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By Andrew McGrath, Geraldine Lyons, Sarah Barcelona

In the dynamic and challenging modern industry landscape, understanding and unleashing the true role and contribution of technical teams is crucial to business success. The cyclical nature of industries has led to shifts in the technical professional’s place within the organization and the technical skills that are desired most. This paper reframes the pivotal role that technical professionals play within complex operating assets to maximize value and realize full potential. This investigation focuses on the Rio Tinto Kennecott Technical group’s cultural journey, which is underpinned by an investment in its people. The conflict between legacy industry beliefs and the necessity for cultural change emerges. This is illustrated by a deep dive into the evolving case study of Kennecott’s Bingham Canyon Open Pit Mine Technical team. Here, a multi-faceted approach to cultural change is helping to unlock the team’s contribution to the life extension of an aging asset. Guided by a vision and strategic roadmap, this approach is part way through a 5-year implementation period and is yielding encouraging business outcomes.

Feb 1, 2024

By R. Jolicoeur, J. F. Jackson, M. A. Green

"The design, construction and commissioning of Kiena Gold Mines Limited's new mill was completed in 15 months ending in September 1984. Rated at 1250 tonnes per day the mill incorporates the latest innovative technology such as semi-autogenous grinding, carbon in pulp, pressure stripping and induction furnace refining. The mill is housed in a pre-engineered building with the leach tanks and thickeners located outdoors in spite of the intense winter cold. 1.0 INTRODUCTION AND HISTORYThe operations or Kiena Gold Mines Limited are located in Dubw1sson Township, approximately 10 Km west of Val d'Or, in the Abitibi region northwestern Quebec. Comprised of 59 mining claims covering 1214 hectares, a large portion of the mining property is overlain by the waters of Lac de Montigny. Sometime between 1911 and 1914 Barney Parker discovered gold in a shear zone on an island in Lac de Montigny that now bears his name. The first shaft the Parker Shaft, was sunk in 1936 from the island to a depth of 136 meters but owing to the known veins being of limited extent and the onset of the Second World War operations were terminated in 1940. In the early l960 1 s exploration drilling indicated an orebody of 4,500.000 tonnes at 6.3 grams of gold per tonne. A causeway was built to link the island to the mainland in 1963 and a new 3 compartment shaft was sunk to 403 metres. The orebody was further delineated and the ground conditions within the orebody and surrounds were evaluated.At the end of 1965 the property was placed on a care and maintenance basis as a mining operation would be marginal with gold selling at $35 per ounce."

Jan 1, 1986

By Michael J. Brown

Load testing is important for controlling the quality of piled foundations. The Statnamic test is an alternative to existing testing methods with a load duration that lies between that for static and dynamic tests. Current methods of analysis offer excellent correlation between static and Statnamic tests for coarse-grained soils but often over-predict the capacity for fine-grained soils. Thus a calibration chamber is being used to produce instrumented beds of clay with reproducible properties. A model pile placed in the beds can be loaded at varying rates using a computer controlled servo-hydraulic system. Results from the modelling will be used to improve methods of analysis and govern the design of a full-scale study. Initial results suggest the rate effect can be represented by a power law relating pile velocity and resistance. Statnamic loading of the model pile produced large negative pore pressures in the clay bed.

Jan 1, 2002

By M. I. Brittan

Cyanide leaching of two West African gold ores was studied in multiple laboratories to provide process-engineering data for plant design purposes. Unusually slow leach extraction kinetics were observed using routine cyanide leach test procedures with pregnant solution monitoring. Carbon-in-leach testing, however, showed normal rapid kinetic behavior, with the same ultimate gold extractions being reached in much shorter elapsed times. Kinetic curves based on washed solids assays also exhibited more typical leaching characteristics. The results bore all the hallmarks of some equilibrium inhibition of the leaching. It was surmised that ore gangue components were responsible for weakly adsorbing gold-cyanide complex reaction product, thereby holding up soluble gold in the solid phase. The term ?preg-borrowing? was coined to describe the reversible phenomenon and distinguish it from irreversible preg-robbing. The two ores investigated may represent an extreme form of a more general effect that in most instances might pass unnoticed. The effect can lead to misinterpretation of kinetic leach curve data and underestimation of calculated ore head grades.

