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By Y. C. Liu, G. A. Alers

The anisotropy of Young's modules has been measured in a series of Cu-Zn alloys containing from 1 to 28 wt pct Zn and cold-rolled to 97.5 pct reduction in thickness. These modulus data show a transition in texture as a function of zinc content. In alloys containing 3 pct Zn or less, the texture is essentially that of copper. A transition is clearly seen to develop in 5 and 8 pct Zn alloys, and to have been completed in a 12 pct Zn alloy. Increasing the proportion of zinc to 28 pct does not produce any further changes in texture. The ease and clarity with which this texture transition can be seen in the modulus data is in great contrast with the inccertainty in the visual detertiination of the range of texture transition from a series of pole figures. It is also shown that the rolling texture of the high zinc content alloys cannot be a one-COIIIponenl texture, characterized by the (110)(112) ideal orientations, as usually assumed. A second, quite important component must also be present. Furthermore, the present data are inconsistent with matrix orientations on which the "oriented growth" hypothesis of the Formation of recrystallization textures is based. THE rolling textures of binary fcc alloy systems have generally been considered to lie between two terminal textures. One of these terminal textures is the copper type and the other is the 70:30 brass type. Alloys of intermediate solute content exhibit a texture which is said to be a transition between the two terminal textures. On the basis of efforts to correlate rolling and recrystallization textures, two concepts have been advanced in the literature on the nature of these transition textures. One school1 suggests that the addition of alloying elements, e.g., zinc, causes a gradual rotation about one of the (111) poles from the (358)( 523) ideal orientation of the copper-type rolling texture to the terminal {1 10)( 112) ideal orientation used to describe the rolling texture of 70:30 brass. This concept is depicted in Fig. 1 with the angle of rotation corresponding approximately to the zinc content and is designated here as the "rotational concept", since the ideal orientation of the transition textures varies continuously with alloy content. The other concept,' the "mixture concept", suggests that the copper-type rolling texture is a two-component texture. {358) (523) and {110)(112). The addition of alloying elements affects only quantitatively the relative amounts of these two components—a decrease in the amount of material in the {385}(523) orientation and an increase of that in the {110)(112) orientation with increasing solute content. An experimental distinction between these two concepts is essential to a better understanding of both the mechanism of formation of rolling textures and the subsequent formation of recrystailization textures in fcc metals. Because of the lack of resolution inherent in pole figures, it has not been possible to differentiate between the two concepts on the basis of this data. Both concepts, in fact, make use of the same set of pole figures but interpret them in a manner acco-rding to the view held.'" Experimental results obtained from inverse pole figures or selected-area electron diffraction3j4 simply -yield more refined pole figures but do not eliminate the ambiguity of interpretation. Quantitative measurement of an entirely different, orientation-dependent property must thus be considered

Jan 1, 1967

By Keith A. Heasley, Timotlly M. Barton

Historically, the surface subsidence over underground coal mines has been predicted using empirical profile or influence functions which have little or no connection to the actual mechanics of the subsidence- Without a mechanistic basis, establishing the exact site-specific parameters to use in these empirical methods has been problematic. A practical subsidence predictive method based on mechanics has the appealing capability of allowing the determination of site-specific parameters from fundamental properties of the overburden with minimal field calibration work. This paper presents a case study where a mechanics-based, boundary-element program is used to calculate the surface subsidence associated with several panels of a Northern Appalachian longwall coal mine. The program used in this case study is called LAMODEL, and it incorporates a frictionless, laminated overburden into a general purpose displacement-discontinuity code primarily designed for calculating the stresses and displacements in coal mines or other thin seam or vein type deposits. In this paper. the program is used to calculate both the underground convergence and the resulting surface subsidence at three longwalls. The subsidence results from the model are compared with field measurements and analyzed The results from the case study in this paper demonstrate that the laminated model with calibrated properties can easily provide fairly accurate subsidence predictions and is fairly flexible for fitting measured subsidence. However, additional subsidence predictive case studies are recommended in order to ultimately evaluate the potential of the laminated overburden model for practical subsidence prediction

