Gold distribution within the batholith is heterogeneous and anomalous. Although the background Au content of the batholith is estimated to be 3.2 ppb Au by RNAA , the estimated median gold content of the batholith is 10 pp b (with P84 =32 and PI 6=3.1 ppb), much higher than that of ""normal"" granites (I to 5 ppb A u). The gold mineralization exhibits a close relationship with shear zones (e.g. Belmoral Mine) or with diorite dykes (e.g. Sullivan, Perron and Courvan mines).The following sequence of geological events is proposed: (I) pretectonic emplacement of the batholith, which is cogenetic with its volcanic host rocks; (2) regional metam orphism and deformation with localized shearing; and (3) hydrothermal alteration and quartz veining. We conclude that: (1) the Bourlamaque batholith is a gold-enriched intrusion, and (2) the determination of average gold content may be an effective method f or distinguishing ""sterile"" intrusions from those with potentials for gold mineralization.RESUMELe batholite archéen minéralise de Bourlamaque, daté de 2710+-54 Ma, est une intrusion homogène, constituée principalement de diorite quartzique, qui a été recoupée par des dykes tardifs de diorite, d'aplite et de composition mafique. Il contient aussi des enclaves de roches ultramafiques metasomatisees. L 'étude géochimique confirme le caractère calco-alcalin du bath olite et les profits des ETR sont semblables (La/ Yb=3.9 a8.1) a ceux des volcanites intermédiaires afe tsiques de la région de Val d'Or dans lesquelles le batholite fait intrusion et à ceux des unites calco-alcalines du Groupe de Blake Ri ver a Rouyn. La distribution de Au dans le batholite est à la fois anomale et hétérogène. Bien que le bruit de fond du batholite ait été estime à 3.2 ppb A u par AANR, sa médiane a été estimée a10 ppb Au (avec P84=32 et PI6= 3.1 ppb) , ce qui est nettement plus élevé que la valeur des roches granitoides ""normales"" donnée dans la littérature (1 a 5 ppb A u). Dans la batholite, la minéralisation aurifère est intimement associée aux zones de cisaillement (e.g. mine Belmoral) au aux dykes de diorite (e.g. mines Sullivan, Perron et Courvan).La séquence des évènements géologiques suivante est proposée: (1) emplacement pre-tectonique du batholite, lequel est cogenetique avec les roches volcaniques encaissantes; (2) deformation et metamorphisme regional avec des cisaillements tectoniques locaux; et (3) altération hydrothermale et développement des veines de quartz. Nous concluons que: (1) le batho lite de Bourlamaque est une intrusion enrichie en Au; (2) la determination de la teneur en Au peu être une méthode efficace pour distinguer les intrusions stériles de celles qui possèderaient un pot entiel pour des minéralisation s aurifères."

Jan 1, 1989

By Lifeng Yang, Xiang Zhang, Liang Yuan, Yonghui Wang, Bing Hou, Mian Chen, Rixing Zhang

Large-scale hydraulic fracturing technique has been widely applied to the development of shale gas reservoirs, where the interaction between natural fractures and critical fracture zones has substantial impact on the propagation of hydraulic fractures. Therefore, it is of significant importance to understand and experimentally verify such mechanism. To reach this end, tri-axial fracturing tests were implemented on 400mm×400mm×400mm block samples collected from Longmaxi shale outcrops. The interplay between hydraulic and natural fractures was investigated during the tests, factoring in the role of pump rate in affecting the created fracture network. Based on the experimental results, the critical fracture zone, defined as the weak formation zone nearby the wellbore created by staged pressure implementation that is observed rapid fracture propagation upon next stage of pressure increase, was thoroughly investigated. The analysis illustrates that given the high brittleness of the shale formation, abundant critical fracture zones are generated around natural fractures with pressure building up at a relatively low pump rate. As the pump rate increases, hydraulic fractures initiate and come into play with critical fracture zones, implying emergence of a large number of micro-cracks. A changing pump rate modifies the way of interaction between hydraulic and natural fractures and the subsequent formation of fracture network. Long term fracturing fluid injection with relatively low pump rate below the activation of critical zones is suggested. Also proposed is appropriate timing when applying a specific pump rate that will contribute to the improvement of hydraulic fracture propagation.

Jan 1, 2015

By A. C. A. Howe, J. C. Rowntree

"The Bernie Lake pegmatite near Lac Du Bonnet in southern Manitoba is a complexly zoned pegmatite containing several lithium-bearing units in addition to the western world's largest known reserve of cesium. The pegmatite forms a flat-lying ellipsoidal body within an east-west-trending Precambrian amphibolite. The pegmatite enclosed by this vertically schistose amphibolite lies near the eastern tip of a granitic intrusive. The relationship of this intrusive to the pegmatite is obscured by Bernie lake. To date, the pegmatite body has been delineated aver an area of approximately 80 acres; it attains a maximum thickness of 280 feet. Several distinct zones, including three assemblages of economic importance, comprise the pegmatite itself. The combined spodumene and lepidolite assemblages provide a recoverable defined lithium ore reserve of almost 5 million tons averaging more than 2 per cent lithium oxide. The recoverable cesium ore of the pollucite assemblage provides 300,000 tons averaging more than 20 per cent cesium oxide; this represents more than half of the western world's pollucite reserve. The Bernie Lake pegmatite deposit, owned by Chemalloy Minerals Limited, is well located with respect to the growing United States markets, and its reserves of cesium are large enough to enable it, under favourable economic circumstances, to become the major producer of this metal in North America."

Jan 1, 1967

By A. Anderko, R. D. Springer, R. D. Young

A thermodynamic model has been developed for calculating phase equilibria and other properties of multicomponent electrolyte systems. The model has been designed to reproduce the properties of both aqueous and mixed-solvent electrolyte systems ranging from infinite dilution to solid saturation or pure solute limit. The model incorporates formulations for the excess Gibbs energy and standard-state properties coupled with an algorithm for detailed speciation calculations. The excess Gibbs energy model consists of a long-range interaction contribution represented by the Pitzer-Debye-Hiickel expression, a second virial coefficient-type term for specific ionic interactions and a short-range interaction term expressed by the UNIQUAC equation. The accuracy of the model has been demonstrated for common acids and bases and for multicomponent systems containing aluminum species in various environments.

Jan 1, 2005