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By Z. Zhang, X. -G. Chen, F. Breton, A. Arici

"The microstructure of Al-10Si-0.3Mg-0.5Mn alloy with 0.27% Zr and 0.19% V addition was quantitatively analysed and compared to the base material. The addition of Zr and V in the AlSi10Mg alloy exhibit a beneficial effect on the Si modification, resulting in the reduction of the size of eutectic Si particles on both as-cast and T6 conditions. The quantitative image analysis results show that the Zr and V addition and T6 treatment can reduce the size of the intermetallic phases. In addition, the presence of Zr and V is favour to the partial dissolution of the intermetallic phases during the T6 treatment. Different heat treatment procedures were tested to optimize treatment parameters. The mechanical properties of the alloys were evaluated using hardness measurements and tensile tests. The results show that the addition of Zr and V can remarkably improve the mechanical properties on as-cast and T6-treated conditions. The correlation between the microstructure and mechanical properties of the alloys is discussed.INTRODUCTION Al-Si-Mg foundry alloys have been widely used in automotive and aerospace industries due to their high strength-to-weight ratio, heat-treatable capability and excellent castability. The alloying elements such as Cu, Mn, Fe are traditionally added into Al-Si-Mg alloys to improve their mechanical properties (Mohamed, Samuel, Samuel & Doty, 2009). In recent years, the attention has been paid to the effect of the transition elements such as Zr, V, Ti, etc, as minor alloying additives, on the properties of aluminum alloys (Elhadari, Patel, Chen, & Kasprzak, 2011; Kasprzak, Amirkhiz & Niewczas, 2014; Shaha, Czerwinski, Kasprzak, Friedman & Chen, 2015; Shaha, Czerwinski, Kasprzak & Chen, 2014; Mahmudi, Sepehrband, Ghasemi & 2006; Meng, Cui, Zhao & Zuo, 2013). Kasprzak et al., (2014) and Shaha et al., (2015) reported that additions of Zr, V, and Ti in Al-Si-Cu-Mg cast alloys can improve the alloy mechanical properties at high temperature by forming stable intermetallics and precipitates on as-cast and heat treatment conditions. On the other hand, the mechanical properties of near-eutectic and eutectic Al–Si cast alloys depend not only on the chemical composition but also, even more importantly, on microstructural features such as the morphology and size of eutectic silicon and intermetallic particles, which are present on both as-cast and heat treatment conditions (Mohamed et al., 2009). However, there is rather limited information on the effect of Zr and V on the microstructure features and mechanical properties of near-eutectic Al-Si-Mg cast alloys."

Jan 1, 2018

What Bottleneck? ??Resurgence of BC Mining Industry; ??Climate of heightened activity ?Increases pressure placed upon regulatory agencies; ??Current EA and permitting system, when Federal agencies are involved, remains duplicative and inefficient ?not necessarily leading to better decision making; ??Inefficiencies will impederecovery

May 1, 2006

By Simon C. Dominy, Alwyn E. Annels, Mark A. Noppé

Abstract - Mineral Resources and their subsequent conversion to Ore Reserves are of key importance to mining companies. Their reliable estimation is critical to both the confidence in a feasibility study, and also to the day-to-day operation of a mine. Together with sampling, assaying, geological and other errors introduced during interpretation and estimation, additional errors are likely to be introduced during the application of technical and economic parameters used for conversion of resources to reserves. There is thus a requirement for high-quality interpretation and estimation to be supported by high-quality data. Any company expecting to make sound investment or operational decisions must base this on both relevant and reliable information. An Ore Reserve statement generally contains a single set of grade and tonnage figures without a discussion of the potential inherent errors in these estimates. Some sensitivity studies may be run, but confidence limits are rarely quoted and, if they are, often do not take into account many of the factors that cause uncertainty in the grade and tonnage estimates. Mineral Resource and Ore Reserve estimates thus carry certain errors leading to uncertainty and risk; some of these are unquantifiable for various reasons, for which the operator should be aware. This paper presents a review of the potential sources of error that might occur during a resource estimation program, which are carried through into the reserve estimate. A number of methods are discussed that allow the estimator to be more transparent about the inherent risks in his/her estimate. Emphasis is placed on data quality, and the requirement for strong quality management to be linked to continuous improvement.

