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By K. C. Corin, Z. G. Song, J. Y. Liu, M. W. Zhang, State Key Laboratory of Mineral Processing-BGRIMM, J. G. Wiese

"In the present study effect of grinding media on flotation of two mineral systems have been investigated, viz. sulphide minerals (including a pure chalcopyrite and pyrite mineral, and two different base metal sulphide ores), and oxide minerals (quartz, hematite and cassiterite). It was shown that mild steel media milling produced lower recoveries in the case of chalcopyrite and pyrite, as compared to the case of milling using ceramic media. For oxide minerals, the effects of using mild steel media as opposed to ceramic media were not as significant as was for the sulphides, although, after mild steel milling, at acidic pHs their recoveries were significantly reduced. For two base metal sulphide ores, viz. Nkomati and Dexing ores, the differences resulting from different milling media , although marginal, were opposite for each of these ores.For oxide minerals XPS showed that oxides and hydroxides of iron (e.g. FeOOH) adsorbed on the surfaces of the minerals. In the case of the Nkomati ore, adding Fe2+ or F3+ ions after milling with chrome steel media resulted in reduced talc (gangue) recovery, but increased water recovery and reduced concentrate grades. Further investigations are currently in progress to examine the Fe ions effect on the talc surfaces and froth properties.INTRODUCTIONGrinding of ores is necessary to liberate the valuable minerals from its gangues to allow for their selective recovery during mineral processing such as flotation. The grinding process inevitably involves contact of the ores with the surface of the grinding device and the grinding media. Accompanied by grinding, several phenomena can occur including the grinding medium wear, formation of precipitated species on the ore surfaces, chemical reaction, galvanic effects, changes in the Eh of solution, etc. There is a considerable body of literature on the differences observed in the flotation of various ores after milling using various grinding media. Laboratory studies have used balls or rods made from mild steel, ceramic, stainless steel or chrome steel to investigate the effects of different grinding media on mineral flotation. It is found that the interactions between the ore and the grinding environment can affect flotation separation of sulphide (Wei and Sandenbergh, 2007; Bruckard, 2011), oxide (He et al., 2014) and carbonate minerals (Song, 2009 and 2010). For example, mild steel milling produces relatively high concentrations of Fe ions in the pulp, affecting the recoveries of minerals compared to the case of ceramic media. On the other hand, the stainless steel media or chrome media are reported to be beneficial to the recovery of sulphides, when compared to the cases of using mild or carbon steel media (Rey and Formanek, 1960; Peng et al., 2003a,b; Huang and Grano, 2006; Bruckard, 2011). It is not clear, however, whether these Fe ions may affect the surface properties of the minerals involved or the general pulp/froth behaviour and hence their floatability. In addition, in the study of an low-S PGE ore carried out by Miettunen et al. (2012), forged media grinding in the CO2 atmosphere led to the highest Pt and Pd grades and recoveries, but the high chrome grinding media gave lower flotation recoveries than those using the forged media."

Jan 1, 2016

By J. L. Huisman

Bio(hydro)metallurgy is the latest development in the ongoing search for efficient and economic metal winning processes. In addition to bioleaching, other biotechnology-based applications are becoming more and more accepted. In this paper the THIOMET process for general effluent treatment is described. With this process, it is possible to produce sulfide on-site and on-demand and to use the sulfide to precipitate metals, even selectively when required. The process is ideally suited as a treatment to remove metals after, for example, an acid regeneration process. Another process is proposed that deals with stainless steel pickling bleeds. Such effluents typically contain nitrate, iron, nickel, chromium(VI) and other species. This one process handles these compounds, as well as other metals.

