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By P. Kobylin, K. Haavanlammi, K. Valkama

"Base metals and precious metals can be recovered from a nickel matte or nickel concentrate using the Outotec nickel chloride leaching process. The raw material is leached with hydrochloric acid and the metals are recovered by solvent extraction, where ammonia is used to control the pH. Ammonium chloride is regenerated to ammonia and the side product of this step is calcium chloride solution. The regeneration utilizes either calcium oxide or calcium hydroxide. The calcium chloride solution is used to convert sulfuric acid into a hydrochloric acid solution while producing pure gypsum as a side product. The regeneration and reuse of ammonia and hydrochloric acid in this process will have a positive impact, from the point of view of both operating costs and environmental sustainability. This paper concentrates on the test work and technical concept development performed by Outotec to implement and develop chemical regeneration and recycling into a vital part of the nickel chloride leaching process.INTRODUCTION According to a nickel market analysis, the nickel market is expected to grow in the future. Main driver for this growth is the increase in stainless steel consumption as the living standards are equalizing globally. The expected increase in the amount of electrical cars and the need for nickel in the batteries of electrical cars also gives potential for the increased need for nickel in near future. At the moment the use of nickel in nickel-cobalt-manganese (NCM) and nickel-cobalt-aluminium (NCA) Li-ion batteries is in the range of 14 ktpa. It is estimated to increase to the level of 90 ktpa by 2025. In every era of the nickel industry, Outotec has been constantly developing new processes to create environmentally sustainable and economically viable processing routes. The Outotec® Nickel Matte Chloride Leaching process is a great example of a process that is flexible regarding raw material and could also treat nickel raw materials that are difficult for smelters. Outotec’s main options for pyrometallurgical nickel treatment include the Outotec® Direct Nickel Flash Smelting process (DON) and the Outotec® Ausmelt TSL process. The DON process is operated in Boliden Harjavalta Nickel Smelter in Finland. Ausmelt process is in use for example in Daye nonferrous plant in China. In the Outotec® Direct Nickel Flash Smelting Process, a sulphide nickel concentrate is processed in an Outotec Flash Smelting Furnace (FSF). Producing concentrates and processing them by Outotec Direct Nickel Flash Smelting to matte followed by hydrometallurgical refining offers a reliable route from concentrate to product. In the DON process, high-grade matte with low Fe content is produced in the FSF and the valuable metals in the slag are recovered in an electric furnace (EF). The Outotec® Ausmelt TSL process can use a large variety of raw materials (concentrates, secondary material and scrap metal) as feed. Fuel and oxygen are injected into the furnace through TSL (Top Submerged Lance) and this enables efficient smelting. Both Flash Smelting and TSL plants produce nickel mattes, which can be refined with Outotec hydrometallurgical processes."

Jan 1, 2017

By Cherie H. Tilley

The possibility of drilling oil wells from underground locations is not a new concept. It bas not been cost effective for the oil industry in the past and therefore disregarded. Today's state of the art in tunneling and shaft sinking greatly improves the potential for this type of oil field development scheme. This report presents a plan for providing a aeries of drilling bases and the design of the drilling location. The design minimizes the amount of excavation needed to develop the oil field and maximizes the use of rapid excavation techniques.

Jan 1, 1983

By Jorj O. Osterberg

The Osterberg (O-Cell) Method makes it possible to separate the side shear resistance (skin friction) from end bearing. The O-Cell is placed on or near the bottom of a drilled shaft and after the concrete is poured and cured, an equal upward and downward pressure is applied. From the test, the load-upward deflection curve in side shear and the load-downward deflection curve in end bearing are drawn. Typical curves are shown where the ultimate load in side-shear is reached and where the ultimate load in end bearing is reached. Several examples of tests in which the test load reached ultimate loads far in excess of what was expected are shown. The side shear in rock sockets is shown to be much larger than generally estimated. Examples are given of where side shear is smaller than expected and the reasons discussed. Disturbance of the sides of drilled holes due to poor construction techniques and ways to avoid these conditions are considered. Examples of bottom hole disturbance are given and ways to prevent the disturbance are discussed. A graph showing the actual measured capacity of drilled shafts compared to the estimated capacity as a function of the hardness and strength of the soil or rock is presented.