By L. R. Herrmann

The research described in this report is the first phase of a comprehensive program for the development of a characterization for the structural properties of rock masses. The mathematical expression of the characterization is especial' tailored for use in conjunction with modern structural analysis procedures. The objective of the first phase of the project is to determine the feasibility of representing the structural properties of rock masses in terms of the analysis of an appropriate "representative volume" the results of this investigation are described in detail in the body of the report. The current state-of-the-art concerning the understanding and description of the fundamental mechanisms of rock behavior are determined from a survey of existing literature. The development of a representative volume that captures the most important of these mechanisms is described, In order not to unduly obscure the fundamental aspects of this development, the mathematical analysis of the representative volume is limited to plane strain conditions. A subroutine for the numerical evaluation of the proposed model (i.e., the analysis of the representative volume) is presented. The steps necessary for the incorporation of the subroutine directly into existing two-dimensional finite element structural analysis programs are described. Comparisons between the predictions of the proposed characterization and published results of simple laboratory tests are presented and discussed. Finally recommendations are given concerning suggested improvements of the model and the extension of it to the general three-dimensional case.

Jan 1, 1974

By Peter Rubie, Toni Kojovic, Fengnian Shi

"Mining companies have recognized that characterization of ore breakage plays an essential role in the design and optimization of comminution circuits.Recently the Julius Kruttschnitt Mineral Research Centre (JKMRC) has developed a new breakage model incorporating the effect of particle size, and a new breakage characterization testing device, called the JK Rotary Breakage Tester (JKRBT), which allows rapid testing of particle breakage under high energy single impact and low energy repetitive impact conditions.Positive feedback received from mining company sponsors to the new technology has prompted the JKMRC to further validate the device and the model through a formalized validation program using machines designed and manufactured by Russell Mineral Equipment (RME). The first unit was installed and commissioned at the Anglo Platinum laboratory in Johannesburg in March 2007 and four more major mining companies will participate in the validation program in 2008, including Barrick, BHP Billiton, Rio Tinto and Teck Cominco. The results from validation tests at the JKMRC and Anglo Research have shown that the JKRBT generates statistically similar breakage parameters to the traditional Drop Weight Test, but with significant advantages over its predecessor. Application of the JKRBT in geometallurgical testing with the AMIRA P843 GeM project has confirmed the JKRBT device offers a rapid and consistent method for determining the hardness of drill core samples. The JKRBT has the potential to revolutionize ore testing, with applications in laboratory impact breakage characterization of rock samples, drill cores, coal and other materials. It also stands poised to significantly advance the process control and management of comminution circuits since the concept is readily adaptable to on-line ore hardness measurement.INTRODUCTIONMining companies have long recognized that the performance of a comminution machine such as a crusher or an autogenous / semi-autogenous grinding (AG/SAG) mill depends not only on the machine operating conditions, but also on the “hardness” of the feed material to be broken. This recognition has driven significant interest in laboratory particle breakage characterisation and testing. The laboratory breakage characterization tests can be roughly classified in two broad groups based on their primary breakage modes: tumbling and impact/compression. The famous Bond ball/rod mill tests (Bond, 1952 and 1961) represent the typical tumbling test and have become the industry standard for estimating the specific energy (kWh/t) of rod and ball mills. However, as the energy application in the single particle impact tests can be well defined and controlled, the latter have received significant attention in the last 30 years. It was estimated that mining companies worldwide spent over three million US dollars on single particle impact breakage characterization testing in 2006."

Jan 1, 2009

A Simulation Study on Two-Stage Grinding with High-Pressure Roller Mills By the application of high-pressure roller mill (HPRM) in the field of mineral processing, computer simulation can be used to predict overall performance of a grinding circuit based on data obtained from HPRM comminution test in pilot scale or industrial scale. Using the model developed by Klymowsky and Liu for HPRM comminution and an extended Plitt's model for classification, steady-state of a closed circuit grinding can be calculated by means of a virtual locked-cycle-test conducted on computer. This paper presents the result of a simulation study on two-stage grinding with HPRM as the comminution device. The emphasis is put on the influences of circuit-configuration and way of recirculating classifier's coarse-product on the overall circuit performance. The results show that two-stage grinding with HPRM has its merit and flexibility in meeting demands of various grinding tasks in mineral processing.

