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By J. Aguilar-Santillan, H. Balmori-Ramirez, R. C. Bradt, I. Vernet-Patiño, F. Cunha

Kyanite is an alumino-silicate mineral that has been widely used for the production of refractory products for industrial applications. Kyanite provides a high alumina content, it readily produces mullite during firing, good hot strength of products and can be adapted to produce dimensional stability of products during firing. This research addresses the application of kyanite in mixes to produce (0 dense mullite aggregates with the addition of alumina, (ii) dense composite refractory aggregates of forsterite / spinel with additions of magnesia, and (iii) dense cordierite aggregates with the addition of talc. Effects of attrition milling and conventional ceramic processing are addressed as they affect the properties of these unique aggregates.

Jan 1, 2004

By J. H. Baek, S. Alexandrovskii, D. W. Lee, B. K. Kim

Nano-phase titanium carbide was synthesized by Mg-thermal reduction process using a novel route of Mg-thermal reduction. The processes are based on I) feeding of TiC14+CxC14 x = 1, 2 ) solution into liquid magnesium, 2) Mg-reduction of metal chlorides, 3) TiC formation by the reaction of released Ti and C atoms, and 4) vacuum separation of residual liquid phases of Mg and MgCl2. In this study, the process for titanium carbide production with composition close to stoichiometry and the minimum content of impurities was optimized with the various process parameters such as concentration of initial solution, its feeding rate and reaction temperature, as well as a kinetic study.

Jan 1, 2004

By C. Kuehmann, B. Tufts

QuesTek Innovations has applied its Materials by Design® methodology to computationally design a new ultra high-strength corrosion resistant steel. Ferriurn® S53 eliminates the need for toxic cadmium coatings currently used on conventional steels in landing gear systems. S53 has the strength of 300M steel, and corrosion resistance similar to 15-5PH stainless steel. S53's corrosion resistance improves stress corrosion cracking resistance and reduces susceptibility to hydrogen embrittlement, improving component reliability and providing an opportunity for extended overhaul and repair intervals. Ultimate tensile stress is 1965 to 2000MPa. S53 was designed to be mechanically equivalent to 300M, with the key addition of intrinsic corrosion resistance. Alloy design, microstructural characterization, and mechanical properties are discussed herein.

Jan 1, 2006

By Sadough vanini Ali

The silicon anisotropic wet chemical etching technique is widely employed for fabricating various microelectromechanical system (MEMS) structures for advantages such as simple etching equipment and its capability to fabricate special microstructures. In this paper, we consider a complete theoretical derivation of the analytical solution based on geometrical and kinetic aspects of step flow on any surface and with a mathematical method we derive new equation for calculating the microscopic etch rates of surface atoms for a new range of concentrations and temperatures. Furthermore, a novel equation is presented for the calculation of the microscopic activation energies for some typical surface atoms and a new comparison of activation energies between some atoms is made that divides atoms into three categories. The results demonstrate agreement with the experimental results.

Oct 1, 2011

By J. Larose, E. Irissou

The aerospace business has always been driven by innovation. A significant portion of the overall business technology development strategies is still based today on improved materials and coatings. In this highly regulatory business environment, large amounts of funding are required to increase the maturity level of novel technologies, but the evolution process still remains a delicate endeavor. The technical risks involved during technology development obviously need to be managed and mitigated throughout the development cycle, but other hurdles almost inevitably get encountered, such as budget limitations, transition from lab scale to production scale, loss of focus, intellectual property negotiations and supply chain integrity. This presentation will cover some of the issues raised when a great idea is slowly morphed into an aerospace production part.

Jan 1, 2010

By J. Fournier

A novel sol ? gel (SG) synthesis procedure utilizing varying ratios of glycine and ethylene glycol to total metal cations has been developed to create high purity nanometer sized La0.65Sr3.5MnO3 powders. X-ray powder diffraction (XRD), transmission and scanning electron microscopy (TEM, SEM), and dynamic light scattering (DLS) have confirmed that the crystallite sizes of such powders are ~ 20 nm, and the aggregate particle sizes vary between 100 to 300 nm. Mixing varying weight percents of SG LSM powders with commercially available Praxair LSM in a composite LSM/YSZ functionally graded cathode has been shown, through the use of electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV), to exhibit enhanced oxygen reduction kinetics vs. at conventional cathode materials.

Jan 1, 2005

By J. Fournier

A novel sol ? gel (SG) synthesis procedure utilizing varying ratios of glycine and ethylene glycol to total metal cations has been developed to create high purity nanometer sized La0.65Sr3.5MnO3 powders. X-ray powder diffraction (XRD), transmission and scanning electron microscopy (TEM, SEM), and dynamic light scattering (DLS) have confirmed that the crystallite sizes of such powders are ~ 20 nm, and the aggregate particle sizes vary between 100 to 300 nm. Mixing varying weight percents of SG LSM powders with commercially available Praxair LSM in a composite LSM/YSZ functionally graded cathode has been shown, through the use of electrochemical impedance spectroscopy (EIS) and cyclic voltammetry (CV), to exhibit enhanced oxygen reduction kinetics vs. at conventional cathode materials.

