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By C. M. Offenhauer

Abstract Zirconium markedly affects the formation of graphite in cast iron and may promote the formation of normal flake gaphite, fine flakes of eutectiform graphite, or spheroid nodular graphite, according to the composition of the Iron and the amount of the zirconium addition. Usually, it is employed in the form of a complex addition agent in order to facilitate its introduction and to guide its effect. The reported applications of zirconium as an inoculant for the production of pearlitic high-strength cast iron indicates that it is most effective as a silicon-manganese-zirconium alloy. Added in this form it reduces chill and minimizes zones of ferrite and eutectiform graphite. In low-sulphur cast iron, zirconium in amounts greater than 0.10 per cent tends to promote the development of eutectiform graphite. These irons are characterized by freedom from primary cementite or normal flake graphite and exhibit very little tendency to shrinkage on solidification. In hyper-eutectic low-sulphur cast iron, zirconium causes the formation of a partially nodular graphite structure. A combination of magnesium with silicon-zirconium alloy was found to produce completely nodular graphite structures without the hazards associated with the addition of elemental magnesium.

Jan 1, 1949

By M. SIDDARAJU, Rameshwar Sah, Satendra Kumar, Arvind Jaiswal

The study explores a novel process to sinter porous iron ore with improved productivity and quality. The iron ore is pre-processed with calcined lime to temporarily close pores, preventing water absorption during granulation. This enhances reaction kinetics and early slag formation during sintering, resulting in significant improvements in sinter productivity, product yield, and cold strength property.

Feb 28, 2022

By J. H. Van Reenen, H. Thiele, C. Bergman

For some time spirals have been the process equipment chosen to recover metal in the size range 0.15 to 3mm from ferrochrome and silico/ferro manganese slags. Recoveries of metal obtained using spirals are usually about 70%. Spirals are also difficult to control. By combining a novel gate on the Apic pneumatic fines jig with the recently developed Apic classifier, metal recoveries of 76% and grades of over 90% have been obtained for FeCr and SiMn slags in the size range 0.15 to 3 mm. The paper compares classifier operating performance and costs with those spirals for FeCr and SiMn metal recovery from slags. The classifier technology can also be applied to chromite and iron ores and coal fines.

Jan 1, 2004

By Robert M. Valentine, Randall L. Lentell

Interpretive geotechnical investigations were performed for the construction of approximately 15,250 m (50,000 ft) of wastewater interceptor tunnels in Austin, Texas. Subsurface materials consist of claystone (or clay shale), siltstone, altered volcanic tuffs, chalk and limestone. Special conditions include multiple crossings of Onion Creek with cover ranging from about 1/2 to 3 m (2 to 10 ft.), and the potential for mixed-face conditions consisting of water-bearing gravels overlying clay shale or siltstone. The methods and results of the geotechnical investigations are discussed and the inferred construction conditions are compared to those encountered during tunneling. A suggested format is presented for interpretive geotechnical reports for underground construction projects.

Jan 1, 1985

By Fawad S. Niazi

Ever since the use of the cone penetration test (CPT) in geotechnical practice, attempts have been made to correlate CPT parameters with pile capacity components of unit end bearing (qb) and unit shaft resistance (fp), thus deriving multiple CPT-based pile design methods. These methods focus on "capacity" only without consideration to complete axial pile load-displacement (Q-w) response. Estimated capacities from these methods also exhibit considerable scatter without any consensus on their consistency. In addition, load-displacement curves obtained from axial load tests on highly expensive and extensively instrumented piles can exhibit different shapes. Nevertheless, a single value from the curve so obtained dictates the design capacity. Currently, there are at least 42 different criteria defining capacity with considerable variation in the values obtained thereof. The Randolph elastic solution, which provides a framework for analytical evaluation of pile load-displacement response, requires the profiles of soil stiffness. The fundamental soil stiffness defined by the small-strain shear modulus (Gmax) can be obtained from shear wave velocity (Vs) readings via seismic piezocone tests (SCPTu). The secant stiffness (G), which softens from Gmax corresponding to operational load levels, can be obtained by generating stiffness reduction curves from back analysis of load tests. Then, using appropriate G values, the Q-w curve can be defined for conditions similar to the database from the pseudo strain (w/d). Thus, a complete framework for optimal integration of SCPTu data, Randolph elastic solution and back-analysis of field operational stiffness can be established for complete axial pile foundation analysis.

