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By Renaud Cousin

Supported gold catalysts were prepared by Direct Anionic Exchange on an alumina support and tested during the reaction of CO oxidation and of saturated and unsaturated hydrocarbons (C1 to C3). The catalysts showed high activies over a range of concentrations and temperatures compatible with an application to automotive exhaust cleaning. Furthermore, a complete resistance to thermal ageing at 600°C in the absence or presence of water was observed due to the obtention of strongly anchored nanosized gold particles during the preparation step.

Oct 1, 2003

Sustainable Development SAFETY ?Safety is the most important element of sustainability. ?One bad experience or incident can mar a company?s reputation for a long, long time. ?News travels faster than ever ?Internet, blogs, texting, peer-to-peer communication, etc. and unfortunately sometimes the information is not always accurate. ?Rarely do we hear in the news about the mining companies or projects that are done safely ?we always hear about the exceptions. ?Safety is just like TQI / TQM ?the process of improving can never stop.

May 1, 2010

By Andreea Catalina Gluhoi

The oxidation of propylene and methane has been investigated over two series of Au/MOx/Al2O3 and Au/MIOx/MIIOx/Al2O3 catalysts (M, MI, MII =Li, Rb, Mg, Mn, Ce, Zr). Whereas the effect of the presence of MOx or MOI x/MOII x on the oxidation of methane is relatively small, a large enhancement in activity is observed for propylene oxidation. Synergistic effects have been observed by combining ceria or a transition metal oxide (high oxygen storage capacity) with an (earth) alkali metal oxide.

Oct 1, 2003

By Emile D. L. Rienks

We have studied the interaction of NO with the quasi-hexagonally reconstructed Au(100) surface. Using variable temperature scanning tunneling microscopy we have observed formation of the unreconstructed phase of Au(100) after NO exposure. This NO adsorption induced phase transition is observed in a window of temperatures around 170 K. Under the same conditions, CO and O2 cannot drive the phase transition, suggesting weaker interaction. Thermal desorption spectroscopy experiments provide an estimate for the strength of NO chemisorption on Au(100) of 57 ± 4 kJ mol-1.

Oct 1, 2003

By R. Gordon, J. Palich, W. Qian

The EarthProbe DCIP system deploys tightly spaced electrodes connected to a centralized data acquisition system that enables arbitrary selection of current and potential electrodes through relays. Rapid data collection (approximately 1000 readings per hour) and advanced signal processing allow for efficient use of conventional and novel arrays and the removal of natural and cultural noise. What is unique about the system is its electrode and borehole cable design, which allows seamless integration of borehole and surface measurements. EarthProbe operates in four configurations - surface, borehole, borehole-to-borehole, and surface-to-borehole (a variant of the borehole-to-borehole configuration).

Jan 1, 2011

By W. Geslin

Backward extrusion process is a metal forming process, which limits the manufacturing?s extra thickness when compared with classical die forging technique. Because of a lack of alloy?s mechanical behavior knowledge, the basic strategy of design is as follow: ?Definition of a small scale blank ?Performing experiment in order to get useful process data ?Improvement finite element simulation conditions ?Development of the full scale blank forming process (design of tools,...) using the finite element simulation A comparison between the result of modeling and the experimental data has been done to validate the finite element simulation.

Aug 1, 2010

"The South African Mineral Resource Committee (SAMREC), a Working Group of the SAMREC/SAMVAL Committee (SSC), under the joint auspices of the Southern African Institute of Mining and Metallurgy (SAIMM) and the Geological Society of South Africa (GSSA) developed the SAMREC Code. The Code sets out minimum standards, recommendations and guidelines for public reporting of exploration results, mineral resources and mineral reserves in South Africa. It is applicable to the reporting of all styles of solid mineralization or economic deposit. However, certain commodities, namely coal and diamonds, have specific additional reporting requirements. The Code does not apply to oil, gas or water."