Jan 1, 1999

By O. A. Carson

Introduction Although the equilibrium conditions of the copper-tin alloys have been the subject of a ?great amount of research, the equilibrium diagram is still in doubt. The first systematic investigation of the series was made in 1894 by Le Chatelier, who published a freezing-point curve. In 1895, Roberts-Austen and Stansfield published the complete liquidus and partial solidus curves, which they modified somewhat in 1897. Their liquidus as given in 1897 is essentially that accepted today (Figure 3). Haycock and Neville also published a liquid us curve in 1897. In 1898, William Campbell published a series of micrographs showing the changes in microstructure which accompanied the thermal changes of Stansfield? s diagram. The classic work on the bronze series was published by Heycock and Neville in 1903. Their diagram was based on both thermal and microscopic evidence, and is the first for this series of alloys which can be considered nearly complete. Further, it was the first bronze diagram in which any attempt was made to apply the phase rule in the interpretation of the thermal and microscopic results. That portion of Heycock and Neville's diagram covered by the present work is reproduced in Figure 7.

Jan 1, 1929

Laboratory electrical resistivity measurements of rocks are reviewed. Inductive and galvanic methods are discussed together with the ten important experimental factors which should be considered in an investigation.These experimental factors are electrodes, sample preparation, measurement errors, temporal current variations, current density, frequency, electrolyte composition, electrolyte saturation, pressure, and temperature.

Jan 1, 1969

By G. W. Center

This manual is intended to assist federal, state, and local regulatory and planning agencies, the mining industry and consulting engineers in determining the regulatory, environmental, technical and economic constraints influencing the site selection, planning, construction/operation and reclamation phases of a waste disposal facility. The information presented illustrates that factors affecting an individual site may be simple or very complex. This manual discusses methods for making future land use decisions, determining regulatory requirements, evaluating physical, chemical and structural properties of the disposed waste and selecting appropriate waste disposal methods and control techniques. Procedures and guides in the manual will assist personnel in assessing the complexities of waste disposal on a site specific basis. The major types of waste disposal systems are discussed and evaluated in terms of their advantages and disadvantages and applicability to varying site conditions and waste characteristics. Appropriate references following each chapter provide more detailed data on material presented in the text.

Jan 1, 1982

By Branagan D. F

The geology of the area studied is briefly described, together with the prospecting methods used in the search for copper, lead, zinc and uranium ore bodies.Four prospects, Mt. Corella, Yanasinga, Lawlor's and Greenmount, which were diamond-drilled, are described in detail and geochemical results are discussed in relation to the mineralization found. Copper anomalies were found wherever intrusive rocks were mapped, and showed a much closer relation to geology and mineralization than did the predominantly lead and zinc anomalies.Geochemical prospecting aids in the overall mineral search programme because of its speed and economy, as it helps to pinpoint areas worthy of detailed geological examination. Geochemical anomalies are a guide to favourable zones but may not indicate the presence of ore.INTRODUCTIONDuring 1953-55 the National Lead Company of New York carried out a search for minerals in an area south and west of Cloncurry (Fig. 1) in rocks of Precambrian age. After reconnaissance mapping, a number of prospects were chosen for closer examination by detailed geological mapping and geochemical sampling, and from these prospects, five sites were selected for drilling.This paper records the salient features of the exploration programme and discusses the geology and geochemistry of four of the prospects-Mt. Corella, Yanasinga, Lawlor's and Greenmount. Practically all the prospects examined showed high zinc "anomalies" or "dispersion" trains. Greta, Mt. Corella and Lawlor's prospects showed some copper anomalies and, to a lesser extent, lead anomalies. In particular, Greenmount exhibited striking copper anomalies.

Jan 1, 1960

By ATF Publications

The following is a summary of the changes that were incorporated into the new Federal Explosives Regulations, 27 CFR Part 55, dated 9/2000. However, in light of the recent events of September 2001, additional changes in the Federal Explosives Laws and Regulations may be forthcoming. The nature and extent of any such potential changes are impossible to gauge at this time. However, this synopsis of the changes contained in the September 2000 Orange Book, ATF P 5400.7 was current at the time of this writing. Any questions regarding this paper should be directed to the Public Safety Branch in ATF Headquarters in Washington, D.C.

