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By Suzanne Paradis

Geographic distribution ? Deposit economics ? Temporal distribution ? Tectonic settings ? Basin architecture ? Morphology ? Ore-fluid chemistries Key exploration criteria

May 1, 2006

By D. Shishin

Continuous integrated experimental and thermodynamic modelling work is conducted in Pyrometallurgy Innovation Center (PYROSEARCH). The target is to develop a tool, which is capable to predict the compositions of phases, phase equilibria and enthalpy balance for pyrometallugical processes with higher accuracy. All these can be achieved by thermodynamic calculations based on Gibbs energy minimization algorithm. Recent developments made it possible to predict important factors, such as the chemical solubility of Cu in slag as a function of matte grade, temperature, P(SO2), Fe/SiO2 ratio in slag, wt% Al2O3, CaO and MgO in slag. In industrial practice, it is not only chemical solubility, but the overall amount of slag, which affects the recovery of copper and other valuable metals. It will also impact the energy balance. The presence of solids in the slag matrix influences the physical entrainment of matte in slag. Oxygen enrichment which is sometimes used to control the temperature of the furnace, may also affect the volatilization of minor elements into the gas phase. Same is true if additional fuel is used to compensate for heat balance. In other words, all key process parameters mentioned above are interrelated. Present study demonstrates the ways thermodynamic modelling can be used to link those process parameters on the example of copper smelting. INTRODUCTION Research methodology involving integrated thermodynamic modelling and experimental approach has been recently reported by the authors (Shishin, Hayes, & Jak, 2018 Shishin, Hidayat, Jak, Decterov, & Belov, 2016). Present paper reviews the updates and discusses challenges in the development of a large self- consistent thermodynamic database. The database covers the Al-Ca-Cu-Fe-Mg-O-Pb-S-Si-Zn-(Ag, As, Au, Bi, Ni, Sb, Sn) chemical system. The database works in the environment of FactSage software Bale et al., 2016 and related family of products: ChemApp (Petersen & Hack, 2007), ChemSheet and SimuSage. A list of phases, and thermodynamic models is shown in Table 1. For the copper industry, most important phases are Gas, Slag, Spinel and Liquid matte/metal/speiss. Black-colored elements represent the base system, elements in green can be considered as slag modifiers (slagging elements), and elements in red are minor. Ni is highlighted because it was included recently, in 2019, and currently under development. In addition to copper, the database covers the conditions typical for lead and zinc pyrometallurgical extraction. It is developed in consistency with the experimental results for high concentrations of Pb and Zn. Examples of applications in the present study include the thermodynamic analysis of fluxing for an agitated copper reactor to show the effect of Fe/SiO2, and calculations of copper slag cleaning using reductant.

Jan 1, 2019

By Henk Dijkman, Wageningen University, Paula Gonzalez Contreras, Irene Sánchez-Andrea, Jan Weijma, Silvia Vega

"More than 20 years ago, Paques B.V. introduced innovative biotechnologies to recover metals and to remove sulfate from aqueous streams. These technologies find their origin in the exploration of microorganisms involved in the global sulfur cycle. Currently, several sulfur cycle biotechnologies are applied successfully at full-scale. The sulfur cycle is closely linked with the iron cycle, and also the latter offers opportunities for application of innovative biotechnology for the mining industry. Microorganisms of the natural iron cycle carry out reactions that are not feasible by chemical methods such as ferrous iron oxidation with oxygen at pH below 4. Iron oxidation with oxygen can be conducted using microorganisms living at pH between 0.5 and 7 and at temperatures between 0 and 95ºC. Remarkably these microorganisms can also carry out arsenite oxidation at similar acidic conditions and high temperatures. Making use of the extreme features of these microorganisms, Paques and Wageningen University have developed a biological process to precipitate arsenic as scorodite. This biological formation of scorodite is a novel combination of biological oxidation and biocrystallization. Depending on the level of saturation, biological oxidation rates and operational conditions, we could control the formation of the iron precipitates such as jarosite and scorodite. Currently new microorganisms have been harvested from hot springs and rock acid mine drainage to foster the growth of specialized microbial communities with potential high iron and arsenic oxidation capacities and higher resistance to other metals. In our paper we address the ongoing research and development of the bioscorodite process.THE USE OF IRON TO REMOVE ARSENIC In 2015 several environmental disasters related to the release of mine wastewater and tailings occurred. On August 5th, a waste water spill occurred from the Gold King Mine near Silverton, Colorado. A dam holding the tailing pond was damaged and spilled three million US gallons (11 ML) of mine wastewater and tailings, including elements such as cadmium, lead and arsenic, into Cement Creek, a tributary of the Animas River in Colorado. “At their peak, arsenic levels were 300 times the normal level and lead was 3,500 times the normal level” (The Guardian, 2015). In early November, another collapse of a mining dam in the Brazilian state of Minas Gerais spilled between ten and sixteen thousand US gallons of water and sediment after a dam failed from an iron ore mine. Arsenic and mercury polluted the Doce River, arsenic levels were found more than ten times above the legal limit in some places of the river (The Guardian, 2015). Waste production is inevitable during Mining. However, a preventive waste management strategy could have minimised waste production, maximised waste reuse and classified waste by their hazardous degree."

