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By Y. Dong, L. Li, L. Yu

Converter slag has become an important secondary raw material. Consequently, vanadium bearing converter slag is of great interest for the recovery of vanadium. Solidified converter slags are made up of three main mineral components: dicalcium silicate, calcium ferrite and wustite. Vanadium in modified slow cooling down converter slag of Magang is found mainly concentrated in a separate mineral phase. The mineral phase with high content of vanadium (24%, wt, V205), concentrating 83% of vanadium, can be separated from the slag for economical vanadium recovery. Some characters of the mineral phase were discussed comparing with dicalcium silicate, one of the typical mineral phases in converter slag studied well.

Jan 1, 2004

By Z. S. Abisheva

The Zhezkazgan copper sulfide ore deposit in Kazakhstan contains both rhenium and the rare osmium isotope "osmium-187" (187Os) in the high isotopic purity of 99.4 ± 0.2%. This isotope is believed to have originated as a result of the disintegration of one of the rhenium isotopes, according to the reaction: 187Re75 ?> 1870576 + B- + v~ (where B is a 13-particle, v~ is a 3-disintegration antineutrino). The distribution of osmium and rhenium in metallurgical byproducts produced during the recovery of copper from these ores has been studied and process flowsheets for the processing of rhenium and osmium-containing byproducts have been developed.

Jan 1, 2007

By V. Ramachandran

The successful advent of solvent extraction (SX) reagents for copper recovery and improvements in electrowinning of copper to produce LME grade A copper cathode have paved the way for the hydrometallurgical treatment of copper oxide and low grade sulfide ores. This has resulted in about 25-30% of the world's copper being produced today by the Leach-SX-EW process. The obvious next step was to develop processes for the hydrometallurgical treatment of copper sulfide concentrates, as an alternative to a typical smelter-refinery complex. The current paper updates the processes that have been developed to date with emphasis on processes that are being commercialized or that are seriously under consideration for commercialization. Most of the discussions relate to the hydrometallurgy of chalcopyrite concentrates, which account for about 70% of the world's known copper reserves. In summary, in the last thirty years, the hydrometallurgical treatment of copper sulfide concentrates has attained full maturity and will be a serious option to contend with while evaluating any future new copper plant.

Jan 1, 2007

By R. V. Kumar, F. Tailoka

In order to use ZnO laden dust as a possible desulphurization reagent, it is important to evaluate thermodynamics of the Zn-O-S system. At temperatures greater than 1450 K, there is an uncertainty in the thermodynamic data for the reaction of zinc with sulfur to form Zinc sulfide. In this work, the standard free energy has been determined using an electrochemical cell: Pt, Mo, MoO2/YSZ/ZnO, ZnS, S02, Pt., between 1198 and 1602 K. AG° varies from -145,880 to -88,100 J (± 2500) , with a phase change to ZnS (g) by sublimation occurring between 1450 and 1460 K. This is supported by thermogravimetric analysis which shows about 80% weight loss in ZnS from 1273 to 1473 K. Feasibility reactions were also performed and confirmed that ZnS (g) is formed when ZnO reacts with FeS (1473 to 1653 K) or with Fe-Csat-S(1473-1673 K). There is therefore potential for the utilization of ZnO laden waste as an additional or alternative reagent for desulfurisation.

Jan 1, 2004

By G. E. Wood

THE INSTABILITY of copper prices and their low levels since late 1974 are of great concern to both producers and, to a lesser degree, consumers of copper. The price levels portrayed by the "neutral long-term" price trend are assumed to have been enough to encourage sufficient investment to provide adequate world production capacity and yet not so high as to encourage development of excessive over capacity. The identification of the present level of this trend has taken on special importance for governments and for corporations active in the world copper industry. One approach to the possible determination of such a price is through the use of moving averages. In this way, the effects of relatively short-term price movements can be dampened, as can those related to business cycles. From such averaged price data, long-term trends can be sought over a selected time period. The choice of the past time period for which a price trend is sought may have a major effect on the result'. For example, in the period 1885-1973, the long-term price trend for copper in constant dollars showed a decline, whereas in the period 1919-1973 it was rising. For the purposes of discussion, an appropriate choice of period might be a relatively short and recent one so that the majority of the present cost factors would be present throughout. It should also be long enough to cover a number of full business cycles.

