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By E. Czech

Hydrogen generated through aluminum-assisted water split reaction is a novel, efficient and environmentally friendly method. It has been found previously that the passivation of aluminum can be prevented in neutral (pH=7) or near neutral pH conditions in water by grinding aluminum with a catalyst, such as A12O3, SiO2 or SiC. Recently, the best results have been obtained by using water-soluble inorganic salts (WIS), ground with aluminum. The massive, rapid corrosion reaction of the Al-WIS system which takes place in regular tap (or marine, or ground) water can be utilized to produce hydrogen by aluminum-assisted water split reaction, in-situ, on-demand. The reaction offers clean, low-cost, environmentally benign and entirely recyclable technology for on-board on-demand hydrogen generation. Besides pure gaseous hydrogen, only pure solid aluminum hydroxides AlOOH or Al(OH)3 are formed as the reaction products. The hydrogen yield and Al-WIS reaction efficiency are high. From 1 g of mechanically alloyed aluminum powder, up to 1.25 liters of hydrogen were generated, i.e. efficiency up to 92% was achieved. The amount of hydrogen and hydrogen generation rate depend on various reaction parameters. The effect of chemistry and concentration of additives, water temperature, powder particle size and milling conditions on the reaction kinetics will be presented and the possible process mechanism will be discussed.

Jan 1, 2005

By C. Stapel, P. D. Roberts, D. G. Jones, W. G. Macdonald, R. J. De Meijer

"Measurement of natural radioactivity has been used in both a qualitative and a quantitative way in mineral exploration, particularly in the search for uranium. In the last ?ve years, the Kernfysisch Versneller Instituut (KVI) and British Geological Survey (BGS) have designed, built and tested a new detector system that greatly improves quantitative applications in mineral exploration, especially on the sea?oor and in the nearshore zone. The new system is an enhancement of an earlier BGS design. The major improvements comprise the use of a highly sensitive ?-ray detector, together with new data processing, from which concentrations of natural radio nuclides may be deduced in real time. After laboratory analysis of samples, these concentrations can be converted into mineral percentages. Once the mineralogy of an area has been characterized, this conversion can also be done in real time.Thus far the system has mainly been used to map heavy-mineral concentrations in coastal subtidal and intertidal sediments. For such work the multi-sensor detector probe is towed on the sea?oor and various parameters are recorded continuously. The probe contains, in addition to the gamma-ray detector, a water-pressure sensor (giving water depth) and an acoustic device to measure bottom roughness. The system, when used together with high-precision positioning systems such as D-GPS,enables the production of detailed maps of bathymetry, bottom roughness, and sea?oor radioactivity or mineral distribution. These maps allow mineral concentrations to be readily correlated with sea-bed topography and sediment type. In the same way, ?-ray detectors could be used advantageously during dredging operations to provide on-line assessment of the mineral content of the dredged sediment as well as to guide the direction of dredging. Additionally, the same technique could be used to monitor the subsequent fate of a dredge spoil after dumping on the sea?oor.Natural radioactivity arising from potassium and the thorium and uranium decay series has potential use for the fast and reliable assessment of siliciclastic and phosphatic impurities in limestones. Detection of such impurities may preclude the use of the limestone for chemical or cement production.Apart from its use in exploration, the technique has signi?cant potential in mineral processing, particularly of heavy minerals. It can be applied as on-line quality control in dry and wet separation processes and for process control, by using decisions based on the results to control valves and other instrumentation. In addition, it can also be used in environmental monitoring of waste arising from mineral extraction and processing. In conclusion, the technique described has a diversity of applications in exploration, mining and mineral processing."