Jan 1, 2003

By T. Maio

Twelve years ago, Kennecott Utah Copper modernized its Refinery in conjunction with the modernization of the Kennecott Smelter with the latest flash smelting and flash converting technologies. The Refinery modernization consisted of installation of new polymer concrete cells, installation of KIDD TPS (total production stripping) system, installation of automated materials handling system, and the construction of a new hydrometallurgical slimes treatment process and precious metals plant. This paper outlines the Refinery operations and process improvements. Also presented are the newly implemented technologies and operating results of one of the world' s largest and most modern electrolytic copper refineries.

Jan 1, 2007

By X. Xe, B. Myhre, N. Zhou, B. Sandberg, Z. Chen

Effects of microsilica and reactive alumina type on flowability, flow decay and working time of Al2O3-SiC-C castables for blast furnace trough were investigated. The results show that at a targeted self flow values of (80 ± 10)%, water demand markedly decreases with increased microsilica addition. The nature of reactive alumina has a strong influence on flowability of the castables. Higher microsilica content contributes to a longer working time. The flow decays gradually until the working time and then drops abruptly. In addition, microsilica have positive effect on both cold strength and hot strength.

Jan 1, 2004

By K. Fujita, T. Kikuchi, Y. Sakamoto

Ceramic fibers were classified as a category 2 carcinogen by The European U legislation. Therefore we developed non-fibrous insulating castable which utilizes n porous aggregate, which is composed of Calciumhexaluminate. Although at beginning we applied alumina cement as binder for non-fibrous insulating castable, kind of formulation had a poor resistance to spalling. We developed non-fibrous insulating castable without alumina cement. This solved a problem which pre\ formulation had a poor resistance of spalling. We applied a new non-fibrous insub castable for reheat furnace in steelworks, then we could achieve good result which condition equivalent to ceramic fiber insulating castable.

Jan 1, 2004

By Brian Putland, Fred Kock, Leigh Siddall

Single stage semi-autogenous / autogenous (S/AG) milling has become a common design for a variety of ore types with the advantages of being comparatively low capital cost and flexible for future expansion. The single stage SAG/AG milling option is ideal for starter projects with significant exploration and expansion potential. Currently a number of the largest SAG mills designed are installed in single stage configuration. This paper discusses the challenges associated with the process design of single stage SAG/AG milling circuits, the design flexibility required to ensure a robust circuit and the operating techniques adopted at successful installations.

Jan 1, 2012

By Shamil Shaikhutdinov

CO adsorption on gold particles deposited on well-ordered alumina and various iron oxide films has been studied with temperature programmed desorption (TPD) and infrared reflection adsorption spectroscopy (IRAS). Structural characterization has been performed with scanning tunneling microscopy. Data show that the CO adsorption exhibits a size effect in that small particles adsorb CO more strongly. The effect generally vanishes after annealing to 500 K. For annealed samples, CO TPD and IRAS spectra are nearly independent of the particle size and supports studied. The results indicate that the CO interaction with gold surfaces is essentially similar and involves low coordinated atoms.

Oct 1, 2003

By Yasser Mohamed

Daily field management of earthmoving operations requires quick and regular decisions for allocating available equipment to different jobs on a project. A general foreman?s day starts with matching several activities with a suitable set of available equipment to achieve the highest productivity and lowest unit cost. Usually, this decision-making process needs to be quick, and depends to a great extent on the foreman?s experience, which varies from one individual to another. Many analytical solutions with various degrees of sophistication and optimization exist to address such decisions. However, adopting any of these solutions is contingent on how accessible and easy-to-use the solution is. This paper discusses the development process of a webaccessible solution for evaluating earthmoving fleet composition and allocation scenarios. The solution relies on discrete event simulation and an optimization backend engine, but introduces the user with a simplified and easy-to-use interface that is accessible from any mobile device, and is customized to specific user?s needs. The developed system gathers most equipment and site-related input data from a company?s information systems to minimize user input. The user mainly needs to formulate equipment and job combinations and allocation scenarios (e.g. soil type, quantity, and hauling distance), according to equipment availability each day. Then the system will evaluate the productivity and unit cost estimates for each scenario, allowing the user to choose the most suitable one. It may also be used to automatically recommend the optimum solution given an available list of equipment. The paper presents the process followed in prototyping the proposed system in collaboration with a major Canadian earthmoving contractor, and customizing it to the user needs within the company. It also describes the overall structure of the developed system and its core simulation model.

