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By R. Clarkson

"Free gold particles occur in many base metal and precious metal mines throughout the world. Due to the high density and malleability of gold, large circulating loads of free gold particles can build up over time in grinding circuits. This gold is often deposited in unintended traps throughout the mineral processing system.These unidentified free gold deposits represent a serious security risk as well as an inaccessible inventory of gold. Deposits of free gold particles often remain undetected by mine management until they are accidentally discovered while repairing mill equipment.Nuclear tracers have been used to determine the free gold recovery efficiency of gravity recovery equipment, drills, and sampling equipment (Clarkson, 1994, 1995; Walsh and Rao, 1986; Walsh and Kelly, 1992). In November, 1993, the author inspected the grinding circuit at La Mine Doyon in Rouyn-Noranda, Quebec and made recommendations to recover coarse gold and to eliminate gold traps from the circuit. In 1995, the author salted mineral processing circuits with radioactive gold particles. The gamma and X-ray radiation from gold’s nuclear isotope (Au198) were detected through steel, in pipes, and in moving equipment using scintillometers. The radiotracers proved to be a safe, rapid and accurate method of identifying gold traps and improving security.Nuclear TracersWhen particles of gold are placed in a nuclear reactor, some of the gold atoms (Au197) absorb another neutron in their nucleus to form gold’s radioactive isotope (Au198). In the process of radioactive decay, this isotope emits high energy gamma rays and X-rays which are easily detected (even through steel) with scintillometers.Radioactive gold (Au198) has a very short halflife of 2.7 days. At the relatively low activity levels used for tracing, the particles remain detectable with a small hand-held scintillometer for about 10 to 14 days. After 14 days the irradiated gold is close to background levels and within two months it is essentially non-radioactive. The radiation has no effect on the recovery characteristics of the gold particles. The gold radiotracers are very safe due to their very low level of radiation, short half-life, and their inherent physical and chemical stability. However, the use and possession of even mildly irradiated gold is strictly licensed and regulated."

Jan 1, 1997

By W. J. Weymark

"The Gregg River project is located 40 kilometres southwest of Hinton, Alberta, adjacent to and east of Jasper National Park. This metallurgical coal mine has been developed as a joint venture between Gregg River Coal Ltd. (a subsidiary company of Mana/ta Coal Ltd.) and seven Japanese companies. This 200-million dollar project consists of a conventional truckshovel open-pit operation and a coal preparation plant rated at 2.14 million tonnes of clean coal per year. Mining operations started in October 1982 with plant start-up following in April 1983. Introduction This paper is an overview and update of the Gregg River project, a metallurgical coal mine being developed as a joint venture between Gregg River Coal Ltd. (a subsidiary of Manalta Coal Ltd.) and seven Japanese companies. The Gregg River Coal leases cover 3440 hectares and are located 40 kilometres south of Hinton, Alberta, adjacent to and north of Cardinal River Coal Mine (Fig. 1). This 200-million dollar project consists of a conventional truck-shovel operation and a coal preparation plant rated at 2.14 million tonnes of clean coal per year. A total of 31.5 million tonnes of clean metallurgical coal will be sold to the Japanese over a fifteen-year term. At present, mining operations are ahead of schedule and the plant started up on schedule in April 1983. Access and Climate An all-weather road, Highway 40, connects the minesite with Hinton (the nearest commercial centre) and a Canadian National Railway (C.N.R.) spur line connects the minesite with the C.N.R. main line in Edson. Hinton is accessible by road chartered airline and rail. ' ~h~ rug~ed and varied topography in the area creates large vanations m temperature and precipitation over short distances. The region is characterized by precipitation throughout the year long cold winters and short cool summers. The mean temperatur~ of the area range from a low of -14°C in January, the coldest month, to a high of 12°C in July, the warmest month. Long-term precipitation data indicates a mean yearly precipitation of 870 mm of which 620Jo occurs during the summer months."

Jan 1, 1985

By D. R. Murray

A four-year study was carried out to determine the ability of coniferous trees to aid in the reclamation of uranium tailings at Elliot Lake. Five species were planted: white cedar, white spruce, jack pine, scotch pine and red pine. More than 570 bare-root, two-year-old seedlings were planted on bare tailings and in areas of established grasses. A further division was made between areas of coarse and fine tailings. Over-all survival and growth of the trees has been far below expectations based on previous experience with several varieties of grasses. The criteria for assessment have been per cent survival and yearly growth as determined by plant height. Pine was superior, with 68% survival when planted in bare coarse tailings, 45% for vegetated coarse tailings and 34% for vegetated fine tailings. Cedar had the worst survival rates at 49%, 14% and 7% respectively. No species survived on bare fine tailings. The survival and growth of the coniferous trees have been related to species, environmental conditions and tailings properties.

