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By R. P. H. Willis

Uranium is back on the radar. Uranium has always been a controversial metal, from its role in the arms race to its claim to be the only viable alternative to fossil fuel. This paper will cover its properties and use, its occurrence and production in South Africa, the current market drivers and its future role as a primary energy fuel. It will highlight the difference between uranium used to make a bomb and uranium used in a power station. The recent significant uranium price rise will be put into context of the market drivers including geopolitical issues. Planned expansions in nuclear power station capacity will be reviewed, as will new mine production. Future demand will also be speculated on.

Jan 1, 2006

By W. H. Van Niekerk

The metal zinc has been around since only about 1400 AD. This may sound like a long time, but when compared to fellow base metals copper and lead, which were discovered in 5000 and 4000 BC respectively, it is evident that zinc is a fairly new kid on the block. This may also be the reason why many new facts and benefits of zinc are still being discovered. For instance, it has been discovered only in the last few decades that virtually no life on earth is possible without zinc. In this address it will be shown that zinc is not only very useful to mankind, but is in fact vitally important for all forms of life. It will be shown that zinc is natural, zinc is essential for life, zinc protects, zinc contributes to the well-being of society and that zinc is fully recyclable. It is therefore hoped, that by the end of this address, zinc will no longer be viewed only as the metal that is responsible for the nice colour of roofing sheets and steel buckets, but may indeed be man?s best friend.

Jan 1, 2005

The objective in control blasting is to reduce overbreak to control the final pit wall slope, shaft, drift, ditch, bench, etc. to the final planned excavation limit.

Jan 1, 1990

The objective in control blasting is to reduce overbreak to control the final pit wall slope, shaft, drift, ditch, bench, etc. to the final planned excavation limit.

Jan 1, 1991

The objective in controlled blasting is to reduce overbreak to control the final pit wall slope, shaft, drift ditch, bench, etc. to the final planned excavation limit. The six main types of controlled blasting utilized today are: 1) Line Drilling 2) Cushion Blasting 3 Smooth Wall Blasting 4) Buffer Blasting 5) Presplitting or Preshearing 6) Air Deck Presplitting

Jan 1, 1992

"The objective in controlled blasting is to reduce overbreak to control the final pit wall slope, shaft, drift ditch, bench, etc. to the final planned excavation limit. The six main types of controlled blasting utilized today are:1. Line Drilling2. Cushion Blasting3. Smooth Wall Blasting4. Buffer Blasting5. Presplitting or Preshearing6. Air Deck Presplitting"

Jan 1, 1994

By David J. White

The decreasing availability of land in urban areas, and the increasing demand for urban development is leading to the construction of taller and heavier buildings at increasingly marginal sites. Such structures usually require founding at depth and modern construction methods are making the economics of piled foundations ever more attractive (Salgado, 1995). However, the urban environment is not suited to pile driving. Conventional dynamic installation techniques (i.e. drop hammer or vibro-piling) induce vibrations and settlement in a zone close to the pile, and cause noise and dust pollution. Damage to existing structures resulting from pile driving vibrations is not uncommon (Tomlinson, 1986).

Jan 1, 2000

Pressing-Drill Method - A Representative Method for Taking Analysis Samples from Recycled Materials

Sep 13, 2010

By J. F. Jackson, R. W. Mau

"The first commercial installation in the mineral industry of the ""Verti-Press"" pressure filter was made by Falconbridge Limited at the Strathcona Concentrator to filter copper concentrate. The filtercake produced contains 6 - 7% H2O, an improvement from the 12 - 13% H2O produced by an internal drum filter, at rates of up to 20 t/hr. A novel slurry feed system incorporates a hose pump and a pressurized slurry accumulator.INTRODUCTIONIncreased copper production from Falconbridge Limited operational mines in the Sudbury Area has exceeded the current refinery capacity. A copper concentrate has been produced to overcome this constraint and has been shipped to custom smelters either as a slurry or as a 12 - 13% moisture filtercake utilizing an internal drum filter.With the treatment of the new Deep Copper Zone from the Strathcona Mine, copper concentrate production was forecast in excess of the installed dewatering capacity. The filtercake was too wet to transport by truck and the custom smelter refused to handle this product at the truck unloading site. The filtercake had to be trucked to a rail spur and transloaded into gondola cars. This system was expensive, incurred unaccountable losses and the concentrate was assessed a moisture penalty.To reduce the concentrate moisture content to permit direct shipment by truck, two basic systems were available; vacuum filter followed by a thermal dryer or a pressure filter. Past experience with the high capital and operating costs of dryers led Falconbridge to closely examine the pressure filter alternative.COPPER CONCENTRATE PRODUCTIONThere are two separate circuits at the Strathcona Mill; one treating nickel ore and the other treating copper ore.The rougher concentrates produced by both circuits are conditioned with lime and cyanide before the copper-nickel separation in a flotation columns. The concentrate consisting of cha lcopyrite with mi nor cubanite is very clean as shown in Table I. Currently 50% of the copper in the plant feed reports as copper concentrate, in the past, this has been as high as 70%."