Jan 1, 2016

By F. E. Goodwin

Since the last CIM Zinc and Lead Conference ten years ago, significant technical and market forces have influenced how these metals are used, and the geographic distribution of their uses. Unprecedented price fluctuations have opened competitiveness issues, while the rapid growth of the Chinese market has created challenges both inside and outside China. Recent technical developments in battery energy storage, coatings, castings and chemical applications of lead and zinc will be reviewed together with the influence of these trends on end use markets.

Jan 1, 2008

By F. Nava-Alonso, A. Uribe-Salas, C. Rodriguez-Rodriguez

Ozone has been proposed to pretreat refractory ores before the cyanidation process for precious metals extraction. As pyrargyrite is one of the silver species most common in Mexican refractory ores, the ozonization of this silver sulfide was studied. The effect of pH and ozone concentration on silver dissolution was evaluated by means of a factorial experimental design. Two levels of sulfuric acid concentration and ozone in gas concentration were evaluated: 0.18 and 0.72 mol/L of acid and 0.054 and 0.077 gO3/L, respectively. The highest silver dissolution was obtained when using the higher acid and ozone concentration.

Jan 1, 2011

By Paul W. Richardson

"Introduction And AcknowledgmentsTHIS PAPER outlines the geology and discusses the geological problems of the Mindamar mine. It is impossible to acknowledge the contributions of ideas of all the geologists who have worked in the area. Among the more important contributors are K. DeP. Watson, W. S. James, B.S.W. Buffam, and L. J. Weeks, and John MacPherson, the resident geologist at the mine.A mineralogical and chemical study of the ore and country rock is being carried •on by Dr. Watson at the University of California, Los Angeles.General InformationThe Mindamar mine is on Cape Breton Island, forty miles south-west of Sydney (Figure 1). The nearest railway stations are at St. Peters, which is thirty-two miles southwest of the mine, and at Sydney. Good gravel-surfaced roads connect the mine to the railways.The mine is producing at the rate of 600 tons a day of ore containing zinc, lead, copper, and minor amounts of silver and gold. At the present time the mill feed averages 9 .per cent combined metals, of which zinc makes u:p 7 1per cent and lead and copper each 1 per cent.General GeologyThe ore being mined ,by Mindamar occurs in a shear zone parallel to a northeasterly striking, vertically dipping, series of rocks consisting of rhyolite tuff, rhyolite, minor more basic flow rocks, and diorite (Figure 2). In the vicinity of the mine, these rocks have been termed the Mine Series. They belong to the Bourinot group, which has been assigned by L. J. Weeks to the Middle Cambrian. At the latitude of the mine, the Bourinot group is bounded on the northwest by the Stirling fault and extends eastward for two miles."

Jan 1, 1953

By Robert B. Parsons

"1984 was an eventful year in the courthouse f or observers 0/ the mining tax scene in Canada. For the first time in a number of years, the Federal Court heard several important tax cases which pertain directly to the resource industries. Tax Notes discusses/our cases that could affect the taxation 0/ operations and investment in the mining sector.Capital Gain or Income?Ever since tax reform, risk-takers in the exploration business have maintained that the taxation of capital gain s is a significant impediment to raising risk capital. It must be akin to rubbing salt in the wound, then, when an entrepreneur sells shares and the Court upholds Revenue Ca nada taxing the gain as ordinary income instead of capital gain. But, this is precisely what happened in the case of The Estate of Murray Watts, et al. v. The Queen.The issue that had to be decided by the Federal Court, Tri al Division, in this case was whether or not the profit from the sale of shares in Hearne Coppermine Exploration s Limited in 1968 was a capital gain, or income subject to tax.Hearne was incorporated in July, 1967. At that time, the three plaintiff s, together with seven other individuals, subscribed for 400,000 shares at 10 a share. The plaintiff subsequently subscribed for an additional 500,000 shares at $1.A pooling agreement was entered into by all ten shareholders regulating the disposition of any o f their shares; any sale required approval of seven of the ten initial sub scribers. It also provided for the sale of their shares 30 days after any public offering."

