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By Yanping Xiao, Ton van Sandwijk, Gus Van Weert, Larry McHugh, Thomas Zabev

"All attempts to remove significant amounts of arsenic from enargite via neutral or reductive pyro routes have required operating temperatures between 600 and 700 º C, too high to propose an equipment development program. Operating at reduced pressures, or using hydrogen or elemental sulphur as a sweeping gas did not help to lower these temperatures. Admixing iron powder gave excellent results, but still required 700 º C. By fortuity, in recent experiments to produce tennantite from an enargite mineral sample, it was observed that enargite was completely converted to bornite, chalcopyrite with minor residual tennantite within an hour at 400-450 ºC. This is believed to be due to the presence of pyrite in the mineral sample treated. All earlier decomposition work appears to have been done on predominantly enargite (i.e. low pyrite) samples, or at high operating temperatures, ignoring possible reactions at lower temperature. The decomposition of enargite into iron substituted tennantite plus some bornite under evolution of liquid elemental sulphur, followed by further decomposition of this tennantite into bornite and volatile arsenic sulphides, appears experimentally feasible at these low temperatures and mimics described ore genesis pathways at > 250 ºC in saline solutions. We suggest two pathways to describe the observed experimental results:20 Cu3AsS4 + 12 FeS2 ???5 Cu10Fe2As4S13 + 2 Cu5FeS4 + 31 S(l)31 S(l) ???31 S(g) (evaporation)5 Cu10Fe2As4S13 ???10 Cu5FeS4 + 10 AsS(g) + 5 As2S3(g)"

Jan 1, 2014

By Sadan Kelebek, S. O. Fekete, Gerhard W. Heinrich, Peter F. Wells

"For many years, rejection of pyrrhotite at the milling stage has been a viable method for sulphur dioxide abatement. Pyrrhotite rejection options have included the use of selective pyrrhotite depressants in flotation; a depressant which has recently come into use is diethylenetriamine (DETA). This reagent has been the subject of recent research and development efforts in the processing of nickel-copper sulphide ores.In the present study, adsorption trends for DETA have been monitored under the dynamic conditions of flotation using a spectrophotometric method which has been adopted for this purpose at Falconbridge Limited. The results indicate that the adsorption of DETA is quite fast and in the majority of cases, accounts for the disappearance of 75-95 % of this reagent from pulp's liquid phase. The adsorption decreases linearly with an increase in the DET A dosage from 100 git to 600 git. The tailings produced in flotation tests were subjected to washing with deionized water at 60 °C to examine the desorption of DET A. These results indicate that the amount desorbed increases with increasing DETA dosage used during flotation but is less than 7 per cent of that adsorbed. It was found that adsorption of DETA alone, even at relatively high levels, does not always cause depression of pyrrhotite. A new combination of reagents identified in the metallurgical laboratories of Falconbridge Limited utilizes sulphur dioxide with DETA. These reagents together are capable of efficient depression of pyrrhotite on a consistent basis."

Jan 1, 1995

By G. Molloy

The purpose of this paper is to demonstrate the value of applying continuous improvement, in particular 5S and standard work, in an underground environment. 5S and standard work are two aspects of Lean manufacturing that have been applied in many industries. At Vale Canada Limited, the focus is to first stabilize the process, commonly through the use of 5S, standard work and other continuous improvement techniques. In parallel with building an engaged workforce, these approaches aim to incrementally stabilize and improve a process. 5S is an employee-driven, systematic methodology to reduce waste in all its forms through attaining, maintaining, and improving workplace organization. Identified as a foundational part of any improvement process, 5S aims to remove wastes that impact on the overall efficiency of the area. Standard work is used to formulate a common approach to how tasks are carried out to ensure consistency. Standardization involves identifying, establishing, and following the best method. The aim is to eliminate the variation that can occur when there is not a pre-defined established standard. Demonstrating the value of 5S and standard work in an underground environment will be achieved by first understanding the overall concept of Operational Excellence and continuous improvement as practiced within our operations. The paper will then cover a real application of 5S and standard work within the underground environment at Thompson, Manitoba.