Sep 13, 2010

By Forrest T. Moyer

Frequency rates of injuries per million man-hours of exposure were improved during 1965 slightly to moderately over those of 1964 at metal mines, nonferrous reduction and refining plants, nonmetal mills, stone quarries and mills, sand and gravel operations, and slag operations. However, at metal mills and nonmetal mines the rates of occurrence of work injuries were less favorable. The severity rates of injuries during 1965 were better than in 1964 at metal mines and mills, stone quarries and mills, and slag operations. Conversely, severity rates were worse at nonferrous reduction and refining plants, nonmetal mines and mills, and sand and gravel operations.

Jan 1, 1966

By Frank Chase, M. Terry Hoch, George Karabin, Joseph C. Zelanko, Christopher Mark

Pillar recovery continues to be a significant ground control hazard. During the past decade, 10 miners were killed during pillar extraction operations in southern West Virginia. Studies conducted during the past decade have identified a number of “risk factors” that can be used to evaluate pillar extraction plans: •Cut sequence •Final stump •Timber or Mobile Roof Supports •Roof bolting •Intersection span •Depth of cover •Roof quality •Age of workings For each of these factors, rock mechanics science suggests which alternative would be expected to be more risky. For example, numerical models were used to evaluate different cut sequences, and indicated that less roof convergence occurred with the outside lift method than with the Christmas tree in the particular environment simulated. For many of the risk factors, accident statistics confirm the science. One finding was that currently almost 70% of the retreat coal in southern WV is being mined with MRS. In contrast, timber supports were used in 70% of the past decade’s pillaring fatalities. This paper discusses each of the risk factors in turn, presents the relevant accident statistics, and shows how the risk factors can be combined to estimate the overall hazard. It also addresses the use of pillar design to minimize the risk of global stability hazards including squeezes, massive collapses, and bumps.

The Bureau of Mines has reviewed those portions of the "Tariff Schedules of the United States Annotated 1963" that are of interest to the minerals industry. This study shows to what extent rates of duty were altered (increased or decreased), and provides a bridge where possible from the old Schedule A classification sys tem to the new TSUS system of statistical reporting of import data. In general the new tariff has corrected previous classification defects and inconsistencies, but the rates of duties have not been materially changed.

Jan 1, 1965

By Jasper L. Stuckey

PYROPHYLLITE, first identified as soapstone,1 later as agalmatolite,2 and finally as pyrophyllite,3 has been known to occur in North Carolina for more than 130 years and has been produced intermittently in commercial amounts for the past 100 years. Pyrophyllite mining, however, has become a major industry in North Carolina only during the past 25 years. North Carolina and California are the chief producing states. Current annual production averages 125,000 tons, of which slightly more than 90 pct comes from North Carolina. Distribution and Geologic Setting: All known pyrophyllite deposits in North Carolina are associated with rocks of the Carolina Slate Belt,4 which is composed of a vast series of metamorphosed volcanic and sedimentary materials, occurring as two zones extending in a northeast-southwest direction across the state. The larger of these zones, lying in the central Piedmont region, varies from 8 to 50 miles wide. The smaller zone lies along the eastern edge of the Piedmont region and is partly covered by coastal plain sediments.

Jan 1, 1958

By D. DePaoli, P. Zhang

"Phosphate ore is one of the most significant secondary resources for rare earth elements (REEs), and Florida phosphate is of particular interest due to its much higher ratio of heavy REEs, especially yttrium. Analyses of numerous samples from different phosphate processing streams in Florida showed that heavy REEs account for about 50% of the total REEs in Florida phosphate with yttrium accounting for approximately 30%. It was estimated that the amount of yttrium from US phosphate processing could meet the world demand for this critical element. This research aimed at recovering both REEs and phosphorus from a phosphate flotation tails. This tails is composed of mainly silica and phosphate with a small fraction of heavy minerals including monazite and xenotime. Since the specific gravity of silica is 2.6 versus 3.2 for phosphate and 4.5-5 for rare earth minerals, pre-concentration of the minerals of interest by gravity separation was investigated first. A pilot scale shaking table was used in this study. One pass gravity concentration achieved a shaking table concentrate analyzing over 600 ppm REEs at about 40% recovery. Flotation of the shaking table concentrate resulted in a product containing 1809 ppm REEs and 26.37% P2O5 with corresponding recoveries of 73% and 82%. Sulfuric acid leaching at 75oC could recover over 60% REE and nearly all the P2O5. Higher REEs (>90%) recovery was achieved by conducting leaching at higher temperature with concentrated sulfuric acid. The phosphoric acid from leaching of the flotation concentrate is of superior quality compared with that generated from regular phosphate rock.INTRODUCTION Rare earths are a group of 17 elements including those of the lanthanum series, as well as the non-lanthanides, yttrium and scandium. These elements have very specific critical uses in a multitude of markets. For example, lanthanum is used as a catalyst in breaking down crude oil to produce gasoline, diesel and jet fuel and neodymium is the core magnetic component in high-strength magnets for electric car batteries, wind turbines and hard disk drives. Rare earths are also essential for many military applications. Many of these applications have no substitute materials and the move to green technologies has dramatically increased their demand."