Jan 1, 1997

By Z. Manafi

Bioleaching of a copper sulfide ore containing "activated pyrite", using a mixed culture of mesophilic bacteria, was studied. This type of copper ore had been found unsuitable for flotation because it produces a concentrate containing relatively high iron concentrations and, therefore, a low copper grade. Microscopic observations showed that pyrite particles had been activated by the formation of a thin film of chalcocite. Hence, a bioleaching process was considered as an alternative to treat this ore. Following shake flask and acid consumption tests, column tests of the crushed ore (75% -12.5 mm) were initiated and the effects of culture medium, agglomeration, and irrigation type on copper recovery were studied. The results showed that all the columns containing bacteria had copper recoveries around 90% compared to the abiotic control column with a recovery of 50%. It was concluded that bioleaching could be successfully utilized to process copper ores containing activated pyrite.

Jan 1, 2007

By N. J. Shackleton, N. A. Chapman, V. Malysiak, C. T. O’Connor

In this study, the effect of using conventional crushing and high-pressure grinding rolls (HPGR) in combination with dry or wet milling was investigated using a base-metal sulphide (BMS) sphalerite and a platinum group mineral (PGM) ore to determine how these processes affect the flotation performance. In sphalerite, irrespective of the crushing procedure (HPGR or conventional), dry milling resulted in the highest grades and recoveries of zinc, whereas in PGMs, similar treatment produced the poorest results. The results were investigated further by the effect of factors such as percentage liberation and particle size on the flotation results.

Jan 1, 2012

By D. Yamada, T. Tanaka, N. Inouchi, J. Nakahigashi, H. Yoshimura, T. Nonishi

The use of cereal food materials as lubricants was investigated in an attempt to develop nonpolluting lubricants. Suspensions of wheat flour in water and other types of cereal food lubricants were prepared and their friction coefficients measured. The results indicate that a cereal food lubricant containing 30% lipids, 2% proteins, 60% carbohydrates and 0.6% calcium carbonates has the lowest friction coefficient for a sheet (cpTi-1). As example applications, the lubricant was tested with a forming press and a screw-fastening device. In both applications the cereal food lubricant performed relatively well in comparison to conventional lubricants and thereby has potential for practical applications.

Jan 1, 2006

By P. M. May, V. Gella

The deportment and speciation of trace elements during mining and minerals processing is becoming an area of increasing concern with regards to potential health and environment risks. The use of chemical modelling can enhance our basic understanding of the deportment and speciation of trace metals under conditions present in gold processing solutions, and assist in laboratory and field investigations. In this paper, we report the results of chemical speciation modelling using the JESS software package for the trace toxic elements Pb, Cd, Hg, Se and Te in cyanidation solutions of varying salinity and relate the models to experimental data. The speciation of mercury is examined in detail.

Jan 1, 2011

By S. M. C. Santos

Preliminary bench-scale studies were carried out on the leaching of a zinc sulphide concentrate from Somincor, Portugal, and the purification of the resulting pregnant solution using solvent extraction techniques. The sulphide concentrate contained 36% Zn, 36% S, 2% Fe and 4% Cu. The leaching was carried out with sulphuric acid in the presence of ferric sulphate as the oxidant. Important leaching parameters, such as the effect of reaction time, the solid-liquid ratio, temperature and concentrations of acid and oxidant, were investigated. After leaching, the recovered solution was contacted with an organic phase containing Acorga 5640 to remove the copper. Subsequently, the removal of iron from the leaching solution was achieved with a mixture of Cyanex 272 and TBP. This solvent mixture was relatively selective for iron over zinc. The stripping of the loaded solvent was performed with 200 g/L H2SO4. Six countercurrent extraction stages achieved a separation of about 99% of the iron from the leaching solution. The iron-free leachate can be further treated to recover minor metals by cementation, and finally, zinc by liquid-liquid extraction. The advantages of the suggested process relative to the traditional jarosite process are discussed.

Jan 1, 2006

By Richard K. Komarek, Antonios Zavaliangos, Roman T. Dec

Current industrial compacting and briquetting practices are largely based on trial-and¬error techniques. This paper introduces a two dimensional finite element model of compacting/briquetting process in the roller press. Compared with other modeling techniques used in the past, finite element method offers the most versatile approach because it incorporates adequate information about powder behavior, geometry and frictional conditions and offers predictions for the density distribution, velocity field, stress distribution, roll force, roll torque and other important process variables. More over, when the model includes elasticity, it offers predictions on the internal stress state in the briquet after its exit from the pressing zone. This enables to perform realistic computer experiments which are helpful for establishing the pressing system design, forming cavity geometry and process conditions necessary to produce compacted or briquetted product with the desired properties.