Jan 1, 2006

By A. Hayatdavoudi, D. Chitila, F. Boukadi

"Shale oil and gas have provided a tremendous boost to energy production in the United States even though the characteristics and behavior of shale are yet to be fully understood. Hydraulic fracturing is often applied to horizontal shale wells to stimulate production. This experiment seeks to determine effects of cyclic variable temperature, water vapor and exposure time on shale micro fracture propagation. We used 22 small Pierre shale specimens and subjected them to aforementioned conditions. Fractures developed in 19 specimens. Combination of high temperature and high water vapor generated the largest number of micro fractures on the specimen surfaces.INTRODUCTIONShale oil and gas have contributed immensely to energy independence in the United States. Most if not all shales depending on their total organic content (TOC) and their clay content bear the promise of being a source rock. For example, the Eagle Ford shale play, located in south Texas, is one of the key contributors to the recent rise in oil and gas production in the United States. Data from the U.S. Energy Information Administration (EIA), published in 2014, states that monthly oil production from Eagle Ford wells increased from 340 barrels per day (bbl/d) in January 2009 to nearly 1 million bbl/d in June 2013. Natural gas production has also increased at a similar rate over the same period, from 5.8 million cubic feet per day (MMcf/d) to nearly 4,000 MMcf/d (EIA, 2014).According to the railroad commission of Texas (RRC) 2014 published information, the Eagle Ford shale play is an important play because it produces gas and more oil than other shale plays in the United States. It is an organic-rich play with carbonate shale percentage in the 70% range in south Texas and the shale content increases moving to the northwest. High carbonate proportion renders this play brittle and suitable for hydraulic fracturing treatments."

Jan 1, 2015

By P. Hajiani

"Feasible and sustainable separation of lanthanides outside of China has been a dilemma for the past few years. The present technique uses REE electrophoretic mobility (Ui) variation in an electrical field to separate them. The present invention relates to a system and a method to separate and refine rare earth elements/compounds produced in hydrometallurgical processes while they are dissolved in an acidic medium, without any intermediate precipitation step. This process uses free-flow electrophoresis to isolate REE from the concentrate simultaneously without any pre-treatment or intermediate steps related to the nature of elements.INTRODUCTIONRare earth elements (REE) invariably occur together in nature, and any given mineral contains several or most of them. Production of high purity individual rare earth (RE) elements/compounds from their ores generally requires two stages of processing, including mineral processing and hydrometallurgy.Depending on the ore, mineral processing and hydrometallurgy treatment of the ore before REEs purification is relatively simple and quite achievable though conventional methods. However, producing individual REE from mixed REs compounds is tremendously tedious. RE processing often requires dozens of steps, each resulting in minute improvement in the complex RE streams. Separating and extracting a single REE requires a great deal of time, resources, and expertise. Today, advanced RE refinery facilities cost hundreds of millions of dollars to build. The high purity RE concentrates are separated into individual REE using solvent-based or ion exchange methods. Although there are several techniques to separate REEs, most of them suffer from different types of drawbacks. For instance, solvent extraction requires a great number of steps to achieve high purity REEs. The process which uses ion-exchanger for separation and refinery operates with low REE concentration in solution which leads to very large liquid volume quantity, bulky tanks, dehydrators, pumps, etc. The low concentration will adversely affect the water consumption as well as other chemicals. Similar chemical properties of those three valent elements do not allow them to be isolated easily one from one another using conventional separation techniques. Solvent extraction has been successfully applied for rare-earth refining (lanthanide, scandium and yttrium) for the past few decades in China. Since then, efforts have been dedicated to develop other techniques which could be applied industrially around the world."

Jan 1, 2016

By F. Liu, H. A. Meier, D. M. Valiveti, P. A. Gordon

Hydraulic fracture is a frequently used technique in the Oil and Gas industry to create high permeability pathways for extraction of hydrocarbons. Numerical simulation of this method poses challenges such as representation of 3D fractures, propagation of randomly oriented fractures in 3D media, enabling fluid leak-off from fracture to poro-elastic medium. We have developed a numerical model using the Generalized Finite Element Method (GFEM) to simulate fluid driven fracture in a poro-elastic medium that addresses these challenges. In the GFEM framework, special enrichment functions are used to augment the solution space in the displacement and pore-pressure fields in order to accurately capture the response in the vicinity of the fracture. Adaptive refinement of the finite element mesh is also employed to facilitate accurate and efficient solution of the model. Our model fully couples fluid flow in the fracture, represented with the lubrication approximation, to the geo-mechanical behavior of the bulk poroelastic rock, comprised of an elastic rock skeleton saturated with fluid. Fracturing fluid exerts traction on the fracture surface and is also allowed to leak-off into the poroelastic medium using a transfer function approach. Stress intensity factors (SIFs) are evaluated based on the Contour Integral Method, accounting for the fluid pressure on the fracture surface. The SIFs are used to govern a full 3-D evolution of the fracture. Verification of the model is performed for known behaviors for the poroelastic response and fluid flow in the fracture.