Aug 1, 2013

By T. I. Kunkel

The economic prosperity of many Canadian communities depends on resource extraction within the traditional territories of Indigenous people. The geographic sites where these resources are situated are also areas where these Indigenous people have sustained themselves for millennia through hunting, fishing, trapping, and gathering activities. These traditional activities provide not only sustenance, but also cultural and spiritual values, and the ability to transmit oral Indigenous cultures and customs from generation to generation. The multimillion dollar revenue mine project proposed within the Cariboo Chilcotin region of British Columbia is situated geographically in a location which has sustained the Tsilhqot?in people for millennia. However, this group of people have important social and cultural values nested within the traditional activities at this location. These values are typically not at the forefront of resource development. Using Indigenous research and grounded theory, this research paper briefly outlines Aboriginal values of the First Nations communities within the Cariboo Chilcotin region and some lessons learned from the Tsilhqot?in people during the environmental assessment of the mine proposal.

Aug 1, 2013

By C. O. Aksoy

Operating the underground marble quarries effectively, it is important to evaluate the deposit blocks economically which are affected by the suitability of the topography and configuration of bedding. The joint sets within the deposit and the spacing between these discontinuties are also of great importance. In this study, the marble deposits that could be geomechanically eligible for underground excavation have been selected throughout Turkey and these selected reserves have been classified accordingly by Q-Rating System. These classified marble deposits that forms groups of 1,2, and 3 (groups were determined by evaluating the O-rating, topography, quarry situation, cracks, joints etc.) are convenient for this type of production. Nevertheless, when the auxiliary factors (topography, location, production method etc.) regarding the deposit have also been investigated, the most convenient sub-group of deposits (Afyon Tiger Skin, Burdur Beige, Diyarbakir Pink and Mugla White) have emerged. The sizing of the pillars have been performed utilising Bieniawski?s stress profile. The LAMODEL software, developed by National Institute for Occupational Safety and Health (NIOSH), USA and run under the laminated displacement discontinuity method, has been used to size the pillars. This work brings in a novel opportunity to Turkey, in which no underground marble quarry has been attempted up-to-date similar to its several examples in Italy, USA, etc. This study serves as a reference for the marble operators and for the pioneering application of laminated displacement discontinuity method in hard rocks.

Apr 1, 2005

By F. King, R. Sutherby, J. Been

With thousands of kilometers of buried oil and gas pipelines throughout the country, carrying flammable, high-energy hydrocarbons, the integrity and safety of this transportation and distribution network are paramount. The pipeline industry has the primary responsibility for pipeline safety and has in many ways taken the lead in dealing with safety issues. Over recent years, regulatory demands have increased, requiring operators to comprehensively evaluate their pipelines through indirect and direct inspections and to manage risk through integrity programs. Mechanistic and correlative models have been developed that assist in the prediction of pipeline integrity and the determination of reassessment intervals. These lifetime prediction models are based on decades of laboratory research as well as pipeline operating data, material data, and field monitoring data pertaining to soil conditions and CP. An overview is presented of an integrated approach towards the development of such models for the evaluation of external cracking and corrosion of transmission lines.

Jan 1, 2005

By A. Sargeant

This paper evaluates the application of post consumer glass as a cementing agent in underground mine backfills. The underlying theory indicates that glass is pozzolanic and, when used in a finely divided form, behaves as an activator to generate binding products, thus contributing to the development of backfill strength. The objective of this study was to evaluate the strength performance of backfills when Normal Portland Cement is replaced with various percentages of post consumer glass. The study evaluated the performance of backfills prepared using tailings from three mines. Each backfill was prepared using unique recipes, and were evaluated at cure times of 7, 14, 28, 56, 112 and 224 days. Laboratory work involved visual, physical and chemical material characterization followed by strength evaluations. Results of strength assessment revealed that backfill prepared with glass is reactive and can contribute to the strength of backfill. The results also indicated that the reactivity of glass may be affected by the incorporation of slag within the recipe, the availability of lime and the level of hydration of the binders. The study concluded that, at 15 % glass replacement of NPC, backfill prepared with mine tailings, NPC and glass can achieve improved or equivalent strength performance compared to backfill prepared tailings and NPC alone.