Jan 1, 2004

By O. G. Olvera, D. G. Dixon, E. Asselin, L. S. Quiroz

Dissolution rates of chalcopyrite (CuFeS2) were calculated using electrochemical impedance spectroscopy (EIS). The calculated dissolution rate decreased by a factor of 3.2 after the electrode was passivated. The results presented in this work indicate that the reduction of Fe3+ was the rate-controlling step for fresh CuFeS2 electrodes while the transport of cations within the passive film limited the dissolution rate for the passivated electrode. The transfer of cations at the electrode/electrolyte and passive film/electrolyte interfaces did not affect the dissolution rates of the fresh and passivated CuFeS2 electrodes, respectively. The catalytic effect of pyrite (FeS2) on the dissolution of CuFeS2 continued after the passivating treatment. The contact of fresh and passivated CuFeS2 electrodes with different FeS2 particles resulted in increased dissolution rates, due to an increase in the reduction rate of Fe3+.

Jan 1, 2014

By T. Newton, G. A. Bezuidenhout, P. J. Tauetsile, F. Trask

The technology to selectively leach gold, silver and base metals from ores, concentrates, and wastes, using an alkaline glycine solution, has initiated significant interest in using the new technology in various environments such as in-situ, in-place, dump, heap, and vat and agitated tank leaching. It has been shown that glycine acts synergistically with a number of other lixiviants to lower the net consumption of the other lixiviants while allowing low cost glycine solution recovery. Glycine is a non-toxic, stable, environmentally benign reagent that is available in bulk industrial quantities. It has the ability to dissolve most copper oxide and sulfide minerals, as well as native copper, whilst not interacting with acid consuming gangue nor dissolving iron and various or ubiquitous gangue elements. It acts synergistically with small amounts of cyanide to leach gold-copper ores at leach rates higher than either glycine or cyanide on their own, while significantly reducing cyanide consumption and eliminating detoxification requirements. The leaching behaviour of various glycine based systems will be reviewed, followed by the evaluation of the adsorption of gold onto activated carbon. Where the economics merit it, copper can be easily recovered using solvent extraction or sulfide precipitation.

Jan 1, 2017

By J. Keith Haddock

"The Luscar Mine is a metallurgical coal mine located in the foothills of the Canadian Rockies, 41 km southeast of Hinton, Alberta. The mine is operated by Cardinal River Coals Ltd., a 50/50 joint venture between Luscar Ltd. and Consolidation Coal Company of Canada. The mine produces a high quality medium volatile metallurgical coal which is sold on the export market principally to Japan and South Korea. Operations consist of a surface mine with capacity to produce 3.0 million tonnes per year and an underground mine which is currently mothballed due to market conditions.GeologyBedrock units within the Luscar minesite are of Devonian to Upper Cretaceous age. The commercial coal measures in the area are, however, confined within the Lower Luscar Formation. The Luscar Formation consists of a 460-metre thick sequence of interbedded sandstones, shales and coal seams. The sequence is primarily deltaic in origin, and is bounded to the north and south at the Luscar mine by tectonically induced thrust faulting.The only mineable coal seam at Luscar is referred to locally as the Jewel seam. Average thickness of this coal measure is usually 10.5 m to 14 m, although in some areas folding and faulting has produced ""pods"" of coal from 15 m to over 40 m thick while in others the structural deformation has thinned the coal to 3.0 m to 4.6 m. Waste within the Jewel seam seldom exceeds a metre of shale, carbonaceous shale or infrequent sandstone stringers.Reserves and Coal QualityProven surface mineable reserves, based on pit scheduling through 1996, are 50.8 million raw tonnes. An additional 19.2 million raw tonnes are contained in possible extensions to the present planned operations. These surface mineable reserves are considered to be those reserves within 155 m of the surface. Underground reserves, located within 770 m of the surface show that 25.7 million raw tonnes have been proven to date in additon to 27 .5 million indicated and 260 miIJion inferred.Coal specification at Luscar Mine is as follows:"