Aug 1, 2013

By R. F. Favreau

"After a blast, the volume of the blasted rock normally occupies more space that it did before the explosion. The degree of such swell significantly affects the efficiency of digging the muck with a shovel or dragline. This paper explains why swell occurs, and describes the new subroutine SWELL of the blast simulator BLASP A which can simulate blast-induced swell. Results are also presented which display the effect of various blasting parameters on the degree and distribution of the swell within the muck pile of a bench blast. IntroductionIt is a common opinion that fragmentation is the most important of the various aspects which affect the efficiency of excavating rock with explosives. This paper proposes that, in fact, displacement and swell of the blasted rock are as important as fragmentation if the excavation process is to be rapid and efficient. It must ""a priori"" be recognized that a minimum degree of fragmentation is indeed necessary. For a given shovel or dragline, this minimum degree of fragmentation may be defined as follows: even the largest fragment of rock must be easily contained within the bucket. Once this criterion is met, however, there are good reasons to believe that displacement and swell take over as the key criteria which influence the rate of mucking, in cubic metres/hour. If the muck pile is not well displaced and swelled, the teeth of the bucket have difficulty penetrating between the rock fragments even if fragmentation is good and, as a result, the mucking is slow and inefficient. The purpose of this paper is to use computer simulations on the model BLASP A to demonstrate the effect of the blast design parameters on the displacement and swell of the blasted rock."

Jan 1, 1993

By T. T. Chen, J. E. Dutrizac, G. Poirier

In the Waelz kiln process, EAF dust is converted to an Fe-rich slag, a (Zn, Fe)-rich dust that is recycled to the kiln and the Zn-rich Waelz oxide which is subsequently up-graded for the recovery of zinc. To clarify the reactions occurring, the Waelz kiln products from a European Waelz plant were characterized mineralogically to determine the mineral species present, their micro-textures and the metal carriers. The EAF dust contains 27 % Zn, and consists mainly of ZnFe2O4 and ZnO, together with minor to trace amounts of NaCl, PbCl2, KCl, CaO, Ca2Fe2O5, Fe203, FRO, Pb oxide and various Ca-Fe-Al-Mn silicates. The KCI and NaCI sometimes agglomerate the other particles. The slag consists of nodules which often exhibit colloform structures. The slag contains of variable amounts of Fe, FeO(OH), FeO, gypsum, Ca(OH)2, Ca2SiO4 and various Ca-Fe¬Al-Mg-Mn silicates as well as minor to trace amounts of ZnFe2O4, Cr-Fe oxide, Mn-Fe oxide and other species. The Waelz oxide contains 57-61 % Zn, and consists predominantly of ZnO, with minor to trace amounts of KCI NaCl, Pb(OH)Cl, Pb20(SO4), Pb chloride, ZnSO4, ZnFe2O4, Ca2SiO4, Ca2Fe2O5, Ca-Fe silicate and NaZn4(SO4)(OH)6Cl.6H2O. The KCI agglomerates the other particles in the Waelz oxide. The recycled dust appears to be a mixture of EAF dust and Waelz oxide, but it contains relatively more coarser-grained metallic Pb and Pb oxide particles.