Jan 1, 1985

By Fathi Habashi

A new era in pressure hydrometallurgy is marked when the roasting - leaching - electrowinning process in the zinc industry was replaced by direct pressure leaching of zinc concentrate. Since then, the technology has received recognition as the technology of the future. Large autoclaves of unprecedented size have been manufactured and installed in a number of metallurgical plants for recovering copper and nickel from their concentrates or liberating gold from its refractory ores. An attempt to recover alumina from clay using pressure technology is underway. Autoclaves lined with acid resisting bricks or with titanium clad may weigh as much as 800 tonnes were transported successfully from the manufacturing workshop to the mine site over long distances.

Jan 1, 2014

By William H. McCracken, William G. Holroyd

"The People's Republic of China could very well be considered the largest untapped mineral and metal resource in the world. The proven reserves of antimony, barite, bauxite, fluorspar, graphite, lithium, magnesite, mercury, molybdenum, phosphate, pyrite, rare earths, talc, tin, titanium, tungsten, vanadium and zinc are among the largest in the world.Any company involved in the purchase or supply of industrial raw materials has undoubtedly followed the phenomenal growth of some of the Chinese mineral commodities, where growths in production of more than 200010 have occurred during the past ten years, for commodities like barite, cement, gold, gympsum silver and talc. Others, like bauxite and phosphate, experienced production increases in one year alone of over 45%, from 1986 through 1987!A popular rationale in the United States during the past two years has been the acknowledgment by Professor David Calleo, of Johns Hopkins School of Advanced Studies, that ""America is not sinking-the rest of the world is rising"". While we recognized this rise to be that of economic power for Japan, Korea, Brazil, Taiwan and, more recently, the newly-combined Germanies, China has also successfully completed her own modern five year development binge. But with each boom there is also a bust, and the start of the 1990sfor China shows signs of economic distress. China posted a budget deficit equivalent of US$1.9 billion in 1989 coupled with official inflation at 18010. Projections for 1990 are for US$1.8 billion deficit and inflation as high as 24%. However, government spending in the first seven months of the year climbed 16.4%, outpacing an 11.6% rise in revenue. Spending increases have been related to the government policy to keep prices on domestic goods artificially low, through subsidies, and to bailout inefficient state companies."

Jan 1, 1991

By E. Lehtila, J. J. Talja, R. Jahila

Kopar Oy is acknowledged for engineering and manufacturing of robust systems for bulk material handling, especially at power plants and non-ferrous smelters. We have over thirty years of experience with systems specifically designed for hot and abrasive conditions, aiming at low cost of ownership, low operational expenses and high availability. Although Kopar has numerous applications in mechanical conveying, there is an increasing number of pneumatic conveying applications at copper smelters. They relate to conveying of concentrate, and primary and secondary flue dusts. Challenges of pneumatic conveying for concentrate are mechanical and do relate to broad particle size distribution and high abrasivity of the concentrate and the silica. Therefore, special attention shall be paid to system design and ceramically lined bends in the pipeline. Challenges of pneumatic conveying of primary flue dust relate predominantly to material stickiness and poor flowability which are mainly due to fine particle size and formation of sulphates and furthermore, crystalline water. Additional challenges of secondary dust, the white converter dust, are primarily due to the extremely fine 0.1–1.5 µm particle size and problems which come with this. Effect of material characteristics like size distribution, morphology and chemical composition in pneumatic conveying are discussed in detail. INTRODUCTION Fine materials like concentrate, feed mix, flue dusts (from waste heat boiler and electrostatic precipitator) and secondary dusts need to be conveyed at smelters. Both horizontal and vertical conveying and combination of those are used. For the purpose, both mechanical and pneumatic conveying are applied. Most widely used equipment are drag chain conveyors and various combination of pneumatic systems, e.g. air lift, dense-phase and dilute phase pneumatic conveyors. Kopar has 30 years’ experience with multiple material handling systems. Furthermore, acquired companies like Elmomet Oy and SITE Oy (both currently fully merged and integrated into Kopar Oy) have even longer history, especially in pneumatic conveying. It is commonly known that the finer the dust the more difficult it is to be conveyed pneumatically. Sulfates with crystal water makes it all even more difficult, if not ineligible. Challenges related to pneumatic conveying of various fine materials is discussed in detail in the paper.