Jan 1, 2011

This is the second of a series of reports on properties of commercial motor fuels made pursuant to a cooperative agreement between the Cooperative Fuel Research (C.F.R.) Committee and the Bureau of Mines of the Department of the Interior. The first report gave data oil motor gasolines sold during the minter of 1935-36.3/ These gasoline surveys report results of inspections, in oil-company laboratories, of samples of gasoline obtained by representatives of oil companies from service-station pumps in marketing areas throughout the country. In the present survey are presented inspection data on 239 samples of regular- price gasoline, 166 samples of premium-price gasoline, and 157 samples of third-grade gasoline, a total of 562 samples collected during the summer of 1936.

Jan 1, 1937

This is the second of a series of reports on properties of commercial motor fuels made pursuant to a cooperative agreement between the Cooperative Fuel Research (C.F.R.) Committee and the Bureau of Mines of the Department of the Interior. The first report gave data on motor gasolines sold during the winter of 1935-36.3/ These gasoline surveys report results of inspections, in oil-company laboratories, of samples of gasoline obtained by representatives of oil companies from service-station pumps in marketing areas throughout the country. In the present survey are presented inspection data on 239 samples of regular-price gasoline, 166 samples of premium-price gasoline, and 157 samples of third-grade gasoline, a total of 562 samples collected during the summer of 1936.

Jan 1, 1937

By Engelmann. William H.

In pursuit of innovative methods to improve mining productivity, the Bureau of Mines is investigating the use of inorganic salts as drilling fluid additives for penetration enhancement. Laboratory diamond drilling tests were performed on Westerly Granite with aluminum chloride solutions and on Sioux Quartzite with aluminum nitrate and aluminum, calcium, sodium, and zirconium chloride solutions as drilling fluid additives. These drilling results were compared with the average drilling performance using distilled, deionized water on Sioux Quartzite (12 replicate tests) and Westerly Granite (3 replicate tests). Maximum in-creases in penetration per given time and bit life were obtained when drilling with zero point of charge (ZPC) concentration solutions of each additive. For Sioux Quartzite, maximum increases in penetration and bit life ranged from 96 to 115 pct and 64 to 99 pct, respectively. For Westerly Granite, maximum increases in penetration of 155 and 165 pct and bit life of 109 and 136 pct were obtained at or near ZPC aluminum chloride concentrations of quartz (7.3 x 10-7 mol/L AIC13) and alkali feldspars (1.1 to 1.5 x 10-6 mol/L AIC13), respectively. This simultaneous increase in penetration per time together with extended bit life should result in increased productivity and reduced bit costs.

Jan 1, 1987

By D Pilone

The Tyrrhenian micro-nodules, findable at low depths (200/600 m under s l) are a reasonable reserve of manganese. They can be easily and cheaply recovered but do not contain valuable metals as in the case of oceanic nodules. In this work a hydrometallurgical process for manganese recovery from Tyrrhenian nodules is presented. The studied treatment includes the following operations: magnetic enrichment, reducing leaching, leach liquor purification and electrowinning . The study shows that the most important step in the process is the preliminary manganese enrichment. It can be done directly on the platform reducing not only the transport cost, but also the residue mud in the metallurgical plant. The leaching parameters such as status and size of nodules, temperature, composition of leaching solution and S/L ratio have been investigated. After purifying the leach liquor by iron precipitation as ammonium jarosite , the conditions to electrowin manganese have been investigated. The yields of both manganese leaching and iron precipitation together with current efficiency and specific energy consumption in the electrowinning step are given.

Jan 1, 2000

By E. Iasillo, R. R. Carneiro

Independent of the method chosen to forecast production, an accurate method to project metal extraction is needed in order to accommodate leach cycles that exceed leach data on hand and thus be able to accurately forecast production. Metal extraction data must be developed for each ore type identified in the deposit in order to apply the correct rate of leaching when a specific ore is being treated. Curve fitting is used to model the rate of disengagement of metal into the pregnant solution. This paper provides a description of a curve fitting algorithm developed by Mr. John T. Bartlett, inventor of the METSIM™ process simulation program. A methodology is provided by which the metallurgical data developed is evaluated to determine if accurate projections may be made from the data. A criteria has been developed to help determine when a column experiment may be terminated.

