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By Frederick A. Mumpton

Recent findings by medical workers on the association of certain zeolite minerals with the high incidence of pleural mesothelioma in two small Turkish villages have caused considerable excitement both in medical circles and in the synthetic and natural zeolite businesses. The 42 cases diagnosed between 1970 and 1977 in one community of 600 population in a region of altered volcanic tuff represent a virtual epidemic of this rare malignancy which normally strikes only about one person in a million. Cancer workers around the world expect that detailed environmental and epidemiological studies of the disease in these areas will shed considerable light on the cause of this particularly lethal form of lung cancer. Scientists and engineers developing uses for zeolite materials in industry and agriculture, however, are justly concerned that the preliminary results available on this situation will be used by environmental and regulatory organizations to label an entire group of miner- als as carcinogens on the basis of what is little more than circumstantial evidence. Although there is no question as to the large number of cases of mesothelioma in these areas of central Anatolia, the work to date has suffered from a lack of sound geological and mineralogical input. Ataman (1) stated that a "correlation" exists between mesothelioma and zeolites in this region; however, the geological data needed to document a direct relationship between the presence of zeolites in the volcanic tuffs surrounding the villages in question and the rate of malignant lung disease in the inhabitants have g been obtained, nor has evidence that suggests a cause-effect relationship between zeolites and cancer been reported. To provide fundamental information on the distribution of zeolite minerals in areas of central Turkey where high incidences of pleural mesothelioma have been reported and to evaluate from first-hand knowledge the published reports and news releases of medical workers engaged in assessing the problem, the following investigation was made.

Jan 1, 1979

By Walter Frank

The purpose of the work covered by this contract is to develop a ground and pilot conductor connector which will significantly improve mine trailing cable splice performance. This work compliments the work completed under Contract 00357100 on the development of crimp connectors for the phase conductors of trailing cables. A brief discussion on splice problems is presented as an introductory means and substantiates the need for the development and test programs outlined in this report. As with the phase development work, the ground and pilot connector work is essentially of an empirical nature. As a result time is devoted to explaining the derivations of the test procedures used. In order to familiarize the reader with connector terminology a section is devoted to a glossary of pertinent terms. The connector design effort includes connectors for splicing ground and pilot conductors. A distinction is made between connectors suitable for splicing round and flat ground configurations. The same also applies to the pilot conductors. During the course of this work, much time has been devoted to the question of suitability of round cable configurations for trailing cable applications. This is discussed in detail along with resulting conclusions and recommendations. A field test program was conducted in order to confirm ground and pilot connector laboratory data. This testing also determined the viability of the connector designs and recommended installation techniques in a mine environment.

Jan 1, 1979

By Conochie D. S, Grave N. C

Disposable-tip emf cells at present used in liquid steel can be used to measure the state of oxidation of high-iron slags produced in non-ferrous smelting. This provides a new tool for the control and evaluation of pyrometallurgical operations.An investigation of oxygen potential variations throughout a typical nickel smelter using the flash smelting technique gave a valuable insight into the process. Correlations of oxygen potential with ferric to ferrous oxide ratio and nickel content in slag were in reasonable accord with equilibrium data in the literature indicating that the probes may be used both as a plant investigation tool and possibly as a means of obtaining thermodynamic data for slags.

Jan 1, 1979

By Réjean Lévesque

SIDBEC-NORMINES a été incorporée en 1976. Depuis la fin de 1977, ses activités comprennent outre la concentration au lac Jeannine, près de Gagnon, du minerai de fer extrait du gisement du lac Fire, I'exploitation d'un atelier d 'enrichissement secondaire et une usine de bouletage à Port Cartier. L 'objectif principal de SIDBEC-NORMINES est de produire six millions de tonnes de boulettes d'oxyde de fer par année, dont trois millions auront une faible teneur en silice afin de répondre aux exigences de la réduction directe. Les installations de SIDBEC-NORMINES sont adjacentes aux installations portuaires de la Compagnie Minière Québec Cartier, à l'est de la ville de Port-Cartier. L 'ensemble est conçu pour produire les deux types de boulettes avec deux circuits d'agglomération installes en parallèle. La production de concentré enrichi (68% Fe et plus) est obtenue dans une usine d'enrichissement utilisant le precédé de séparation magnétique hum ide ahaute intensite (separateurs Jones). À l'usine de bouletage proprement dite, on effectue Ie broyage du concentré et sa mise en boulettes sur disques; l'in duration des deux types de boulettes est obtenue sur deux chaînes d'agglomération Dravo dont chacune a une capacité annuelle nominale de trois millions de tonnes.