Jan 1, 2018

By H Aral

A rotating magnetic field can be produced in a magnetic separator by using a magnet rotor fitted with alternate north-south magnetic poles, similar to the rotors currently used in modern eddy current separators. Rotation of the magnetic field causes ferromagnetic particles to rotate during magnetic separation. The particle rotation can then be used simply to remove entrapment during a conventional attraction magnetic separation (RMF lift separation), or it can be used to roll particles away from non-rotating particles, and to move them out of the separator under their own rotation (RMF rotation separation). RMF (rotating magnetic field) separation is a separation for ferromagnetic particles. These particles have a very ordered magnetism that is locked into directions of easy magnetisation in the crystal. As a result, if the external field rotates, the particles attempt to rotate with it. RMF separation uses this fact to rotate the ferromagnetic particles in a rotating field. In contrast, paramagnetic particles have a magnetism that can point in any direction with almost equal ease, and these will not rotate in a rotating field. By making use of this difference in magnetic properties, RMF rotation separation can separate ferromagnetic particles from paramagnetic, even when the particles have similar susceptibilities. Some particles such as both chrome spinel and ilmenite can contain ferromagnetic regions within a paramagnetic matrix. These ferromagnetic regions can vary from very small regions dispersed throughout the crystal, through thin lamellae, to larger more bulky regions. Although most natural ilmenite is ferromagnetic and generally has a higher magnetic susceptibility than paramagnetic chrome spinel, the susceptibility ranges for the two minerals overlap considerably (Allen, 2000a) due to the presence of these ferromagnetic elements, frequently making the conventional magnetic separation of these two minerals impractical. It is known that roasting a mixture of ilmenite and chrome spinel particles increases the magnetic susceptibility of the ilmenite while leaving the spinel susceptibility substantially unchanged. This makes the use of conventional (susceptibility attraction) magnetic separation more practical for the separation of these two minerals. However, very little is known about the effects of roasting on the response of ilmenite and spinel particles to a rotating magnetic field. For example, although the optimal ilmenite roasting conditions for conventional magnetic separation are quite well established such conditions may or may not be optimal for RMF rotation separation. Low intensity conventional magnetic separation on the basis of magnetic susceptibility can be made more accurate if it is carried out in a rotating field, because the rapid spinning of the separating particles prevents the formation of magnetic flocs, and reduces entrapment and entrainment. Medium intensity RMF rotation-only separation (no attraction component) has the ability to separate rotating (ferromagnetic) from non-rotating (paramagnetic) particles, irrespective of their relative magnetic susceptibilities. RMF rotation separation is of particular interest in this case because ilmenite particles generally rotate much better than the mainly paramagnetic chrome spinel particles, and roasting could enhance this difference further. Further information on the use of RMF to separate minerals can be found in Allen (2000a; b and c). The aim of this series of tests on a number of Australian ilmenites was to compare some different oxidising and reducing roast methods and to establish whether the use of RMF rotation separation improves the chrome spinel rejection.

