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By Charles Zahn

Direct mass spectrometric determination of alcohols in the presence of hydrocarbons has not been possible because of the similarity of hydrocarbon and alcohol mass spectra. Experiments have demonstrated that by converting the alcohols to their trimethylsilyl derivatives, characteristic mass spectra are obtained free of interference from hydrocarbon ion fragmentation. Hexa- methyldisilazane is the reagent selected for the conversion, An improved method of preparing the reagent is given, Mass spectrometric determination of alcohols as trimethylsilyl ethers now is not only possible without prior separation from other materials, but the range of the room-temperature mass spectrometer is also extended to include the C10 alcohol region. Water does not interfere because it is converted to hexamethyldisiloxane, which has its own distinctive mass spectral peak, Experience indicates that other compounds such as glycols, amines, and phenols probably could also be determined by mass spectrometry of their trimethylsilyl ethers. Studies on the similar detemination of phenols in coal oils have been started, When mass spectrometry is not available, gas-liquid chromatography of alcohols before and after their conversion to the trimethylsilyl derivatives probably could be performed. The preparation and properties of the trimethylsilyl derivatives of 23 alcohols, 2 glycols, 3 amines, and 1 mercaptan are detailed. INRODUCTION During investigations by the Bureau of Mines at the Pittsburgh Coal Research Center relative to the development of Fischer-Tropsch processes, complications were encountered in the mass spectrometric analysis of alcohols in hydrocarbon oils. The fragmentation peaks of the alcohols and the hydrocarbons were so similar that an accurate analysis was not possible, Since involved separation techniques are necessary to isolate alcohols from hydro-carbons for separate determinations, efforts were turned to the search for a

Jan 1, 1962

By Chen Lin

Tectonic stress is an important parameter for understanding the dynamics of underground engineering and for the exploitation of coalbed methane. Multiple-period structural features usually have complex spatial relationships in tectonic superposition areas, which provides evidence for identification of the sequence of the tectonic stress period. Conjugated joints and slickensides are used to reconstruct the tectonic stress of the No. 8 Mine in Pingdingshan. Based on the geological unit division and field measurements, data on hundreds of joints and slickensides are collected from 33 stations. The tectonic stress results indicated by the conjugated joints show that there are mainly four directions of tectonic stress: NEE-SWW, NW-SE, NE-SW, and NNESSW. The tectonic stress results of the slickensides indicate that there are mainly four directions of tectonic stress: NNE-SSW, NNW-SSE, NEE-SWW, and NW-SE. According to the systematic analysis of the joints and slickensides, this paper separates the superposed joint and slickenside sets and identifies the tectonic stress periods with their abutting relationships. Three tectonic stress periods are determined and the sequence of the tectonic stress periods is NE-SW, NW-SE, and NEE-SWW. The results are consistent with other tectonic stress measurements for both the region and the locality.

By J. Parreira

This paper presents a deterministic/stochastic model that was created to compare an autonomous haulage truck system to a manual one by calculating and estimating benchmarked Key Performance Indicators (KPIs) such as productivity, safety, breakdown frequencies, maintenance costs, labour costs, fuel consumption, tire wear, and haulage cycle times.

Aug 1, 2013

By F. M. Makarinsky

"SynopsisThe Kanichee open pit mine and milling complex is situated approximately four air miles north-west of Ternagami, Northern Ontario, in Strathy Township. Mining and milling production commenced in January 1974.Milling throughput currently is at a rated capacity of 500 tons per day, seven days per week. A bulk nickel-copper sulphide concentrate is produced, and is trucked daily to the smelter at Falconbridge Nickel Mines Limited, Falconbridge, Ontario, some 120 road miles from Kanichee. Concentrate grades produced are in the order of 4.0% Ni and 8.0% Cu, with corresponding recoveries of 68-70% nickel and 86-90% copper. Stage additions of 100% guar-gurn solution reagent to the flotation cells for depression of talcose minerals, proved to be the major break-through for optimizing metallurgical performance.2. HistoryThe present Kanichee Mining property is known to old-timers in the Temagami area as the former Cuniptau Mine. Several attempts were made in the mid '30's and 40's to extract the ore at a profit, but each effort resulted in failure.In 1933-36, Cuniptau Mines Development Co. Limited, later called Cuniptau Mines Limited, sank a 245-foot vertical shaft and completed 2,200 feet of lateral work on the 100-140 and the 225 foot levels. Fifteen tons of ore were sent for testwork to the Mines Branch, Ottawa, Ontario.Cuniptau Mines Limited, in 1936, milled some 3,000 tons, and the resulting concentrate was put through a pilot smelter situated on the present mine site. Metallurgically, the smelting results were not encouraging, primarily due to the high melting point of the talcose minerals in the concentrate. From the period 1937-48, minor exploration work was done by Ontario Mining Corporation, Ontario Nickel Mines Limited, and Trebor Mines Limited. During the period 1948-49, 128 diamond drill holes, totalling 40,900 feet were evaluated by Trebor Mines Limited. In 1961, the name was changed to Ajax Minerals Limited, during 1968, five diamond drill holes were sunk, totalling 1,700 feet. Since that period the property has remained idle."