Jan 1, 2002

By B. K. Gorain, A. W. Stradling

"The traditional metallurgical scale-up techniques for flotation plants are based on lumped flotation rate constants, dimensionless hydrodynamic numbers and the use of safety factors. Once the plant has been designed, the flotation principles that govern scale-up play almost no role in the optimization of the circuit to meet its metallurgical targets. This deficiency can potentially lead to a plant design incapable of meeting its targets, especially when circuits incorporate large flotation cells. This paper demonstrates the application of the k = PSbRf model in providing a suitable framework for flotation modelling, scale-up and circuit optimization, thus presenting an integrated approach to the problem. Studies were conducted at Teck Cominco’s Red Dog concentrator to characterize cell hydrodynamics, gas dispersion properties, froth flow behaviour, entrainment and ore floatability to obtain the key data necessary to develop a model for the flotation circuit. The findings of these studies are presented in this paper, which provide valuable insights into the modelling and optimization of the Red Dog flotation circuit. IntroductionThe traditional methodology for flotation scale-up and plant design is based on the ruleof- thumb with safety factors and dimensionless hydrodynamic group similitude considerations. With the recent trend toward larger flotation cells with volumes of 150 m3 and greater in concentrators, the problem of scale-up has become even more acute. The scale-up factors that may have been tolerated on smaller cells are not applicable to larger cells. The transportation of froth in these large cells adds further complexity to the problem. Arbiter et al. (1980) foresaw this problem and pointed out that if scale-up were attempted by rule-ofthumb and trial-and-error, the probability of failure would then increase with scale. This problem is confounded by the fact that the design and scale-up considerations used for a new flotation circuit play almost no role in optimization of the circuit to meet its metallurgical target. This results in a plant design, which may be incapable of meeting its metallurgical targets. There have been several instances where new concentrators have required significant circuit modifications and additional capacity to achieve design targets."

Jan 1, 2003

By P. E. Hand

Coal is a complex heterogeneous commodity that can be mined in a number of ways and needs to be processed to a homogeneous quality that satisfies the customer?s requirements, while attempting to maximize revenues. Only a small proportion of coal is suitable for metallurgical use. Export coals cover a wide range of qualities and some coals can be used optimally in the raw state for energy production. Critical quality parameters vary and can be a combination of heat value, ash, volatiles, sulphur, phosphorus, sizing, amongst others. The level of beneficiation is generally dictated by the washability of the coal, mining contamination, and the target product quality. The steps in the coal chain covered in this paper comprise exploration, mining selections, production, the washing process, and product delivery. Many points of sampling are needed to maximize yield at the correct quality, and some of these will be described in the paper. Keywords coal chain, coal beneficiation, sampling.

Jan 1, 2014

By W. H. Ode

Because trade increased among various nations after World War II, the Coal Committee of the Economic Commission for Europe established a Classification Working Party in 1949 to develop an International system for classifying coal. Although national classification systems existed, they had been developed in accordance with characteristics of domestic coals without reference to coals of other countries. Terms for describing similar or identical coals differed in each nation. This caused confusion in evaluating coals shipped in international trade and also hampered exchange of technical information on problems of coal utilization. Experts4/ participating in the classification project early in their work agreed that two systems should be formulated, one for the higher rank coals or so-called "hard" coals in European terminology and the other one for the lower rank coals, the latter designated mainly as brown coals and lignites in the various countries. Rank refers to the degree of metamorphism (progressive alteration) in the natural coalification series from lignite and brown coal to anthracite. The system for classification of hard coals was published late in 1956 as a document of the United Nations.5/ Results of a study for applying this system to American coals were published in 1958.6/