Jan 1, 2008

Kinetic Behaviour of Solid/Solid Separation of Ultrafine Particles in Aqueous Suspension

Sep 13, 2010

Kinetic Dependence of Refractory Gold Sulfide Biooxidation Using Different Microorganism Association In this investigation, refractory sulfide concentrate from a deposit located in northern Russia was treated using biohydrometallurgical technology. The objective of this work was to compare the accelerated refractory sulfide concentrate biooxidation abilities of the pure and mixed mesophilic and moderately termophilic acidophiles cultures. Pure culture of Acidithiobacillus ferrooxidans and two associations of the: Acidithiobacillus ferrooxidans + Acidithiobacillus thiooxidans and Acidithiobacillus ferrooxidans + Acidithiobacillus thiooxidans + Leptospirillum + Sulfobacillus were used in this investigation. Results of sulfide concentrate bioleaching were analysed using the enzyme catalysis theory. Different effective kinetics parameters were calculated for Michaelis-Menten equation, such as Michaelis' constant and maximum rate of the enzymatic reaction. It was shown that the increase of microorganisms' species decreased Michaelis' constant. Lower Michaelis' constant characterises increasing bacteria ferment affinity to substrate (treated concentrate). As a result, the rates of sulfide minerals biooxidation have increased. This investigation has demonstrated that cultures of the different microorganism species, including moderately termophilic, allow to enhance different parameters of the biohydrometallurgical technology for the refractory gold sulfide concentrate treatment. We can see that bacterial leaching stage duration decreased and sulfide minerals oxidation increased. When the bioresidues were subjected to the hydrometallurgical stage, which includes aeration and sorption cyanidation, the operation factors were also enhanced. The decrease of aeration duration and the growth of the precious metal extraction by sorption cyanidation was achieved. Cyanide consumption was also reduced. The results of this investigation were used in design of an industrial plant.

Sep 13, 2010

By P. W. Lotz

Traditionally, bottle roll tests have been used to optimize the extraction process for best gold extraction and recovery. Such tests typically involve exposing the ore to defined reagent concentrations (lime, cyanide and sufficient oxygen) and balance the gold input with recoveries and losses. With mounting pressures to accommodate sustainability issues during development work, it became apparent that much more information would be required on the interactions and kinetic behaviour of solid and solution species during the entire leach process. This information is vital to enable proactive management of critical issues such as cyanide, arsenic, water and tailings management. Inadequate management of these aspects has led to temporary closures and, in cases of non-compliance, to the dynamically changing regulations. MINTEK?s advanced leach facility (ALF) is being developed with the aim of bridging the knowledge gap between the gold leach process and the predictable environmental impacts upon discharge. The facility aims to monitor all parameters of relevance such as pH, Eh, dissolved oxygen, metals, cyanide species, and viscosity during the entire process to enable more informed decisions on practical interventions. The presented set of data reflects first experiences gained from processing a refractory gold ore concentrate. Attempts at optimizing the process were limited due to the developmental nature of the work. Data relating to leaches with differing preoxidation conditions and cyanide staging is presented.

