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By D. R. Taylor

Treatment of bentonite clay with mineral acids yields a modified clay product of high surface area and acidity which exhibits enhanced adsorptive and catalytic properties. A highly specialized segment of the clay industry based on this process has evolved into worldwide business with a capacity of about one-half million tons/yr. This paper will present data on the chemistry, mining, manufacturing and applications for acid- activated clays.

Jan 1, 1986

By Rudolf Fahn

Bentonites are best suited for the preparation of acid activated clays with efficient adsorption properties. They are weathering products of acid volcanic ashes and their natural deposits are world-wide spread. The main constituent of bentonite is the aluminium hydrosilicate nontmorillonite with a high ability to swell. Süd-Chemie owns bentonite deposits in Germany and subsidiaries in Italy, Mexico and Arizona.

Jan 1, 1979

By R. Fahn

Bentonites are best suited for the preparation of acid activated clays with efficient adsorption properties. They are weathering products of acid volcanic ashes and natural deposits are spread worldwide. The main constituent of bentonite is aluminum hydrosilicate montmorillonite with a high ability to swell. Physical and Chemical Properties of Montmorillonite The clay mineral montmorillonite is named after its place of discovery, near Montmorillon in southern France. The structure of this clay is shown in [Fig. 1]. The montmorillonite crystal consists of about 15-20 silicate plates. Each silicate plate is composed of three layers. The central one is formed by aluminum or by ferric hydrate octahedrons, the two outer ones consist of silicon dioxide tetrahedrons. In the presence of water, the montmorillonite crystal swells and water molecules become deposited between individual silicate layers. Two types of natural bentonites are known: the Western type, which is a natural sodium bentonite (high swelling grade), and the Southern type, an alkaline earth or calcium bentonite (low swelling grade). Southern bentonites have efficient adsorption properties of their own. They are called natural active earths or fullers earths. Acid Treatment of Bentonite Under the influence of a mineral acid, the exchangeable alkaline earth ions of bentonite are substituted by hydrogen ions. Moreover, depending on the acid concentration, temperature, pressure, and reaction time, a more or less pronounced leaching process takes place. Thereby Al-, Fe-, and Mg-ions are extracted from the octahedron layers. This results in a change in the crystalline structure of montmorillonite and in an increase of its specific surface area and porosity, as shown in [Fig. 2].

Jan 1, 1983

By Robert J. McNally

There are three primary plant nutrients-nitrogen, phosphorus, and potassium--expressed in any fertilizer compound as percent N, percent P2O5, and percent K20, in that order. This article will be concerned with the first two. The chief source of P205 is phosphate rock. As found in the western states phosphate rock is essentially tricalcium phosphate-calcium fluoride (fluorpatite). As such, it is quite water insoluble. The principal phosphate fertilizer used is single superphosphate, produced by reacting sulfuric acid with phosphate rock in the proper proportions.

Oct 1, 1956

By C. J. Brown

Since its commercialization thirty years ago, the Recoflo® short bed ion exchange process has been extensively utilized for the recovery of a wide variety of acids and metal salts. In addition to a reduction in resin bed height from 200 cm to 300 cm to 15 cm to 60 cm, the process has a number of features such as utilization of fine mesh resins in a compressed bed which together make it ideal for a number of applications. The process has been extensively exploited, for example, in the metal finishing industry for recovery of valuable chemicals from electroplating, anodizing, etching and pickling wastes. More recently, it has also been applied in the primary metals industry for purification of copper electrolytes and metals recovery from leachates. The paper discusses several of these applications and some of the issues that were found to be key to their success.

Jan 1, 2004

By Collins D. N

The Olympic Dam Copper Smelter Acid Plant is a hybrid plant capable of producing sulphuric acid from either sulphur burning, metallurgical gases or a combination of both. Commissioning of the Acid Plant on sulphur burning commenced in early April 1988 and commissioning on combined sulphur burning and metallurgical gas commenced in August 1988. During commissioning on sulphur burning a number of acid spills occurred due to balancing of tower flows and control of acid dilution. A number of other significant problems were encountered including failure of boiler gaskets, failure of strong acid pumps seals, the fracture of the teflon dilution water injector and the subsequent failing of the acid circulation pump, tank steel failures and various instrumentation problems. The Commissioning of the Acid Plant on metallurgical gases commenced in August and with the exception of the production of oleum in the boiler economizer was relatively trouble free. Oxygen Plant commissioning commenced in May 1988 and was without significant incident. An outline of the basic equipment for the Acid Plant and Oxygen Plant is presented together with aspects associated with the commisisoning of both plants.