Jan 1, 2015

By Jeonghwan Kim

Intelligent Excavation System (IES) has been considered to be one of the desirable solutions to improve the productivity, quality and safety of the current earthwork processes. IES is composed of various hardware and software modules including task planner (work command generator), local and global work environment sensors, GPS and other sensors to acquire the excavator?s status, robotic controller and electronic valves, and the manipulator (excavator). A data communication manager was required to coordinate the signal or data-flow in between these modules considering the operational status of IES such as; excavation start/completion, truck detection, terrain model update, emergency stop, local sensing, GPS/motion sensor data handling, and so on. This paper presents the role and functions of this data communication manager. After every possible operational status of IES operation was identified, a protocol of each communication process in the form of string-type was made. The components of IES are connected with either wired or wireless network. Therefore, they can communicate with the manager using socket (TCP/IP) communication. The data communication manager is also capable of accessing a web-based project management information system, which constantly updates the performance of excavation robot to online database.

Aug 1, 2013

By Laxman M. Amaratunga

Laboratocy flarmnability tests were perfonned on dust samples from Fraser Mine in a 1.2 L Lindenburg horizontal tube furnace to detennine the percentage of sulphur oxidized during ignition. The explosion pot ential of sulphide dusts depends on their degree of spontaneous oxidat ion, which was measured by the quantitative analysis of so2 gas released during ignition. Test results indicated that dusts with low sulphur content could exhibit a higher degree of oxidation than a sample with high sulphur content. txlst characterisation using image analysis techniques suggests that the structure and the texture of dust are important factors influencing the explosibility of sulphide dust at ignition temperatures. Therefore for safe mine operations% sulphur content cannot be considered as a reliable single index that could be used to predict the potential of a sulphide dust explosion. Physical, chemical and mineralogical characterisation of dust plays an important role in the detennination of suitable indices for the prediction and prevention of sulphide ore dust explosions.

May 11, 1988

By Euler De Souza, Kyle Penner

"Booster fans play an important role in assisting main fans by boosting the air pressure of the ventilation air passing through it. The correct placement of underground booster fans in a mine is a critical decision since it not only influences the mine’s operational capacity in terms of costs and efficiency, but also affects safety and environmental conditions. There are many booster fan installations around mines that are inappropriate, in some cases resulting in system failure (fan stall) or in a major negative impact on mine production. Inadequate booster fan placement has resulted, in some cases, in extensive air leakage which has compromised the economics of the operation and, in other cases, in recirculation of contaminants which has seriously compromised safety. This paper provides guidelines for proper design and siting of booster fans underground, to not only achieve an economic ventilation system but to create safe work conditions and efficient atmospheric conditions. Procedures for the planning, installation, operation and maintenance of booster fans are also presented. A case study illustrating the design and siting of a major booster fan installation in a potash mine, supported by computational fluid dynamics analysis, is presented.INTRODUCTIONIn large underground operations with complex ventilation networks offering high resistances, the never ending increased required quantities of air can almost only be supplied through use of high pressure main fan systems. These fans may, in effect, induce significant leakage losses in the system, having a negative impact on safety performance. In such cases, booster fans can be designed to decrease the main fan pressures and reduce the leakage flows, improve system efficiency and reduce costs. In well designed systems, booster fans can thus be used to redistribute the airflow and assist the main surface fans.When the pressure supplied by the main fans is insufficient to meet the ventilation circuit pressure requirements, booster fans are placed in strategic locations where pressure boosting is essential. Booster fans are typically sited in sections of the circuit offering high ventilation resistance and requiring this form of ventilating air motivation. Booster fans are thus required when the mine expands, and so the resistance of the ventilation network, and the primary fans no longer can supply the required pressure and flow."