Jan 1, 2009

By Zengjie Wang

Kinetic study of hydrochloric acid leaching of Panzhihua ilmenite from China is presented. Both temperature and concentration of hydrochloric acid have significant effects on the rate process of Fe dissolution from ilmenite ore, while the ratio of liquid to solid has little effect on the Fe dissolution. The Fe dissolution is found to follow the spherical model f (??) =1-(1- ??)1/3 and the apparent activation energy is calculated as 47.21 KJ/mol, suggesting a chemical reaction controlled mechanism. The dissolving behaviors vary at different kinetic stages. At the beginning the amount of the dissolved Fe and Ti increased monotonically with leaching time, while about 15 minutes later the dissolved Ti in the form of TiOCl2 began hydrolyzed into TiO2 fines reunited on the ilmenite ore surface, as observed by SEM and EDS technique. For the unreacted ilmenite particles covered by a layer of hydrolyzed TiO2, the leaching seemed to be as a selective leaching of iron and because Ti dissolved from and hydrolyzed rapidly again into the unreacted ilmenite particles. The leaching process can be ended 4 hour later when almost of Fe has dissolved into the solution and TiO2 remains as solid residues. The effects of acid concentration and leaching temperature were also investigated.

Jan 1, 2009

Kinetic Study on the Leaching of Vanadium from LD Converter Slag Using Sulfuric Acid In order to reduce the environmental impact due to land disposal of LD (Linz-Donawitz) converter slag from steelmaking plant and to valorise this waste material, an acid leaching study was carried out to assess the effect of several parameters on the kinetics of vanadium dissolution. The characterisation and morphology of the feed investigated using XRD, XRF. The factors influencing leaching vanadium such as particle size, temperature, slurry density and the concentration of sulfuric acid were investigated and optimised. The maximum vanadium recovery about 95 per cent achieved at 70¦C, S/L: 1/15, acid concentration: 3M and for 150 minutes of leaching time. The dissolution of vanadium in sulfuric acid shows that there are two stages in the kinetics of leaching. At the first 15 minutes, there is a sharp increase in the amount of vanadium extracted and at longer leaching time, the extraction increase slightly. In the present work, the shrinking core model (SCM) was used to describe the acid leaching of vanadium compounds. A summary of the controlling regimes in the SCM are examined below for short time (less than 12 min.) and long time (more than 30 min.) stages. So, it was found that the kinetics of leaching in both stages is controlled by solid product diffusion regime.

Sep 13, 2010

A composite iron ore-reductant pellet is a mixture of fine iron ore and fines of coal/char/coke, bonded at essentially room temperature with sufficient green strength for subsequent handling. In ironmaking, these pellets offer the advantage of fast reduction, utilisation of fines, non-coking coal and coke breeze. The composite pellet-based alternative ironmaking processes constitute a promising route for ironmaking in future. The present paper is a brief review of kinetics and mechanism of reduction of iron oxides into iron and other associated reactions, when these pellets are heated to high temperature. It would draw significantly from investigations conducted by the author and his co-workers.

Jan 1, 1999

By M. Kinne

Catalyst preparation/ characterization Slightly modified DP (~Schumacher et al. Catal. Lett. 89, 109, 2003) CeO2 HAS 15 from Rhodia calcined in air for~ 2h BET: ~188m2/g, particles size: 5.7nm (TEM, XRD) + HAuCl4 at pH of 6.5-7, (>95% of the Au was deposited) ? Au/CeO2 (2.6wt% Au, ICP-AES) A new conditioning procedure was applied, including heating at low temperature in N2 and H2/N2 mixtures) Patent DE 10205873A1. Very small Au particles <2nm, for CO oxidation catalyst as Au/TiO2, Au/Fe2O3, and Au/Co2O3 Here Au particles size <3.5nm (XRD) Summary ? CO is nearly exclusively adsorbed on the Au particles ? Positive reaction orders of 0.5 are found for CO and H2O ? Ea= 40kJ/mol ? The catalyst is very active and stable ? During WGS reaction huge amounts of formates are formed and cover the surface ? The activity of the catalyst seems to be correlated with the formate species.