Jan 1, 2001

By C. Gherghel

The planning and operation of ventilation network systems for uranium mines require special considerations since ventilation is the primary technique of controlling ambient concentrations of radon progeny. The major environmental challenge facing the ventilation engineer is the requirement to dilute radon progeny to below the Working Level Month per year of worker exposure required by law. The application of large airflow volumes and the utilization of low residence times constitute some of the factors considered by the design engineer. Good mine planning and sequencing are also critical for protecting the health of miners. The mine ventilation must have such characteristics as flexibility, high air distribution efficiency, rapid air transit times, zero recirculation and no short-circuiting. A well established maintenance program for all ventilation appliances must be in place to guarantee control of the distribution system. Real-time monitoring systems permit assurance the adequate quality of air is delivered to working places. A case study for an operating mine is used to demonstrate how the ventilation system is successfully managed and operated using the above concepts.

Jan 1, 2009

By Kevin Malone

Mercury, or quicksilver as it is often called, has many applications in modern technology. Used principally in electrical apparatus, industrial contol instruments, insecticides and fungicides, electrolytic preparation of chlorine and caustic soda, chemical processes, pharmaceuticals, and dental preparations, the liquid metal has unusual properties that make it a preferred material for many industrial uses. United States consumption of mercury during the past 40 years shows a rising trend. In all except 4 years, U.S. production has been less than the domestic requirement, and imports, principally from Spain, Italy, and Mexico, have supplied most of the deficit. After World War II, domestic output decreased rapidly until 1950, when it was the lowest in the 100 years covered by production records. Higher mercury prices since 1950 have reversed the decline in domestic output and reduced the gap between U.S. production and consumption. Domestic output in 1958 was the highest in peacetime since 1883; however, the nation still imported 28 percent of its mercury requirements from 1950 to 1960 the price of mercury was high as a result of industrial applications of the mercury cell, the impact of the cold war and the Korean war, and the Government stockpiling program. The stockpiling program, in effect, put a floor under mercury prices even though only 9,428 flasks of domestic mercury went into the stockpile under the original program which ran from July 1954 to December 31, 1957. Under an extension of the program, an additional 17,463 flasks was purchased.

Jan 1, 1962

By Kent R. Van Horn, W. P. Sykes

Since Honda and Murakamil in 1918 proposed their constitutional diagram of the carbon-free iron-tungsten system, considerable effort has been expended by several investigators in attempts to define more positively the structural features of the alloys. The existence of an intermediate phase corresponding to the formula Fe3W2 (68.7 per cent W) was proposed from evidence of a purely metallographic nature by one of the present authors2 in 1926. Since that time the identity of this phase has been confirmed by Arnfelt3 and by Takeda,4 both of whom employed X-ray methods as well as the microscope and the chemical analysis of isolated microconstituents. According to Arnfelt, Fe3W2, as crystallized from the iron-rich melts at a temperature above 1450° C., contains by analysis 68.7 per cent W. The lattice of this phase is characterized by trigonal symmetry. Arnfelt, moreover, proposed a second intermediate phase formed at some temperature between 1450" and 1000" C. by a peritectoid reaction involving Fe3W2 and the iron-rich solid solution. A melt containing 25 per cent W was cooled to 1000" C. and heated for 100 hr. The precipitated tungsten-rich constituent was separated and found by analysis to contain 62.6 per cent W. This composition agrees closely with that represented by the formula Fe2W (62.2 per cent W). Diffraction patterns from the concentrated precipitate showed a hexagonal unit cell. Takeda confirmed the data of Arnfelt regarding Fe3W2 but was unable to detect Arnfelt's second intermediate phase. While Takeda failed to describe in detail the treatments employed, he stated that in alloys containing 40 per cent W which were quenched after heating at various temperatures between 1200" and 1450" C. no evidence of the second phase (Fe2W) was observed 'either in the microstructure or in the diffraction patterns of isolated residues. He therefore considered the existence of this low-temperature hexagonal compound as disproved.

