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By Nosa O. Egiebor, Kafui Nyavor

"The effectiveness of sulphuric acid, nitric acid, and hydrogen peroxide pressure oxidation on the cyanide extractability of gold from a double-refractory concentrate is presented. Whileover90% of the sulphide content could be oxidized by either of the two acid pretreatments, only 65% was achieved by the peroxide oxidation. Carbon oxidation by both acid and peroxide pressure oxidation were less than 15%. Although the peroxide pressure oxidation pretreatment resulted in much lower sulphur and carbon oxidation, it gave pretreated residues with decreased levels of preg-robbing activities and higher gold recoveries during subsequent cyanidation, thus indicating some deactivation ofthe preg-robbing carbon during pretreatment with hydrogen peroxide. The refractoriness due to carbon preg-robbing activity was found to contribute more to the refractory behaviour of the concentrate than the occlusion of gold particles by the sulphide mineralization.IntroductionGold ores and concentrates are classified as refractory when a significant portion of the gold content cannot be extracted efficiently by conventional cyanidation, even after fme grinding (Weir and Berezowsky, 1984); (Demopoulos and Papangelakis, 1987). The refractory behaviour of precious metal ores and concentrates is generally attributed to two main factors: The presence of carbonaceous materials which could cause preg-robbing activity during cyanidation (Zaitseva et al., 1973); (Nice, 1971); Scheiner et al., 1971); (Eisele et al., 1983), or occlude gold-bearing minerals (Wells and Mullens, 1973); (Gasparrini, 1983); (Chen and Reddby, 1990), and the occurrence of sulphide minerals which can occlude gold, thus reducing the access of lixiviants (Schwartz, 1944); (Weir et al., 1986); (papangelakis and Demopoulos, 1990); (Michaelis, 1989); (Schweigart, 1965). When the refractoriness is due to a combination of these two factors, the ore or concentrate can be referred to as being ""double-refractory"". Because of the rarity of gold ores exhibiting this double-refractory phenomenon, only a few studies have been carried out on their suitability for pretreatment by existing techniques."

Jan 1, 1992

By Peter G. Kovalchik, Rudy J. Matetic, Susan B. Bealko, Adam K. Smith

Overexposure to noise remains a widespread and serious health hazard in the U.S. service providing and goods producing industries. Excessive noise can lead to poor verbal communication and reduce the ability to recognize warning signals. These dangerous work conditions can also cause stress and fatigue. Occupational hearing loss is a permanent illness, with no recovery currently possible. Method: National Institute for Occupational Safety and Health (NIOSH) has recognized Noise Induced Hearing Loss (NIHL) as one of the ten leading work related diseases and injuries in the United States, and has emphasized its importance as one of the critical areas expressed in the National Occupational Research Agenda. Results: One of the most serious noise problems in the goods producing industries is the operation of continuous mining machines during underground coal mining. In order to minimize occupational hearing loss, noise hazards are “designed out” early in the design process. NIOSH is leading a national initiative called Prevention through Design (PTD) to promote this concept. This paper describes the quiet by design approach of a noise control that reduced noise exposures of continuous mining machine operators by 3dB(A) using the four functional areas of PTD, namely Practice, Policy, Research, and Education.

By P. B. Bucky

THE purpose of this paper is to present a scientific method for deter-mining the proper span and shape of roof for safe and economical mining; at present, these two vital factors wherever pillars are left to support the roof are determined by local practice or general experience. To develop the method described here, experimental laboratory work was done. The arch adopted was a segment of a circle, a flat roof being considered an arch with an infinite radius. Hitherto, arches have been used underground without the background of stress analysis that generally precedes arch construction on the surface. In many cases results have not been as expected, because of the lack of knowledge of the factors affecting its strength and behavior. A theoretical and experimental study of arches should furnish informa-tion that will make it possible to design safe and economical surface structures as well as underground openings. For example, on the subject of mine drifts and tunnels, the present idea is that arching their backs increases their strength; this paper will indicate that this is not always true, and if it can be shown that under certain conditions arching becomes unnecessary an economic saving will result. In room-and-pillar work a question may arise as to whether arching the roof and gobbing the excavated material will result in timber saving, and a decrease in the dan¬gers from falls of roof. It is to be distinctly understood that each mine must be treated as an individual problem, and that answers to these ques-tions and many others can now be found after experimental laboratory data have been obtained.