Jan 1, 1977

By P. B. Demarsh

"Location: - On highway 59, 17 miles east of Val d 10r near junction of Montreal highway in Northwestern Quebec.Life; - Started production 1952, ceased 1965.Ore: - Pyrite, chalcopyrite and small amounts of free gold and goldsilver tellurides in narrow quartz-carbonate-tourmaline veins in granodiorite. Specific gravity 2, 70.Capacity: - 700 tons daily Bevcon ore supply, l 000 tons daily when custom ore available.Assay: - Heads 0 .140 oz. per ton; tails 0. 009 per ton; extraction 92.5%.Grind: - 75% minus 200 mesh at 700 tons; 68% minus 200 mesh at 1000 tons. Detention time 28 hours and 21 hours respectively.Treatment: - Cyanidation process.Reagents: - Per ton. Aero Cyanide (NaCn) 0, 50; crushed unslaked lime 1. 75; zinc 0. 03; litharge 0. 10; steel consumption 2. 25.Water: - Pumped from land-lock spring fed lake l 1/2 miles distant.Cost: - Per ton. Crushing 0. 13; grinding 0 .32; filtration 0. 07; cyanidation 0.14; miscellaneous 0.29; total 0.95.Power: - Hydro-electric, 25 cycle, 12, 000 volts reduced to 550 volts.Labour: - Predominantly French Canadian, nucleus English Canadians.Tailings: - Impounded low lying pond.Personnel: - 15 including supervision.Flow sheet: - Canadian Mining Manual l 9 5 6 .Building: - Wood truss construction: 3/ 4 in. siding, ten test and 1/ 4 in. transite outside. Corrugated galvanized iron roof. Ground level foundations. Internal self induced heating. Wood stave tank equipment."

Jan 1, 1966

By A. A. Sirkeci, M. Tarkan, N. Acarkan, O. Kangal, G. Bulut

This investigation deals with the evaluation of the tailings of the Kirka Borax Plants. In this respect boron in the tailings was recovered and the utilization of the clayish fraction was investigated. There are five tailings ponds in Kirka four of which are used for the tailings of the borax concentrator and the remaining one is used for the tailings of the sodium penta-borax plant. Experiments were conducted with samples taken from ponds containing coarse fraction and fine fraction. Coarse fraction of Borax Concentrator were screened through a set of sieves. The fraction above 1 mm was removed with 41.5% recovery and 33.3% B203 content. Scrubbing was applied above 0.1 mm and products containing 32 to 34% B203 were obtained with recoveries around 35%. The tailings of sodium penta borax plant was also screened and it was found that 15% of boron reported to +1 mm size fraction with 35% B203 content. Sample containing fine tailings was treated by cycloning. The cyclone overflow was found to be below 6µm and it was separated to be used in the subsequent tests. The usage of cyclone overflow in paper, ceramics, glass, pigment and drilling industries was investigated. Since this fraction is mainly composed of carbonate minerals rather than clay minerals it was suggested that it may be used for construction and moulding purposes. Furthermore, the B203 content of the cyclone overflow was reduced to 2.4%.

Jan 1, 2004

"This document sets out the Exchange’s expectations and requirements for a valuation of mineral properties and outlines: the general purpose of valuation reports; guidelines respecting circumstances where the Exchange will require a valuation report; and valuation standards, guidelines and methods that are generally acceptable to the Exchange, 1. IntroductionThis Appendix sets out the Exchange's expectations and requirements for a valuation of mineral properties and outlines:(a) the general purpose of valuation reports;(b) guidelines respecting circumstances where the Exchange will require a valuation report; and(c) valuation standards, guidelines and methods that are generally acceptable to the Exchange.Mining industry standards and guidelines for valuations and valuation reports can be found in the Canadian Institute of Mining, Metallurgy and Petroleum Standards and Guidelines for Valuation of Mineral Properties (""CIMVal"") published in February, 2003 (www.cim.org). CIMVal consists of two parts, Standards and Guidelines. The Standards are mandatory and must be followed in order for a valuation to be CIMVal compliant. The Guidelines in CIMVal are not mandatory, but are strongly recommended.The Exchange requires that CIMVal Standards be used by Issuers and their professional advisors when preparing valuations and valuation reports on mineral properties. The CIMVal Guidelines should be followed by Issuers and their professional advisors in preparing valuation reports on mineral properties, with the exception that the valuation methods and guidelines under Section 4 Acceptable Valuation Methods and Guidelines below, must be followed."