Jan 1, 2019

By D. S. Salonine

Aluminum alloys offer a wide range of capability with a unique combination of advantages that makes them the materials of choice for numerous products and markets. One of the most important applications is their use as the primary structure and outer envelope in aerospace vehicles. Wide and thorough studies on hot working and microstructure evolution of aluminum alloys have been made in Russia. The most important appear to be: - introducing the structure diagrams in strain rate - temperature coordinates which show areas of different microstructures (non-recrystallized, recrystallized, and mixed) after the hot deformation and the following heat-treatment for common aluminum alloys (Yu.M. Vainblat); - studying the press-effect ("structural effect" by V.I. Dobatkin); - learning the influence of hot worked substructure on aging mechanisms; conducting researches on press heat-treatment. These works allowed a deeper understanding and a better control of the mechanical behavior of aluminum products. Comparisons are made to equivalent developments in Europe and America.

Jan 1, 2004

By Y. Jin, H. You, H. Pang, B. Lin

Successful application of steam assisted gravity drainage (SAGD) on the recovery of land facies ultra-heavy oil in Xinjiang oilfield depends largely on shortening the preheating period with the aid of the micro-fracturing technology, which is conducted through controlled water injection to a pair of horizontal wells to create homogenously distributed microcracks in the zone between the two wells. The numerical simulation of this mechanical process is yet to be investigated. Up to date, there has been research work on rock mechanics during the SAGD production period of marine deposited ultra-heavy oilsands, but the counterpart research on land facies ultra-heavy oilsands of Xinjiang oilfield is left undone. In this regard, this study is attempted to perform numerical simulation of the fracturing process on land facies unconsolidated oilsands. With this objective, the study first investigates geological and physical identification of the field collected cores, then carries out mechanical analysis on laboratory triaixal test results, based on which numerical simulation of the fractured zone is performed. The simulation is applied through a finite element platform adopting extended Drucker-Prager constitutive model, with the parameters determined by experimental work. It is verified that hydraulic fracturing of unconsolidated oilsands generates a microcrack feature in terms of a dilative zone instead of linear apertures. The extent to which the fractured zone propagates is visually demonstrated based on the magnitude distribution of equivalent plastic strain or volumetric dilation. Evaluation of the connection of injection and production wells can possibly be determined by the expansion of the saturated region around each well. Finally, the implications on the efficiency of hydraulic fracturing in stimulation of the pay zone are investigated.

Jan 1, 2015

By G. M. Ritcey, B. H. Lucas

In the conventional alkaline leaching of concentrate containing nickel, copper and cobalt, copper is usually removed from the system, prior to nickel reduction, by sulphide precipitation. A new process is described for the selective extraction of copper and separation from cobalt and nickel, using liquid-liquid extraction. General Mills LIX-63 dissolved in a kerosene diluent is the extractant. Trace amounts of co-extracted cobalt and nickel are easily removed by a scrub treatment, and copper is recovered from the extract by sulphuric acid stripping, thus providing a solution amenable to the oroduction of electrolytic copper. Estimated processing costs are included together with a proposed flowsheet.

Jan 1, 1972

By M. Aushouri, S. H. Mansouri, N. Aminizadeh

A thermo-chemical model of the Peirce-Smith copper converter in blowing the copper stage has been developed to predict the molten temperature. The key assumption of the model was that white metal and gas phases in the converter were in thermal and chemical equilibrium. In this model, the chemical reaction of white metal and oxygen was accomplished completely. So long as sulfur existed in the bath, the generation of Cu2O was frozen. The reaction rate was considered to be constant and controlled by the reacted sulfur. The converter temperature was calculated by heat balances over time. The model was validated by a detailed comparison with measured industrial data. A good agreement was obtained. The converter temperature depended on process parameters such as oxygen efficiency, molten emissivity and oxygen enrichment.