Jan 1, 2019

By J. R. Kadambi, E. Kucukal, J. Furlan

"Hydrocyclones are used in various industrial applications, including mineral processing and tailings management, to separate or classify solid particles and/or liquid droplets from multiphase feed. The fluid flow in a hydrocyclone (used in mineral processing) was investigated numerically and experimentally using particle-image velocimetry (PIV) and refractive index matching techniques. Two turbulence models were used in the calculations: the k–? model and the Reynolds stress model. Particle image velocimetry measurements were taken at various spatial locations along the cyclone. Computational results were validated globally using pressure and flow-rate readings at the boundaries, and locally by comparing the PIV velocity-vector maps and profiles.RÉSUMÉ On utilise les hydrocyclones dans diverses applications industrielles, dont la minéralurgie et la gestion des résidus, pour séparer les particules solides et/ou les gouttelettes liquides de l’alimentation polyphasée, ou pour les classifier. Une étude numérique et expérimentale sur l’écoulement des fluides dans un hydrocyclone (dont on se sert en minéralurgie) a été menée à l’aide des techniques de vélocimétrie par images de particules (PIV, de l’anglais particle image velocimetry) et d’appariement des indices de réfraction. Deux modèles de turbulence ont été utilisés dans ces calculs, à savoir le modèle de turbulence k–? et le modèle aux tensions de Reynolds (RSM, de l’anglais Reynolds stress model). La valeur de la PIV a été mesurée à diverses positions spatiales le long du cyclone. Les résultats de ces calculs ont été validés globalement à l’aide de relevés des pressions et du coefficient d’écoulement d’une extrémité à l’autre de l’hydrocyclone, et localement à des coordonnées spatiales spécifiques en comparant les cartes et les profils du vecteur vitesse PIV."

Jan 1, 2017

By Walter Valery, Sergio Vicuna, Roberto Valle, Hamer Arevalo, Ben Burger, Lui Vargas, Alex Jankovic, Jim Seidel, Eduardo Nozawa

This paper describes the design, the first three years of operation and optimization of a large, single stage SAG mill at Minera Yanacocha’s Gold Mill facility located in northern Peru. The Gold Mill was commissioned in March 2008 with a 32’ x 32’ EGL, 16.5MW single stage SAG mill, to process 5 million tonnes per annum high grade oxide Au/Ag ore. Operational control, feed size distribution, grinding media, mill liner, grate and pulp lifter optimisation have allowed the mill to operate 15-30% above design throughput rates, but with a product P80 coarser than design. As part of the optimization, full grinding circuit surveys were conducted. Historical operating data and survey data were analyzed and used to evaluate possible circuit changes and determine alternative operating strategies. A number of changes were implemented which allowed the SAG mill to operate similarly to a large ball mill and achieve finer mill product that was closer to design. This paper summarizes life to date data analysis and improvements made by Minera Yanacocha as well as the grinding circuit optimisation study conducted by Metso Process Technology and Innovation.

Jan 1, 2012

By D. A. Riva

"The Line Creek Project is located in southeastern British Columbia, approximately 25 kilometres north of Sparwood. The design is to produce a total of2.7 million tonnes of coal annually. This is made up of1.4million tonnes of thermal coal and 1.3 million tonnes of metallurgical coal.Construction commenced in the spring of 1980 and mining operations began in July 1981. The thermal processing plant, maintenance and dry facilities, as well as extensive road and bridge construction, were completed in early 1982. A collective agreement was signed with the International Union of Operating Engineers, Local 115, in June 1981.The first unit train left Line Creek on February 18, 1982 with a load of thermal coal bound for the Ssangyong Corporation in Southern Korea. It was the start of a ten-year contract to supply 350,000 tonnes annually to fire their cement kilns. Additional contracts for 750,000 tonnes will fuel the boilers of Korea Electric Company's San Chon Po and Go-Jeong power stations. Metallurgical coal shipments are scheduled to leave the Roberts Bank port in Vancouver in April 1983.Tracking an introductory presentation given at the 1981 CIM Annual General Meeting in Calgary, this paper highlights the salient developments by which ""The Line Creek Project"" has progressed during the past year to the"" Line Creek Operation"". Line Creek has com e on stream as scheduled and will meet all contractual commitments pertaining to timing, volumes and quality for thermal coal. The first train load left the plant in mid-February, and the first boat load to Korea departed Roberts Bank in mid-April. Metallurgical coal deliveries will commence in April 1983."