Jan 1, 1979

By Edward O. Reinbold

The paper presents the results of a study which involved collection and analysis of airborne pollutant concentration data in two producing underground room and pillar metal mines which use diesel powered equipment in the area near the face. The results include the concentrations of CO2, CO, NO, NO2 and respirable particulate matter measured with the latest portable instruments, and the carbon and hydrogen contents of the particulate matter samples determined by combusting them in a Elemental Analyzer. The carbon and hydrogen contents are used to estimate the amount of diesel particulate matter in the mine ambient air. The short term grab sample concentration data, although not suitable for determining compliance with ACGIH Threshold Limit Values (TLVs), are related to the TLVs so that they may be compared conveniently. Lognormal frequency distributions and the arithmetic mean of the concentration measurement data are used to compare different mine situations. Conclusions are drawn as to which pollutants are most important to control under actual mine production conditions.

Jan 1, 1979

By E. D. Palmes

A new type of personal sampler for quantitative estimation of atmospheric concentrations of contaminant gases was first reported from this laboratory in 1972. The sampler requires no pumps or flow regulators and employs instead the motion of the gas molecules them-selves to furnish the power for sampling. Under this grant, work was completed on development of a kit for the field determination of both NO2 and NO. Detailed instructions for the preparation of the samplers and the use of the kit was supplied to the Technical Project Officer. Attempts were made to adapt the same type of sampler to the measurement of SO2 and CO. Both gas chromatographic and turbidimetric procedures for the final estimation of the S02 proved to be unsatisfactory. For CO no reagent was found which would react sufficiently rapidly with this gas to utilize the essential feature of the diffusion sampler, the maintenance of a diffusion gradient which is at least approximately numerically equal to the ambient concentration. A number of publications on use of the NO2 sampler, both at occupational and community air pollution levels, have resulted from this work.

Jan 1, 1979

Mining at Waihi on the Martha Hill commenced in 1878 and between 1892 and 1953 produced 35 million ounces of bullion from some 13.5 million short tons of ore from 40 named quartz reefs. The general geology of the ore is recorded in detail with differing interpretations by Bell and Fraser (1912) and Morgan (1924). The reefs and stringers have formed by fissure filling and replacement in mainly quartz andesite dacite flows within the Waihi 'Graben'. The host rocks are extensively propylitised with intense alteration forming zones of kaolin adjacent to the main reefs.

Jan 1, 1979

By Emil Szaks

[A great number of papers have been presented at various Engineering Society meetings on the Unit Train subject. Moat are descriptions of facilities that have been constructed or are abort to be built. Many describe the facility as being the World's fastest, newest, largest, incorporating the latest technology and so forth, Many are duplications of installations that have been recently constructed, sort of carbon copies but perhaps arranged differently. The trend has been to incorporate loop tracks, rotary dumpers, indexers and, of course, the snivel coupler equipped unit train. How that the energy crisis has increased the use of coal, there has been a tremendous Increase in applications for permits to construct rail to river coal loading facilities. This paper is different. It does not describe any single existing facility, but is given to alert prospective terminal owners and engineers that there are items that require considerable study and evaluation beside merely selecting an indexer, car dumper, stacker, ship or berg loader and so on. An important item is the selection of the railway car which in turn can affect the selection of the method of loading and unloading. Let us list a few of the items that should be considered and discuss the areas that require examination:]

Jan 1, 1979

By Wilhelm Knickmeyer, Johannes Henneke

PREFACE For about 1 year Bergbau-Forschung GmbH, central research institute of the German Coal Mining Industry, undertakes full size tests for waterjet assisted tunnel¬boring in German coal mines (Fig. 1). These tests are performed with a tunnelborer of 2.6 m diam in an upper [ ]

Jan 1, 1979

Demand for primary aluminum ingot increased during February, and several producers temporarily suspended new bookings for ingot. Alcoa announced that it would restart a potline at its Warrick, IN aluminum smelter by April 1, 1979, increasing the operations of that plant to its full capacity of 290,000 tons per year. At the end of February, it was reported that Alcoa would reactivate two of the seven units at its idle Point Comfort, TX smelter in May 1979, increasing the company's annual capacity by about 60,000 tons.

Jan 1, 1979

By H. Sahay

This paper summarizes the history and ore-grade statistics of mining the Ming orebody, and then details the mining methods. Included are raising, stoping, drilling and blasting techniques. Particular attention is paid to ground support, ventilation and pumping requirements.