Jan 1, 1978

By L. Lafrenière

A trend in mining exploration is to increase the number of geophysical parameters collected and interpreted for geological features in a given area. Airborne technology now allows us to simultaneously combine electromagnetic, gravity, aeromagnetic and radiometric surveys. We report the results of a multiparameter survey conducted in the area of Kamiskotia, Ontario. This area is located near and on the West side of the multi-metalliferous Kidd Creek deposit. Various metallic occurrences are reported in the studied area. Integrating multiple parameters in the interpretation produces a more detailed pseudogeological map than what has already been published. 3D interpretation has been undertaken using some of these parameters and suggests that future work is required in 3D earth model solutions in order to fully use all parameters.

Aug 1, 2013

By W. L. Brown

"The properties of Base Metal Mining Corporation are in Yoho Park about 2 1/2 miles northeast of Field; British Columbia; on the main line of the Canadian Pacific railway. There are actually two mines; the Monarch on mount Stephen and the Kicking Horse on mount Field; separated by the steep valley of Kicking Horse river. The outcrops of the orebodies range from 4; 900 feet to 5; 300 feet above sea-level. The concentrator is situated below the Monarch mine and is connected to the main portal by an aerial tramway. The ore from the Kicking Horse mine is conveyed by aerial tramway to a storage bin on the main highway and is then trucked to the concentrator.During the construction of the Canadian Pacific railway through Kicking Horse valley, galena float was found at the base of mount Stephen. The East Monarch outcrop was staked in 1894. The outcrop of the West Monarch ore body on the cliff face of mount Stephen was not discovered until 1916. The Kicking Horse orebodies on mount Field were discovered a few years later. In 1912, a 75-ton concentrator was erected, which operated at intervals until 1924. During this period approximately 42,000 tons were mined and milled, largely from the East Monarch orebody. In 1928, the Base Metal Mining Corporation, Limited, was formed to take over the Monarch and Kicking Horse mines. A 300-ton differential flotation concentrator was erected and production started in the autumn of 1929. In a very short time, however, the low price of metals forced the mill to shut down until August 1933. From 1929 to 1935, when the mill again ceased operation, a total of 256,500 dry tons of ore, averaging 1.59 oz. silver per ton, 9.7 per cent lead, and 12.6 per cent zinc, was mined and milled, largely from the West Monarch orebody. After a period of further underground development, the concentrator reopened in 1940 and is still in operation. From 1940 to the end of 1944, 354,363 tons of ore was milled, averaging 5.32 per cent lead and 10.47 per cent zinc."

Jan 1, 1954

By E. Dernedde

A few studies have suggested that the rate of adsorption of hydrogen fluoride on smelter grade alumina is determined by kinetic factors. However, no performance equation for dry scrubbers has appeared in the literature so far. Experimental data from a pilot dry scrubber with co-current flow were compared with results of kinetic models of adsorption, film diffusion and pore diffusion. The pore diffusion model was deemed the most appropriate. It was transformed into a performance equation for steady-state operations of dry scrubbers by the inclusion of the alumina recirculation. Operating results of industrial dry scrubbers with co-current flow were successfully evaluated by means of the performance equation. The average fluoride content of the alumina was also estimated by using the pore diffusion model.