Oct 1, 2003

By C. J. Pretorius

More than 30 percent of the global demand for zircon (ZrSi04) is supplied by South Africa. A significant amount of the zircon is exported, and beneficiated products are then imported for industrial applications locally. Beneficiating the zircon locally could have a positive impact on the local market, since zircon is only one of many such cases. Ammonium acid fluoride serves as an alternative anhydrous fluorinating agent for zircon in the synthesis of several metal fluorides1,2. It provides an effective dry fluorinating method and is easier to handle than hydrogen fluoride or fluorine gas. Zircon exposed to extreme plasma temperatures dissociates and becomes more reactive. The reaction of the plasma-dissociated zircon (Zr02.SiO2) with the ammonium acid fluoride (NH4F.XHF, where x= 1 to 5) forms two main intermediate compounds (NH4)3ZrFr(s) and (NH4) 2SiF6(s), the latter decomposing to form volatile products at relatively low temperatures, providing easy separation of the silicon and zirconium compounds. The ammonium zirconate compound decomposes to form zirconium tetrafluoride (ZrF4), which can be further manufactured into zirconium metal, to name but one product. Data on the kinetics of the reaction of ammonium acid fluoride with zircon and plasma-dissociated zircon, combined with the thermo¬dynamic parameters of the reaction, is essential for the development of an industrial process for the production of a precursor for the manufacturing of zirconium metal, namely anhydrous ZrF4. Both the reaction kinetics and reaction parameters will be included in this study, as well as some proof that the reaction proceeds to ZrF4 on a small batch scale. If the exact reaction parameters can be pinned down, a wide spectrum of anhydrous metal fluorides can be synthesized through this fluorination route.

Jan 1, 2012

By J. D. Steenkamp

In a paper presented at the Heavy Minerals Conference 2001 a laboratory scale investigation on the beneficiation of an ilmenite containing waste stream by magnetizing roasting was reported1.This waste stream contained a high concentration of ilmenite, which was contaminated by chromite and other gangue minerals. Interpretation of the results of the investigation was based on the assumption that during magnetizing roasting of an ilmenite concentrate, under the oxidizing conditions, the magnetic properties of the chromite would remain constant. In this article the following hypothesis was tested: The magnetic susceptibility of chromite would remain constant during magnetizing roasting of an ilmenite concentrate under the oxidizing conditions reported by Gouws and Van Dyk1. The results of this study indicated that the hypothesis is not true. The increase in the magnetic susceptibility is not significant though and it is expected that it will not influence the final ilmenite quality to a large extent. Based on the assumptions that the bulk magnetic susceptibility of the waste stream samples represents that of the ilmenite in the waste stream, and the bulk magnetic susceptibility of UG1 chromite that of the chromite in the waste stream, the results also served to confirm that the waste stream with a high chromite content should be roasted under oxidizing conditions, in a reactor with a well-defined retention time distribution (i.e. a fluidized bed reactor), at a roasting temperature of 750°C (rather than the higher temperature ranges of 800°C and 850°C).

Jan 1, 2003

By E Oktay, I Yusufoglu, C Kahruman

Powder and spherical pellets of MoO2 were oxidised under controlled conditions in the temperature range 674-791 K at oxygen partial pressures of 8.1-30.4 kPa. Weight increase during the reaction was determined by thermogravimetric analysis. It was concluded that the reaction is 0.6th order with respect to oxygen concentation and that the activation energy is 148 kJ/mole. In experiments conducted with powder, fast transfer of reaction heat to the gas phase created isothermal conditions, but the temperature of pellets rose by a maximum of 54 K at 674 K and 105 K at 791 K. The rise in temperature caused structural changes such as sintering and crack formation, which had a considerable effect on the reaction rate. The findings should be taken into account in the design of equipment and choice of operating conditions for roasting MoS2

Jun 21, 1905

Kinetics of Reclamation of E-Waste by a Bioleaching Route

Sep 13, 2010

By B. S. Terry, C. L. Harris

Reduction kinetics from slags containing CuO(0.5), ZnO, PbO, NiO and SnO into a Cu-based metal phase were subjected to computer simulation using a previously developed model for the kinetics of metal-slag-gas reactions that assumes mass-transfer control in all phases. The effects were examined of changing bulk Fe oxide activity, gas reducing potential, temperature, Fe content of the Cu phase and metal/slag ratio. The results permit practical conclusions to be drawn about industrial slag-cleaning practice, but the model is still limited in terms of thermodynamic inputs and the idealisation of reaction conditions