Jan 1, 1979

To provide cooler air to miners working in hot areas of mines, particularly new deep hardrock mines. Approach Air supplied to hot working areas of mines is cooled by passing it through a series of water sprays. How It Works Water nozzles mounted inside a section of ventilation tubing release cooling sprays of water into the air being blown through the tube. The prototype of the water spray cooler consists of six evenly spaced water sprays located inside a 10-ft. long section of 16-inch-diameter fiberglass ventilation tubing. See diagram. This section of rigid tubing is installed into one of the positive pressure ventilation tubing lines that conduct fresh air into working stopes. The intake manifold to the six water sprays is connected to the mine?s cool water line, and the water valve on the manifold is opened. Warm ventilation air being supplied to the stope passes through the water sprays, and is cooled by the lower temperature water.

Jan 1, 1979

By C. M. St. John

A series of analyses of possible mining excavations associated with the development of copper nickel deposits of the MINNAMAX site in Northeastern Minnesota is presented. Specific areas such as roof and pillar stability and excavution orientations are addressed. The majority of these analyses were conducted using a boundary element method but some cases were also analyzed using the finite element method. Comparable results were obtained using the two methods but the boundary element method required less data preparation time and computer run time. Results of the analyses, as well as indicating the capabilities of geotechnical numerical models, provide some insights into behavior around multiple excavations in jointed rock.

Jan 1, 1979

By Nathaniel Arbiter

The development of flotation machines since the first industrial use of the process can be divided into three stages. The first, up to about 1930, was marked by diversity in the means for contacting floatable mineral with the air/ water interface and for generating the interface, as well as in cell design. By 1927 Taggart (1) could list 170 patents covering flotation cells, and he mentioned dozens which were or had been in operation. He divided cells into eight categories according to design, type of separating interface, and where in the cell and how separation took place. These were: (1) Film or skin flotation with wet or dry oiling of surfaces; (2) pulp body process with bubbles generated chemically by pressure reduction, by vacuum or by boiling; (3) agitation-froth processes involving local supersaturation with air; (4) bubble column; (5) pneumatic; (6) cascade; (7) subaeration; and (8) combination and miscellaneous types and processes. Most widely used then were the agitation-froth, sub- aeration, pneumatic types. By 1943 a significant reduction in categories had occurred to the two main divisions of mechanical and pneumatic cells according to whether agitation and aeration were (a) by an impeller with or without compressed air, or (b) by compressed air alone. Cells at that time were still relatively small; the Morenci Concentrator completed in 1942 used 432 1.7m3 (60 cu ft) Fagergrens for roughing 45,000 and later up to 55,000 t/d.

Jan 1, 1979

By J. P. Jarrell

Environmental considerations are of increasing importance in determining the acceptability, schedule and cost of expansion ofCanada's uranium processing industry. Environmental considerations must be addressed in the early stages of facility planning. This results in a dilemma, as the process data needed to predict physical environmental impacts are not yet available from process design activities. Hence, a business risk is incurred if plant design is carried forward to meet these requirements prior to project (or site) approval. On the other hand, project scheduling normally mitigates against leaving process design engineering until such time as project approval is obtained. This paper examines the experience gained in Eldorado Nuclear's proposed expansion of refining capacity as viewed by an environmental engineering consultant. The history of the project and the relationship to process design functions in the two-year period prior to the Port Granby environmental hearings are reviewed. During the Port Granby public hearing, there was a consensus that normal operation of the proposed refinery could be successfully integrated with the site's natural environmental constraints. Moreover, the radiological impact from plant operations was demonstrated to be inconsequential. However, concerns were raised relating to plant upset and accident situations. These concerns are summarized. Process data requirements identified during the environmental hearings are discussed. Finally, the concerns for on-site burial of radioactive waste are reviewed. These concerns focussed on long-term stability of the waste in the presence ofgroundwater transport, erosion and glaciers. The AECB's position on waste management with regard to this project is reviewed in light ofthe implications for design.

Jan 1, 1979

By Charles D. Wood

"Selected Topics,? in reviewing the control of emissions from diesel engine powered equipment used in underground mining, explores these fields of interest: hydrogen as fuel; lubricating oil as a source of particulates; applicability of stationary source scrubbers; worldwide diesel exhaust scrubbers; instrumentation technology for measurement of N02; control of emissions through application of sensors and microprocessors; use of fuel additives; technology transfer of marine diesel practice; technology required to use 4-stroke, aftercooled, turbocharged, direct injection engines; oxidation and reduction catalysts for diesel engine exhausts. "Selected Topics? makes recommendations for research and provides a bibliography and lists of references.