Jan 1, 2011

By S. F. Guo, B. W. Zheng, X. L. Huang, S. W. Qi

"The study of mechanical characteristics of rock discontinuities under different shear deformation velocities is an important premise of rock slope dynamic response analysis. According to disposing and calculating the experimental results of previous research about peak shear strength of rock discontinuities under different shear deformation velocity of constant normal loading, the law of influence of shear velocity on the total friction angle is studied. Based on the research results, it can be found that the total friction angle of rock joint specimens varies in the form of negative logarithm with the variation of shear deformation velocity. It’s also indicated that the total friction angle of rock joints decreases with the increase of shear deformation velocity for rock joints of relative strong homogeneity and isotropy. However, the total friction angle of rock joints increases with the increase of shear deformation velocity for rock joints of relative strong heterogeneity and anisotropy and the latter amplitude of increase is less than the former amplitude of decrease. The physical property and microscopic geometry of rock joints play an important effect on the increase or decrease tendency and amplitude variation of total friction angle with the increase of shear deformation velocity.INTRODUCTIONThe rock slope dynamic response is largely restricted by rock discontinuities. Hence the study of dynamic characteristics of rock discontinuities, especially the dynamic shear characteristics is an important premise of rock slope dynamic response analysis (Qi et al., 2007). Seismic load is both dynamic load and cyclic load (Liu et al., 2011). Under the dynamic and cyclic shearing actions of seismic load, the rock slope which is stable under the condition of static load may slide along the rock discontinuities whose shear strength reduce and then the earthquake landslides occur. The strength degradation and deformation mechanism of rock discontinuities under the dynamic and cyclic shearing actions is one of the key problems to be solved in the work of earthquake prevention and control of engineering slope. Based on the above understanding, predecessors conduct some researches which focus on the shear behavior mechanical characteristics of rock joints under cyclic shearing actions (Plesha, 1987; Hutson & Dowding, 1990; Jing et al., 1992, 1993; Huang et al., 1993; Qiu et al., 1993; Homand et al., 2001; Lee et al., 2001; Jafari et al., 2003; Liu et al., 2011, 2013). However, there are a few researches about the mechanical characteristics of rock joints under different shear deformation velocities because of the restriction of shear apparatus. Crawford and Curran (1981) conducted a series of one-way cyclic direct shear tests on four kinds of natural rock joints under different shear deformation velocities varying from 0 to 200 mm/s. The tests showed that at low normal stresses the peak shear strength of soft rock joints exhibited an increase up to a certain velocity, after which it remained essentially constant. For rock joints of intermediate hardness, the peak shear strength was essentially independent of shear deformation velocity; whereas for hard rock joints, the peak shear strength of which showed a significant variation with the shear deformation velocity. Jafari et al. (2003) carried out a series of conventional triaxial tests on artificial rock joints of regular saw-tooth shape with axial loading rate from 0.05 mm/s to 0.4 mm/s."

Jan 1, 2015

By D. Purdie

"This paper aims to remind researchers, designers, operators, and managers about the benefits of seeding in the design of precipitation stages in their flowsheet. Including a high density solids (HDS™) process encourages the precipitating solids to form on the surface of existing precipitated particles. This paper discusses the application of the HDS technology at Kennecott Smelter, where the authors have witnessed significant improvements in settling and filtration rates. The authors have also applied this technology at various smelter bleed treatment plants worldwide with similar improvements in precipitation and filtration rates. HDS is a registered trademark of De Nora Water Technologies. RÉSUMÉ Cet article a pour objectif de rappeler aux chercheurs, aux concepteurs, aux exploitants et aux administrateurs les avantages de l’ensemencement dans la conception des étapes de précipitation de leur schéma de traitement. L’introduction d’un procédé des boues haute densité (procédé HDS™, de l’anglais high density sludge) encourage la formation de substances solides précipitantes à la surface des particules précipitées existantes. Cet article porte sur l’application de la technologie HDS à la fonderie Kennecott, où les auteurs ont observé des améliorations importantes au niveau de la vitesse de sédimentation et de filtration. Ils ont également appliqué cette technologie à diverses usines de traitement des rejets liquides des fonderies dans le monde entier, et ont constaté des améliorations similaires en termes de vitesse de précipitation et de filtration. Le procédé HDS est une marque de commerce déposée du fabricant De Nora Water Technologies.INTRODUCTION In 1966, the lead author worked as an assistant smelting metallurgist for the Tsumeb Corporation Limited copper and lead smelter in Tsumeb, Namibia. The smelter produced copper and lead, as well as cadmium and arsenic trioxide as byproducts. The cadmium was concentrated in the lead blast furnace off gas dust, and was collected by a baghouse. The baghouse dust was leached with dilute sulfuric acid (H2SO4) in a batch process. The iron and arsenic in the solution were oxidized with potassium permanganate (KMnO4) and basic ferric arsenate (BFAS; Fe(AsO4)x(SO4)y(OH)z·wH2O) was precipitated using milk of lime. The cadmium was cemented from the purified solution using zinc dust."