Jan 1, 1985

By L. Magne, A. Pinto, M. Maldonado, J. A. Finch

Estimation of gas holdup from electrical conductivity measurements has been used in lab and industrial installations. The approach is based on the application of Maxwell's model, which relates the concentration of a dispersed phase in a continuous medium to measurements of the electrical conductivity of the dispersed phase, continuous medium and the resulting mixture (dispersion). When applied to inferring the collection zone gas holdup in a three phase system and to facilitate real-time on-line measurement, the slurry is assumed to behave as the continuous medium and gas bubbles as a nonconducting dispersed phase. This article derives an equation for estimating gas holdup in a three phase system, eliminating the assumption that the slurry behaves as a continuous medium but rather as a dispersion of non-conducting solid particles in water. In this formulation only water behaves as the continuous medium in the sense of Maxwell, and gas holdup in a three phase system is then calculated from the application of the Maxwell model twice: (1) to determine solid content in a two-phase system, and (2) to determine solid plus gas holdup in a three phase system. To validate the new equation and quantify the errors incurred by assuming slurry is the continuous phase a laboratory flotation cell was instrumented to continuously measure the conductivity of two and three phase dispersions with known solids contents. As the amount of gas in a lab flotation machine is difficult to measure directly or by another indirect technique such as using pressure signals, 2.5 mm dielectric plastic spheres having a density of ca. 1.3 g/cm3 were used instead of air bubbles for validation. Experimental results demonstrated that the continuous medium assumption underestimates gas holdup and that the resulting bias error increases linearly with the solid content and decreases with the magnitude of gas holdup.

Jan 1, 2016

By V. V. Zubkov

The systems of geophysical monitoring have been already put into operation at coal mines and ore mines. Since at present it is rather difficult to conduct mine experiments; it is necessary to start a new step in joining of geomechanics and seismic. The linking geomechanical and geophysical monitoring at coal mines and ore mines today became possible due to progress in development of numerical methods of modeling of stress state and technology for processing of seismic information. This paper describes one potential step in linking geomechanical and seismic monitoring at coal mines and ore mines.

Aug 1, 2013

By L. P. Chrismas

"IN 1975, Nova Scotia produced 1.8 million tons of coal with a FOB mine value of $47.6 million. Of this total, about 30 per cent or 600,000 tons was coking coal and the remainder was steam and industrial-grade coal. The Nova Scotia Power Corporation consumed 630,000 tons in three generating stations and 570,000 tons were sold to Sydney Steel for making coke for its steel operations. Exports, principally to Great Britain, comprised 370,000 tons in 1975 in addition to the 300,- 000 tons shipped to other provinces for use by cement and pulp and paper companies. In 1975, just over 100,000 tons of coking coal were imported into the province from Alberta. Before 1975, low-volatile coking coal was traditionally obtained from the United States. In 1975, production came from seven individual mines and one project involving reclamation from mine dumps in Pictou County. Of the seven producers, four are owned by the Cape Breton Development Corporation, a federal Crown corporation; the remaining three are small independent mines, but, even though small, they are sizeable contributors to the economies of their local areas. After 101 years of continuous operation, Devco's Princess mine was closed in 1975. The Nova Scotia coal industry, in terms of value, accounted for about half of total mineral production in 1975. The industry provides jobs for 3,000 men and women. It is also significant that in 1975 Nova Scotia produced about 6.5 per cent of Canada's total coal production of 28.3 million tons. Detailed statistics on Nova Scotia's coal industry appear in the Appendix."