Jan 1, 1989

By T. Patten

Inter-Mountain Labs, IML, performed a study comparing mining waste rock sample analysis by Net Carbonate Value (NCV) and Modified Sobek acid-base accounting procedures. The study looked at 468 waste rock samples and compared the data for Neutralization Potential (NP), Acid Generation Potential (AGP), Net Neutralization Potential (NNP), and the ratio of NP/AGP. The study found that a majority of the samples were below 50 Tons CaCO3/kTons. This subset of ?low-level? samples was also examined separately for Acid Base Accounting parameters. The analysis compared the NCV procedures to the Modified Sobek procedures and concludes that the NCV procedures are as protective of the environment as Modified Sobek procedures.

Feb 27, 2013

By M. Misra

The removal of lead and other heavy metals present in an active US Army small arms firing range soil was evaluated in a pilot scale test program at Ft. Polk, Louisiana. Two different acid based extraction processes in conjunction with conventional physical separation methods were used. Physical separation processes consisting of screening and gravity operations removed most of the coarse lead particulates and slugs. Hydrochloric acid leaching followed by precipitation of lead as hydroxide recycled clean soil containing less than 500 mg/L. total lead and less than 5 mg/L TCLP lead. Lead extraction efficiency with hydrochloric acid was 96 percent. The results of lead removal by physical separation in conjunction with acetic acid leaching were not consistent over the whole test period and the total soil processed.

Jan 1, 1998

By S. A. Braley

Drainage of acid mine water into surface streams of coal mining areas is one of the most serious problems of stream pollution, since there is no known method that completely prevents its forming and no economically feasible treatment after it has formed. The mine acid problem differs from other pollution hazards because acid production does not end with cessation of mining but actually becomes more evident when pumping is stopped. The acid problem in the Pennsylvania, Ohio, West Virginia, and Kentucky bituminous coal areas of the U. S. began with the first operation in 1761, and the volume of acid discharge today is largely the cumulative result of years of mining. Provided they lie above the drainage area, the oldest mines, now long abandoned, are almost without exception producing acid in the same manner as those now operating or recently abandoned.

Mar 1, 1956

By J. Lu

The impact of acid treatment in agglomeration/acid curing on copper extraction and acid consumption was investigated with respect to acid dosage and moisture. Without the addition of water, no agglomeration occurred. At an acid dosage above 15 kg/t, the acid was not completely consumed during acid curing. With the addition of 6.2% water, the particles agglomerated together. Copper, iron, magnesium and manganese were dissolved as sulfates and enriched in the fine fraction of the ore. The copper extraction and net acid consumption increased with increasing acid dosage. The copper extraction for acid curing with the addition of 6.2% water was higher than that without the addition of water due to the improved permeability and the increase in the contact with acid-soluble copper. During acid curing, the reaction of sulfuric acid with muscovite, abite and nacrite mainly took place on the surface of the particles while the reaction of sulfuric acid with clinochlore occurred not only on the surface but also inside the particles.

Jan 1, 2007

By Gus Van Weert, Samuel A. Bolorunduro, David B. Dreisinger

"Silver is currently lost as jarosite during the pressure oxidation of sulphides and cyanidation of the residues yields 5-10% of silver. Efforts to recover silver from complex sulphides, which contain economic fractions of silver require an understanding of the behaviour of acanthite during pressure oxidation. However, previous studies of acanthite (Ag2S) reaction have been complicated by the formation of argento-jarosite and uncertainties arise on the interpretation of the results.In this work, the acid pressure oxidation of high-grade natural silver sulphide mineral (acanthite) was carried out at 110-150°C and under the conditions similar to that of pressure oxidation of complex sulphide. The predominant product of reaction is elemental sulphur. The rate of reaction increases with increasing temperature and with the presence of ferric ions. The kinetics is controlled by chemical reaction with activation energy of 72.6 kJ/mol. The rate of reaction decreases with the presence of silver sulphate in the initial slurry. The proposed overall reaction is close to: []"

Jan 1, 2003

By Gus Van Weert, Samuel A. Bolorunduro, David B. Dreisinger

"INTRODUCTIONAcid pressure oxidation of high-grade natural acanthite was investigated in the range of 110-150°C and in the sulphate media. High acidity and low pulp density were used to prevent the precipitation of silver.RESULTS AND DISCUSSIONTwo sets of acanthite specimens were obtained from La Valenciana and Ingleterra mines, Mexico. Pressure oxidation tests were conducted on 1 litre scale in a standard 2-litre Parr titanium autoclave.EFFECT OF TEMPERATURE ON THE REACTION OF ACANTHITEThe effect of temperature on the rate of oxidation is presented in Figure 1. The rate of reaction increased with increasing temperature."