Jan 1, 2003

By Yasuhiro Aoki, Akihiro Sato, Mikiya Arai

In this study, a freckle formation model based on the Rayleigh number was applied to actual multi-component Ni-base single crystal superalloys and verified in large scale casting trials. Finally, new Ni-base SC superalloys having a balance between castability and creep strength has been developed.

Jan 1, 2010

By S. Burling

Australia has a number of uranium deposits, but they vary significantly in their mineralogy, grade and textural characteristics. Therefore, information from traditional (or conventional) sources regarding the fundamentals of leaching the uranium and gangue minerals is not always applicable when studying particular ores. Empirical studies on particular ores can be effective in understanding leach systems and can lead to improvements in process design, but there remains a lack of fundamental understanding which is necessary for ongoing process optimisation as ore bodies continue to vary. ANSTO Minerals has undertaken a program of work to address some of the fundamental questions of uranium leaching, including the unexpected impact for some ore types of leaching at high oxidation potential.

Aug 1, 2010

By B. Szpunar

Structural and mechanical changes of urania are investigated when oxidized to U3O8. The CASTEP ab-initio quantum mechanical program, employing density functional theory is used. The total energy technique is implemented to investigate changes in the lattice constants. The ab-initio calculations predict a 36% increase in the volume per uranium atom when transforming from UO2 to U3O8, which agrees very well with experimental data. The implication of this prediction on the linear expansion and fuel fragmentation is discussed. The calculated elastic constants of urania are in good agreement with experiment. The predicted mechanical properties of UO2 and U3O8 are compared.

Aug 1, 2010

By K. Fukuda

The volatilization behavior of heavy metal in electric ash melting furnaces has a strong relation with its distribution between molten salt and slag. In this study, the distribution ratios of heavy metals between molten salt and slag phases were measured using a hermetic cell. The experimental results showed a relatively rapid loss of Pb and Zn from the salt in the first few hours followed by slow heavy metal vaporization with an almost fixed metal distribution between molten salt and slag. The distribution ratios of Pb and Zn decreased with increasing slag basicity. The mechanism of this effect can be explained by the chlorinated reaction of PbO and ZnO by CaC12.

Jan 1, 2004

By Geoffrey C. Streeton

A continual objective of mine operations is to reduce ground control costs without compromising the overall safety or performance of the installed ground support. Any change in the ground support regime must not result in a less secure or safe workplace. The due diligence required to implement a change in rockbolting practice is extensive, particularly when the new bolting system has not been used at any other mining operation. Factors such as yield, shear strength and embedment strength must all be investigated to gain an understanding of how the rockbolt can be expected to perform. This paper also discusses the substantial cost reductions and efficiency gains which can be achieved through the introduction of the Jumbolt rockbolt.

May 1, 2001

By M. J. A. Ruszala

Aggregates production is a huge global industry which uses an enormous amount of energy and produces a massive amount of unsalable fines. Reducing the amount of energy used per tonne of product and/or the amount of fines produced, would make a quarry more efficient. This reduction would make the quarry more environmentally friendly and profitable. This research looks at modelling Mountsorrel Quarry, a granite quarry in the United Kingdom (UK), using JKSimMet and Split-Desktop software packages in conjunction with the European Union (EU) project, EE-Quarry. Samples submitted to drop weight tests confirmed Mountsorrel Quarry granite as an extremely hard granite. Rock fracture data (t10) and energy of comminution (ECS) data were obtained from analysing the results. Split-Desktop image analysis software was utilized to determine the particle size distribution (PSD) of the primary crusher feed, as it contains particles too large to screen manually. It was also found that <1% of the feed is fines, which at Mountsorrel Quarry are classed as particles smaller than 5 mm, and that no particles were larger than 3,810 mm. JKSimMet was used to create a flowsheet of Mountsorrel Quarry. The crusher product PSDs were simulated and found to have strong correlations with experimental data, calculated by screening samples from conveyor belts, especially in the fines region, with a mean difference of 1%. The simulated primary crusher product PSD showed that it contains ~6% fines. A simulation over the entire quarry showed the product to be within the size range produced at Mountsorrel Quarry, and with a simulated fines content of 13%. When the CSS on the primary crusher was altered from 165.1 mm (the operating size on site) to 100.0 mm, it increased the overall percentage of fines produced by 3%, increased the power draw by 140.6 kW, but reduced the overall plant production percentage of fines by 2%. Two blasts were analysed on adjacent rock faces. They had identical blast designs, but the order of deck detonation varied; the first blast detonated the bottom deck before the top and vice versa in the second blast. For each blast, measurements of the feed PSD to the primary crusher, the number of particles that required secondary breakage on the quarry floor, acoustic levels and vibration readings were measured. No significant difference was identified between the two blasts in any of the parameters measured. In conclusion, a working model of Mountsorrel Quarry has been made in JKSimMet that has been validated against data from site and Split-Desktop has been used to simulate the primary crusher feed PSD, something that was previously unknown. The effect of reversing the order of deck detonation in a two deck blast was also analysed but with no significant difference between the two blasts found.