Jan 1, 1979

By J. C. Engel

Recent innovations in mine safety include the use of mercury vapor lamps for mine vehicle illumination. Such lamps, however, extinguish whenever the line voltage at the machine momentarily sags or is interrupted. The lamps must then cool for several minutes before they will restart. By supplying reduced high frequency power to the lamps from an auxiliary source, it is possible to maintain ionization in the arc tubes preventing the lamps from extinguishing. Essentially an auxiliary high frequency supply, the keep alive system provides additional power to the lamps automatically whenever the lamps are in danger of dropping out. The system can also provide the operator with the ability to dim the lamps at will for periods of up to three minutes by simply interrupting the 60 Hz power to the conventional ballasts. Each unit, housed in a steel explosion proof enclosure with a volume of approximately 0.6 ft3, is capable of servicing up to six 175 watt H-39 mercury lamps and two 100 watt H-75 reflector flood lamps. A total of 16 units were produced for the USBM under this contract and its extension.

Jan 1, 1979

By Philip W. Holland

This Bureau of Mines report discusses the results of three independent reconnaissance geochemical surveys conducted in the vicinity of the Bush Dome reservoir in the Bureau-owned Cliffside field near Amarillo, Tex. The surveys consisted of (1) determining the helium content of area ground waters, (2) determining the helium content of area soil gases and ground waters, and (3) determining the helium content of soil gases collected on a grid sampling pat- tern in the Cliffside field area. The native natural gas in the Cliffside field contains about 1.8 percent helium. To date, approximately 54 billion cubic feet of gas containing approximately 39 billion cubic feet of helium has been injected into the center of the Bush Dome structure. The research work, which was completed under contracts, was done to determine if helium concentration levels in ground water and soil gas could he used as an indication of the presence of helium in a subsurface natural gas accumulation. Results of the surveys were positive in that helium-in-water and helium-in- soil-gas anomalies were detected in portions of the Cliffside field area. All helium analyses were performed by mass spectrometric techniques.

Jan 1, 1979

By John D. Godfrey

Geological mapping on the Canadian Shield in northeastern Alberta outlined severalgranitoid rock massespotentially suitable as building stone. A particularly attractive prospect, the Chipewyan Red Granite, was subjected to an aerial survey and ground check. The petrologic and fracture characteristics critical for quarrying and use as a building stone were assessed in the course of detailed mapping at two of the most favourable sites. The extension of good rock was tested to shallow depths at one site by shallow diamond-drill coring. , The Chipewyan Red Granite displays a warm red colour, medium grain size and fairly massive texture, and takes a good polish. Deleterious geologic features studied in outcrop and subjected to structural analysis included regular joint systems, quartz veins, pegmatite dykes, basic shear zones and fault zones. Many of these key geologic features are systematic and hence predictable for stone quarrying purposes; other features, such as irregular fracelM tures, are non-systematic and arefar less predictable. The megascopic structural features studied show similar preferred orientations which appear to be collectively related to the tectonic history.

Jan 1, 1979

By Joseph B. Gillenwater

Miss Gertrude Carey lived next to us in Martinsburg, West Virginia for several years. She was a retired school teacher. She was also a cousin to Messers Dan and Joe Baker who owned and operated Standard Lime and Stone Company, a predecessor of Martin Marietta Corporation. She-was well acquainted with the Baker family and their history. Here is one of the legends she told my wife, Jean, and me. The Bakers were originally Tanners. They had a tannery near Frederick, Maryland. There were several boys in the family and when they were grown each man had specified responsibilities. Will Baker was assigned the duty of locating, buying, and transporting tanbark and lime. As he traveled through Maryland, Virginia, Pennsylvania, and West Virginia to locate and buy tanbark, he also talked the farmers out of some pieces of lime, which the farmers had produced in holes dug and filled with layers of limestone and wood. Will Baker took the lime and soaked a piece of hide in the milk of lime. If the lime did not spot the hide, Will Baker would get the farmer to burn some lime for him, and further tests would be made. If these tests were good - the Bakers bought the land. They eventually discovered that the limestone that would make lime that wouldn't spot the hide would also be suitable for producing steel. They began producing lime just outside Harpers Ferry, West Virginia in pots and upright kilns. That stone too small for the kilns was just perfect for railroad ballast. Now you know how "Baltimore Blue Bloods" got together!!

Jan 1, 1979