Jan 1, 2005

By M. L. F. Gameiro

The aim of this study was to check the feasibility of non-dispersive solvent extraction to recover copper from ammoniacal solutions using hollow fibres as contactors. Data of mass transfer using the B3-diketone LIX 54 as extractant was obtained. The influence of tube and shell hydrodynamics on the extraction rate of copper was studied. The overall mass transfer coefficient of copper was calculated from the experimental data by performing steady state material balance. Simultaneous extraction and stripping experiments were carried out using different volume ratios of feed phase to stripping phase. The results obtained showed that practically all the copper content was removed from the ammoniacal feed solutions. The recovery of copper reached nearly 100% in several extraction-stripping experiments.

Jan 1, 2007

By M. J. Hadianfard

The effect of holding at temperature on fatigue life of a 10 vol% particulate SiC reinforced Titanium alloy has been investigated. The influence of holding time at 600°C on fatigue of this material has been studied by using tension-compression tests, scanning electron microscope and image analysis. The specimens were heated to 600°C by using a controlled atmosphere furnace; hold at this temperature for time ranging from 0 to 100 hours, and then fatigue tested at room temperature under controlled constant plastic strain. The number of cycle to failure found to decrease with increasing of the holding time. In addition the fracture mechanism and number of debonded particles has been significantly influenced by holding time at 600°C.

Jan 1, 2004

By T. Watanabe, M. Nakagawa, K. Kimapong

Lap joint of A5083 aluminum alloy and SS400 steel was produced by Friction Stir Welding (FSW) Process. The effect of welding parameters such as rotational speed, traverse speed and tool dimensions on the mechanical properties and the interface microstructures of the joints were investigated. FSW process could successfully produce the lap joint between A5083 aluminum alloy and SS400 steel. The variations of rotational speed, traverse speed and pin depth of a rotating tool gave rise to various characteristic interfaces of the lap joint and had conspicous influences on the joint properties. The increase in hard and brittle intermetallic phase and defects formed at the interface of the joint decreased the mechanical properties such as the shear load of the joint.

Jan 1, 2004

By H. Dundar, C. Dzomeku

An extensive testwork was performed around the HPGR plant at GoldFields Ghana Limited Tarkwa Gold Mine. The HPGR was used to prepare the feed for heap leaching. The circuit was configured in such a way that the edge material from the HPGR discharge was recycled for further crushing while the product from the centre reported to the heap leach section. The set-up of the Polysius HPGR provided an opportunity to study the effect of different design and operating variables. This paper will discuss the results from the tests performed to assess the effect of rolls’ speed and applied pressure on the capacity and the grinding efficiency of the HPGR. Applying different pressure values appeared to have an influence on the amount of edge material recycled.

Jan 1, 2012

By A. Fischersworring-Bunk

The new inline six spark-ignition engine is the realization of BMW's concept of efficient dynamics at high technological level to achieve the attributes of low weight and high efficiency, The paper presents different aspects of the development and manufacturing of BMW's inline six-cylinder engine magnesium-aluminium composite crankcase, Reference will be made on the AJ magnesium alloy optimization approach to balance between mechanical properties and the high pressure die cast ability requirements, Next to this aspect some mechanical design issues will be covered, with CAE methods playing an instrumental role in the early project stage for the assessment of the compound concept, Due to the compound design chosen, the interface posed challenges to both design and productions, A set of novel techniques has been used to cope with these tasks.

Jan 1, 2006

By A. Chaisantikulwat

Most solid-oxide fuel cell (SOFC) modeling emphasizes steady state cell operation. However, understanding the dynamic behavior is essential to predict the performance and limitations of SOFC power systems. In this work, we demonstrate a dynamic model of a SOFC, and we simulate a feedback control scheme that can maintain output voltage despite load changes. Dynamic response is determined as the solution of coupled partial differential equations derived from conservation laws for energy, mass and electric charge. From such a model, the step responses to system input variables can be determined. Low order dynamic models that are sufficient for feedback control design can be derived from the step responses. The development of the partial differential equation model is outlined, and the limitations of the control system are discussed.

Jan 1, 2005

By J. Gao

We present results from our investigation of the concept and practice of using surface-charged latex nanoparticles as building blocks for conductive membranes. Nanoparticles were synthesized by free-radical co-polymerization of two hydrophobic monomers, butyl acrylate (BA) and methyl methacrylate (MMA), a crosslinker, N, N'- methylenebisacrylamide (BIS), and a charged monomer, sulfonate styrene sodium salt (NaSS), in water. The resultant nanospheres were characterized with static and dynamic laser light scattering. Thin films were cast from concentrated particle dispersions, followed by incubation at ?110 °C. Conductivity, water uptake and final charge content were measured. The membranes have higher conductivities than both amorphous films cast from sulfonated BA-MMA-Styrene copolymer chains and BA-BIS-MMA-NaSS gel films. TEM images and neutron scattering spectra confirm the particulate structure of the membranes.