May 1, 2007

By R. Hagiwara, S. Kobayashi, K. Yasuda, T. Nohira, K. Kondo

To establish a process for the electrochemical recovery of rare earth elements from used magnet scraps, the electrochemical formation of RE-Ni alloys in molten NaCl-KCl-RECl3 salt at 973 K was investigated. Cyclic voltammetry and open-circuit potentiometry indicated the formation of several phases of RE-Ni alloys. The formation potential for each RE-Ni alloy phase was determined from the results of scanning electron microscopy and X-ray diffraction of alloy samples prepared by potentiostatic electrolysis of a Ni plate electrode at various potentials. The optimum electrolysis conditions for the separation of Nd, Dy, and Pr are discussed.

Jan 1, 2014

By A. A. Ruitenberg, G. Ruitenberg, J. Chandra

"The Caledonian Belt is mainly underlain by Late Precambrian and possibly Early Palaeozoic rocks, which are in part overlain by younger strata. Most of these rocks are weakly deformed, except for those in some linear . zones, which have been intensely deformed by cataclasis. Mineral deposits related to two distinct metallization episodes have been recognized. The earliest are zinccopper- lead sulphide deposits, which have been concentrated in the axial regions of late-stage cross-folds within the main cataclastic zone. The host rocks are andesitic and dacitic tuffs which show effects of intense talcose alteration, silicification and chloritization. Deposits related to the second episode are mainly composed of copper sulphides with locally abundant tennantite and tetrahedrite, which occur in brecciated and fractured carbonate-quartz veins. These veins postdate the late-stage cross-folds. VLF-EM and high-sensitivity magnetics proved to be very effective in delineating the geology of these deposits."

Jan 1, 1972

By M. R. Shadnam

This contribution provides an assessment of research and development efforts to optimize SOx, NOx and mercury capture in flue gas. Coa, characteristics and combustion conditions in a power plant have an impact on the types and concentration of flue gas pollutants. These factors can also affect the amount of pollutant removed. This contribution would also provide a comparative study of the technologies that holistically aim remova, of SOx, NOx and mercury altogether in coal-fired power plants. A portion of this contribution provides background information on regulatory drivers.

Jan 1, 2010

By A. Fyson, M. P. Smith, Margarete Kalin

"Drums containing 0.07 m3 of pyritic waste rock from a zinc/copper mine, with and without Natural Phosphate Rock (NPR) additions (40 kg/t waste rock) were set up outdoors. The effluent chemistry has been monitored over a period of 709 days. In the presence of NPR, the cumulative acidity discharged from 7 out of 8 drums was 80 % less than that discharged from drums without NPR. Mixing NPR throughout the drums was more effective in reducing acidity than placement of the NPR in a layer in the drum. NPR treatment was more effective for 'fresh' waste rock than for material which had weathered for more than 4 years. It is concluded that application of NPR to pyritic waste rock could greatly reduce acidity generated.IntroductionWaste rock dumps are significant sources of acid, generated by the oxidation of sulphides. Oxygen and water supply are oxidation rate-controlling factors, and oxygen supply is the reaction-limiting component. If secondary minerals can be formed on the surface of the rocks, pyrite oxidation and therefore acid generation may be reduced or inhibited. Neutralizing agents such as limestone do not prevent the oxidation of pyrite but treat the resultant acid mine drainage (AMD) or acid rock drainage (ARD).Meek et al. (1991) determined in pilot scale experiments that apatite mixed with tailings was more cost effective than liming or use of PVC liners to reduce oxygen and water penetration into the tailings. Phosphate is not acting as a neutralising agent but it creates a chemical condition on pyritic surfaces which prevents reactions of the oxidising agents. Precipitation of principally iron phosphates physically isolates the pyrite surfaces from further oxidation (Ziemkiewicz 1990; Evangelou 1994). The chemistry of the phosphate effects has been described by Spotts and Dollhopf (1990). Secondary mineral formation was evident in the leach pile at Gibraltar when leaching was impaired (Scott, 1991) indicating a link between oxidation and the mineral-formation process. This paper reports on effluent characteristics when waste rock is generating acid in the presence of NPR."