Jan 1, 2002

The introduction consists of back-ground information, of an historical and statistical nature, relating to the Thompson mine. The geological presentation is based on illustrations that are intended to provide a progressively closer look at the ore occurrence. The illustrations consist of an index map, a geological map of a 15-by 85-mile area including the Thompson mine, a series of four maps dealing with the geophysics and geology of a 6-by 4\f.j-mile area at Thompson, a mine level plan and corresponding section, two sto11e 11lans and corresponding sections, and photo-graphs and photomicrogra11hs of the various one types. T HE Thompson mine is located about 400 miles due north of Winnipeg. The ore deposit was dis-covered in February, 1956. Five years later on March 25, 1961, the Thompson production facilities were officially dedicated with the shearing of the first nickel produced at the Thompson refinery. Full production, at an annual rate of more than 75,000,000 lbs. of refined nickel, was attained later in the year.

Jan 1, 1963

By Alessandro Navarra

Discrete event simulation provides a computational framework in which the use of smelting equipment can be analyzed and optimized, leading to the development of alternative modes of operation. Much of the complexity of copper and nickel smelters is centered on the converter aisle. These converters operate in parallel, produce batches, and set the tempo for the downstream operations. In practice, smelter staff schedule daily operations to coordinate the smelting furnaces and converters with downstream operations. Thus, a realistic simulation of smelter operations, over hundreds of days, should incorporate converter scheduling algorithms as presented in this paper.

Jan 1, 2014

By H. Higuchi

The Sumitomo Metal Mining Company Ltd. (SMM) started to produce electrolytic nickel at the Niihama Nickel Refinery in 1939. In 1992, the conventional matte electrorefining process was converted to the matte chlorine leach electrowinning (MCLE) process, which is currently in practice. SMM has mainly used two kinds of nickel matte as the raw material for the MCLE process. Treatment of new raw materials, which have different impurity contents from the original nickel matte, has become mandatory because of changes in the market. Therefore, the MCLE process has been required to increase its flexibility to treat the different impurity contents in the new raw materials. An increase in the capacity for iron removal is included in such requirements. A new iron removal circuit in the MCLE process, based on a process development study, was recently installed. The iron removal circuit is in operation, and efforts are currently underway to optimize the performance of the circuit by changing the present operating parameters. In addition to the removal of the iron, the application is also expected to improve the nickel recovery. The outline of the new circuit and the current iron balance in the MCLE process are described in this paper, together with the effect of the circuit on iron treatment capacity.

Jan 1, 2006

By D. Zagidulin

Short term electrodeposition experiments (up to 80 min.) at two current densities 220 and 275 A/m2 with varying concentrations of thiourea and glue were performed to determine the optimum levels of glue, thiourea and current density for industrial copper electrorefining. White Light Interference Microscopy was used to acquire digital images of the morphology of the electrodeposited copper. Scaling analysis was employed to pa-rameterize the morphological information encoded in the images. The limiting rough¬ness, *, the critical scaling length, Lc, and the aspect ratio, 4*/ Lc, were determined as a function of the deposition time and the amount of organic additives. These parameters were used to calculate the dynamic exponent, B, the roughness exponent, 1/z, and the as¬pect ratio exponent, y, plotted as a function of glue and thiourea concentrations. These 3D plots allowed us to find conditions corresponding to the minimum of B and y, at which the deposited copper is characterized by a small roughness and a dense structure.

Jan 1, 2007

By G. D. Garland

The influence of natural electric currents, induced in the earth by changes in the earth's magnetic field, on the electric logging of boreholes has not always been recognized. Measurements made with fixed electrodes of changes in the vertical potential gradient in a hole near Calmar, Alberta, have indicated the effect of earth currents related to magnetic disturbances. It is found that appreciable errors in self-potential logging could arise during periods of magnetic storms, but the precise pat-tern of disturbance in any area seems to depend on the local structural conditions. As the amplitude of the natural earth currents increases toward the auroral zone, it is suggested that periods of magnetic disturbance be avoided, if possible, when electric logs are taken in the northern part of the western sedimentary basin. NATURAL electrical currents flow continuously near the surface of the earth, apparently as a result of electromagnetic induction