Jan 1, 2001

By Milner A, Brockway D, Hodges S

The combustion of brown coals in Latrobe Valley power stations produces approximately 500 000 tonnes of solid wastes each year. This material, which includes precipitator ash, char and furnace ash, is hydraulically sluiced to large ashing ponds and the supernatant solution is ultimately discharged to the sea. There are significant operational and capital costs associated with the current ashing system. The ash produced from the Latrobe Valley coals is unique and has a wide variety of potential applications including soil conditioning, concrete and cement extenders, fillers in non-metallic materials, components of building products. In addition, with the application of appropriate technology, it is possible to extract char, sodium sulphate, calcium carbonate and magnesium metal (as the chloride) in substantial quantities from the ash. Research has been carried out to explore the prospects of these various options for ash utilisation. The research has focused on detailed characterisation of the ash material and the potential extraction efficiency for various species under various conditions. From this work a conceptual process has been developed and subsequent studies have been directed towards understanding variables and optimising operating regimes for product extraction. Currently, the work is concentrating on the separation of char, the development of high-grade carbon products and the extraction of sodium sulphate.

Jan 1, 1992

By K. B. Hodgins, P. Ouellette

"The North American mining industry faces challenging emissions regulations in the coming years with the introduction of new standards for off-road diesel engines. In order to remain competitive, industry stakeholders must invest in new technologies that are economically and environmentally sustainable.Westport Innovations Inc., Vancouver,British Columbia, has developed high-pressure direct injection (HPDI) technology that allows diesel engines to run primarily on natural gas with no intrusive engine modifications while reducing emissions of nitrous oxides (NOx), particulate matter (PM), and CO2 with no loss in performance. This is accomplished through late-cycle, high-pressure direct injection of natural gas into a diesel engine combustion chamber at the end of the compression stroke. A small amount of diesel fuel is injected first to initiate combustion, followed by the natural gas fuel main injection. The diesel cycle and its operating characteristics are fully retained including high combustion efficiency, lowspeed torque, high-power output, no engine knock, and fast response to load changes. Natural gas has not been an attractive fuel alternative in mining operations due to the reduced performance associated with spark ignition engines and the added weight and space required for compressed natural gas tanks. However, liquefied natural gas (LNG) can be stored with less impact on weight and space than compressed natural gas (CNG) by virtue of its increased energy density over CNG.Westport has applied HPDI technology to the Cummins QSK series engines for high horsepower applications such as power generation and mine haul trucking. HPDI can also be applied to other engine manufacturer platforms and market applications. Westport is interested in demonstrating the unique characteristics of HPDI in mine haul trucks to show diesel performance with low emissions levels using low-cost LNG fuel.Retrofitting a Tier 1 engine with HPDI would provide emissions reductions below the EPA 2006 Tier 2 standards while maintaining the performance and efficiency of the Tier 1 platform. The longer-term target is the Blue Sky voluntary standards of 3.8 g/kW-hr (2.8 g/bhphr) of NOx + non-methane hydrocarbons (NMHC), and 0.12 g/kW-hr (0.09 g/bhp-hr) of particulate matter (PM) and future standards. Typically, an HPDI engine is capable of reducing NOx emissions by 40% over diesel operation at the same efficiency. On a mining truck meeting Tier 2 standards, this NOx reduction would translate into NOx emissions approximately 14 t per year lower than under diesel operation. PM emissions are typically reduced by some 60% with HPDI fueling, which would translate into a yearly reduction of 650 kg. Similarly, engine-out greenhouse gas (GHG) emissions are reduced by 21%, resulting in a yearly reduction of approximately 950 t per vehicle.Above those of emissions reduction, efficient natural gas usage in mine haul operations would offer significant benefits in terms of fuel cost savings, which may be further combined with monetary emission credits. HPDI technology would enable operators to exercise environmental stewardship while gaining a competitive advantage in advance of new Tier 2 and Tier 3 emissions regulations. The advantages of natural gas use among mine haul truck operations can be replicated across a broad range of engines and applications."

Jan 1, 2005

By Chris Breeds, Ken Johnston, Omar Fulton

This paper describes the process typically involved with obtaining permits for quarry blasting in urban, suburban, and rural areas, including: content of SEPA (State Environmental Policy Act) driven documentation; regulatory review and comment; public interaction; public hearing(s); periodic regulatory review(s); negotiated solutions; monitoring; and the role of public interaction, demonstration(s), and education in the process. Case studies will be presented of projects undertaken in the State of Washington that illustrate the approach and regulatory interaction as well as the importance of public interaction throughout the process. Reference will be made to the role of national and state regulations and local codes and ordinances that provide additional limitations on blasting practice. The paper will also present regional blast monitoring data that are used in the permitting process and the layout and design of blast monitoring systems typically required as conditions of the quarrying permit. Our presentation will include tools, which we have developed to assist with explaining blast related phenomenon to both regulators and the public.