Aug 1, 2013

By R. S. Jr. Stronach

"IntroductionThe property of Campbell Red Lake Mines, Limited, is in Balmer township, Red Lake area, Patricia portion of Kenora district, Ontario. It consists of a group of twelve claims which had been staked and re-staked a number of times before George W. and Colin A. Campbell staked them in 1944. Messrs. Brewis and White incorporated Campbell Red Lake Mines, Limited, in July, 1944, to acquire these claims from the Campbell brothers, and in November of the same year re-assigned their option on the controlling interest of the treasury shares to the Dome Exploration Company (Quebec), Limited, a wholly owned subsidiary of Dome Mines, Limited.A long known exposure of sulphides on the northeasterly portion of the property, which returned low gold assays, on sampling, was the only showing of interest at this time. However, Dr. H. C. Horwood's report and map of the district had recently been published and favourable structure W3.S indicated in Balmer township. It was on the strength of this showing and Dr. Horwood's report that Dome Exploration became interested in the property.Between. January, 1945, and April, 1946, a diamond drilling programme was carried out, with completion of sixty-one holes. Five holes proved the surface showing to hold no commercial interest, so routine cross-sectioning of the property from north to south was started. The fourth hole of the series returned excellent ore intersections and from that time on the programme changed to one of extending these values. The final results of the drilling showed that what is now known as the A zone has a continuous length of some 1,200 feet, a width of 4½ feet, and an overall grade of about 0.5 oz. gold per ton. There were many other intersections of ore grade outside this A zone which could not be successfully correlated .at that time, but underground work has opened many of them. It may be said here that practically all the work to date has been confined to the southeast claims of the property."

Jan 1, 1950

By L. Long

Stirred milling of nickel laterites offers possibilities for improving liberation and selective size reduction of soft nickel-bearing minerals in laterites. Batch grinding tests were performed in a Netzsch LME4 stirred mill on siliceous goethitic (SG), goethitic (G), and saprolitic (SAP) nickel laterite samples (- 2000 ?m particle size) to evaluate the effect of stirrer speed, solid content, water salinity and grinding time. A fine mineral product (-38 µm) was used to evaluate the effect of selective grinding and Ni upgrade. The optimum grinding time for the highest Ni upgrade was 0.25 min, 0.1 min and 0.1 min for the SG, G, and SAP nickel laterite, respectively. A new feed (38-2000 µm) for each nickel laterite sample was prepared for batch grinding tests under the optimum grinding conditions. Upon grinding the 38-2000 µm feed, the - 38 µm product confirmed the effect of selective grinding and nickel upgrade. Size classification followed by stirred milling is a suggested process for Ni upgrade. The best Ni upgrade result was achieved on the SG nickel laterite among the three samples. The Ni grade increased from 0.85% to 1.37%, with 27.8% Ni recovery. Bottle roll leach tests showed that for SG and SAP samples selective grinding had no dramatic effect on Ni extraction due to the slow leach rate of hard mineral particles. Stirred milling of G sample increased the surface area of goethite, resulting in higher Ni extraction. Gravity concentration through a Knelson Concentrator was not effective in the further treatment of the stirred milling products either due to the poor operating conditions or due to the mineralogy characteristics of the feed samples. The energy requirement in the stirred milling was investigated. The first pass of the signature plots study is critical for the purpose of selective grinding, because the best result on selective grinding is achieved in the early stage of the grinding process.