Jan 1, 1960

By N. A. D. Parlee, M. M. A. El-Naggar, G. 8. Horsley

The apparatus was of a modified Sieverts type1&apos;2 with a reaction tube designed to function also as the cell component of an oxygen pressure gage. The reaction tube assembly is shown in Fig. 1 and described in Table I. The main body is a 1-in.-OD 15 mol pct calcia-stabilized zirconia tube. The ground-glass joint, g, the male part of which carried a prism for optical pyrometer use, was connected to the remainder of the Sieverts apparatus. The calibration of the cell (at its 1000°K operating temperature) for internal oxygen pressures (PO2in) in the range 0.2 to 10 9 atm was made against internal air pressures measured by mercury manometer and McLeod gage. At very low po2in values down to l<Tn atm the performance was checked by comparing pQ calculated from electromotive force measurement when the apparatus was filled with a) pure CO gas and b) a CO-CO2 mixture of the ratio CO-CO2 = 1:0.398, with Po, values calculated from the equilibrium constants of the following reactions at 1000°K:

Jan 1, 1968

By Han Jie

The results of full scale plate load tests on stone columns on soft clay in coastal areas are presented in this paper. Four load tests were made, two of which were performed on the ground treated with stone columns, one on an isolated stone column and the last one on the untreated ground. For a given stress range, the settlement of the rigid plate, the stress concentration factor, and the excess pore water pressure were measured. It is found that the distribution of vertical stress beneath the rigid plate supported by the composite ground of stone columns is very different in shape from the one by the untreated ground, that the stress concentration factor has a relation with the stress level and time, that the stone columns increase the bearing capacity up to by 2 times, and that the ground stabilized by stone columns is of great advantage to keep the foundation stable.

Jan 1, 1991

By Mónica Maria Jiménez Correa

A geração de resíduos sólidos tem se convertido em um problema para a sociedade. Milhões de toneladas de resíduos sólidos são produzidos diariamente no mundo causando numerosos problemas ambientais e sociais. Além disso, o acelerado consumo junto com o avanço tecnológico e o curto ciclo de vida dos produtos têm elevado a quantidade e complexidade dos resíduos sólidos descartados, tornando a situação ainda mais complicada. Nas últimas duas décadas, a indústria de equipamentos eletroeletrônicos (EEE) tem acelerado sua produção vertiginosamente, tendo como resultado o subsequente aumento na geração de resíduos de equipamentos eletroeletrônicos (REEE). Os REEE apresentam na sua composição materiais tóxicos e se descartados irregularmente, podem contaminar o meio ambiente e causar danos à saúde publica. Por outro lado, a sua reciclagem é um assunto que merece atenção especial, não só do ponto de vista de tratamento de resíduos, mas também do ponto de vista econômico. A fim de contribuir com a reciclagem e a diminuição dos resíduos sólidos, o presente trabalho pretende apresentar um estudo do processamento mecânico das placas mães de computadores descartados, visando recuperar o cobre, o níquel e o zinco presentes no resíduo.

Aug 7, 2018

By Galen H. Clevenger, MARTINUS H. CARON

Although there are exceptions, oxidized silver ores containing the higher oxides of manganese are generally refractory to hydrometallurgical methods of treatment. When these ores are of high enough grade they can be smelted; indeed, some rather low-grade ores of this type have been smelted at a profit because of their fluxing value. In the past, when these ores could not be smelted, they either were not treated or were treated at low efficiency, generally by cyanidation. The need for thorough investigation of the problem was therefore evident for some time before the writers began their research. The problem of treating manganese-silver ores seems to have been recognized first about 35 years ago by C. W. Goodale in applying pan amalgamation at Tombstone, Ariz. He attributed the low extraction of silver to the fouling of the mercury by manganese rather than to the presence of a refractory compound of manganese and·silver. Although definite knowledge as to the cause of the poor extraction of silver was lacking, a more or less effective preliminary treatment, that is, a chloridizing roast, was applied. E. M. Hamilton, in 1909, was perhaps the first to define clearly the problem as it affects the cyanidation of silver ores and to suggest possible methods of preliminary treatment. Most of the work done in the interval between the appearance of Hamilton's paper and the assumption of the investigation by the authors was in the nature of routine tests covering suggestions already made rather than of research directed to a fundamental study of the problem. No practical application has so far been made of any of these proposed processes. The investigation described in this bulletin has proved that there s a refractory compound of manganese and silver-probably a manganite- insoluble in cyanide solution and other common solvents for silver. Although this compound has not been isolated from natural ores, it has been made synthetically, and shows all the characteristics of the natural product. Furthermore the authors have shown definitely that heating in air a relatively small amount of a silver compound with a large excess of silica (in the proportions ordinarily occurring in a commercial silver ore) renders