Aug 1, 1995

By B. S. Terry, C. L. Harris

After measuring the kinetics of Ni reduction from a SiO2-saturated fayalite slag into a Cu-based metallic phase on a laboratory scale, a general model was developed that is capable of simulating mass transfer to and from metal-slag, slag-gas and metal-gas interfaces for multiple species. The model was used to simulate the reactions that occur when Cu and Ni are reduced from fayalite-based slags into a Cu-based metallic phase. Good agreement was achieved between model predictions and experimental data

Aug 1, 1995

The widely accepted kinetic model for the gaseous reduction of hematite is critically examined. The formation of the wustite layer during internal reduction cannot be explained in terms of solid-state diffusion. Present evidence indicates the existence of a micropore system in the wustite adjacent to the magnetite with the gas/solid type of reaction occurring not only at the iron/wustite interface but also at the wustite/magnetite interface. During the partial reduction of dense hematite pellets, in a controlled atmosphere, porous magnetite and wustite are formed as products. The mean pore size, as measured by mercury injection, increases with time at constant temperature and with temperature increase over the range 6500C to 950&#176;C. The sizes of the pores indicate that Knudsen diffusion is the principal gaseous transport mechanism across thick layers of magnetite or wustite.The kinetics of the gaseous reduction to iron are consistent with a mixed control mechanism involving the interaction of gaseous diffusion effects with a first order reversible chemical reaction at the iron/wustite interface. Because of the larger pore sizes in the iron layers, ordinary molecular gaseous diffusion must be the principal transport mechanism. The usual experimental methods used for establishing the validity of chemical rate ~ontrol are incapable of differentiating between the mixed control- mechanism and exclusive chemical control.Some implications of mixed control kinetics are developed, including a predicted independence of rate on reducing gas pressure at higher pressures.INTRODUCTIONAn extensive literature review of the reduction of iron oxides has been compiled recently by Themelis and Gauvin (1962). From the large number of papers published and the widely divergent opinions of workers in this field, it appears that a simple unified quantitative analysis of reduction kinetics is not possible. The aim of the present paper is to show that a major cause of confusion is due to the attempts of many workers to interpret experimentally observed reaction rates in terms of a single rate controlling mechanism without due regard to other rate processes which must occur simultaneously.Some of the differences in behaviour reported for particles...

Jan 1, 1964

By Jai Ghosh, Aprad E. Torma, Roger Guay

The catalytic effect of ferrous ion in the industrial biohydrometallurgical heap and dump leaching processes is explained. During the bacterial leaching of metal sulfides, ferric ion will partly be hydrolyzed and a variety of sols, gels, amorphous and/ or crystalline mono- and polynuc- lear hydroxo- and sulfato complex species formed, especially by olation and aggregation reactions. There are many problems associated with these iron precipitates especially in the purification of leach solutions. The present study will discuss the iron precipitation reactions; gives kinetic and thermodynamic evaluations of the effect of temperature on pyrite and ferrous iron oxidation; and reports on the tolerance of heavy metal ion concentrations by Thiobacillus ferrooxidans.

Jan 1, 1989

By James P. Stewart

This case history describes the engineering design and construction for the Contractor of a 35-ft-deep excavation for an 800-square-foot addition to an existing sewage pump station. The site posed unexpected geotechnical complications that included deep gravelly soil, a history of local construction difficulties, groundwater consisting of heavy salt brine, and the need to underpin the existing pump station. The project took an interesting twist when the Owner issued a change order limiting the dewatering discharge to a fraction of that required to lower the water table. This documents the interesting circumstances of this job and documents the unusual subsurface conditions in the Syracuse, NY Lakefront area.

Jan 1, 2003