Jan 1, 1975

By Francis E. Federspiel

In 1984 and 1985, at the request of the U.S. Forest Service, the U.S. Bureau of Mines examined the 87,720-acre South Boise Yuba study area (formerly known as RARE II Wilderness Recommended area I-4553) to evaluate mineral resources. The study area and additions are in Blaine, Camas, and Elmore Counties, 10, about 60 mi east of Boise. Granitic rocks of the Cretaceous age Idaho Batholith occupy the western two-thirds of the study area. A Tertiary age granitic complex has intruded, and broken into small blocks, Paleozoic age sedimentary rocks in the eastern third of the study area. Tertiary Challis Volcanics overlie both of these rock types. Principal mineralized structures are gold-and silver-bearing quartz veins and shear zones trending northwest to easterly in the Cretaceous granitic rocks. Copper, lead, and zinc are accessory metals in many mineralized structures.

Jan 1, 1987

By O. P. Hood, G. St. J. Perott, S. P. Kinney

"FOREWORD (By O. P. Hood, Chief mechanical engineer).During the war certain suggestions concerning power production were made by Mr. Walter E. Trent to the War Inventions Board, and at the request of the War Department facilities for experimental work were provided on the grounds of the. Bureau of Standards.The experiments were along the line of controlling the conditions of combustion in a closed space. In order to reduce slag troubles, experiments were carried out for removing ash from powdered coal. After the war, work along this line was continued, resulting in the Trent Process, which agitates or beats together powdered coal, water and oil.A new technology had previously been given to ore preparation by the use of small quantities of oil in water with froth flotation, and although the methods, results and mixtures of the Trent Process were quite different, yet the same physical phenomena of differential wetting used, and the possibility of there being interesting results in fuel technologic was evident. A cooperative agreement was entered into, whereby the Bureau of Mines was to investigate the underlying physical and chemical facts and make them public, and the Trent Corporation was to pay the cost of the investigation.The several reports as made have been available to any one interested, and are now to be published. While the Bureau of Mines felt justified in investigating the physical phenomena so far as might be done in a laboratory, and so far as public interest might reach, no attempt was made to discover the commercial possibilities which development might bring. The question of commercial possibilities must be left for commercial enterprise to answer."

Jul 1, 1921

By Lewis V. Wade

This paper summarizes the results of the rock mechanics monitoring program performed as part of Old Ben Coal Company's longwall coal mining demonstration project conducted in cooperation with the United States Bureau of Mines. The work described herein included installation of instruments, collection of data and data analysis performed during mining of the first longwall panel in Mine No. 24. The rock mechanics monitoring program included both surface and underground instrumentation and was designed to achieve the following purposes: 1 -To provide the capability to observe unusual situations during mining so that remedial measures could be instituted quickly 2 -To formulate design guidelines for future longwall mining efforts; 3 -To evaluate surface subsidence, and its character, rate and potential effects on cultural features, and to develop criteria to assist in predicting subsidence for other mines having similar roof conditions. Six previous attempts with longwall methods in Old Ben Coal Company's Hine 21 had been unsuccessful due to roof control problems. A description of these attempts is given by Moroni (1973). In preparation for the present longwall operation a study was performed to review existing data on the previous unsuccessful attempts, to establish coa1-and floor-strata bearing capacities in Mines Nos. 21 and

Jan 1, 1977

By Chen Lin

Tectonic stress is an important parameter for understanding the dynamics of underground engineering and for the exploitation of coalbed methane. Multiple-period structural features usually have complex spatial relationships in tectonic superposition areas, which provides evidence for identification of the sequence of the tectonic stress period. Conjugated joints and slickensides are used to reconstruct the tectonic stress of the No. 8 Mine in Pingdingshan. Based on the geological unit division and field measurements, data on hundreds of joints and slickensides are collected from 33 stations. The tectonic stress results indicated by the conjugated joints show that there are mainly four directions of tectonic stress: NEE-SWW, NW-SE, NE-SW, and NNESSW. The tectonic stress results of the slickensides indicate that there are mainly four directions of tectonic stress: NNE-SSW, NNW-SSE, NEE-SWW, and NW-SE. According to the systematic analysis of the joints and slickensides, this paper separates the superposed joint and slickenside sets and identifies the tectonic stress periods with their abutting relationships. Three tectonic stress periods are determined and the sequence of the tectonic stress periods is NE-SW, NW-SE, and NEE-SWW. The results are consistent with other tectonic stress measurements for both the region and the locality.