Jan 1, 1982

By Donald A. Cranstone

"This paper provides a bird's eye view of the pattern of gold discoveries since 1823, the year of Canada's first gold find, up to 1983. Within this 160-year period, more gold was discovered in Canada during the last ten-year period (1973-1982) than during any previous decade. The record suggests that the potential for further major gold discoveries is high, which bodes welt f or the future of Canadian gold mining.IntroductionCanada has an impressive history as a gold producer. Since 1921 we have occupied second or third place among the world 's gold producing nations, after South Africa and most of the time the U.S.S.R. Canadian gold production over the last hundred years has added up to some 6 per cent of all-time world production.The sharp rise in the price of gold in the 1970s led to a surge of gold exploration, which in turn resulted in the discovery of significant quantities of gold in Canada. How do these recent discoveries rate in comparison with those of the more distant past? For example, are the quantities of gold in notable discoveries of recent year s, such as Hemlo and Detour, in the same league with the amounts of gold discovered around 1910 in the Porcupine and Kirkland Lake district s of Ontario? Can the combined gold content of the recent discoveries be likened to that o f the almost 40 major Canadian gold deposits, along with numerous smaller ones, discovered in Canada during the 1920s and 1930s? What are the implications of the more recent gold discovery record for future rate s of gold discovery in Canada?This paper attempts to glean answers to such questions from an overview of the period that begins in 1823, the year of Canada's first gold discovery. Gold deposits come in two major types: placer deposits and lode deposits in solid rock . Placer gold is distributed in sand and gravel. Gold in solid rock occur s mostly in gold ore filling fissures."

Jan 1, 1985

By Eirik Sundvor, Hany Doss, Peter Vogt, Kathleen Crane

"Abstract - In 1989-1990, the SeaMARC II side-looking sonar (11 to 12 kHz) and swath bathymetric system imaged more than 80 000 km2 of the seafloor in the Norwegian-Greenland Sea and southern Arctic Ocean. One of our main goals was to investigate the highly oblique (115°) junction between the Mohns and Knipovich ridges, and to determine, using new morphotectonic data, whether or not this junction is stable or in a state of readjustment. These findings are presented in this paper.Along the northern Mohns Ridge, we observed a highly segmented rift valley undisturbed by transform faults. In contrast to the elevated Reykjanes Ridge, the Mohns Ridge is dominated by deep en echelon fault-bounded troughs, which are bordered by high rift valley volcanoes. These segment boundaries are interpreted to be sites of recent to present volcanic activity, based on their high acoustic reflectivity. The northwestern flank of the Mohns Ridge is marked by shallow quasi-linear ridges parallel to the present orientation of the Mohns Ridge. The orientation and geographic position of these ridges suggest that they were formed at the Mohns Ridge. Only in the northernmost cases are some of these off-axial ridges non-linear. The degree of the non-linearities increases slightly with proximity to the Mohns-Knipovich bend. In addition, because no transform fault was detected between the Mohns and Knipovich ridges, we conclude that the Knipovich Ridge must be obliquely spreading to the NW-SE."