Jan 1, 2003

By Douglas G. Fox

Outputs from industrial activities planned in the Riley Ridge natural gas project are modeled to determine the potential locations of air pollution impacts on the Bridger and Fitzpatrick Wildernesses in Wyoming. The nature of modeling, especially with regard to its realism, is discussed. Alpine lakes which, along with their watersheds, have minimal buffering capacity are being studied because of their sensitivity to acidic deposition from proposed new air pollution sources. A hypothesis which relates a source's emissions to deposition and lake chemistry in a worst-case sense is presented. Research designed to test the hypothesis and reduce uncertainties is outlined and progress reviewed. Focus is placed on the meteorological transport and atmospheric deposition parameterization contained in the hypothesis.

Jan 1, 1984

By T. van Sandwijk, G. Van Weert, E. Molleman

This paper reports on test work that explored the dissolution/precipitation reaction: ZnS + 2HCl - ZnC12 + H2S, which is part of a process used in the production of pure ZnS. The research focused on the influence of proton activity on the dissolution of zinc concentrates obtained from the Brunswick Mine No. 12 in Canada (Brunswick Mining & Smelting); the Red Dog deposit in Alaska (Cominco Ltd.); and the Tara deposit in Ireland (Outukumpu Zinc). A comparison between the results of the experimental dissolution as a function of pH and the dissolution predicted by thermodynamics suggest that the three concentrates contained sig¬nificant amounts of the more reactive mineral wurtzite, although XRD analysis showed mainly the presence of the mineral sphalerite.

Jan 1, 1999

By S. A. Braley

THE first commercial production of bituminous coal in the United States was in 1820, and formation of acid in the areas from which the coal was removed began at that time. Thus it is 130 years since the development of mine acid began. The coal operator has had to deal with the acid water produced in his mines, and his losses from corrosion of pumps and equipment have been tremendous. Other industries and the public have been forced to spend large amounts for their water requirements because of the acid discharge from the mines. There are many contradictions in the literature on this subject probably because of variations in the analytical procedures followed and differences in the methods of calculation and reporting. The opinions previously expressed may be summarized as follows:

Jan 8, 1951

The New South Wales Department of Mineral Resources has, since 1974, administered the Derelict Mines Rehabilitation Program (DMRP) to reduce the environmental impacts of abandoned and orphan mine sites. The application of the DMRP is presented in case studies of sites from the South Maitland Coalfield featuring residual drainage of acidic and saline water in a semi urban and rural community setting. The acidity here is typically derived from iron oxidation in shallow underground coal mine workings and in surface emplacements of coal washery reject materials. This paper presents summary information on AMD investigation, monitoring and rehabilitation. The experiences of community expectation, stakeholder consultation and peer review are discussed.

Jan 1, 2003

By Charles A. Sorrell

Two red muds, two fly ashes, and several aluminosilicate minerals were subjected to direct treatment with concentrated H2SO4 at temperatures of 175°C and below. X-ray analysis showed that virtually all the sulfate reaction products remained in the solid residue because of their low solubilities in x SO Substantial portions of the Al2O3 Fe2O3TiO2, Na2O, and K2O components of the materials reacted to form water soluble sulfates, which were then removed by H2O leaching at 55°C. The solid residue after water leaching consisted largely of amorphous silica and, in lime bearing compounds, CaSO4, The reaction and leaching processes were effective in removing all or nearly all the Al2O3. Fe2O3, TiO2, Na2O, and in lime components in the fly ashes, red muds, china clay, bentonites, the nephelioe fraction of nepheline syenite, and a plaster insulating brick composed of anorthite and mullite. Reaction with potassium feldspar and petalite took place, with formation of alkali aluminum sulfates, but the reaction rates and yields were extremely low. Potassium feldspar can be heated with Na2O and x O in air at 700°C for 24 hours, or with CaO at 1000°C for 24 hours, after which the reaction product kaliophilite, nepheline, and leucite-like phases, prove to be very susceptible to H2SO4, reaction and H2O leaching, providing yields near 100% of the Al2O2 content. An alternative method of H SO treatment consists of heating the sample in a silica tube and passing H2SO4 vapor over it. Preliminary results indicate that this method can be effective in enhancing the kinetics of reaction with the Al O component of potassium feldspar and offer the possibility that formation of Al2 (SO ) Fe2(SO4)3 and TiOSO4 can be accomplished selectively by taking advantage of the fact that the upper stability limits of the respective sulfates in the presence of H2SO4 vapor will be different.

