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By József Faitli, Barnabás Csoke, Károly Solymár, Zoltán Hatvani, Dimitri Papanastassiou

In most cases, the sizing of dry or wet mills for ore processing is primarily based on the determination of the Bond grindability index, using the Bond-Kjos-Rowland relations. In several cases, grinding takes place under conditions different from these and the grinding conditions have a great influence on the postgrinding process. This is particularly true for the grinding of bauxites where grinding takes place in alkali, often in higher temperature in alkali Liquor. So it is necessary to develop a testing method providing a reliable grindability index even under these special circumstances and allowing a more precise mill sizing. Therefore we surrounded the grinding crucible of the Hardgrove mill with a crucible furnace to heat it. The new heated mill is suitable to determine the grindability index under temperature-controlled circumstances, in liquids (water and alkali) with different temperatures. The required heating power is 2000 W. In the implemented equipment we installed four 230V/500W electric heating wires made from heat-resistant alloyed material and surrounded by ceramic insulators. The temperature and temperature-gradient are measured by four PT100 platinum thermal resistors. The data acquisition and control program written in the C language in the Lab Windows CVI program environment measures the voltage proportional to the temperature. Determining the grindability indices of hungarian and greek bauxites experimentally, first dry grinding tests were carried out under standard conditions. During wet and alkaline grinding, to 50 g of dry bauxite 85.5 g of industrial alkali with a concentration of about 200 g/l was added. As grinding aid 2 g of CaO (4 % of dry bauxite) was dosed. From the data it can be concluded: - The tested bauxites show a similar behaviour against temperature change. However, the extent of grindability change is different for different bauxites. - Soft Hungarian boehmitic bauxite can be ground in a high-temperature alkaline medium better than hard Greek one. The increase of grindability according to the high-temperature Hardgrove indices: (kHT = Dry o HT,alkaline H /H ): for hard Greek and soft Hungarian boehmitic bauxites: kHT = 1.7 and 2.4 respectively; according to estimated Bond indices (kB,HT =Wi,dry/Wi,HT, alkaline ): kB,HT = 1.6 and 2.1. - The increase of grindability is the most important factor the reaction of kaolinite with caustic liquor and lime and the loosing of the textural structure at 80 ºC and especially at 100 ºC.

Jan 1, 2003

By Jury P. Nazarov

"At present the traditional study of crystal lattices of nmerials in a topic “flota tion mineralogy ” is used up. The present investigation is development of the a sclsical approaches to t he analy sis of ideal crystal lattices and f ormation on the basic obtained results of consultation, having practical chara cter.The strategy of develop ment floatation reagents i s offered, which basic pr inciple – complementary assembling m olecules forming surface co mpounds so thatth e steric charact eristic of the “visitor "" (of a polar gro up of molecule SAS) corresponded to the st er ic requirements of the ""o wner"" (elementary cell of a mineral), or coincided inter molecular cavities). In itsh case process of for mation of surface com pounds ca n be considered(a first approximation) as a realization of a principle of the design er "" LEGO "".The approach, which basic idea consi deration actioonf reactant ions and ions of ele mentary cell as three-di mensional objects is developed. And at suchp paroach the laws of a ster eometry - laws describin g spatial effect s are applicable. Thus it is possible toconsider a miner al surface as a mat r ix - basis for formation of the requirem ents to polar group of a molleec cuollector, and or (it is possible) depressant. As a whole approach represents a generalized principle double com plementation, enveloping both power, and geometric asp ects (concept ""lock "" and “key "" - spatial conform ity. Figure 7 (left). Fragment of a crystal lat tice of ap atite. Oleic acid ions interact on ly with th e calcium cations locate d on a long axi s of an elementary c ell. Magenta colour represe nts the calciu m cations, which are n ot particip atin g in interactio n, as th e degree of screening by ions neighbours exceeds 1.Figure 2. (right)The illustration of space complementary. “Afterbuilding” an elementary cell of apatite (radical PO4) related molecules of the visitor – alkyl phosphate (polar group PO4). Cations of calcium are not shown."

Jan 1, 2003