Jan 1, 2005

By Robert J. McCarthy

There are two things on everyone's lips when mining folks gather these days - one is the exciting business opportunities that now exist for mine development and expansion, and the other is the dire shortage of human resources needed to design, manage, and even operate the mines. Years of stagnant industry growth, limited employment opportunities, and unwarranted perceptions of remote and harsh working conditions have caused mining to be a less than desirable career choice. Attrition and reduced entry to the workforce has resulted in shortages for not only mining professionals, but also skilled trades people and operators. Consequently, to survive, let alone grow, mining companies, suppliers, and educators are all pursuing innovative solutions with technology, inter-industry recruiting, centralized services, and strategic partnerships. This paper describes some of these initiatives and proposes others, now that the people are gone!

May 1, 2008

By A. Morales

Flue dusts from a copper smelting furnace (continuous furnace), have been extensively characterized. The main phases detected have been cuprospinel, anhydrous copper sulfate (chalcocyanite), lead sulfate (anglesite) and arsenic oxides (claudetite and arsenolite). As minor phases, zinc sulfate (zincosite) and several copper or copper/iron sulfides were detected (digenite, anilite, bornite, cubanite), and also a copper oxide (tenorite). The suspension of this material in water leads to the partial dissolution of copper and zinc (chalcocyanite and zincosite) and arsenic oxides. The hydrocyclone classification of the residue makes it possible to obtain two fractions: a copper-rich coarse fraction and an arsenic-rich fine fraction. The coarse fraction can be recycled to the smelting furnace and the fine fraction can be mixed with wastewater sludge from a paper factory, to make both residues inert before disposing them to landfill.

Jan 1, 2007

By M. Reza Bateni, M. Zandrahimi, J. A. Szpunar

Titanium aluminides and nickel aluminides offer the potentials, as coating materials, for high temperature and aerospace applications. In this research, attempt has been made to develop Al-Ti and Ni-Al intermetallic compound coatings on the surface of Inconel 738. The coatings applied through pack cementation and simultaneous diffusion annealing processes. Scanning-electron microscopy (SEM), energy-dispersive X-ray spectrometry (EDAX) and grazing angle X-ray diffraction were used for evaluating of coating structure. It was demonstrated that the pack cementation technique could be used to develop TiAl3 and AlNi intermetallic compounds coating on Inconel 738 substrate. When pack cementation technique is based on a halide-activated pack with aluminum and titanium powders, the coating consists of TiAl3 intermetallic compound phase. Whereas, by pack aluminization of Inconel 738, the coating consists of AlNi intermetallic compound phase.

Jan 1, 2004

By Daniel B. Leznoff

The cyanoaurate anions [Au(CN)2]- and [Au(CN)4]- are shown to be useful building blocks for synthesizing supramolecular coordination polymers. For the gold(I) unit, aurophilic interactions often increase the structural dimensionality of the system and can impart increased thermal stability to the metal-polymers produced. A series of polymers of the form M[Au(CN)2]2(Ligand)x have also been prepared and show large colour changes upon changing the ligand, thus illustrating a sensor-type application. Both building blocks can mediate significant antiferromagnetic and ferromagnetic interactions between transition-metal centres in the polymers. For the gold(III) unit, no metal-metal interactions are observed, although weak Au-N(cyano) interactions control the intermolecular packing. Several structural examples of cyanoaurate-based coordination polymers are presented, including 2-D and 3-D arrays and a supramolecular square.

Oct 1, 2003

By M. Bueno

Between 1993 and 2003, a series of AG and SAG mill pilot plant trials were conducted using Hardinge Ical pilot plant scale SAG mills on numerous ore samples and ranging across a wide variety of operating conditions. The data from these tests were used to evaluate the design of SAG and AG mill circuits for over a dozen projects, of which about half were eventually constructed and commissioned. The data were also used in the development of SAG mill modelling, scale-up and simulation procedures by several consultants who had access to part of the data set. Recently, we have had the opportunity to bring this data together and further analyse the consolidated dataset. This paper reports on the outcomes of this analysis that has identified the impacts of different AG/SAG circuit flowsheets and operating conditions on energy efficiency and operating cost.

Jan 1, 2012

By A. D. Akerman, D. D. Young, G. R. Baiden

The development and maintenance of underground roadways are increasingly important aspects of the modern mining process. With the trend toward automation and track-less mining, roadbeds capable of with standing increased wheel loading have proven necessary to maintain high vehicle speed and reduced maintenance costs. Concrete has been used successfully on some roadways in order to obtain the required characteristics. However, this solution usually involves unacceptable expense. The objective of the Road Router project was to create a drift floor profiling machine capable of cutting a smooth surface out of the existing rock floor of development drifts and ramps. This surface would provide a durable, high strength, low rolling resistance roadbed that would allow for reduced operating cycle times and lower maintenance costs of scoops and haulage trucks. The Road Router has the potential to offer an alternative to concrete with substantial cost savings.

Jan 1, 1997