Jan 1, 1934

By M. Schultz

The cost of remediation often drives the selection of the preferred remedial alternative at hazardous waste sites. The use of probabilistic cost/risk analyses can aid in predicting costs of remedial alternatives. Three types of information are discussed in performing cost/risk analyses: (1) data on the quantity of contamination versus the contaminant concentration; (2) unit costs of remediation for the remedial alternatives; and (3) risk to contaminant concentration relationships. Cost/risk evaluations are performed on a site-by-site basis, to account for combined risks of different contaminants and differences in quantity to be remediated versus contaminant concentration. The cost/risk analysis produces a graph of risk versus cost for each of the remedial alternatives. These costs are then compared to facilitate selection of a preferred alternative. An example of comparison of alternatives is illustrated for a historic coal gasification site.

Jan 1, 1992

Probabilistic seismic hazard analyses (PSHA) have now gained wide acceptance in the development of design criteria for major projects. When used with regional criteria the procedures have also allowed the preparation of more rational seismic zoning maps. Seismic zoning maps using various levels of results from PSHA studies around the Pacific Rim now include Canada, Indonesia, New Zealand and the United States. Some Pacific Rim countries such as Chile where the seismic exposure is dominated by subduction events have no subdivision into separate zones.Approaches to risk based zoning are being considered in several Pacific Rim countries including Australia. Australian studies must face problems similar to parts of the Eastern United States where seismic activity is low with irregular and infrequent occurrences of moderately large earthquakes. The perception of the seismic exposure by both regulatory agencies and the public at large is different when considering areas of low seismicity. There is therefore a need to make different interpretations of the results of PSHA studies in these areas of low seismicity. The aim of this paper is to explore some of these differences by comparing the results from two site specific studies from areas with widely differing seismic activity rates.

Jan 1, 1990

By Habib Zughbi, Paul Zulli

"A key step towards sustainability in iron and steelmaking is to optimise the use of raw materials and energy consumption, and consequently minimise CO2 emissions. Models based on a Process Integration (PI) approach play a key role in evaluating various scenarios and the impact of introducing changes in raw materials and operational conditions on the overall energy consumption and CO2 emissions. BlueScope uses a PI based comprehensive model for its Port Kembla Steelworks (PKSW), called the Integrated Steelworks Energy and Emissions Model (ISEEM). ISEEM is tightly coupled to the configuration of PKSW. It is based on mass and energy balances as well as thermodynamic relationships. ISEEM is a steady-state model and is used to predict overall and detailed unit-by-unit energy consumptions and CO2 emissions. It is also used for plant-based scenario modelling. This paper investigates the impact of major changes to PKSW configuration, including the shutting down of a blast furnace and cokemaking battery, on the energy consumption and CO2 emissions of the plant. It discusses some of the issues involved in updating the model and some identified opportunities."

Jan 1, 2015

By R. L. Wiegel

The National Science Foundation, Erie Mining Co., and University of Minnesota Mineral Resources Research Center jointly sponsored a project to demonstrate the use of a small computer in the control of cyclone overflow size on one line in the Erie Mining Co. concentrator. The Erie circuit, similar to most taconite circuits, uses magnetic separators to reject tailings following each stage of grinding, resulting in additional variations in the demands made on the grinding circuit because of weight rejection fluctuation. Mathematical models were developed for rod milling, ball milling, hydrocycloning, fine screening, and five stages of magnetic separation. These models were used in concert to simulate the operation of Erie's circuit from rod milling through finisher magnetic separation.