Jan 1, 1995

By K. A. Hughes

Under the oxidizing conditions of the McClean Lake Tailings Management Facility (TMF) hydrocarbons entrained on the surface of tailings material from mill processes are gradually converted to soluble bicarbonate ion. This has been observed to be a process occurring over approximately three years likely encouraged by the presence of a microbiological community within the tailings mass and in the water column. A recent tailings sampling campaign has provided evidence that bicarbonate ion is participating in the conversion of gypsum to calcite. In older tailings, equilibrium with calcite appears to be controlling the terminal bicarbonate ion concentration.

Aug 1, 2010

By M. P. Tibbs

An autonomous spray application system for a structural Thin Spray-on Liner (TSL) is targeting productivity and safety on underground coal continuous miners by potentially replacing steel mesh, and has broader applications as surface support and confinement in metalliferous mines and civil tunnelling. Polymer chemistry, coating formulation, geotechnical assessment and the autonomous application system are being developed as an integrated package as part of a continuous miner automation project. This polymer-based TSL system has significant benefits over conventional steel mesh skin confinement, including being more automatable by spray application, providing complete skin confinement and active skin reinforcement as a fast-curing composite with substrate, and having effective fire retardant properties for the polymer and the underlying coal. This paper presents a preliminary assessment of distance sensing systems that would enable autonomous adaptation of a nominal spray path to spray a consistent thickness of TSL (nominally 5mm) over an irregular topography. Two alternate sensors are assessed; firstly, a 2D LIDAR mounted on a linear axis is used to produce a 3D surface profile for generating an adapted spray path; and secondly, a robot end-effector-mounted ultrasonic sensor is assessed for wall following techniques to dynamically adapt a nominal spray path.

Aug 1, 2013

By I. Kylmakorpi

In non-ferrous metal smelting, when the concentrate entering the furnace contains high levels of moisture, energy requirement for heating and drying increases and large volumes of exhaust are produced. To solve this problem, rotary dryers and flash dryers using direct heating, and also steam dryers using indirect heating have all been used for drying concentrate. The focus of this paper is to present the development and current applications of the Kumera Rotary steam dryer. The advantages of this technology are numerous, including reduced heating requirements, environmental friendliness, operation reliability and minimum maintenance needs; making it a top choice for drying concentrate.

Jan 1, 2008

By Karim Ramji

The extractive sector today faces growing social, legal and political risks (SLPs) from so many different stakeholders including national and local governments, name and shame groups, civil society and environmental groups, and the ?Occupy? movement. Beyond these stakeholders, there are the indigenous peoples who have growing legal, social, political and economic influence which can often determine the outcome of the Project. The development curve in the extractive sector from initial exploration to mine start-up has become longer, steeper and more risky and expensive as these SLPs have grown in scope and complexity. Even if a project is permitted or starts commercial production, its ongoing development and operations are also facing these SLPs. The continuous assessment of these SLPs and the strategy to mitigate for them has now become critical for every project in the extractive sector. A project will only be successful if it is able to obtain the legal permits to operate, then withstand any judicial reviews, and then also to be able to gain and maintain the Social License to Operate (SLO). Stakeholder identification, management and engagement are key risk-mitigation tools. This paper focuses on the growing influence that indigenous peoples are now enjoying and the impacts on the extractive sector. Indigenous peoples are a unique stakeholder group because their legal rights and interests to lands and resources, their aboriginal title and rights, are gaining more recognition. When indigenous peoples form alliances with other stakeholders, this simply adds to their growing momentum and leverage, and this can become a daunting challenge for the extractive sector. More due diligence is required by companies to understand and assess the challenges posed by operating in areas claimed by indigenous peoples. There is a real need for mining companies to develop an effective indigenous engagement strategy to address these challenges in order to successfully convert risks into opportunities. Early identification and engagement with the indigenous peoples is required and the goal should be to conclude an Impact Benefits Agreement (IBA) with the affected indigenous peoples. The real objective must be to develop a real and transparent relationship between the company and the indigenous peoples so as to gain and maintain the SLO.