Jan 1, 2018

By A. H. Lang

THE recent production of important quantities of high-grade muscovite at the Purdy mine, near Eau Claire, Ontario, bas brought that district into prominence and bas added another strategic mineral to the list of Canadian products. The discoveries are thirteen miles west of Mattawa and about two miles north of the Trans-Canada highway and the Canadian Pacific railway. HISTORY Clear mica of low power factor is in considerable demand in Canada and in the United States for war purposes such as radio and telephone condensers, aircraft spark-plugs, radio tubes, and transformers. Some muscovite (white mica) bas been produced in North Carolina and New Hampshire, but the United States trade bas depended largely on importations of muscovite from India and of phlogopite (amber mica) from Madagascar. For many years Canada bas been a substantial producer of phlogopite, but was unable to compete extensively in the United States with importations from abroad. Canadian production of muscovite bas been negligible as no important deposits were known. Ever since the construction of the Canadian Pacific railway, attempts have been made from time to time to mine the pegmatite dykes in and near the Eau Claire area, but, although some feldspar has been mined, no appreciable muscovite was produced. Lace in 1941, J. Purdy and H. MacDonald discovered a dyke containing large crystals of high-grade muscovite from which they are reported to have sold $700 worth of mica. They recorded claims 35974 and 35975 in December, 1941, and claim 36095 in May, 1942.

Jan 1, 1943

By Louis Frost

The coal-mining industry of Nova Scotia, particularly of the island of Cape Breton, today faced as no other industry with economic problems calling for progressive engineering with production on an economic basis, must soon enter upon a phase of reorganization wherein all factors conducive to the cost of producing coal relative to the prolongation of the life of the collieries with the ultimate winning of the maximum submarine area must be closely reviewed. Bearing this in mind and applying the process of elimination to coal-mining costs generally, we are left with only three channels through which we may approach the problem of cost reduction in producing coal: (a) intensive mechanization (b) reduction in the cost of labour (c) reduction in the cost of materials. Assuming that mechanization has reached an economic stage and that labour costs have reached an economic limit, we must turn our attention to the general material costs, which may be classified as 'live' and 'dead' costs. The former take in all things which can be accredited with a fractional depreciation and written off the balance sheet over a period of years. On the other hand, the ?dead'costs-of which the cost of supporting the underground workings form part must be completely written off: for these, no return may be expected, other than the economic return in the reduction of the cost per ton of coal produced.

Jan 1, 1928

By R. P. Zahn

The need for quantitative mineralogical data to characterize ore types before they are processed is becoming increasingly necessary. Mineralogical data (modal abundances, grain size, liberation/locking characteristics, mineral textures and associations) can provide invaluable information to facilitate the identification of metallurgical issues that may arise during processing of a particular ore. This paper will discuss the use of QEMSCAN analysis in conjunction with bench scale flotation test work to determine metallurgical characteristics for several ore types that will be fed to the Morenci concentrator upon commencement.

Jan 1, 2007

By Kenneth Blower

This paper gives a detailed coverage of the ore flow through the primary crusher, cobbing plant and concentrator, including equipment sizes, recoveries, reagent consumptions and product descriptions. Special features, such as rubber chutes, rubber-lined mills, pebble-mill grinding, steam-hooded filters and process control instrumentation, are also discussed.

Jan 1, 1968

By A. Sutherland Brown, Stuart S. Holfand

"The Northeastern part of the Cariboo district lies in the big bend of the Fraser River between Quesnel and McBride. The area shown on Figure 1 extends from just west of Wells to Isaac Lake, about 30 miles across the regional strike of beds.Topographically the area extends from the moderately well dissected Interior Plateau in the west through a transition zone to the fully dissected Cariboo Mountains in the east.The area is an important source of lode and placer gold. The Cariboo Gold Quartz and Island Mountain lode-gold mines have produced more than 32 million dollars in bullion since 1932. Placer-mining has probably produced an equivalent or greater amount, although only 15 million dollars is officially recorded because accurate statistics. were not kept until fourteen years after the origiiaal gold rush of 1860.The regional structure of the Barkerville district was summarized by Lang in the Jubilee Volume (1948, pp. 141-149). Since then a large amount of detailed and areal mapping by the writers has expanded the information available and made necessary a complete revision of the regional geology. Much of the information summarized in this paper, together with a full discussion of the revisions, may be found in British Columbia Department of Mines Bulletins, Nos. 34 and 38, but other information is as yet un-published.Rocks of the Kaza group are exposed in the core of the Lanezi anti-clinorium between Spectacle and Isaac Lakes. The main part of the group is composed of greenish micaceous greywacke and greenish schist with knots of garnet, biotite, or both, and minor amounts of pebble conglomerate. The upper 1,000 feet is composed of white to brown quartzites and brown phyllites. Altogether, about 6,000 feet of the group is exposed. 1t is of latest Precambrian, i. e. Windermere, age."