Jan 1, 1933

Comparative Studies on Balls Versus Spheroidal Tetrahedrons Working Media to Ore Grinding in an Industrial Drum Mill

Sep 13, 2010

By Paul Staples, Chris Morley

"The development of the Cerro Verde, Amplats Mogalakwena and Boddington projects over the last few years has helped to establish the use of high pressure grinding rolls (HPGR) in comminution circuit designs in large-scale hard-rock applications. The increasing acceptance of this innovative and sometimes controversial technology has had the natural effect of prompting many other new projects to examine HPGR as an alternative to the established, usually SAG-based, comminution circuit design approach.At the current stage of development of the technology, HPGR-based circuit capital costs are generally higher than for the equivalent SAG-based circuit, so that HPGR must offer sufficient operating cost benefits to offset the additional capital costs over an acceptable pay-back period. It is usually necessary to undertake comprehensive project-specific trade-off studies to quantify this effect.This paper describes the processes involved in the execution of a typical SAG-HPGR trade-off study, from the preliminary assessment of ore characteristics and project criteria, through testwork, circuit modelling, equipment selection and cost estimates, to a project-economics comparative assessment of the options. The trade-off study determines both the technical feasibility of the respective technologies and their commercial viability in the given project setting.The paper concludes with a cautionary note to the effect that, while HPGR has many potential benefits, it is not a panacea, and that, for some ore types and project conditions, the more established conventional technologies are often more appropriate."

Jan 1, 2010

Detachment of Particles from Bubbles in a Stirred Cell

Sep 13, 2010

By R. Hart

In this paper, problems that have been experienced with the rockpass system at Kloof Mine No. 3 Shaft are described. Actions that have been taken to overcome the problems are also described. These include the use of slugshots to remove hang-ups, the abandonment and waste filling of passes, and design criteria adopted for an alternative pass system.

Jan 1, 2006

By D. van Rensburg

Jointed rock slopes are generally stable, as there is no freedom of movement for blocks of rock. In an open- pit mining environment, blasting opens up space into which blocks of rock can fail, resulting in the common occurrence of slope failure. Prior to the blasting of a trim pattern, the immediate highwall is scaled, where loose rock material is removed by means of a mechanical scaler. As mining of the pit progresses, the height of the scaled highwall from the pit floor progressively increases. These highwalls are never scaled again for the remainder of the pit life, and time-dependant deterioration contributes to these highwalls becoming subject to rockfall and, sometimes, slope failure. This paper documents the development of a South African innovation, a remote-controlled mechanical highwall scaler, a world first for the mining industry. The scaler will enable open-pit highwalls to be scaled from crest to toe whenever the need arises. It will reduce the risk associated with highwalls and deliver on the Anglo American promise of producing safe, profitable platinum.

Jan 1, 2012

By D. H. Pulling

Statistics for copper consumption from various sources show that the importance of production from secondary sources is increasing. This is of particular significance in countries such as the U.K ., which are totally dependent on secondary material for the supply of home-produced copper . A brief survey of the U.K . industry has shown that, in the past, relatively high profit margins have not encouraged high cap ital investment and development of more sophisticated operating techniques, but set against a background of rapidly escalating operating and energy costs , together with an ever-increasing demand for copper , it is anticipated that the industry will see great changes in the near future. With this in mind, an experimental furnace for continuous smelting of copper-bearing scrap has been developed at the University of Birmingham. This furnace has been designed to combine the conventional operations of blast furnace or reverberatory smelting, usually followed by converting, in one unit, and incorporates many of the features of the WORGRA and Noranda processes for continuous primary smelting . It consists of a long, sloping channel, constructed of chrome-magnesite refractory, which: is churned near the top. Smelting is effected lower down the channel, where iron, etc., in the scrap is oxidized and slagged off with silica flux. Provision is made for oil injection to increase oxidation rates. Metal can flow from the bottom of the channel, and slag from the top, so that a counter-current flow is achieved. The approximate molten capacity is 25 kg. Various scrap charges, both synthetically made and as supplied from various industrial smelters, have been successfully smelted. Metal of 83 -95 % Cu has been produced, depending on the original charge composition and the degree of air injection, although air injection was also found to considerably increase the copper loss to slag. Recoveries of other valuable non-ferrous metals in the charge were good.

Jan 1, 1977

By D. E. Redmon

The Federal Bureau of Mines has studied the locations and general features of 90 pegmatites found in north-central New Mexico. The dominant valuable product of the pegmatites is muscovite, both sheet and scrap. However, the Harding pegmatite in Taos County is mined only for beryl. Many attempts have been made to recover scrap mica on a large scale by mechanical beneficiation of pegmatite, but the operations heretofore have been short-lived. The Globe mine and the Apache mine, both near Petaca in Rio Arriba County, have been the most important sources of sheet mica in New Mexico. Recognition of the growing need for some of the minerals derived from pegmatites led the Bureau of Mines to investigate the occurrences of pegmatite.

Jan 1, 1961