By R. F. Hinds

A pressurizing system was designed and built to apply a radial pressure of 5.000 psi to rock samples. Samples of the Bradford, Weir and Kirkwood sandstones were subjected to radial pressures parallel and perpendicular to the bedding in the system and the changes in conductivity, porosity and permeability were deter-mined. Asymptotic decreases in conductivity, porosity and Klinkenberg permeability were observed over the 0- to 3,500-psi range. From these data, the increase of formation factor over the same range was calculated. The cementation exponent expressed in the Archie equation was found to increase with pressu,re. The rate of change varied from formation to formation. Only small differences were observed for samples taken parallel to the bedding as comnared to those taken perpendicular to it except for the Bradford sand. Above 3,500 psi the data are not good enough to tell if the properties continue to fall-off asymptotically or in a different manner. A possible explanation for the probable litnit of the asymptotic rate around 3,500 to 4,500 psi is that this represents the maximum pressure which the formations have unrdergone during their geological life as a result of burial. INTRODUCTION For many years measurements have been made in the laboratory of the properties of oil-bearing sandstones with little consideration being given to whether these properties had been changed when the samples were moved from their original position in the ground to the laboratory. Relatively little has been reported in the literature on the effect of pressure on the properties of sandstones. The changes in permeability for eight typical consolidated oil-bearing sandstone samples with overburden pressure (0- to 15,000-psi range) was presented by Fatt and Davis' in graphical form. In 1953 Fatt' also reported the relationship between porosity and overburden pressure for four typical consolidated oil-bearing sandstone samples (0- to 5,000-psi range). Fatt later described the changes of formation factor and porosity of 20 typical oil-bearing sandstone samples with overburden pressure changes (0- to 5,000-psi range) giving the values of the coefficients and exponents in the Archie' equation, and the more general Winsauer equation', where C, k and m are empirical constants, F is the formation factor, and + is the porosity. During the experiments of this investigation the core was contained in a neoprene rubber sleeve as shown in Fig. 1. It was held between two steel end members which were mounted in a steel cylinder. The unassembled pressure cylinder with its component parts is shown in Fig. 2. The core was insulated from the two steel end members by a Teflon sleeve with a small hole in the

By George J. Conroy

Electrical power generation was studied in a laboratory-scale, open-cycle vortex MHD generator, which offers several advantages over straight-channel generators that require separate combustors. Compactness, lower capital cost, and high-energy release are obtained by combining the combustor and generator into one unit in the vortex generator. In addition, the vortex generator uses a simple solenoid rather than the more complex and expensive saddle magnet required for straight channel generators. Although the vortex generator must utilize combustion gases with a low Hall coefficient in order to be efficient in direct comparison to the linear generator, the primary motivation for this experimental device in terms of ultimate objective was to investigate the vortex generator with applications to direct coal firing and with combustion taking place in specially designed expansion nozzles. The vortex device offers one decided advantage over the linear device in this regard because slag deposits do not degrade or short-circuit the coaxial electrodes as is the case for a linear machine. The experimental vortex generator consists of a modified cyclone burner 7 ½ in ID by 21 in long, with the inner wall used as one electrode together with a coaxial center electrode. Power was obtained by impressing an axial field of 3,000 G from an air core solenoid magnet. Tests were conducted by seeding natural gas seeded with potassium acetate and burning with preheated oxygen-enriched air. Power generation was lower than calculated because theoretical plasma velocities were not achieved.