Jan 1, 1949

By T. W. Wlodek

"AbstractIn this paper a new type of durable 'spiral-rolled' drill set is introduced and its performance discussed. Efficient and economical mine drilling-depends to a great extent on durability of the drill-set employed. Premature failure of this element damages the drill bit and is costly when tungsten carbide bits are used.Time of drilling of 'spiral-rolled' drill sets introduced at present in Canada is considerably larger than for the presently used drill steel, but laboratory simulated service tests and practical field tests show that the 'drilling life' of the spiral-rolled drill set is several times that of ordinary drill steel.Some features of differential plastic deformation and differential surface rolling, so called 'spiral-rolling', are given.Relations between the drilling machine drill set and characteristics of the ore are discussed. The effect of shims on conical drill rod attachments, the mechanism of failure of drill steel, .and stresses during mine drilling, are analysed.IntroductionIN MINE DRILLING operations, the main interests are: the drilling machines as a source of working energy, the drill set as the tool transferring the working energy to the cutting edges of the bit, and, finally, the drilling characteristic of the .ore or waste rock.This paper includes a review of the possibilities of metallurgical and mechanical improvements in the drill set, with particular attention to drill steel and the attachments.For economical and efficient mine drilling operations, a durable drill rod, attachment, and drill bit are essential. Premature failure of any of these parts interferes with mining operations and is costly."

Jan 1, 1955

By Philippe Henry

HYDROMETAL is using suitable technology to reintroduce lost metal units into the industrial cycle, thereby saving resources and energy while keeping the environment cleaner. Hydrometal is treating on average 60000 t per year of complex materials through a unique hydrometallurgical recycling concept. Zn, Cu, Sn, and Pb are the most important in volume, but in the last 15 years, Hydrometal has also developed a few specific recycling treatments for the minor metals including Ge, In, Co, etc. In 2010, Hydrometal commenced the recycling of RE (Rare Earths) from wastes generated by the RE refining industry in Europe and has decided to initiate new recycling projects for the RE recovery from the magnet or glass industries. Two case studies of recycling of materials in our integrated hydrometallurgical facility (Hydrométal) in Belgium are discussed: recycling of cerium from polishing sludges; and recycling of Ni- Co from cement produced in the zinc industry.

Jan 1, 2014

By L. H. Smith, D. S. Taylor

"AbstractSherritt has been applying hydraulic drives to concentrator equipment since 1967. The initial application was made on a bank of 5- by 5-in. slurry pumps. This has now been extended to all slurry pumps requiring less than 40 hp and several conveyors which require variable-speed or low-speed/high-torque characteristics. The pump motors are directly connected through a flexible coupling, whereas the conveyor systems are directly mounted onto the head-pulley shaft extension.The different applications and design concepts will be described, with outlines of the operating and maintenance advantages and disadvantages and costs. The paper also outlines future possible applications, together with the limiting conditions, of such systems.IntroductionSHERRITT GORDON MINES LIMITED has been operating a mining division in Northern Manitoba for almost 50 years. The original mining operation was at Sherridon, Manitoba and was a copper-zinc producer. This mine was exhausted in 1948 and the mining plant was moved north to its present location at Lynn Lake, Manitoba. The Lynn Lake Mine is a nickel-copper producer. Since 1960, two new mines have been discovered and brought into production in the general vicinity of Lynn Lake. The first of these was the Fox Mine, a copper-zinc property operating at 3,000 tons per day from an underground operation. This mine started production in May 1970."

Jan 1, 1977

By J. E. Dutrizac

Mercury balances have been obtained for the flotation circuits at Pamour Porcupine Mines, Timmins, Ontario, and at Brunswick Mining and Smelting Corporation, Bathurst, New Brunswick. The mineral form of mercury in both deposits has been ascertained. At Pamour Porcupine, the mercury is approximately evenly divided among sphalerite, native silverelectrum and tetrahedrite-tennantite; at Brunswick Mining, this element is contained mostly in the sphalerite, although tetrahedrite (and possibly pyrite) also contains minor quantities.