Jan 1, 1982

By L. W. Beckstead

The use of acid ferric sulfate solution as a lixiviant for chalcopyrite concentrates has been of little interest from a practical standpoint due to the formation of a tenacious layer of elemental sulfur which severely impedes the reaction progress. CuFeS2 + 4Fe+3 ?Cu+2 + 5Fe+2 +2s° For example, an acid ferric sulfate leach of chalcopyrite concentrate results in only 12% copper extraction in a three hour leach at 93°C. Experimental results suggest that particle size is the only controllable variable which has a significant effect on the rate of acid ferric sulfate leaching at ambient pressure. Size reduction of the concentrate prior to leaching was exam¬ined using various methods of grinding. Of the grinding methods considered, attrition grinding was found to be the most effective. Leaching of an attritor-ground product (median particle size 0.5 microns) resulted in approximately 90% copper extraction in a three hour leach at 93°C. Energy measurements suggest that the costs associated with attrition mill¬ing are not unreasonable. Evidence indicates that "activation" or stored strain energy is not responsibile for the enhanced reaction kinetics of the finely ground concentrate, but rather the experimental results can be explained simply in terms of the increased surface area due to size reduction. Leaching reaction mech¬anisms operative in the acid ferric sulfate system are discussed and the application of ultra-fine grinding technology to other systems is considered.

Jan 1, 1976

By A H. Clemens, P Lindsay

Acid producing potential static tests have been undertaken on sample lithologies from New Zealand coal mines, to rank the lithogies into acid producing waste rock and stable non-acid producing waste rock. Results indicated that the main acid producing waste rock in the Waikato coal region are the marine Whaingaroa siltstone and the Glen Massey formations and the main alkaline producing lithologies were the Tauranga group volcanic-derived sediments (A & D) and the Mesozoic basement. Coal ash analysis of 28 samples from 28 mines have also been analysed for reactive S percentage and their base potential has been quantified by the chemical index of alteration (CIA). The results provide mine management in the Waikato Coal region with a classification of problematic and stable waste rock types. XRF and CIA values determined from wash drill cuttings would provide a method of determining waste rock volumes and magnitude of palaeo-weathering underground.

Jan 1, 1999

By A R. Gerson

Pyrite, chalcopyrite and mixed sulfide samples, with and without quartz (5 wt per cent S), were subjected to column leaching to mimic natural weathering (cyclic wetting and drying). The pH and SO4 2- concentration of the column effluent was measured over a period of 78 weeks. The pH of the pyrite-only containing column rapidly decreased and remained under pH 4 after 12 weeks of leaching. The pH calculated assuming a 2:1 ratio of H + generation and SO4 2- release was slightly lower than that measured. However, a reduced H + to SO4 2- ratio of 1:1 is predicted if the release of aqueous Fe 2+ is assumed rather than the formation of Fe(OH)3. The pH of all columns containing only chalcopyrite or a 1:1 mole ratio of chalcopyrite and pyrite remained at or above pH 5 for the duration of the leach even though significant SO4 2- was released. One column containing the same initial surface area of pyrite and chalcopyrite but only approximately 0.10 the mole fraction of S as chalcopyrite maintained a pH of greater than five for the first 56 weeks of leaching and showed sporadic acid production thereafter. It is well established that oxidation of chalcopyrite results in a surface layer of polysulfide material. It is the formation of polysulfide that neutralises the acid produced on S oxidation through to SO4 2-. Hence where polysulfide formation occurs extensively on chalcopyrite the resulting solution pH decrease will be less than that based on SO4 2- production. The oxidation rate of sulfide minerals increases with decreasing pH and hence acid formation via sulfide oxidation to SO4 2- causes the subsequent oxidation rate to increase. The addition of calcite (CaCO3)to a pyrite column not only neutralises the acid formed but also decreases the rate of release of sulfate to solution by a factor of approximately 30. This is also the case where chalcopyrite is present mixed with pyrite. The rate of release of sulfate from the mixed sulfide mineral columns (after the initial release of the sulfate already present) was between one-fifth and one-tenth that in the absence of chalcopyrite.

Jan 1, 2003