Jan 1, 1980

By Nick Vayenas

This paper discusses the application of a commercially available state-of-the-art PC discrete-event simulation modeling software, called Promodel, for simulating a typical underground mine hoist system in the Sudbury mining region, in the province of Ontario in Canada. The reasons for using Promodel as a two-dimensional simulation development tool is its simplicity in use and its capabilities to provide enough flexibility to meet the modeling requirements of a mine hoist system. General information of a mine hoist system was collected for building the model. Example of the model?s output is also presented. The application of Promodel in underground mining offers a powerful, two-dimensional simulation environment in an affordable price for mining engineers to analyze and study operational problems. This hoist simulation model is an intuitive demonstration of the mine hoisting elements and the operational logic of the hoist, based on which optimization of the entire mine system materials flow can be considered as part of a mine cycle management feasibility study.

Oct 1, 2009

By Albert Adu-Acheampong

Fairmount Mineral's Maiden Rock underground sand mine historically delivered air to ventilate diesel-powered equipment at its working faces through high-resistance, 381-mm- (15-in.-) diameter PVC distribution lines. In support of plans for expanded production, three new, low-resistance ventilation design alternatives were analyzed. The study determined that adequate ventilation for expanded production was possible with various commercially available, high-volume/ low-pressure fans combined with a systematic layout of control structures. The recommended redesign was implemented in 2001, resulting in a significant increase in flow volumes and a noticeable improvement in the mine environment.

Jan 1, 2008

By David Hoadley, Kenneth R. Maser, Ashok B. Boghani, James E. Billar, D. Randolph Berry, Mackenzie Burnett, Robert H. Trent

3. Application of Proposed Revised Standards 57.11-50 to Mines Surveyed 3.1 Subparagraph (a) 1 "Each mine shall have at least two separate and properly maintained escapeways from each working place to the surface which are so positioned that physical or environmental damage to one will not lessen the effective¬ness of the other, and which meet the requirements of travelways and man hoisting standards These escape¬ways shall reach to within 1000 feet horizontally or 300 feet vertically of each working place " 3. 1. 1 Discussion This section will deal with the 1000 and 300 feet distance requirements, Section 3. 5 will deal with the "environmental damage" provisions. During the course of the mine surveys, it became obvious that one mine's 1000 foot distance was nowhere near equal to another' s --not in the actual distance but in the time required to traverse that distance. This -Ls true for the 300-foot requirement as well. The most obvious example is that one could traverse down a 300-foot raise much faster than climbing up the same distance. The temptation is strong to recommend that the distance requirement be changed to travel times instead. However, this approach would unfortunately lead to a lot of subjective evaluations. Having a time requirement for an entire mine evacuation (Subparagraph 6) is one thing, time requirements and the requisite inspection proce¬dures for each working place are quite another.

Jan 1, 1976

By Woodcock JT

This paper reviews the chemistry of flotation pulps with the aim of gaining a better understanding of the effect of chemical environment in flotation and ap- plying the knowledge to improving the con- trol of reagent additions. Theories of flotation are considered briefly, but they are only of limited help in specifying an appropriate chemical environment and in establishing control techniques. The chemical nature of flotation pulps is reviewed. Four distinct phases are present - solids, an aqueous liquor con- taining many dissolved reactive sub- stances, organic liquids, and gases. All of these vary in many ways and interact with each other. It has now been estab- lished that there are many previously- unsuspected materials present in plant pulps that can or might affect flotation. Concentration profiles of selected para- meters in operating plants are given to show some typical changes that occur. Recent advances in collector chemistry, especially that of xanthate and related species, are reviewed. Modes of decompo- sition and/or formation in pulps of xan- thate, dixanthogen, perxanthate, xanthyl thiosulphate, and monothiocarbonate are reviewed, and their W absorption spectra are compared. Some relevant information on dithiophosphates, mercaptobenzothia- zole, and thionocarbamate is summarized, and some speculative comments are made about reactions of these collectors.