Jan 1, 1979

By W. S. Tremaine

When the Hedley Mascot mill was built in 1935, it was designed as a straight flotation plant. The ore to be treated at that time was a gold ore in which the gold was intimately associated with arsenopyrite and pyrrhotite in highly silicified and garnetized limestone gangue. This material was ground to 85 per cent minus 325 mesh in two-stage grinding and floated in standard flotation cells to produce about a 5-ounce concentrate, which was shipped to Tacoma smelter for refining. This arrangement gave us a recovery of about 89 per cent. Test work indicated that the best way to improve this recovery would be to build a cyanide plant to treat our flotation middling. Arrangements for the construction of this plant were finally approved and work on it was started in the spring of 1940. This plant was of the conventional type in which the flotation middlings were thickened, filtered, and then put through the usual cyanide process. Its capacity was 50 tons of middlings per day. This arrangement worked quite satisfactorily and gave us an increase in overall recovery of 4 per cent. Unfortunately, about the time the plant was completed, we developed, and started to ship to the mill, ore that differed entirely from that met with up to that time. Instead of being hard, it was very soft, the orebody from which- it came being much faulted and brecciated. In many sections, the sulphides were oxidized and the breccia was filled in with a very soft, hydrous iron silicate known as chloropal. When this new ore was mixed with the old ore and sent to the mill, the whole operation was disrupted. The chloropal slimed so badly that the classification, flotation circuits, and cyanide plant would not handle it. The difficulty in the cyanide plant was at the head end, where the 10 ft. by 20 ft. thickener and the 8 ft. by 8ft. drum filter would not handle the middlings containing a large percentage of primary slime and chloropal. This material would not thicken to more than 30 per cent solids in the thickener and, when pumped to the filter, would forma very thin, slimy cake. Overall recovery dropped to between 83 and 84 percent and it was quite apparent that some extensive changes would have to be made in our flow-sheet before this ore could be treated successfully.

Jan 1, 1947

By R. Burnette

Gold has been mined from a variety of deposit types that range in age from Archaean to Recent. The large variability in the geological settings of the gold deposits implies transport and concentration of gold by magnetic, hydrothermal and sedimentary processes. The factors that control the concentration of gold at certain sites and the grade estimation thereof remain major topics of debate. Due to the complex nature of the Witwatersrand Basin a mineralogical study, including mineralogical, petrographic and geochemical investigation was launched on TauTona Mine in order to characterize the various reef facies. The aim of the investigation was to determine if a correlation could be found between macroscopic characteristics of the reef, hanging wall and footwall, and the microscopic nature of the ore (especially gold grade). Petrograpgic and mineralogical results indicate that a correlation exist between gold, detrital and hydrothermal sulphides, uraninite, carbon, detrital heavyminerals and phyllosilicates. No correlation exist between gold and Mg, Fe or S. It appears that clast supported reef is of higher wade than matrix supported, but more work is suggested. No correlation exists between reef thickness and grade. The reef samples had the lowest phyllosilicate content compared to the hanging wall and footwall samples with pyrophyllite the most dominant. All of the correlations diagrams showed significant scatter and suggests a multi- factorial mineralization model. Gold distribution is also controlled by sedimentary features and thus it is not possible to select a single model for the formation and distribution of gold. It is evident that both sedimentary and hydrothermal factors influenced the mineralization and gold distribution on TauTona mine. It is thus essential that all related theories be incorporated in the development of a grade prediction model.

Jan 1, 2011

By B. K. Mishra, P. Patnaik, B. C. Tripathy, I. N. Bhattacharya

Cobalt is an essential metal considering its numerous industrial applications. The demand for the metal is increasing due to its wide range of use in, for example, rechargeable batteries and as an alloying element in super alloys. Cost effective production of Co is critical. Electrowinning from aqueous sulphate solutions is the preferred technology available for the production of Co. Attempts are being made to produce uniform, smooth and bright deposits of cobalt metal. Use of organic additives in the electrolytic bath improves current efficiency and deposit morphology of the metal. We investigated the effect of quaternary amines TEABr, TPABr and TBABr during cobalt electrowinning from aqueous sulphate solutions. Among the additives studied, TEABr yielded the best results. Smooth and bright deposits of cobalt were obtained at low concentration of TEABr (10 mg/L) maintaining a very high current efficiency of 99.6%. X-ray crystallography indicated that (100) is the most preferred plane of crystal growth.

Jan 1, 2014