Jan 1, 1999

"Sedimented hydrothermal precipitates of silica, now fine-grained quartz, are described from a Pb-Zn-bearing vein system. Their discrimination from the wall-accreted fine-grained quartz that is common in the shallow parts of epithermal systems is discussed. Local fine-grained (<0.3 mm) quartz accumulations occur in a suite of veins with otherwise normal drusiform and crustified infills. This sediment may fill the vein above chokes in steep segments (axial plugs), or form continuous layers within the footwall material where the vein is inclined at low to moderate angles. Pads of fine-grained sediment are deposited on the upwards-facing surfaces of wall-rock clasts and of drusiform crystals growing from the vein walls. The asymmetry of these deposits differentiates them from the more common symmetrical, crustified walllining deposits of fine-grained quartz and opaline silica, and requires a gravity-controlled, sedimentary depositional mechanism.Thin section examination shows that much of the fine-grained quartz is present as elongate prisms. The prism habit was present soon after deposition, but it is not possible to identify unequivocally the original sedimented grains. Sedimentation of vein- and wall-rock-derived detritus is also recognized. Deposition of the fine-grained sediment accompanies normal in situ drusiform growth of quartz and other vein minerals. The mammilated and spherulitic textures associated with accretion of amorphous quartz are entirely absent from the Tyndrum veins with sedimented materials. The literature on modern hydrothermal waters and physical chemistry of silica precipitation shows that precipitates of silica suspended in hydrothermal fluids are amorphous and derived from colloidal silica. It is argued that much of the suspended silica was present as quartz at the time of deposition or was converted from amorphous silica almost immediately after deposition.Hydrothermal sediments and their distribution potentially provide information on flow directions and velocity in veins. Plugs of sediment obstruct vertical flow and lead to local flows with large horizontal components. It is shown that sedimentation features occur in other deposits and can involve other minerals. If the features seen here can be scaled up to the size of major veins, they may result in up and downdip variations in mineral assemblages and abundances, which may affect grade."

Jan 1, 2007

By W. H. MacLean, S. Liaghat

The Key Tuffite is a thick (0.3 m to 6 m) and laterally extensive (-10 km) cherty, sulfide-bearing tuff unit in Archean greenstones in the Matagami mining district in northwestern Quebec. It lies at the contact of the Watson Lake Group and overlying Wabassee Group volcanic rocks, and is host to major Zn-Cu volcanogenic massive sulfide deposits. The tuff component is highly altered and its volcanic precursors are not identifiable by petrographic means. The tuff is mixed with a volcanic exhalative component comprising chert, carbonate and sulfides (pyrite, pyrrhotite, and minor sphalerite and chalcopyrite). The normative mineral composition of the Key Tuffite is 33% quartz, 28% sulfides, 16% sericite, 8070 carbonate, 6% chlorite and 9% other minerals. In the vicinity of the Bell Allard and Orchan mines, the precursor tuff components are identified using immobile major and trace elements, as Watson Lake tholeiitic rhyolite (Zr/Y = 1.5 to 3.5, LaN/ybN = 1.7 to 2.8, SiO2 = 72.5 ± 1.2 wt %, and Wabassee calc-alkaline andesite (Zr/Y = 9, LaN/YbN= 4 to 8, SiO2 = 56% to 65%). Immobile element computation techniques were used to calculate mass additions and losses in the conversion of the tuff to the Key Tuffite. Average net amounts of FeP3 (27% total iron), Si02 (14%), Cao (8%), S and K2 (+ 2%), were added, Nap was removed (-2.8%), and MgO was over-all unchanged. Total net mass change was +63%, which comprises mainly exhalative additions, but also includes changes owing to hydrothermal alteration of the tuff component.

Jan 1, 1992

By Helen Shang, Jianjun He

In nickel and copper production, sulfur dioxide (SO2) is generated during mineral smelting. Emission of sulfur dioxide into the atmosphere causes serious health and environment issues. Sulfuric acid plants, which convert the harmful SO2 gas to commercially useful sulfuric acid product, ensures safe and environmentally sound smelter operations. The sulfuric acid plant is mainly composed of a SO2 to SO3 converter, a series of heat exchangers and SO3 absorption towers. The SO2 converter is crucial for minimizing SO2 emission in a smelter. In this paper, steady state and dynamic modelling are carried out for the converter using mole and energy conservations. Simulations are performed to investigate the effect of feed conditions on SO2 conversion. The developed model represents an important component for modelling the acid plant in a smelter and is expected to provide a fundamental tool for the future optimization and control development.