Aug 1, 2013

By Helmer Kraemer

One of the CIM 2003 conference themes is ?Globalization and the impact on mine operations?. In this context, the first official version of the new ?International Rock Excavation Data Exchange Standard? (IREDES) is being released. This new standard is a highly flexible data interface for exchange of information between production equipment and central computer systems. The standard was defined by global players in the mining industry and will soon be used to enhance local operations of global mining companies. Beside the standard definition now other aspects are coming into focus: The question how to design and how to implement IREDES compliant data exchange in practice. Implementation of IREDES covers the following aspects: !" Implementation on in-field production systems !" Communication and networking !" Implementation on databases and commercial IT systems In-field production systems are characterized by a big variety of different automation systems. Therefor, different IREDES implementation philosophies have to apply to those systems. One philosophy uses an integrated IREDES compliant automation system on every machine. The alternative method uses one shared IREDES compliant ?Proxy server? for a number of machines connected to this server using proprietary interfaces. Communication and networking can be integrated openly and independently from hardware infrastructures. The only precondition is that communication and networking has to be Ethernet - TCP/IP protocol compatible. IREDES Implementation on the commercial IT level means to exchange IREDES data sets with databases, simulation software, office packages and special applications. Interfacing is easy as long as the software or the database system provides an interface to the Extensible Markup Language (XML).

May 1, 2003

By G. Song

This paper reports the anodizing voltage, gas evolution and sparking behaviors of an anodized coating formed on AZ91D in a silicate containing solution. According to their responses to an anodizing current, a four-stage anodizing mechanism is proposed. At the same time, the formed coating is characterized in terms of its microstructure, composition, thickness and corrosion performance. It was found that deposition of MgSiO3, Mg(OH)2 and MgO as well as dehydration of Mg(OH)2 are involved in the anodising process; the vigorous gas evolution accompanied by intensive sparking and the corresponding negative anodising efficiency in the later stage of the anodising process are closely associated with thermal decomposition of water due to the high temperature resulting from the intense sparking on the surface of the anodized alloy; the thickness, porosity, and composition of the anodised coating on a magnesium alloy depend on the final anodising cell voltage; and the corrosion resistance of a thick but porous coating containing more silicates appears to be more corrosion resistant than a thin but compact coating containing less silicates.

Jan 1, 2006

By I. A. Menshikh, S. A. Kotov, N. L. Shinkarkin

All the cycle for conversion of natural and reprocessed uranium of ROSATOM’s “TVEL” Fuel Company is concentrated at the Siberian Chemical Plant. Conversion capacities are located on two sites, i.e. the Radiochemical Plant, which refines feedstock, and the Conversion Plant, which produces uranium oxides and uranium hexafluoride. Liquid radioactive waste arising in the process, after pretreatment, is transferred to a dedicated national operator for underground disposal. Environmental strategies pursued by the Fuel Company involve the introduction of process solutions intended to eliminate liquid radioactive waste and convert it into a solid phase. In the 5–7 years coming, work will be performed to refurbish and upgrade conversion facilities of the Siberian Chemical Plant that will principally change its radioactive waste management scheme. This paper describes the current waste management scheme and sets out planned schemes for management of natural and reprocessed uranium waste, which will be implemented in the refurbishment of conversion facilities of the Siberian Chemical Plant. The new technologies for the management of liquid radioactive waste from uranium conversion described in the present paper have an undeniable advantage over the current technology mainly due to significantly less environmental harm.

Jan 1, 2020

By H. Kuboyama

The synergistic effects of polymer additives such as gelatin and polyethylene glycol) (PEG) and Cl- on Cu electrodeposition have been investigated by measuring the polarization curves for Cu deposition, by rotating ring-disk electrode technique and by AC impedance measurements. The cathode potential for Cu deposition was greatly polarized in solutions containing both Cl- and gelatin or PEG, showing evident synergistic effect of polymer additives and Cl- on Cu deposition. The cathode potential was shifted to the less noble direction with increasing the concentration of Cl- in solutions containing polymer additives and showed the maximum polarization at Cl- concentration range between 0.1 and 1 mmol/L. The rotating ring-disk electrode technique revealed that Cu deposition in solutions containing small amounts of Cl- proceeded with initial formation of adsorbed intermediate CuClad. The Cole-Cole plots obtained by AC impedance techniques suggest that the reduction of CuClad is suppressed by polymer additives. The morphology of Cu deposited from solutions containing both PEG and Cl- showed the compacted surface composed of smaller grains due to an increase in the overpotential for Cu deposition.

Jan 1, 2007