Jan 1, 1962

By I. Murray, N. Geoffroy

"Buried pipelines, tanks and other similar equipment are almost always present on large scale industrial sites, including in the oil and gas fields. However, as the proverb “out of sight, out of mind” suggests, it is easy to overlook proper maintenance procedures and simply assume that corrosion protection measures in place are working correctly. Unfortunately, this is not always the case, leading to significant environmental damage and loss of production. This paper describes several cases from various industries where buried equipment failed because of corrosion, sometimes with catastrophic results. It also presents various strategies, based on experience and new research, to help predict and prevent damage to underground metallic structures.INTRODUCTION Metallic underground structures are extremely common in industrial and commercial settings for numerous reasons. Burying pipes, tanks, wires and other similar equipment has numerous advantages: it provides significant protection from mechanical damage, frees up ground space that can be used for other purposes, requires little to no support structure and is generally more esthetically pleasing. However, this last benefit can also be considered the most significant disadvantage of underground equipment: becoming invisible and forgotten. While every engineer is aware of the importance of preventive maintenance, it is also human nature to somewhat forget about equipment that is hard to inspect and assume that everything is fine. This is unfortunately not always the case and failures in industrial settings can have extremely serious consequences. While economic aspects immediately come to mind (loss of production, cleanup cost, etc.), failure of underground equipment also results in an environmental and therefore public relations nightmare, especially in the oil and gas field. Leaks that would have been considered negligible in the past can now make national headlines and perfect reliability, while probably impossible to achieve, is now the goal of most companies. While environmental damage (real or perceived) is most often associated with leaks in the oil and gas industry, it can also affect the mining world. For example, the authors have worked on a project where a buried slurry pipeline had ruptured in the ground, causing a release of perfectly inert tailings. While the economic loss was low, the leak was reported in local media and caused a public relations problem."

Jan 1, 2017

By E. O. T. Simpson

"IntroductionAS COMPARED with coal mines in the United States, and even with some of those in eastern Canada, the coal mines of western Canada, generally speaking, :have made little progress toward mechanization at the working faces. So far as Vancouver island is concerned, there are three main reasons for this : ( 1 ) in some areas, conditions• easy for hand-loading but unsuitable for mechanical loading make high outputs per man •possible by the former method; (2) faulting of the coal seams in ..some areas precludes long-term planning and the introduction and efficient use of expensive equipment; (3) thinness •and other characteristics of the seams in many areas favour hand-loading.No. 8 MINENo. 8 mine of Canadian Collieries (Dunsmuir), Limited, is located in the Cumberland sub-area of the Comox coalfield on Vancouver island about 90 miles west-northwest of Vancouver. The geological structure of this coalfield has been described by J. D. McKenzie. The seams occur in the Comox formation, a subdivision of the Upper Cretaceous Nanaimo Group. The formation is of near-shore origin and was laid down on an irregular surface of' older rocks. The irregular generally have a northeasterly dip, modified by gentile folds and by a •few large, and a number of smaller, faults.Four seams have been worked in the Cumberland area and all vary in thickness and in the amount and number of interstratified bone and rock •bands."

Jan 1, 1953

By V. Panayotov, M. Panayotova

"Finding a reliable relationship between fundamental properties of minerals of non-ferrous metals and their ability to float is extremely important. The approach presented in this work allows us to draw predictive models for an effective flotation, suitable choice of reagents regime and expected technological results before the minerals enter the flotation process. Attempts to adjust the technological regime in already begun flotation are often unsuccessful because the basic physicochemical processes have already taken place. Mineral processing can be optimized on the basis of objective and basic parameters, decisive for the efficiency of the process - the state of the surface of the mineral; assessment of: minerals flotation ability, the need to apply and the type of needed pretreatment, and expected technological results. The theoretical foundations of such an approach are presented in the work, as well as supporting them experimental results, and information on practical implementation in lead-zinc and copper-pyrite ores selection.INTRODUCTIONIncreasing impoverishment of ores of nonferrous metals incoming to the flotation and rising costs for obtaining the final product lead to the inevitable question - will the mineral processing process be beneficial economically, technologically feasible and environmentally safe and what is the way to improve its efficiency. Some of the possible solutions are already in practice - new more efficient and less energy consuming flotation machines and equipment, new - more efficient and selective reagents, new combinations of flotation regimens, and so on.Finding a reliable relationship between fundamental properties of minerals of non-ferrous metals (sulphides and oxides - most of them with semiconductor properties) and their ability to float is extremely important. This is the subject of research, started in the 60s of the previous century and continuing to the present day. Such dependence would enable a realistic assessment of flotation ability (flotability) of minerals before their flotation processing. The basic dependence, displayed by the researchers as Hoberg (1975), Chanturia and Shafeev (1977), Chanturia and Lunin (1983), etc., represents a relationship between bulk properties of minerals and their flotability, considering especially the concentration of the main charge carriers, namely electrons or holes. The bulk properties are practically constant for minerals from a given field. But the 'main arena' of the flotation process is actually the mineral surface (Carta, 1970; Rao, Labonte, & Finch, 1992; Panayotov, 1999; Rao, 2003; Hu, Sun & Wang, 2010). Therefore, we introduce a methodology for studying the surface of minerals, which methodology gives the degree of semiconductor bands bending on the surface and respectively - the charge of the mineral surface and its ability to interact with reagent-collector. The latter can be used to select the most optimal reagent for the corresponding mineral."