Aug 1, 2013

By Kosta Fytas, Nour-Eddine Chaouai

"Selection of the appropriate kriging plan during indicator kriging estimations is of a paramount importance to the precision of ore reserve estimation. However, very little is known on the sensitivy of indicator kriging results when changing the kriging plan parameters (mainly search distance and number of samples). This paper evaluates the effect of the search distance and number of samples on indicator kriging results using a gold deposit as a case study.IntroductionBlock estimation using kriging is based on the autocorrelation function (variogram) on one hand and on the kriging plan on the other. As far as the variogram is concerned it is more or less subjectively adjusted and this is reflected on its parameters (range, sill, nugget effect and anisotropy). The effect of a poor estimation of these parameters on the kriging variance of ordinary kriging has been proven very important (Brooker, 1986). Choosing a kriging plan is generally a difficult matter depending on the estimation type (global or local). Generally there is not a unique kriging plan be cause there is not a unique structural analysis (variogram). There are no rules or dogmas in choosing a kriging plan but it is rather a function of the sampling pattern (David, 1982).Structural analysis requires the hypothesis of quasistationarity but very often either the data available within the zone of quasi-stationarity are too many so that the search distance is reduced during kriging or the data are too few to satisfy a stationary kriging system (Journel and Huijbregts 1978). As a rule, the larger the neighbourhood, the more precise the estimates should be , but for large neighbourhoods the hypothesis of stationarity does not always hold (Rivoirard 1987; Armstrong and Champigny 1989)."

Jan 1, 1991

By Michael K. Watkeys, Jacobus E. Potgieter, E. Guy Charlesworth, Carl R. Anhaeusser, Roger L. Gibson, Alexander F. M. Kisters

Intrusive features of cupriferous noritoids from the deeply eroded Proterozoic granite-gneiss terrane of the Okiep Copper District in South Africa illustrate the emplacement of basic magmas into a mid- to lower-erustal environment. The small, easterly trending intermediate to basic intrusions of the so-called Koperberg Suite display a wide variety of geometries, occurrence and emplacement modes, including dike-, sill- and plug-like bodies. Coeval granulite-facies metamorphism, partial melting and ductile deformation of country rock gneisses during intrusion of the basic magmas led to emplacement and dilation processes of the intrusions which differ significantly from those described for dikes and sills at shallow crustal levels. Regional tectonic stresses are largely negligible due to very low differential stress [( )] during deformation and intrusion, which permits emplacement at high angles to the principal compressive stress and which follows favorably inclined structural anisotropies. Dilation of the basic intrusions is largely determined by compositional differences of host rocks and occurs by thermal erosion, i.e., assimilation of wall rock gneisses. Low length-to-width ratios of basic to ultrabasic dikes and predominantly diapir-like outlines of mesocratic bodies are indicative of low viscosity contrasts between the mafic magmas and high-grade metamorphic host-rock gneisses. Buoyancy-controlled ascent of the basic to intermediate intrusions is expressed by a broad compositional zoning of basic bodies with respect to the granite-gneiss stratigraphy. Various intrusion modes within the stratigraphic column of the granite-gneiss sequence reflect a lithological and structural stratification of the seemingly homogeneous granite-gneiss terrane.