Jan 1, 2007

By C. R. Ross

"The purpose of this paper is to review the activities of international organizations concerned with the problem of dust hazards in mines and to indicate the extent of Canadian participation in these activities. The work of the International Labour Office in sponsoring conferences and reports on the appraisal and control of dust hazards and in the development of standard radio-logical classifications is considered in some detail. Also discussed are the role of technical societies, such as the American Conference of Government Industrial Hygienists, in the development of proposed standards for dust exposure and the functions of international committees concerned with particular hazards, such as the U.I.C.C. (Inter-national Union Against Cancer) Committee on Asbestos and Cancer."

Jan 1, 1969

By C. Dragusanu, J. Sims, J. Connolly

Based on a statistical analysis of the categorical and numerical data from the established geological model, a geochemical classification of mineralization has been shown to be objective in nature and correlated to the envisioned metal extraction process. Multivariate chemical classification has the potential to discriminate within a combined response from different types of alteration and metal abundances. Distinct domains of chemical response determined by clustering analysis were used as a validating criterion for a geologically driven metallurgical testing program. The groups established are spatially linked to the geological process responsible for their genesis, providing clarity in geometallurgical and resource modeling.

Jan 1, 2011

By J. Gebhardt, D. McBride, C. R. Bennett, Croft. N., M. Cross

A comprehensive model of solution flow through heap leach systems requires a numerical solution with the ability to predict variably saturated-unsaturated flow through porous media domains that contain materials with spatially variable properties. The types of flow associated with stockpile leach processes lead to flow problems, such as infiltration into dry soil, drainage, perched water tables and flow through heterogeneous materials. Computational methods for modelling this class of flow behaviour are conventionally based on the classical Richards' equation. However, the governing equations are highly non-linear, difficult to solve, and require iterative numerical solution methods. The pressure-based form of the Richards' equation suffers from poor mass balance, while the mixed form can possess convergence difficulties. An adaptive transformed mixed algorithm is described, which reduces the non-linearity of the problem, optimizes the time step size, and provides a fast, numerically robust scheme that significantly reduces computation (or CPU) time. This method is shown to give fast, accurate solutions on a number of complex flow problems. The utility of this algorithm is illustrated through its implementation within the PHYSICA computational modelling software, which incidentally, provides a framework for a comprehensive heap leach model.

Jan 1, 2005

By C. Allen

In 2004, Boliden Odda underwent an extensive modernisation project targeting mainly the leaching section of the plant. Direct leach technology was introduced as part of this project. The Direct Leach process, developed by Outokumpu, is an atmospheric oxidative leach of zinc sulphide concentrate. The effects of this new processing operation on behaviour of iron in the plant are discussed. As well, the filterability of the new residue on belt filters prior to its deposition in mountain caverns is also discussed. The solids from the direct leach process have been analysed by scanning electron microscopy, and the results of these analyses are presented.

Jan 1, 2006

By Bradley Stoughton

The magnetic oxide of iron, F eO4 , contains a theoretically larger amount of iron ( 72.4 per cent.) than any other commercial ore. It is probable that it has originated in many cases by the prolonged exposure of the hydrated oxide, ZF e20 a + 3H20 to heat and pressure which converts it first into hematite, F e20 3, and then into magnetite. It would thus appear as if nature had already done part of the work of removing all the oxygen and that magnetite should be relatively easy to reduce. That it is, in fact, less reducible than either limonite or hematite, is due chiefly to its dense and compact physical structure, which makes it less pervious to the furnace gases, and also to its characteristic action in resisting crushing to a uniform size, with consequent irregularity in reducing conditions within the furnace. The net result is that the magnetic oxide requires more fuel and more time for its reduction in the blast-furnace than any other iron ore of similar iron content and physical condition. There is another very important reason why the smelting of magnetite is more costly than that of hematite, and its treatment viewed with a great deal of adverse prejudice by blast furnace operators, namely, that magnetite decreases the proportion of heat developed by the fuel in the stack of the furnace, and increases the already excessive heat requirements of the heart.