Jan 1, 1990

By D. G. Bishop

This paper is intended as a review and update of the use of Pressure Injected Footings as deep foundation units in North America. We will discuss various aspects of this pile and then discuss a particular project - the Mobile Alabama Convention Centre which is currently under construction. Pressure Injected Footing is a generic name used to describe a foundation unit that has been in use around the world for some 80 years. It has been used on all types of structures. It is an excellent pile in both compression and tension. It is particularly economic where a layer of granular soils can be found at relatively shallow depths. Other types of piles would penetrate these layers. Caissons are often difficult to construct in these soils because of their lack of cohesion and the often present water table. PIFs can density these shallow layers and carry relatively heavy building loads on them.

Jan 1, 1992

By Woodcock J. T

When an aqueous suspension of pyrite and manganese ore reacts with oxygen, manganese is dissolved by the ferrous sulphate and sulphuric acid produced by the oxidation of pyrite. The kinetics of certain steps in the overall reaction were studied. A rate equation for the oxidation of ferrous sulphate by gaseous oxygen was derived for the temperature range from 1000 to 200° C. An exact rate equation for the production of ferrous ion from pyrite could not be established but it was shown that the temperature, oxygen pressure, pyrite surface area, and the reduction of ferric ion by pyrite are important. A rate equation was derived for the reaction of manganese dioxide with ferrous sulphate. A major facfor controlling the rate was whether or not ferric oxide was formed by hydrolysis at the manganese dioxide surface.It was shown that if hydrolysis was prevented the factor cpntrolling the rate of the overall reaction ,was the rate of production of ferrous ion, and little ferrous ion was oxidised by oxygen. When hydrolysis of iron did occur, the overall rate was not a simplefunction of anyone factor and much ferrous ion was wasted by oxidation with oxygen.INTRODUCTIONIn another paper (Cornelius and Woodcock, 1958) the results of the reaction of an aqueous suspension of a manganese ore and pyrite with oxygen are reported. It is shown that the ferrous ion and sulphuric acid generated in situ by the oxidation of pyrite, dissolves manganese as manganous sulphate. To obtain a better understanding of the process as a whole, the kinetics of certain steps in the overall reaction were studied.When an aqueous suspension of a manganese ore and pyrite reacts with oxygen, the overall reaction may be conventionally represented by equation (1) (Cornelius and Woodcock, 1958).2Mn02 + 2FeSz + 6i02 + 2HzO= 2MnS04 + 2H2S04+ F'ez03 ... , .. (1)

Jan 1, 1958

By Woodcock J. T

When an aqueous suspension of pyrite and a manganese ore reacts with oxygen, manganese is dissolved by the ferrous sulphate and sulphuric acid produced in situ by oxidation of pyrite. In the absence of added acid, the optimum conditions are: a molecularratio of Mn02/FeS2 of about 1·0, a temperature of about 1400 C., and an oxygen pressure between 25 and 90 lb./sq. in. Under these conditions, complete extraction of manganese is obtained in six hours leaching. An addition of sulphuric acid enables an Mn02/FeS2 ratio of 2·0 to be used successfully.Manganous sulphate decreases in solubility with increase in temperature above 1000 C., but even when the solubility limit is reached during leaching, reaction to form MnS04 still proceeds, and on cooling the MnS04 redissolves.INTRODUCTIONMany manganese deposits contain secondary manganese oxide minerals which are difficult to concentrate. Considerable attention has therefore been given to their hydrometallurgical treatment. In most manganese oxide minerals, the manganese is quadrivalent and must be reduced to the divalent state for dissolution. Reduction and dissolution can be accomplished in a number of ways, one method being to use aqueous ferrous sulphate solutions.A possible source of ferrous sulphate is pyrite as it is known that ferrous ion is an intermediate product in the aqueous oxidation of pyrite. It was therefore thought possible, that by heating an aqueous suspension of manganese oxide and pyrite with oxygen, the ferrous sulphate and sulphuric acid formed from pyrite would provide the necessary leaching reagents for manganese in situ. There are certain advantages in producing ferrous ion in situ...