Jan 1, 2004

By A. J. Sinclair

Abstract-Exploratory data evaluation is an essential part of every high quality, mineral inventory estimate. Efficient analysis involves a thorough organization of available quantitative data that are the basis of the estimate and perhaps the formation of composite grades. Data organization and evaluation can involve more than 50% of the time necessary to conduct a mineral inventory estimation. The principal purpose of exploratory data evaluation in mineral inventory work is to improve the quality of estimation by providing insight into characteristics of the variables under investigation. Specific aims include: (1) to recognize and eliminate errors; (2) to provide a comprehensive knowledge of the statistical characteristics of all variables of interest for resource/reserve estimation; (3) to document and understand the interrelationships among the variables of interest; (4) to recognize systematic spatial variation of variables such as grade and thickness of mineralized zones; (5) to recognize and define distinctive geological domains that require independent estimation of mineral inventory; (6) to identify and characterize outliers; and (7) to evaluate similarity/dissimilarity of various types of raw data, especially samples of different supports. These aims are not mutually exclusive but they can all have their own impact on resource/reserve estimation. Error must be minimized. Individual variables can have characteristics that lead to different decisions in the course of estimation. Similarly, interrelations of variables might contribute to the ease (or difficulty) with which estimates of several variables can be obtained. Trends can impose the need for two or more domains, each of which might be estimated independent of the others. Outliers, a perennial problem, require detailed evaluations because they impact on reserves much out of proportion to their abundance. Data, of widely different supports, generally must be standardized if all are to be used for purposes of estimation.

Jan 1, 1998

By D. Perednis

Fuel cells with thin samaria-doped ceria (SDC) electrolyte films deposited onto an anode support using spray pyrolysis were fabricated. The SDC films were deposited onto porous NiO-YSZ substrates at deposition temperatures between 400°C and 450°C. The influence of process parameters such as deposition temperature, flow rate, type of salt and salt concentration on the quality of the film was studied. A smooth dense film was successfully deposited using the precursor cerium ammonium nitrate and samarium nitrate dissolved in butyl carbitol (33.3 vol.%), 2-methoxy-l-propanol (33.3 vol.%), and ethanol (33.3 vol.%) solvent mixture. A deposition rate of 125 nm/h was achieved.

Jan 1, 2005

The Rabbit Lake In-Pit Tailings Management Facility contains frozen layers of tailings due to subaerial deposition during the coldest periods of winter. Thawing is required to ensure full consolidation of the tailings and to regain disposal space presently occupied by ice. Electric resistance heating has been used to heat soil for bitumen extraction and remediation of volatile contaminants. A preliminary evaluation of the application of electric resistance heating to thaw about 0.3 cubic metres of frozen tailings was conducted using tailings frozen at about -2 oC. Visible thawing of the tailings mass was observed after 25 hours, demonstrating the feasibility of this approach.

Aug 1, 2010

By X. Wu, W. R. Chen, J-G. Legoux, B. R. Marple, E. Irissou

Cold gas dynamic spray (CGDS) has been considered a potential technique to produce the metallic bond coat for TBC applications, because of its fast deposition rate and low deposition temperature. This paper presents the influence of spray processes for bond coat, including air plasma spray, high velocity oxy-fuel, and in particular CGDS, on the oxidation performance of TBCs with a Co-32Ni-21Cr- 8Al-0.5Y (wt.%) bond coat. Oxidation behaviour of the TBCs was evaluated by examining the coating microstructural evolution, TGO growth behaviour, and crack propagation during thermal exposure at 1050°C. The relationship between the TGO growth and crack propagation will be discussed.

Jan 1, 2010

By D. C. Van Aken, O. J. Rajtora

A research effort sponsored by the Department of Energy (DOE) and several steel producers, is investigating the benefits of coating steelcasting nozzles with various materials. Coatings were applied to casting simulation nozzles made from industrial tundish nozzles (primarily of magnesia) and industrial submerged entry nozzles (SEN's) (primarily of alumina-graphite) in order to extend casting time prior to nozzle clogging. Nozzles were coated by air plasma spray (APS) using a 9M series APS system from Sulzer-Metco. The ability of these coatings to provide protection from clogging was evaluated using a steel casting simulation. Substrate-coating compatibility was characterized using optical and SEM microscopy.

Jan 1, 2004