Jan 1, 1976

By Harry Piers

A RAPID glance over the history of The Mining Society of Nova Scotia shows that in its fifty years of service, which it is now rounding out, the Society has had an honourable career, rendered signal service to the mining industry of the Province, and helped to shape and improve legislation bearing on our mines and minerals, besicles publishing very many excellent papers and subsequent discussions thereon dealing with all subjects in its field of activity. THE GOLD MINERS? CLUB OF NOVA SCOTIA: The Society has the distinction of being generally regarded as the oldest mining fraternity in Canada ( 1). Iris the direct outgrowth or reorganization of The Gold Miners' Club of Nova Scotia, which was organized in March, 1887, at a period when the gold mining industry was very prominent in the Province. Mr. Geo. W. Stuart, who, in 1934, was the only living member of the parent association, informed me that the seventeen Charter Members of The Gold Miners' Club were John H. Anderson, Charles F. Andrews, A. B. Cox, Clarence H. Dimock, George E. Francklyn, L. W. Getchell, John E. Hardman, Alonzo A. Hayward, Major R. G. Leckie, W. L. Libbey, Edward M. McDonald, G. F. McNaughton, George A. Pyke, H. A. Sanders, C. E. Willis, Benjamin C. Wilson, and George W. Stuart. Others joined later in the same year.

Jan 1, 1937

By G. A. Fenton, A. Vervoort, M. Alvarez Grima

"High-risk underwater mining operations necessitate characterizing spatial heterogeneity and resource uncertainty. Local average subdivision is a method of simulating spatial deposit variability inside a cell through a sequence of discretization stages, during which a cell is further subdivided into four or eight cells. New developments are presented to validate simulated deposit models and deal with point measurements of geotechnical and ore-grade properties. This paper illustrates the relevance of translating spatial deposit variability into financial or operational performance indicators during underwater resource exploitation. Two synthetic case studies highlight the challenges of underwater mining in relation to production plans and equipment selection.RÉSUMÉ Les opérations d’extraction minière subaquatique à risque élevé exigent une caractérisation de l’hétérogénéité spatiale et de l’incertitude de la ressource. La moyenne locale de subdivision est une méthode de simuler la variabilité spatiale du gisement dans une cellule par une séquence d’étapes de discrétisation durant lesquelles une cellule est subdivisée en quatre ou huit cellules. De nouveaux développements sont présentés afin de valider les modèles de simulation des gisements et de traiter des mesures ponctuelles des propriétés géotechniques et de teneur du minerai. Le présent article illustre la pertinence de traduire la variabilité spatiale du gisement en indicateurs de rendement financier ou opérationnel durant l’exploitation subaquatique de la ressource. Deux cas synthétiques soulignent les défis de l’exploitation minière subaquatique par rapport aux plans de production et de choix des équipements."

Jan 1, 2015

By McGill Metals Processing Centre, S. Chang, L. Calzado, X. K. Cao, C. H. Hsin, M. Isac

"Due to the increasingly stringent cleanliness requirements for final steel products, there has been a growing interest in the possible use of micro-bubbles for the removal of inclusions with diameters smaller than ~50µm, present within the steel passing through a steelmaking tundish. However, several technological barriers have prevented the adoption of this technique in industry. These are related to a) the generation of micro-bubbles in liquid steel, b) the measurement of bubble size distributions, and c) the optimization of bubble injection conditions to create micro-bubbles. In the present study, a novel Aqueous Particle Sensor (APS) system was developed for the in-situ, on-line, detection of micro-bubbles in water, generated by a newly designed full-scale ladle shroud, located at McGill Metal Processing Centre (MMPC). Measurement results from the sensor were validated against bubble size data collected through a high speed camera and post-processed through the commercial software, Image J.Control variables and orthogonal experiments were designed to assess the dependence of average micro-bubble sizes and bubble size distributions on key experimental parameters. Those chosen were the air inlet flowrate, the distance of the gas injection port from the slide gate, and the number of injection ports used. The investigation demonstrated that the APS system can be successfully adapted to detect micro-bubbles up to ~800 micron diameters. Using this novel sensor, it was shown that multi-port injection using low air inlet flowrates, closer to the slide gate, were useful in forming small micro-bubbles within the flow through the ladle shroud. The results from the APS system were compared and validated against data resulting from an optical technique. INTRODUCTIONModern industry expects increasingly stringent cleanliness requirements for final cast products. Therefore, the numbers and sizes of inclusions need to be strictly controlled in steelmaking operations. Thus, the cleanliness of steel products depends on the amount, morphology and size distributions of nonmetallic inclusions in steel (Zhang L. & Thomas B., 2003). Since large, deep, tundishes provide longer nominal residence times for liquid steel passing through it to the exit SEN’s, this can provide the ideal place to separate inclusions, and bubbles can assist by removing help attach inclusions and float them to the top surface."