Jan 1, 1924

By Ed Labelle, Terry Overton, Gary Bell

"LocationThe Miller Minerals lime and limestone production facility is located in the Temiskaming district of Ontario at Hailey bury on the west shore of Lake Temiskaming. Located less than 300 km from Sudbury, Timmins, Rouyn-Noranda and Val d'Or, the plant is very well situated to market products to the mining, pulp and paper, and environmental industries. Being located a few kilometres from the Trans-Canada Highway and the Ontario Northland Railway adds to transportation efficiencies.ProductsAt Miller Minerals, two principal products in various sizes are produced, which are limestone (CaC03) and quicklime (CaO).HistoryProduction of limestone products began in 1979 at this quarry site. During the 1980s, limestone products were marketed to a variety of applications for mining, forestry, environmental and agriculture applications. In 1990, the production of quicklime products began, following the commissioning of an Italian-designed vertical shaft calcining plant. During the 1990s, both quicklime and limestone products were produced to meet the customers' demands.From the quarry's conception until 1992, the operation was owned and operated by Dymond Clay Products. In 1992, it was purchased by Miller Paving Ltd. of Markham, Ontario, and became a key part of the company's industrial minerals sector of business. Other Miller interests include dolomite, cement, paving materials and waste management."

Jan 1, 2000

High Pressure Grinding Rolls (HPGR) are said to be a good option in new grinding circuits. Due to their low energy consumption compared to other grinding systems such as SAG milling, there is a strong incentive to check their behaviour for certain ore types. With rising energy prices the operation will become even more beneficial in future. As published in the past, the HPGR is claimed to increase the liberation of the valuable mineral component within an ore. An investigation at the research centre of Polysius was conducted to substantiate the liberation behaviour in finish grinding operations. A pilot scale HPGR test unit (POLYCOM MAGRO) with a roll diameter of 950 mm and processing capacity of 80 t/h was used. Grinding tests were completed with a screen and a two stage drying air separation process (SEPOL). Analysis included standard screen analysis, fractional XRF and modern MLA technology. A technique was developed to oppose the amount of produced slimes (resuming bad flotation) against the positive effect of producing high mass fraction at flotation-easy sizes. The paper shows how effective the use of a dry grinding separation could be in terms of production of mass of liberated metal.

Jan 1, 2012

By D. Atkinson

"Porphyry molybdenum-tungsten mineralization on the east flank of Hudson Bay Mountain crops out over 5 km2 and is intersected to depths of 2 km. Features such as a hornblende-biotite aureole, mineralogical zoning and dike, vein and fracture geometries within lithologies of the Middle to Lower Jurassic Hazelton Group and Cretaceous Skeena Group reflect an intrusive complex, the Upper Cretaceous to Early Tertiary Hudson Bay Mountain stock which has been intersected by drill holes. The stock is believed to be the mineralizing agent. A southeast-dipping granodiorite sill has been outlined by drilling within the Hazelton Group. Molybdenite and scheelite veins cut all rock types; however, the granodiorite sill hosts a higher density of fine-grained, banded, quartz-molybdenite and pegmatitic quartz-molybdenite veins reflecting a competency contrast between the intrusive sill and other country rock. Due to the relative abundance of these veins, grade is higher within areas of the sill. Above the 15000£ cross-cut 20.6 million tonnes grading 0.401% MoS2 and 0.041% W03 have been defined. During exploration of the deposit sampling procedures had to be adjusted because of the nugget effect attributed to drill intersections of banded and pegmatitic veins.IntroductionMolybdenite was discovered in outcrop at the foot of Kathlyn Glacier on Hudson Bay Mountain and first reported by the Geological Survey of Canada in 1944. The deposit has several names: Hudson Bay Mountain or Glacier Gulch, both after its location, and Yorke-Hardy after the original staker.The deposit is on the east flank of Hudson Bay Mountain, 9 km northwest of Smithers, west-central British Columbia, within NTS area 93L/14 (54° 49' North, 127° 18' West, Fig. 1). Hudson Bay Mountain, on the southern edge of the Bulkley Valley, is a dominant topographical feature reaching 2590 m elevation. Mineralization is partly overlain by the Kathyln Glacier which is visible from Highway 16. Access to the 3100 m of underground development is from a portal at 1066 m elevation on the east slope of Hudson Bay Mountain."

Jan 1, 1995