Jan 1, 1984

By J. W. Fuller

DURING the last 20 years, experimenters have sought to utilize pulverized coal in boiler plants, but refractory and slag troubles have usually overbalanced any, gains in efficiency that were obtained. These troubles were caused largely by lack of knowledge of the proper methods of coal preparation and lack of a furnace design that would be adaptable to pulverized-coal firing. When this information was obtained the results were so much more satisfactory that within the last 5 years approximately, 80,000 boiler hp. have been installed in plants ranging from 1000 to 20,000 boiler hp. rated capacity, which are operating at an average of 174 per cent. of rating. The first commercial installation for burning pulverized coal under boilers was made at the Parsons shops of the M. K. & T. railroad in 1916. Of eight 250-hp. water-tube boilers thus fitted, six were operated continuously for 3 yr., when oil was obtained at such a low price as to warrant its use. Since then, this plant has been operating alternately on pulverized coal and oil, depending on prevailing prices. Recently gas has been discovered within 20 mi. of this plant, so that this fuel may also be used. No change in furnace design was made when changing from pulverized coal to oil or gas firing. One of the principal advantages of this method of firing is its ability to utilize, with maximum efficiency, all kinds of coal, irrespective of quality or physical characteristics. In fact, quite a number of the present pulverized-coal installations were made for the purpose of utilizing coal that could not be marketed or used in any other way. The Pacific, Coast Coal Co., at Black Diamond, Wash., formerly hand fired the boilers, using approximately 125 tons of prepared steam-size coal daily. The Black Diamond steam coal is the best quality of coal for steaming purposes mined in that section of the country, and there is a market for all that can be produced. By installing a pulverizing plant, it was possible to substitute coal of a size and quality that had no commercial value, so that 125 tons daily of the best steam coal formerly used at the mines is now marketed.

Jan 12, 1921

By E. W. Steele

IN THE copper-casting department of a modern electrolytic copper refinery there are two kinds of casting furnaces: the first, or anode furnace for casting crude copper into anodes for electrolysis; the second, or refined-copper furnace for casting the cathodes resulting from electrolysis into market shapes, such as ingots, wire bars, and cakes. Both furnaces are reverberatories of practically the same general design and are operated intermittently, putting through a charge normally in 24 hours. The treatment of the copper in both furnaces is similar, in so far that oxidation followed by skimming and reduction (poling) is carried on in both; but in the refined-copper furnace, the work must be done with greater care and it is of extreme importance that not the slightest trace of impurity be introduced into the copper. The furnaces usually hold from 150 to 300 tons of molten copper, which constitutes the daily charge. Except in the case of furnaces in the Lake district, where the concentrates from native-copper ores are charged through the roof, the furnaces are charged through the side doors by charging machines similar to those used in open-hearth steel practice. In 1916, at the Perth Amboy plant, of the American Smelting & Refining Co., located at Maurer, N. J., a study was made of the possibility of firing the copper refinery furnaces with pulverized coal instead of by hand. The proposed method possessed obvious advantages over hand firing and coal was a much cheaper fuel than oil at that time. It was realized, however, that there were several objections to its use, the principal ones being the liability of increasing the sulfur content of the refined copper, and the additional slag that might be produced from the ash. The increase of the sulfur content of the refined copper was the more serious, as more than 0.002 per cent. sulfur is objectionable. In the case of the slag, any increase would be expensive as the copper in this slag would have to pass again through the entire smelting and refining process.

Jan 3, 1925

By Guowen Dong, Qiyong Li, Qiang Li, Tiejun Chen, Zhihong Wu, Junying Wan

In order to search for a more economical and effective roasting additive for extracting vanadium from stone coal and solve the question of the disposal of PVC waste, PVC waste was proposed as a novel roasting additive to enhance extraction of vanadium from stone coal and realize the comprehensive utilization of resources. By adding this roasting additive, the leaching rate of vanadium reached 94.5% under the conditions that the PVC waste addition was 10 wt%, the roasting temperature was 800 °C, the roasting time was 1 h, the sulfuric acid concentration was 15 vol%, the liquid-to-solid ratio was 1.5 cm3 /g, the leaching temperature was 95 °C, and leaching time was 4 h, which increased by 8.4% compared with that of blank roasting. The thermodynamics calculation showed that the decomposition reaction of mica was performed easier with the participation of HCl produced by pyrolysis of PVC. Meanwhile, The SEM-EDS and aperture test analyses demonstrated that more cracks and voids appeared in the roasted sample by roasting with PVC waste, which could facilitate the release and extraction of vanadium. Additionally, the TG-DSC analyses indicated that PVC could provide large amounts of heat for the roasting process to promote the decarbonization and roasting efficiency of stone coal because of its high calorific value.