Jan 1, 2003

By H. Utsunomiya, J. Su, K. S. Tamimi, S. Yue, M. Sanjari, L. Kestens, Hara, A. S. Kabir, R. Petrov

Manufacturing of thin sheet is difficult in industries. Some approaches, such as small-draft multi-pass rolling, intermediate annealing, isothermal rolling and high-speed rolling were proposed to overcome the deformability. In this study, different rolling speeds from 15 to 1000 m/min were employed to twin rolled cast AZ31B magnesium alloy to different reductions. The results show thatAZ31B sheets rolled at 15 m/min and 100 °C has fractured for reductions of more than 30% per pass. However, by increasing the rolling speed to 1000 m/min the rollability was improved significantly and the material can be rolled to reductions of more than 70% per pass. The high speed and heavily deformed materials are fully recrystallized even at 100 °C.

Jan 1, 2014

By D. M. Doyle

"In this paper I will summarized the Falconbridge Nickel Mines1) energy costs and consumption data by fuel, process, cost centre and estimate our future costs and consumption patterns 2) detail the distribution of electrical energy 3) distribution of other forms of energy 4) describe present and planned energy conservation schemes; and 5) discuss economic justification and responsibility.There is sufficient material in this presentation to warrant several technical papers, however we felt that an overview of all our data and endeavors on the subject, would be most beneficial to those companies formulating energy conservation plans. The data briefly referred to in this slide presentation can be found in the technical paper.Over a five year period, total energy costs will vary between $63 and $94 MM depending on the future rate of energy cost escalation. An unrealistic 32% reduction in energy consumption is required to hold our own in the years ahead whereas an attainable 10°;, reduction in energy consumption would save $9 MM over this five year period.Total energy consumption, tonnage of ore delivered to plants and their ration BTU’s per ton of ore, are graphed for the years 1973 through 1976 and forecasted for the 1980’s. In 1974 we along with other member companies of the Mining Association, determined our purchased energy per ton consumption rate and set, as our goal, a 20% reduction by 1980. The dotted lines calculated from the energy audit, based on 1976 data shows there is a potential for a 10% increase in energy per ton. This could result from a lower than forecasted mining rate and operation of the new roasting, electric furnace and acid recovery facilities installed for environmental considerations at designed capacity."

Jan 1, 1978

By Emöke Imre

A point-symmetrical linear coupled consolidation model with displacement boundary condition is suggested for the description of the consolidation around the pile tip after pile penetration. Analytical solution is given. Main features of the solutions are predicted by the analysis of the system of differential equations and, the boundary conditions.

Jan 1, 2002

To minimize the equipment operator?s respirable dust exposure in enclosed cabs of mobile equipment by install-ing cab filtration and pressurization systems and by keep-ing doors and windows closed. Background Enclosed cabs are used on mobile equipment to protect operators from health and safety hazards. The primary health concern is overexposure to respirable dust. Examples of such equipment in mining include drills, dozers, haul trucks, and other equipment. When equipment is new, the operator?s dust exposure is normally at acceptable levels. As the equipment ages and gaskets and seals deteriorate, the air quality inside an enclosed cab can reach a point where it is no longer at acceptable levels for the equipment operators. In an effort to improve the air quality in enclosed cabs of older mining equipment, NIOSH has been performing research to retrofit cabs with new filtration and pressurization systems. Over the past few years, this research has shown that retrofit systems can substantially improve the cab?s air quality back to safe and acceptable levels. How-ever, this is only possible when a positive cab pressure is achieved and maintained. Thus, when a cab door or window is opened, the cab pressure drops to zero and the cab filtration and pressurization system is rendered ineffective. During a recent field study, the magnitude of this impact was noted when a drill operator repeatedly opened the cab door throughout the course of the drill cycle. Upon closer examination, it was determined that the cab door was being opened to manually guide the next drill steel into place each time an additional section of steel was needed to drill deeper holes.