Jan 1, 1925

Results obtained from small scale tests using Australian tin concentrates indicate that metallic tin containing less than 0&#183;1 per cent iron can be recovered by a two-stage process using hydrogen and make-up chlorine. In the first stage the concentrate is ground,. pelletized, roasted, and reacted at 650&#176;C with HCI and H2 to volatilize the tin as SnOI2. The volatilization reaction is conducted with cocurrent gas and solids flow because it was found that the use of cocurrent flow yielded a solids residue substantially free from FeCI2. The second stage uses a technique termed &quot;reflux reduction&quot; during which the SnOl2 produced by volatilization is reduced by hydrogen to form tin and a gas containing HCI and H2 of sufficiently high HCI tenor for recycle to the volatilization stage. The elimination of tin ranged from 98+ to 99&#183;7+ per cent of the tin from concentrates containing 5 to 50 per cent tin, respectively. The process should be capable of continuous operation, and a tentative calculation has shown ,that a treatment rate of 12,000 tonnes of tin concentrate per year could be obtained in a volatilization reactor 1&#183;1 m in diameter and 6&#183;1 m high. The process may have particular application to finely divided concentrates containing less than 20 per cent tin.

Jan 1, 1974

By d&apos, D. V. Andrea

Nine rock properties were determined for rocks coming from 49 locations and having a wide range of compressive strengths. Plots of the nine rock properties versus each other were prepared. A stepwise multiple linear regression analysis was performed to obtain several equations for predicting compressive strength. Both linear and curvilinear relationships were assumed between compressive strength and the other rock properties. The prediction equations had multiple correlation coefficients ranging from 0.947 for an equation with 1 variable (point load tensile strength) to 0.986 for an equation with 25 variables. Of the properties tested only point load tensile strength could be used alone to estimate compressive strength with fair accuracy.

Jan 1, 1965

By Ulf G. Gwildis

The Bright water Conveyance System includes 21 km of tunnels mined by two earth pressure balance Tunnel Boring Machines (TBMs) and two slurry TBMs. The probabilistic baseline approach defined in the Geotechnical Baseline Report (GBR) can representatively be verified by use of a comprehensive tracking system to identify face conditions that allows comparison with the baselines. The glacial geology includes a high lateral variation in soil types that, when combined with the pressurized face tunneling methods, creates challenges for documenting face conditions. Baseline tracking using spoil samples and TBM operational parameters provides information to document actual conditions and support resolution of differing site condition claims.

By S. L. Windes

This report presents physical and petrographic properties of approximately 60 types of rock from operating mines or mineral-investigation projects and supplements Repot of Investigations 4459, Physical Properties of Mine Rock (hereinafter referred to as Part I). The physical properties evaluated include the following: Apparent specific gravity Apparent porosity Compressive strength Flexural strength (modulus of rupture) Impact touchiness Abrasion hardness Scleroscope hardness Modulus of elasticity (Yourg?s modulus) Modulus of rigidity Specific damping capacity Longitudinal bar velocity

Jan 1, 1950

By Víctor De la Cruz

Dado que la mina Rosaura (Lima) se dedica a la explotación de minerales polimetálicos como el zinc, plomo, cobre y plata, la caracterización geomecánica de su estructura, morfología y reservas demostró una tendencia hacia los métodos masivos -en tanto presenta ventajas técnico-económicas comparativas frente a otros posibles métodos como el corte y relleno y conjunto de cuadros. Por ello, el presente texto describe el método de “Hundimiento por Subniveles” (Sub Level Caving – SLC), como el más indicado. El SLC se basa en la utilización del flujo gravitacional del mineral fragmentado a través de la perforación, voladura, y el hundimiento de la roca estéril principalmente de la caja techo. El diseño del elipsoide de extracción determinará la ubicación de los Sub niveles y Drawpoints, los cuales serán críticos para hacer rentable el minado, de forma que los beneficios actuales del método indican niveles altos de Seguridad, recuperación alta de mineral, bajos costos y mejora constante de la productividad.

Sep 9, 2007