By Guowen Dong, Qiyong Li, Qiang Li, Tiejun Chen, Zhihong Wu, Junying Wan

In order to search for a more economical and effective roasting additive for extracting vanadium from stone coal and solve the question of the disposal of PVC waste, PVC waste was proposed as a novel roasting additive to enhance extraction of vanadium from stone coal and realize the comprehensive utilization of resources. By adding this roasting additive, the leaching rate of vanadium reached 94.5% under the conditions that the PVC waste addition was 10 wt%, the roasting temperature was 800 °C, the roasting time was 1 h, the sulfuric acid concentration was 15 vol%, the liquid-to-solid ratio was 1.5 cm3 /g, the leaching temperature was 95 °C, and leaching time was 4 h, which increased by 8.4% compared with that of blank roasting. The thermodynamics calculation showed that the decomposition reaction of mica was performed easier with the participation of HCl produced by pyrolysis of PVC. Meanwhile, The SEM-EDS and aperture test analyses demonstrated that more cracks and voids appeared in the roasted sample by roasting with PVC waste, which could facilitate the release and extraction of vanadium. Additionally, the TG-DSC analyses indicated that PVC could provide large amounts of heat for the roasting process to promote the decarbonization and roasting efficiency of stone coal because of its high calorific value.

By John Goheen

RECENTLY the head burner at a brick. plant with over 40 years' experience said that he had burned brick by guess for over half his lifetime and had used pyrometers for 2 1/2 years but hoped that he would never have to burn kilns without pyrometers again. The ceramic engineer in making a special study of the burning of clay ware and the effect the heat of the kiln has on color and vitrification is also rapidly placing the burning of clay on a twentieth-century basis. Clay ware may be divided into various groups, brick and drain tile; sewer pipe; firebrick; and pottery, which, in turn may be subdivided into special classes. As nearly as the analysis of the clay type of kiln, etc., will allow, there are practically the same problems to solve in burning in all of the processes or operations. The underlying objective is the same, namely the production of the best grade of ware under the most efficient and economical manufacturing system. The principal problem in the production of clay ware is the burning off of the kilns. The most modern steam shovel may dig the clay and the most advanced types of pug mills and wire cut machines or molds of various kinds may be installed, but unless the drying and burning of the ware is successful, all of the previous operations will be useless. On this final operation depends the entire result of the plant. In reality, burning of all. clay ware is purely a heating proposition. The kilns, or furnaces, should be so designed as to give equal distribution of heat. Consequently, the problems of design and construction of kilns to produce equal distribution of heat require serious consideration, as do also the questions of heat control and draft control. The three most important factors in the burning of practically all types of kilns may be

Jan 9, 1919

By I. H. Van Horn

IN the development of the incandescent electric lamp one aim of the investigators has been to establish the fundamentals of lamp design, so that the performance of any new lamp may be accurately predicted. The study of the temperature relations in lamps has done much toward establishing these fundamentals. Fig. 1 gives the typical FIG. 1.-ARRANGEMENT OF PARTS IN MAZDA B AND MAZDA C LAMPS. arrangement of the lamp parts in both the Mazda B (vacuum) and Mazda C (gas-filled) lamps. The outstanding differences are the filament form and the bulb shape. The ideal lamp is one in which the filament operates at a uniform temperature throughout its length. In practice, it is necessary to disturb this uniformity by the introduction of supports and terminals. The amount of cooling at the supports and terminals affects the over-all efficiency of the filament as a light producer. The life of the lamp is ordinarily proportional to the maximum and not to the average filament temperature. The Holborn-Kurlbaum type of optical pyrometer has