Jan 1, 1958

By Mehmet Canbazoglu, Kaarlo Haavanlammi, Hannu Laitala

Cobalt is currently a critical metal because of the increasing number of electrical vehicles forecast for production. Copper and zinc are base metals that are used in many everyday applications, including vehicle production. Eti Bakir Co. Mazidagi Phosphate Plants in the Mazidagi district of Mardin, Turkey is a multi-product facility that produces cobalt, copper, and zinc, as well as fertilizers, from the roaster calcine. Roaster off gas is treated in a sulfuric acid plant (SAP) and the acid itself is utilized in fertilizer production. The comminution circuit, roaster, SAP, and calcine leaching process were developed by Outotec and integrated with the fertilizer production process implemented by Eti Bakir A.Ş. This paper describes the hydrometallurgical calcine leaching process used at the plant, with a focus on the oxidative pressure leaching of the cobalt, zinc, and copper-containing calcine. The cold and hot commissioning phases of the pressure leaching autoclave start-up are discussed together with experiences from the ramp-up period. The production processes of the copper cathode and cobalt and zinc-containing salts are also presented together with some of the plant’s operating parameters. INTRODUCTION The ETI Bakir A.S. fertilizer plant, Turkey, is located in Mardin Province near the border with Syria, (Figure 1). The leaching plant project was started in 2012. The purpose of the plant is to separate the valuable metals from the calcine produced by the pyrite roasters, which are used to produce a SO2 containing gas for the new sulfuric acid plant. Fertilizer production requires sulfuric acid, and for this reason a sulfuric acid plant was built; customer already had access to pyrite concentrate, which is used as the roaster feed. During the engineering phase of the roaster and acid plants it was noticed that the roasted calcine contained considerable amounts of valuable metals like cobalt, copper, and zinc. To recover these metals, a calcine leaching process was developed at the Outotec Research Center in Pori, Finland. The main process connections of the Mazidagi site are shown in Figure 2.

Jan 1, 2019

By Dyson N. F

Mixed cobalt-nickel sulphides precipitated from ammoniacal process liquors derived from nickel sulphide concentrates, mattes, and reduced nickeliferous laterites have been characterized.The mixed sulphides are prone to oxidation on standing and are rapidly leached under relatively mild conditions. The kinetics of the leaching reactions are controlled principally by temperature and oxygen partial pressure. Although the samples have different CO:Ni ratios and have undergone varying degrees of oxidation, there is little difference in their leaching behaviour. The results suggest that a single plant would be able to process mixed sulphides of varying composition. Any copper and zinc present in the mixed sulphides as impurities also go into solution and must be removed prior to recovery of the cobalt and nickel in metallic form.

Jan 1, 1981

Pressure Oxidation of Sulfide Gold-Bearing Concentrates with Double Refractoriness

Sep 13, 2010

By Shanming He, Jinliang Wang, Xiaoming Wang, Chunfa Liao

Large amounts of manganese-rich slag were generated from smelting low-grade manganese ore containing high iron and high phosphorus in electric furnace or blast furnace, which contain 25–40 mass% Mn. This paper describes an efficient hydrometallurgical process for the utilization of high manganese slag instead of conventional usage of pyrometallurgical route for manganese recovery. Pressure acid leaching of manganese-rich slag using air as pressurized gas is studied systematically. The effects of mass ratio of manganese-rich slag to pyrite, concentration of sulfuric acid, leaching temperature, partial air pressure, leaching time, and liquid-solid (L/S) ratio on the separation of manganese with other main impurity components were investigated comprehensively. Under the following optimal process conditions, weight of manganese-rich slag powder,100 g; mass ratio of manganese-rich slag to pyrite, 20:1; sulfuric acid concentration of 140 g/L; air pressure of 0.6 MPa; leaching temperature of 140 °C; leaching time of 1 h; L/S of 7:1; ore size of 75–80 μm; and stirring rate of 600 rpm, the extraction rate of Mn reached 94%, and the dissolution percentage of Si, Al, and Fe are as low as 2%, 6%, and 10%, respectively. The leaching slurry presented a good solid-liquid separation characteristic. The silicic acid formed during sulfuric acid leaching manganese silicates was converted to filterable dehydrated SiO2 particles which precipitated in the residue under the condition of higher temperature with higher pressure. The effect of adding pyrite may be to reduced iron ions and decreased the output of iron hydroxide colloid and also reduced MnO2 to manganese sulfate in sulfuric acid leaching. Thus the formation possibility of colloid such as silica gel and iron hydroxide was decreased, and higher yield of manganese sulfate could be achieved.