Jan 1, 2014

By Catharine E. G. Farrow, David H. Watkinson

The Ni-rich Epidote Zone of the Fraser Mine at Sudbury is characterized by alteration assemblages rich in epidote, actinolite and magnetite which are roughly concentrically zoned and up to hundreds of meters in length. These zones form discrete areas within the igneous Footwall Breccia below the Sudbury Igneous Complex. The assemblages grade from epidotized Footwall Breccia matrix,through actinolite-bearing rocks with few vestiges of original Footwall Breccia textures, into the most intensely altered rock, a magnetite-rich facies. Pentlandite, pyrrhotite and pyrite are the dominant sulfdeminerals; chalcopyrite is minor. The strongest geochemical differences compared to original Footwall Breccia occur where epidote and actinolite dominate the alteration assemblage (EPDZact facies). The most intense alteration facies are typifed by low Cu/(Cu+Ni) values of <0.1. Strong positive correlations exist between Ni and Co, Cu and Au, and among Ir, Os, Ru and Rh. Chondrite-normalized Ni - PGE -Au - Cu plots display an overall increase in all elements from the least to the most intensely altered facies except for Au and Cu. As the proportion of actinolite increases in the EPDZact facies, the chondrite-normalized profles fatten considerably due to low Au and Cu contents. Abundances of Ni, Ir, Ru and Rhalmost ubiquitously increase with degree of alteration. In contrast, Cu, Zn, Ag and Au contents are low in almost all facies. It is suggested that saline hydrothermal fluids moved through the Epidote Zone formation and became more oxidized as they reacted with the Footwall Breccia and with footwall units, including ultramafic rocks. As this trend continued, magnetite-rich zones eventually developed. The occurrence of calcite locally in these magnetite-rich zones suggests that the pH of the fluid increased, causing Cu solubility to drop as activity in the hydrothermal system waned. Sudden changes in fluid composition such as this may have been due to an influx of fluid from bounding ultramafic rocks. Hydrothermal activity was focused along the margins of footwall ultramafic units. Individual hydrother-mal cells may have formed in the Footwall Breccia along pre-existing structures or sulfde concentrations. Metals may have been scavenged from sulfide-bearing Footwall Breccia and possibly Sublayer rocks. Nickel and some PGE were deposited in the Epidote Zone, whereas Cu, Au and Ag continued out-ward into the footwall where they were deposited as Cu-rich footwall veins. Copyright © 1996 Canadian Institute of Mining, Metallurgy and Petroleum.

Jan 1, 1996

By Catharine E. G. Farrow, David H. Watkinson

Abstract-The Ni-rich Epidote Zone of the Fraser Mine at Sudbury is characterized by alteration assemblages rich in epidote, actinolite and magnetite which are roughly concentrically zoned and up to hundreds of meters in length. These zones form discrete areas within the igneous Footwall Breccia below the Sudbury Igneous Complex. The assemblages grade from epidotized Footwall Breccia matrix, through actinolite-bearing rocks with few vestiges of original Footwall Breccia textures, into the most intensely altered rock, a magnetite-rich facies. Pentlandite, pyrrhotite and pyrite are the dominant sulfide minerals; chalcopyrite is minor. The strongest geochemical differences compared to original Footwall Breccia occur where epidote and actinolite dominate the alteration assemblage (EPDZact facies). The most intense alteration facies are typified by low Cu/(Cu+Ni) values of <0.1. Strong positive correlations exist between Ni and Co, Cu and Au, and among Ir, Os, Ru and Rh. Chondrite-normalized Ni - PGE - Au - Cu plots display an overall increase in all elements from the least to the most intensely altered facies except for Au and Cu. As the proportion of actinolite increases in the EPDZact facies, the chondrite-normalized profiles flatten considerably due to low Au and Cu contents. Abundances of Ni, Ir, Ru and Rh almost ubiquitously increase with degree of alteration. In contrast, Cu, Zn, Ag and Au contents are low in almost all facies. It is suggested that saline hydrothermal fluids moved through the Epidote Zone formation and became more oxidized as they reacted with the Footwall Breccia and with footwall units, including ultramafic rocks. As this trend continued, magnetite-rich zones eventually developed. The occurrence of calcite locally in these magnetite-rich zones suggests that the pH of the fluid increased, causing Cu solubility to drop as activity in the hydrothermal system waned. Sudden changes in fluid composition such as this may have been due to an influx of fluid from bounding ultramafic rocks. Hydrothermal activity was focused along the margins of footwall ultramafic units. Individual hydrothermal cells may have formed in the Footwall Breccia along pre-existing structures or sulfide concentrations. Metals may have been scavenged from sulfide-bearing Footwall Breccia and possibly Sublayer rocks. Nickel and some PGE were deposited in the Epidote Zone, whereas Cu, Au and Ag continued outward into the footwall where they were deposited as Cu-rich footwall veins.

Jan 1, 1996