Sep 1, 2008

By M Amanzadeh, S M. Aminossadati, B M. Masum, M S. Kizil, C R. Leonardi

Gas sensing systems are becoming more important in many industries such as oil, gas and mining operations. Particularly in underground coalmines, accurate and reliable monitoring of toxic and combustible gases such as methane, nitrogen dioxide, carbon monoxide and hydrogen sulfide is essential. Available conventional electrochemical sensors for gas measurements in underground coalmines suffer from shortcomings such as cross-sensitivity response, limited lifetime, high calibration cost, maintenance cost and safety. Recent studies have found that fibre optic-based gas sensors have potential to eliminate these issues. These sensors can also be used for long distance and distributed sensing of various gases, both of which are important for underground gas monitoring. The aim of this paper is to review the present underground mining gas monitoring systems and review the new generation of fibre optic-based sensing systems for use in underground coalmines.CITATION:Masum, B M, Aminossadati, S M, Leonardi, C R, Kizil, M S and Amanzadeh, M, 2017. New generation of gas sensors for underground coal mining applications, in Proceedings Australian Mine Vent Conference 2017, pp 189–196 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 28, 2017

By F. W. Jessen, C. C. Patton

Adsorbed films were formed on polished stainless steel specimens from dilute benzene solutions of two crude oil distillation residua. Although the two residua were extremely dissimilar in composition, contact angle measurements showed that the two films increased the wettability of the steel specimens to oil by equal amounts. Furthermore, the wettability of the films was essentially unaffected by the desorption techniques used. Paraffin deposits were formed from heptane-wax solutions on the same stainless steel specimens. These deposits definitely adhered to the surface. Presence of an adsorbed crude oil film on the metal surface increased its free surface energy and resulted in increased deposition of paraffin. The addition to the heptane - wax solution of small amounts of the same distillation residua that were used to form the adsorbed films resulted in decreased cohesive strength in the deposits formed, which resulted in decreased deposition. The presence of a crude oil fraction both in the solution and as a preadsorbed film eliminated the adherence of a deposit of any kind. A mechanism of deposition is proposed which explains the results obtained. INTRODUCTION The natural formation of any predominantly organic accumulation in oilwell tubing, surface flow lines or other production and storage facilities is called a paraffin deposit. These deposits restrict the production of crude oil, causing a substantial increase in production costs because of decreased flow capacity, expense for periodic deposit removal and unproductive downtime. The conditions under which such deposits form, their physical characteristics and the nature and severity of the problem created are extremely varied. Over the past several years, much progress has been made in developing and utilizing methods to remove accumulated paraffin deposition. However, like so many other problems, the basic stumbling block appears to be a lack of understanding of the fundamental mechanism involved in the formation of such deposits. Crude petroleum is known to contain considerable quantities of polar, surface active substances which Doddl has shown to be present at the oil-water interface. Denekas, Mattax and Davis2 observed that the wettability of reservoir rocks was drastically altered by exposure to crude oil fractions; and Zisman, et a1.3 showed that the nature of the compounds adsorbed on a surface would determine its wettability characteristics. Cole and Jessen4 and Ehrig5showed that surface wettability can have a profound effect on the magnitude of paraffin deposition, and Parks6 demonstrated chat the presence of certain adsorbed films on a metal surface would reduce the adherence of paraffin to that surface. Zisman7 has since advanced the theory that the conditions for adhesion are the same as for wetting. Therefore, it was felt that there was adequate evidence to support the supposition that adsorption of compounds from a crude oil might play an important part in paraffin deposition. ADSORPTION-WETTABILITY EXPERIMENTS Initial experiments were conducted to determine the effects of adsorption from solution of crude oil residua on the wettability of a polished stainless steel surface. Distillation residua with initial atmospheric boiling points of 700F were used in preference to the whole crudes in order to concentrate on the molecular weight range of interest, and to eliminate the possibility of composition change due to evaporation of the light ends. Also, these high boiling materials would be expected to be adsorbed from the whole oil in preference to similar compounds of lower molecular weight.

Jan 1, 1966