Jan 9, 1919

By C. B. Thwing

IT is likely that among most races, owing to the ease of finding and working clay, the making of clay utensils was learned earlier than the molding of metal implements. The ancients made good pottery and durable brick in kilns that wasted fully one-half the heat and spoiled fully one-fourth of the ware; and, taking the clayworking industry as a whole, we are doing the same today. The chemical and physical changes involved in the burning of clay are so many and vary so much with the composition of the clay that it is not surprising that the rule-of-thumb methods so commonly employed fail to give uniform results. In its passage from plastic clay to the vitreous or stonelike character the mingled minerals and accidental organic impurities of which the clay is blended must pass through four stages, the second and third usually overlapping, and the fourth often beginning before the third is complete. These stages in their order with the rising temperature are drying, dehydration, oxidation, vitrification. In the first part of the drying stage, usually accomplished in part outside the kiln, the water mixed with clay is dried out at temperatures not much exceeding the boiling point of water. In the later part of this stage, within the kiln, the hygroscopic water, absorbed from the air is expelled at somewhat higher temperatures, this stage being known as watersmoking. Some clays are very sensitive to temperature during the drying stage and if the temperature exceeds 100°, the ware becomes checked. Other clays may be dried more rapidly without danger. In down-draft kilns, the draft is slight during the watersmoking stage and the water driven off from the top rows condenses on the ware in the bottom of the kiln, with the result that high temperatures are likely to be reached at the top of the kiln before the bottom is fully dry. The lag in temperature of the bottom persists to the second stage in spite of the better draft then prevailing.

Jan 9, 1919

By Kirtland Marsh

THE manufacture of gas masks by the Chemical Warfare Service, U. S. A., required preparation of the carbon used in the canisters. The largest plant for the production of this carbon was situated at the works of the Astoria Light, Heat and Power Co., at Astoria, N. Y.; this paper will deal1 with the pyrometry equipment at that plant. Commercial charcoal was found unsuitable for use in gas masks because of its low power of absorption and its poor resistance to abrasion. The best raw material for the production of carbon was found to be coconut shells, but any kind of nut shells or fruit pits were used when sufficient quantities of coconut shells could not be obtained. The shells were first carbonized in retorts, the carbon was then crushed and screened between 8 and 16 mesh, and finally submitted to a special heat-treatment in air; steam treatment was later substituted for treatment in air. The production of gas-mask carbon on a commercial scale was begun at Astoria about Aug. 1, 1917. Temperature control was essential during the initial carbonization of the shells, as well as during the air or steam treatment, and pyrometers were installed for this purpose. The installation and maintenance of all pyrometry equipment was done by the pyrometry department, consisting of an officer in charge, an assistant, and two men. A special pyrometry laboratory was maintained in which all repairs were made.

Jan 9, 1919

R. W. NEWCOMB, New York, N. Y. (written discussion *).-This paper is particularly interesting to me, because it gives data on a much mooted question, viz., the serviceability of Le Chatelier (platinum-platinum-rhodium) thermocouples under severe industrial conditions. It has always been supposed that platinum-platinum-rhodium thermo-couples, used at high temperatures under strong reducing conditions, would not give long service and were subject to rapid volatilization. The fact, however, that the carefully kept records indicate that a little more than 3 gm. out of more than 830 gm. was lost over this considerable period, shows what kind of service can -be obtained from platinum-platinum-rhodium thermocouples,, when properly installed, and well cared for. While the writer has no actual figures on the loss of weight, etc. of platinum-platinum-rhodium thermocouples under service, he was told, by the man in charge of pyrometers at a large industrial plant in which over 400 platinum-platinum-rhodium thermocouples were installed in furnaces doing various kinds of heat-treating work, that the average maintenance cost, for materials alone, including platinum-platinum-rhodium wires and protecting tubes, was 27 c. per furnace, per month:

Jan 12, 1919