Jan 1, 1994

By Min-Yuan Cheng

Landslides not only cause interruption of road traffic but also cause damage to passing by vehicles and injure people in Taiwan. Due to the budget limitation of government, the overall assessments and maintenance of all road slops cannot be fulfilled. Priority of road for maintenance is a crucial task for road maintenance department to identify. The purposes of this research are to develop an assessment method for the landslide risk and to make strategies to maintain or repair the slopes along mountain roads. To aim both needs to take into account the environmental conditions of the slopes, the engineering measures for stabilizing road slopes, the transportation issues, and the human concerns when dealing with the slopes maintenance along the mountain roads. This study firstly establishes the Landslides Damage Risk Evaluation Model (LDREM) to calculate the risk of slope failure, considering the probability of landslides, temporal probability, spatial impact probability, the value of human life, transportation time increased, and travel cost due to detour etc., and then the loss of life and transportation can be calculated. Secondly, based on the value of risk and the risk evaluation, considering the risk acceptance criteria for loss of life could provide assistance for road maintenance department to determine the priority of mountain roads for maintenance.

Aug 1, 2013

By F. Parada Luna, F. Parada Torres, J. Salvo, A. Reghezza

In the pyrometallurgical processes of copper concentrates, arsenic is preferentially concentrated in the dusts carried by the gases as a result of their volatility and subsequent condensation in the gas cleaning train. In this work results obtained by alkaline leaching of the dusts from Ministro Hales roasting plant, belonging to Codelco, are presented. For the Ministro Hales plant the alkaline leaching would be an alternative to the recirculation of dusts to the roasting furnace. The experimental study considered NaOH and NaOH plus NaHS leaching of two samples of dusts, with 4.24 and 2.55% arsenic respectively. The results show that it is feasible to extract 90% of the arsenic and 50% of the antimony at room temperature using only NaOH, and when the temperature increases to 95ºC, the extractions of As and Sb increase. Copper remains in the solid residue with less than 1% dissolution, and the NaOH net consumption was approximately 140 kg/t of dust. In leaching tests with NaOH + NaHS, two types of methods were tested, baking plus leaching with water and direct leaching with a NaOH+NaHS solution. With the second method arsenic extraction increased to 95% and copper dissolution was less than 0.01% at 85ºC, NaOH 100 g/L, NaHS 90 g/L, 1.5 h and L/S ratio of 5/1 (L/kg). The bismuth remains stable in the solid in all cases. INTRODUCTION The presence of arsenic in copper concentrates has increased with time and the environmental regulations are becoming increasingly more stringent. In concentrate treatment pyrometallurgical plants, most of the arsenic is volatilized condensing in the gas train and is collected along with the entrained solids to form the flue dusts. Under these conditions, in smelters of copper concentrates with high arsenic content, the dusts are being treated in hydrometallurgical plants to extract and stabilize the arsenic, which also means that most of the copper contained in the dust is co-extracted with the arsenic. This affects the recovery of copper in the smelter and an alternative such as the selective alkaline leaching of arsenic, would allow the copper from flue dust to be recovered.

Jan 1, 2019

By D. Harris, G. Ye, G. Oprea, J. Rigby, T. Troczynski

Sintering and ceramic bonding in refractory castables take place mainly in the binding system during the first heat-up and in service. Consequently the strength and the corrosion resistance of the hot face layer depend on the sintering ability of the complex mix of ceramic powders constituting the binding system. As a result, the use of nano- sized reactive powders in the binding system mixes would activate the sintering and enhance the ceramic matrix formation at temperatures below 1300°C. Our work presents the experimental data on sintering behavior of binding systems containing magnesium aluminate and alumina nano-powders in the temperature range of 800-1450°C. The results indicated that a ceramic matrix, similar to high temperature fired bricks, could be generated after firing at the relatively low temperatures available in the non-ferrous smelting furnaces.

Jan 1, 2004