By Shanming He, Jinliang Wang, Xiaoming Wang, Chunfa Liao

Large amounts of manganese-rich slag were generated from smelting low-grade manganese ore containing high iron and high phosphorus in electric furnace or blast furnace, which contain 25–40 mass% Mn. This paper describes an efficient hydrometallurgical process for the utilization of high manganese slag instead of conventional usage of pyrometallurgical route for manganese recovery. Pressure acid leaching of manganese-rich slag using air as pressurized gas is studied systematically. The effects of mass ratio of manganese-rich slag to pyrite, concentration of sulfuric acid, leaching temperature, partial air pressure, leaching time, and liquid-solid (L/S) ratio on the separation of manganese with other main impurity components were investigated comprehensively. Under the following optimal process conditions, weight of manganese-rich slag powder,100 g; mass ratio of manganese-rich slag to pyrite, 20:1; sulfuric acid concentration of 140 g/L; air pressure of 0.6 MPa; leaching temperature of 140 °C; leaching time of 1 h; L/S of 7:1; ore size of 75–80 μm; and stirring rate of 600 rpm, the extraction rate of Mn reached 94%, and the dissolution percentage of Si, Al, and Fe are as low as 2%, 6%, and 10%, respectively. The leaching slurry presented a good solid-liquid separation characteristic. The silicic acid formed during sulfuric acid leaching manganese silicates was converted to filterable dehydrated SiO2 particles which precipitated in the residue under the condition of higher temperature with higher pressure. The effect of adding pyrite may be to reduced iron ions and decreased the output of iron hydroxide colloid and also reduced MnO2 to manganese sulfate in sulfuric acid leaching. Thus the formation possibility of colloid such as silica gel and iron hydroxide was decreased, and higher yield of manganese sulfate could be achieved.

By L C. Taylor, H U. Lesiste

This is a preliminary study of the statistical variation of the pressures on a target above a buried explosion. The data were taken at various distances from the charge centerline for three heights of the target above the soil and one charge depth of burial. All tests were conducted in saturated sand. They show that peak pressures and times of peaks are neither repeatable from shot to shot nor rotationally symmetric within a single shot. The peak pressure and time of peak at each location can be represented by cumulative normal distributions. The paper describes the means and standard deviations of these distributions at eight distances from the charge center for each height of target. These are used to determine the change in standard deviation of the distribution with distance from the charge centerline and height of target. The effect of scale on the mean peak pressures and times of peaks and on their standard deviations at a single scaled distance from the centerline of the charge are explored using various charge weights.

Jan 1, 2010

By Jones S. C

The problem of sealing a fluid serieite zone at a hole depth of 4000 ft was overcome by using a composite non-return valve plug and rod assembly which enabled cement to be forced under pressure into the zoneà

Jan 1, 1966

By W. Burr Bennett

The prestressed concrete industry in particular, and the precast concrete industry to some extent, are rank newcomers to the concrete construction field compared to the cement, ready-mixed or concrete masonry industries. This young industry reflects its youth and vigor in its enthusiasm, optimism and the belief that it can reach any goal it chooses to set -- and it is setting its sights high. The prestressed and precast concrete industry fully expects to become the major structural and architectural material by the 1980's. Before exploring how the industry expects to reach this goal, a brief look at the origins and the growth of the industry may be useful in an evaluation of the feasibility of this goal. It was always recognized that concrete, strong and efficient for supporting loads which cause compression, was weak and inefficient when used to carry loads which induce tension. Thus the reason for reinforced concrete in which the concrete efficiently carries the compression in a flexural member while low grade steel bars reinforce the concrete in the areas 'of tensile stress. (Fig. 1). The steel being relatively inexpensive, can passively, but quite effectively carry tensile force while the concrete carries compression. The concrete in contact with the reinforcing also protects the steel from corrosion and acts as insulation to provide a superior "built-in" fire resistance. The major disadvantage of reinforced concrete relative to its main competitor, steel, is its weight in relation to its load-carrying capacity. Reinforced concrete systems, such as waffle slabs, I-beams, thin shells, etc. ,

Jan 1, 1971