Jan 1, 2016

By H. R. Huffman

"This paper reviews the history of iron powder production, and outlines the varions production methods. The uses of iron powder and the reasons for its use are also covered. The paper concludes with a look at future trends in powder metallurgy.INTRODUCTION TO POWDERSTHE IRON POWDER INDUSTRY is enjoying a very rapid growth. The annual consumption of iron powder is now at the 100,000-ton level, twenty times higher than it was at the end of World War II, and the yearly in-crease bas been almost consistent at 20 per cent. This is expected to increase, bringing the tonnage to 200,-000, or even (according to some experts) to 270,000, in 1970. In any event, powder metallurgy is expanding at high speed and making an important impact on the production of iron and steel products. Some indication of the faith in the future market may be indicated by the commencement of three new powder production plants in Canada with a total capacity of 136,000 tons annually."

Jan 1, 1969

By Joseph W. Mills

"The Mic Mac property comprises 994 acres held under mining concession and approximately 2,000 acres held under development licenses in Bousquet township, Abitibi county, western Quebec.Gold was first discovered in this locality by Tom Duval in June, 1936. In February, 1937, Cassels Duval Mines, Limited, was incorporated under Quebec charter to take over the property. In September, 1937, the property was examined by Agaura Explorations, Limited, and an option agreement was signed on October 6th, 1937. In June, 1938, an option for complete ownership was taken on adjoining claims belonging to Norgold Mines, Limited, and in September, 1938, a mining plant was installed and the sinking of a 3-compartment shaft begun. In June, 1939, an option was taken by Mic Mac Explorations, Limited, on seven claims of Mooshla Gold Mines Company, Limited, that adjoined the Norgold block to the east. In December, 1939, a new company, Mic Mac Mines, Limited, was formed, amalgamating the Cassels Duval, Norgold, and Mooshla claims, as well as two claim groups to the west of the mine known as the Vaughan and West Cassels groups."

Jan 1, 1954

By A. Hekmat-Ardakan

Conventional hypereutectic Al-Si alloys such as A390 are used principally for the casting of components used in wear applications requiring abrasive resistance such as in engine or compressor blocks. A comprehensive study was undertaken to investigate the potential of improving the mechanical properties of these alloys by the addition of magnesium. A thorough thermodynamic study of the effect of the addition of Mg to the conventional A390 alloy showed that Mg2Si starts to form as a primary phase at 4.2% Mg as well as in the products of the binary and ternary eutectic reactions forming the matrix. Experiments were carried out in producing castings with different cooling and solidification rates of alloys with up to 10% Mg. Mg additions were found to increase the hardness over the as cast alloy due to solid solution strengthening. Also, T6 heat treatment greatly improved the tensile properties of these alloy compositions due to the strengthening effect of the theta-Al2Cu phase. The elongation of these alloys generally decreases marginally with Mg content. The most significant property improvement of the alloys with higher Mg content is the substantial increase in wear resistance. This is attributed to the dispersion of smaller particles of Mg2Si and their coherence with the matrix as compared to the large Si particles in the conventional alloy. A new rheoforming process for A390 is presented that improves the processing of the semi-solid slurry. Structure modification elements were also added to refine the primary and eutectic silicon greatly improving the processing of the semi-solid slurry.

Jan 1, 2011