Jan 1, 1972

By Martin D. Conyac

A 1984 Bureau of Mines investigation identified ho mineral resources in the Wilderness Study Area (WSA). However, four prospects in the WSA contain anomalous amounts of copper and silver minerals; one had traces of gold. Stratabound copper-silver occurrences appear to be prevalent. Quartz veins in the WSA locally contain trace gold, and one mine adjacent to the area produced some gold in the late 1800's. The WSA is underlain principally by Precambrian and early to middle Paleozoic quartzites, argillites, dolomites and limestones that have been complicated by faulting, generally tilted northeastward, and thrust southeastward over sequences of late Paleozoic sedimentary rocks. The stratabound copper-silver occurrences and gold-quartz veins are in Precambrian and Cambrian rocks in the western part of the WSA, as are similar deposits regionally. Sand and gravel, and limestone are abundant, but plentiful resources of these commodities are nearer established markets. In November 1983 there were 5 small groups of current claims oh the WSA boundary; none are patented claims. Probably less than 35 claims have been located within the WSA, mostly in the northwestern portion; hut over 100 claims have been located outside, near the northwestern boundary. Oil and gas leases nearly surround the boundary and 6 extend up to 1 mile into the study area. There has been no recorded mineral production from within the WSA. From 3 to 5 miles to the west, several lode nines in the Johnnie district have produced several million dollars worth of gold from quartz veins, and some silver and lead from galena-calcite veins. These veins generally trend northeasterly and dip northwesterly and probably do hot extend into the study area.

Jan 1, 1985

By B. Macdonald

In 1991, roofbolts were introduced as a primary support for inseam retreat longwall entries at CBDC's Phalen Colliery. Increasing mine depth (+550 m) necessitated replacing conventional inseam steel sets in these entries because they were being severely damaged during wall retreat and subsequently causing gate end problems. Roofbolts had been used in the Sydney coalfield between 1949 and 1963 in room and pillar working, however, some concerns arose with using roofbolts as a primary support in long (2.2 - 3.4 km) single entry roadways. In order to alleviate these concerns, a phased approach was adopted whereby conventional steel densities remained along with roofbolts. The roofbolt design was such that the roofbolts would be the primary support and the steel sets would experience little or no loading. A detailed geotechnical monitoring program was developed by both CBDC and the Cape Breton Coal Research Laboratories technical staffs. The results of this monitoring were used to build-up confidence in roofbolts and subsequently reduce the steel set densities until eventually only roofbolts were used as a primary support. This paper will discuss briefly the phased introduction of rootbolts at Phalen Colliery and more specifically the development of geotechnical data collection and interpretation.

Jan 1, 1994

By L. Andrews

Keywords: mineralogy, phase-chemical, chemical-looping combustion, XRD, SEM, EDS, QEMSCAN, PGM, slag, matte, ilmenite Mineralogy, traditionally associated with concentrator studies, is being increasingly applied to problems in pyrometallurgy. Such investigations commonly make use of a number of techniques, and the results are combined for a meaningful interpretation, which can lead to a successful solution. Mineralogical applications are described from pyrometallurgical operations. Examples are given of studies and investigations involving mineralogy in chemical-looping combustion, feed monitoring to platinum-smelting furnaces, and losses to slag in base metal and platinum smelting.

Jan 1, 2011

By Joshua Taylor Drake

This report answers specific questions concerning underwater blasting considerations, and blasting safety. The blasting considerations discussed consist of basic blasting principles, and new variables to be accounted for. Blasting safety will include the safety of personnel and structures. The environmental considerations will also be discussed with mitigation methods. To be most effective, this document requires the reader to be familiar with key fundamentals of explosive engineering. In order for a blasting professional to benefit from this report, the following questions will be asked:

Jan 1, 2015

By J. E. Friant

Until 1956, drill and blast was the only way to excavate rock. In that year, a tunneling machine using disc type cutters economically bored a small Toronto tunnel. Its amazing 105 ft/day set a new world record and set the stage for a new industry. The Disc Cutter Role in Excavation Mechanical excavation of hard rock is by now deeply ensconced in the heavy civil construction industry. All over the world, from the Swiss Alp Melange to Hong Kong Granite, to New York Gneiss, huge Tunneling Boring Machines (TBMs) create transportation, water and sewer tunnels. Powerful machines, boasting as much as 6000 hp, bore through rock, excavating in excess of 1400 tons per hour. The tool that makes this tunneling phenomenon possible is the single blade, rolling disc cutter. These hardened steel discs, from 15 1/2 to 19 inches diameter are arranged on a rotating cutterhead, to cut concentric circles in the rock. As the machine is propelled forward under great pressure, rock below each cutter is crushed. But the efficiency of the cutterhead is derived from the science of cutter spacing (distance between cutter paths). The majority of the rock excavated is not crushed, but flakes off in chips and chunks. No pick, tooth, or drag type cutting tool can duplicate the performance of a disc cutter. The economic use of drag type tools is limited to as low as 5,000 psi UCS rock strength in massive formations. In weakly bonded, foliated rock, drag tools do better, but are still limited to rock generally less than 15,000 psi.