Jan 1, 2016

By P. C. Richards

"Future Integrated Gasification Combined Cycle (IGCC) power plants will have superior environmental performance and unmatched efficiency.The Shell Coal Gasification Process (SCGP) is a clean coal technology, which can convert a wide range of coals into clean syngas for high efficiency electricity generation in an IGCC plant. SCGP flexibility has been demonstrated for feeds ranging from bituminous coals to lignites and petroleum coke, and the process is ideally suited for combined cycle power generation, resulting in efficiencies of 42% to 46% (LHV).In the Netherlands, a 250 MWe coal gasification combined cycle plant based on Shell technology is being built by Demkolec, a development partnership of the Dutch Electricity Generating Board (N. V. Sep). The plant is scheduled to start up in 1993. IntroductionBasic ConceptShell's experience with gasification dates back to the 1950s, when the first Shell Gasification Process was commissioned with oil as feedstock. There are now over 140 SGP gasifiers licensed. The experience gained on oil gasification provided a firm theoretical and practical base for the start of coal gasification process development in 1972.At that time, there were serious concerns about the future availability and price of crude oil. Coal gasification (making carbon monoxide and hydrogen by the partial oxidation of coal) was considered to be an important option for refinery applications, because the synthesis gas (syngas) produced can be used as:• a chemical feedstock for making transportation fuels and chemicals;• a source of hydrogen (making use of the water gas shift reaction) for upgrading petroleum products; and• a fuel for heating process streams and/or generating electricity."

Jan 1, 1994

By D. Laguitton

"Mathematics, process theory, process practice and computer applications are the main disciplines that contribute to developing useful techniques for computer simulation of mineral and coal processing plants. As in any multidisciplinary effort, communication or transfer mechanisms must be developed to facilitate the flow of experience between participants of different backgrounds. These mechanisms include written reports, verbal communications, workshops and transfer of computer programs. The SPOC project at CANMET is devoted to computer simulation and as such has addressed, or will address in the near future, problems inherent to methodology transfer. The first major output of the project was the material balance program, MATBAL2, which has been acquired by over 30 organizations. Program documentation, industrial workshops and summer student programs have been used to effect the transfer. This experience is discussed and the future outlined.IntroductionComputer simulation has become a common tool in many different fields of human activity during the past two decades, as illustrated in Figure 1. The total number of articles abstracted in Chemical Abstracts under the general subject entry of “Simulation"" has been following a pseudo-exponential growth since 1972 and was approaching 5000 in 1980, whereas no such entry was even used prior to 1967. This represents over a dozen papers published daily on the subject and should continue to grow to higher figures. Still, progress toward accepting modelling and simulation in mineral and coal processing has been very slow. It will be shown later that this slow acceptance is a cause rather than a consequence of the limited success of the various attempts made so far to draw unambiguous benefits from simulation applications. The real cause of the difficulties in fully accepting the new methodology lies in the multidisciplinary aspect of modelling and simulation, which does not suit the traditionally conservative approach that prevails in designing and operating large and costly processing plants."

Jan 1, 1982

By James A. Finch, Yue Hua Tan, Wei Zhang

"The paper is part of our study of the frother structure-property relationship using bubble rise velocity. Single bubble rise velocity profiles were determined in a 350 cm column for surfactants from the polypropylene glycol (PPG) family. Using velocity at 300 cm, the concentration to reach minimum velocity (CMV) is determined. The CMV is shown to decrease as alkyl chain length (n, number of carbons) increases and as the number of propylene oxide groups (m) increases. Linear correlations log CMV vs. n and m were observed. Taking literature data for critical coalescence concentration (CCC), linear log CMV vs. log CCC correlations were also noted. Mechanisms are briefly discussed, and prediction of CCC made for a commercial polypropylene glycol.INTRODUCTIONAs one of the great enabling technologies of the 20th century, froth flotation is a highly versatile method for physically separating minerals by exploiting differences in wettability (hydrophobicity). Over the last century, flotation reagents have undergone significant developments (Khoshdast and Sam, 2011). One important group of reagents is frothers which are used to reduce bubble size, slow bubble rise velocity and help stabilize froth (Klimpel and Isherwood, 1991).Frothers, originally derived from natural sources (e.g., pine oil and cresylic acid), are largely replaced today by synthetic products which provide more consistent properties. Polyglycols, based on PEO (polyethylene oxide), PPO (polypropylene oxide), or PBO (polybutylene oxide) groups, were first described by Leja and Nixon (1957) and have attracted wide use since then (Farrokhpay 2011). The chemical structure of polyglycols can be represented by a general formula: R(X)mOH, where R = H, or CnH2n+1 and X stands for EO (-C2H4O-), PO (-C3H6O-), or BO (-C4H8O-). The polypropylene glycol ethers (CnH2n+1(PO)mOH) are the most common of these reagents (Pugh, 2007) and the focus of this study.In general, the chemical structure of frother molecules comprises two parts, a non-polar hydrophobic hydrocarbon (alkyl: CnH2n+1) chain and a polar hydrophilic head. By introducing the ether -Olinkage, which acts as another polar site, the propoxy group (-OC3H6-) in the structure makes the frother readily soluble in water (Somasundaran and Wang, 2006), facilitating the industrial use of these frothers. Available as by-products, Dow Chemicals introduced as series of polyglycols, e.g., Dowfroth (DF) 200, 250, 263, and 1012, the most familiar being DF250 (CH3(PO)4OH), a polypropylene glycol methyl ether. While no longer available from Dow, these and other polyglycols are still widely used."

Jan 1, 2016

By Marcel Vallée

"This text consists of two parts, comments on "Classification and Reporting of Mineral Resources for High-Nugget Effect Gold Vein Deposits," by S.C. Dominy, P.R. Stephenson and A.E. Annels, Volume 10, No. 3, pp. 215-233, and related comments on some features of the JORC Code.This paper is, in many respects, a very elaborate and valuable account of the problems encountered in the estimation and classification of high-nugget gold deposits. However, in some key areas, it appears to fall short of its objective to help "resolve satisfactorily most issues" and "contribute to improved estimation and classification" (abstract). One must realize that high-nugget effect gold deposits constitute a very narrow field, despite the occasional bonanzas. This is a field of mostly smaller sized deposits, where limited success and a significantly higher rate of failure occur relative to larger deposits of mostly lower grade. This is shown by the six deposits described in the paper. Thanks for contributing to greater understanding of these complex and nevertheless challenging deposits."

Jan 1, 2002

By Paul M. Clifford, David M. Baird

The Great Northern Peninsula of Newfoundland consists of a Precambrian core of gneisses and granitic rocks, cut by numerous diabase dykes. This complex is surrounded by an envelope of sedimentary rocks of Cambrian to Carboniferous age. Radiometric dates from two granite masses in the core give a mini-mum age of -945 m.y. (Grenville) for the last major tectonic activity. This Grenville deformation conferred upon the core substantially its present structure which has controlled later events to a marked degree. Block movements of the core, dominantly in a vertical sense, have ex-posed it to erosion at intervals. The nature and distribution of the flanking sedimentary rocks and the present relief of the peninsula suggest four such movements. THE Great Northern Peninsula extends some 150 miles north-northeast from the northwest corner of the main body of the island of Newfoundland. It separates the Gulf of St. Lawrence from the Atlantic Ocean, except for the 12 mile wide

Jan 1, 1962

"One of the workhorses of the minerals industry is the autogenous grinding (AG) mill and its derivative the semi-autogenous (SAG) mill. These are relatively well understood, but not so Scrubbers. Scrubbers are mechanically of the same appearance/function, so what is the difference between an AG mill and a scrubber? When, or under what conditions should a scrubber be used and when should an AG mill be used? Can the processes within be mathematically modelled?In the past decades, the minerals industry has focused most of its attention on the modelling of unit processes such as cone crushers, HPGR’s, AG/SAG mills and ball mills within conventional processing circuits. Less attention has been placed on the modelling of scrubbers. This paper reviews the difference between scrubber and AG mill modelling, highlighting some of the similarities, with a view to confident comminution circuit designs.Engineering practitioners should be comfortable with these circuit designs and not shy away from considering AG mills for both small and large scale plants. AG mills can treat both harder or softer ore and scrubbers are for only softer ores. This paper differentiates scrubber and AG mill modelling in a similar way that overflow ball mills and grate discharge ball mills are analysed. Smaller scrubbers (600 kW) are suited to small scale soft ore (100-300 t/h) operations. Larger scrubbers up to 2,500 kW have the capability of very high throughput, in excess of 1,750 t/h with soft fine feed ore. AG mills are scalable up to 28 MW and are capable of treating harder ores at rates exceeding 2,000 to 4,500 t/h. Observations are that the specific energy requirements for the mill grinding duty is wide and varied. This is to a large degree the crux of the matter in sizing, as well as, differentiating, scrubbers from AG mills.INTRODUCTIONAG milling is a mature technology that has been used in minerals processing applications for more than 100 years. In the last 50 years, harder metalliferous ores have seen the introduction of steel balls to assist in the grinding/milling action. Tumbling mills used in such a configuration are called semiautogenous mills (SAG). The greater minerals industry is no newcomer to the use of fully autogenous (AG) mills. Perhaps scrubbers are. What is the difference? When should a scrubber be used versus an AG mill? How are they mathematically modelled?"