Jan 1, 2002

By N. Sahin, K. Baris, A. Ozarslan

This paper aims to assess the current and future role of coal in energy strategy of Turkey and evaluates the compatibility of the policies to the EU energy policy and strategy. The Turkish government set targets to utilize more coal reserves of the country in next decades. However, the country is also in the process of becoming an EU Member State, hence, it is expected that the energy policies have to comply with the EU. Moreover, Turkey ratified Kyoto Protocol, thus the country should limit greenhouse gas emissions. Clean Coal, Carbon Capture and Storage (CCS) technologies are expected to become an important instrument for the mid-term reduction of CO2 emissions from coal-fired power plants. An alternative technique to the conventional CCS methods is CO2 sequestration by mineral carbonation. Turkey has significant resources of magnesium silicate minerals (olivine, serpentine) deposits which can be utilised in CO2 sequestration by mineral carbonation method.

Jan 1, 2011

By W. L. Brien, O&apos

Molybdenum alloys with good strength properties at elevated temperatures were produced by the powder metallurgical internal oxidation method previously applied to tungsten and known as oxyreaction strengthening. Commercial molybdenum powders were blended with 0 to 10 pet of a reactive powder, ZrMo2. The effects of composition, blending procedure, and sintering conditions on strength properties at elevated temperatures were studied. Strengthening was attributed to zirconium in solid solution with molybdenum and to the presence of submicrometer particles of Zr02. Several alloys had tensile strength and stress-rupture properties com-parable with those of the best commercial alloys. The maximum tensile strengths obtained were 92 kpsi at 1,200° C and 53 kpsi at 1,316° C. The maximum stress-rupture life at 30 kpsi and 1,200° C was 145 hours.

Jan 1, 1974

By Jr. Chilson

This paper addresses the slurry pump industry as it exists today by touching on the business aspects, and by discussing research and development for material metallurgy and hydrodynamics for wear improvement which reduce operating and maintenance cost for the customer. It demonstrates why OEM parts give better value for cost.

Jan 1, 1996

By G. R. Peterson

To determine the availability of lead and zinc from demonstrated resources, the Bureau of Mines evaluated 235 mines and deposits in 31 market economy countries. Of the 235 mines and deposits evaluated for this study, 186 were evaluated as zinc operations, 30 as lead operations, and 19 as copper operations. Demonstrated lead-zinc resources of market economy countries in 1981 were approximately 4.3 billion metric tons (t) of ore containing 221 million t of zinc and 97 million t of lead. Of these amounts, approximately 154 million t of zinc and 70 million t of lead are estimated to be recoverable. The analyses indicate that demonstrated resources in market economy countries should be sufficient to satisfy projected demand for primary lead and zinc through the balance of the century. The U.S. lead industry will continue to have a comparative advantage over the rest of the world industry, barring any drastic increase in the cost of compliance with pollution control regulations. It appears that the comparative disadvantage faced by the U.S. zinc industry will probably intensify owing to the relative quantity of lower cost zinc resources in other countries, especially Canada, Australia, Mexico, and Peru.

Jan 1, 1985

By R Castedo, L. M. Lopez, J. A. Sanchidrian

In 2014 the authors presented results from 13 tests made with two blasting seismographs on a vibration exciter. They measured coupling transmissibility as function of frequency (i.e. ratio of the velocity of the sensor mount to the velocity of the ground motion) from 16 to 200 Hz at one or two vibrations levels (5 mm/s or 0.2 in/s, and 20 mm/s or 0.79 in/s) with mounts freely placed, sandbagged, and anchored to a granite slab firmly attached to the plate of a vibration exciter. As the memory capacity of one of the seismographs prevented to cover low frequencies, e.g. 4-16 Hz, a new measuring campaign has been recently made to extend the study down to 2 Hz. In this campaign, two more techniques, in which the sensor mounts were fixed with thermal adhesive or a combination of duct tape and gypsum plaster, have been also investigated from 2 to 200 Hz at 5 and 20 mm/s. Free and sandbagged mounts lead to a weak coupling of the mounts to rock, so that transmissibility depends on the characteristics of the imposed rock motion (peak velocity and frequency). Measurements are accurate only at low frequencies (below 17 Hz for free mounts and 10 Hz for sandbagged) in the tested conditions (velocities up to 20 mm/s). Above these frequencies, ground motion in the measurement can be modified by a factor of 0.16 to 1.22. Anchored, glued and plastered mounts achieve a stiff rock-to-ground coupling, ensuring consistent measurements for the frequencies commonly found in blasting independently of the vibration level and the mount characteristics

Jan 1, 2015