Jan 1, 2016

By S. S. Burns

"AbstractShovels of 18 cubic yard capacity and larger are described which incorporate advanced technology and techniques providing performance and operation tailored to meet the needs of open-pit mining.To achieve the goal s of increased production at lower cost with consideration of maximum availability, lower energy consumption per ton and low •impact on pit power, Harnischfeger Corporation developed a solid -state drive system (""Electrotorque"" - P&H trademark) and applied unique transmission methods.To date, more than 250,000 hours of experience in different parts of the world under varying operating and environmental conditions has proven that the ""Electrotorque"" shovel is the shovel of the future, today.This paper will discuss the electrical features and touch briefly on some mechanical features.Introduction to ""Electrotorque""THE hoist, crowd, propel and swing machinery of an electric mining shovel are driven by direct-current motors.A D.C. motor is used instead of an A.C. motor because the torque output per ampere input is at a maximum and the fact that it is doubly-fed (armature and field ) provides optimum flexibility in control.The power that is available in the pit is alternating current power. It is therefore necessary to change or convert this A.C. power to D.C. power so that the D.C. motors can be used."

Jan 1, 1977

By J. Kicki

The paper depicts the current status of the EKSPERT mining machinery management system and shows the prospects for its further development. The system is the result of a rare attempt to utilize the comprehensive dataset; this refers to a precisely identified group of users and is used to develop a solution with a scope that encompasses other areas of activity within the company. The authors present the incredible flexibility and usefulness of the system used at KGHM Polska Miedz S.A. for everyday control of the mining machinery fleet. The issue of visual aspects of the reports generated by the system is handled separately and used as a tool allowing for implementation of the methodological assumptions of EKSPERT. A concept for creating a system for assisting decision making in the process of mine management with the use of IT tools and production monitoring is also discussed. The solution is based on integration of information from both the monitoring field and visualization of the technological process around the Production Reporting Center.

Aug 1, 2013

By L. Zeka, I. Ndala, J. Frenay, S. Gaydardzhiev

"Reductive leaching of cobalt (III) from a heterogenite bearing ore has been performed. Pyrite was added to the system and simultaneously bioleached in order to provide ferrous iron as reducing agent. Within such arrangement the iron ions are continuously re-circulated inside a Fe 3+ / Fe 2+ loop. As a result Co(III) is solubilized in the presence of Fe 2+ ions in concentrations well below the stoichiometric requirement. The ore has been initially subjected to acid pre-leaching in order to guarantee that the available Co (II) has been entirely removed. Two technological parameters have been studied to show influence on the degree of cobalt leaching: concentration of ferric iron in the inoculum and the presence of bacteria. The bacterial role could be mainly viewed in supplying ferric ions in the system which chemically react with the pyrite to generate ferrous ions used as Co(III) reducing agent. Co(III) dissolution has been less efficient when the concentration of total iron in the system was low, but also when microorganisms were absent. SEM observations on leached heterogenite have evidenced bacterial attack on the mineral; however the precise role of bacterial presence on cobalt (III) leaching is still to be elucidated.INTRODUCTIONCobalt accompanies quite often copper in secondary oxidized ore deposits (Rumbu, 2013). In such associations cobalt is found both as CoII+ as well as CoIII+ (Deliens, 1974). In contrast to cobalt (III), cobalt (II) is leached relatively easy in sulphuric acid solutions. Cobalt (III) when present in mineral form belongs to the heterogenite mineral group with a simplified chemical formulae Co2O3.H2O or CoOOH. In order to be brought in solution, heterogenite should capture two electrons, likewise shown in reaction 1 below:"

Jan 1, 2016