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By H. Sipilä, H. Vartiainen, H. Paarma

"The carbonatite massif of Sokli includes several low-grade Nb showings composed of ores and wastes as identified by routine analyses. More detailed lithologic proportions were determined in two orebodies in the Kaulusrova Nb-mineralized area by a careful geological study and by thorium radiation measurement on 10 cm-long drill core cuttings with a total length of 460 metres. The distribution of Nb in eight X-ray spectrometrically analyzed drill core sample intervals (totalling 35.8 m) was determined by analyzing the intervals semi-continuously by an X -MET analyzer. The geological studies suggest that Nb-mineralized bodies are feasible fo r the sorting of are and waste. This was confirmed by the semi-continuous determination of Nb on the X-MET analyzer.IntroductionThe Sokli carbonatite complex is located in eastern Finnish Lapland. The main ore of the carbonatite massif is a regolithic phosphorus ore in the weathered crust. Large-scale geophysical measurements and diamond drillings have also established several niobium showings within the magmatic carbonatites. Owing to the complicated geology of the massif, the niobium showings occur as irregular zones o r areas displaying complicated structure, texture, mineralogy and geochemistry (Vartiainen and Paarma , 1979; Vartiainen , 1980). The tonnages in areas such as this are large but the grades in-situ are low . The most intensely studied niobium showing is the Kaulusrova area.The exploitation of these showings depends on the feasibility of applying a sorting technique to upgrade the feed and to minimize the amount of material to be treated in the concentration plant. These possibilities o n the Kaulusrova area have been viewed by a detailed geological and X-MET an analyzing study."

Jan 1, 1985

By R. V. Kumar, F. Tailoka

In order to use ZnO laden dust as a possible desulphurization reagent, it is important to evaluate thermodynamics of the Zn-O-S system. At temperatures greater than 1450 K, there is an uncertainty in the thermodynamic data for the reaction of zinc with sulfur to form Zinc sulfide. In this work, the standard free energy has been determined using an electrochemical cell: Pt, Mo, MoO2/YSZ/ZnO, ZnS, S02, Pt., between 1198 and 1602 K. AG° varies from -145,880 to -88,100 J (± 2500) , with a phase change to ZnS (g) by sublimation occurring between 1450 and 1460 K. This is supported by thermogravimetric analysis which shows about 80% weight loss in ZnS from 1273 to 1473 K. Feasibility reactions were also performed and confirmed that ZnS (g) is formed when ZnO reacts with FeS (1473 to 1653 K) or with Fe-Csat-S(1473-1673 K). There is therefore potential for the utilization of ZnO laden waste as an additional or alternative reagent for desulfurisation.

Jan 1, 2004

By M. P. Tibbs

An autonomous spray application system for a structural Thin Spray-on Liner (TSL) is targeting productivity and safety on underground coal continuous miners by potentially replacing steel mesh, and has broader applications as surface support and confinement in metalliferous mines and civil tunnelling. Polymer chemistry, coating formulation, geotechnical assessment and the autonomous application system are being developed as an integrated package as part of a continuous miner automation project. This polymer-based TSL system has significant benefits over conventional steel mesh skin confinement, including being more automatable by spray application, providing complete skin confinement and active skin reinforcement as a fast-curing composite with substrate, and having effective fire retardant properties for the polymer and the underlying coal. This paper presents a preliminary assessment of distance sensing systems that would enable autonomous adaptation of a nominal spray path to spray a consistent thickness of TSL (nominally 5mm) over an irregular topography. Two alternate sensors are assessed; firstly, a 2D LIDAR mounted on a linear axis is used to produce a 3D surface profile for generating an adapted spray path; and secondly, a robot end-effector-mounted ultrasonic sensor is assessed for wall following techniques to dynamically adapt a nominal spray path.

Aug 1, 2013

By Douglas W. Reeve, Hoc Nghia Tran, David Barham

"In kraft pulp mills, the spent pulping liquor is concentrated and used as fuel in the recovery boiler. Extensive deposits are formed in the upper section of the boiler due to the very high ash content of the fuel and the volatite nature of the ash. Deposits are composed of Na2S04, Na2C03 NaCI, some potassium salts and reduced sulphur compounds. Chloride and potassium salts are enriched in the deposits compared to the smelt due to their greater volatility.Severe corrosion of the superheater tubes in a recovery boiler has been traced to three factors: a non-uniform temperature profile in the flue gas, relatively high operating steam temperatures and high chIoride and potassium concentrations in the fireside deposits.The role of chIoride and potassium in superheater corrosion has been explained by increased Iiquid phase in deposits. Together with corrosion studies, this information has shown that kraft recovery boiler superheater corrosion due to the chloride and potassium enriched deposits can be avoided by proper boiler operation and by judicious superheater and furnace design.IntroductionThis investigation of recovery boiler superheater corrosion was initiated by the discovery of severe corrosion of the final stage superheater in a Canadian closed cycle kraft pulp mill(1,2). Metal wastage leading to tube failure was believed to be due to three major causes : the relatively high operating steam temperatures, the uneven distribution of flue gas temperature across the boiler which created a "" hot spot"" and the high chloride and potassium concentrations in the superheater fire side deposit. The mill responded to the problem by i) lowering the superheater steam temperature from 475°C to 380°C, ii) minimizing the chloride content in the spent pulping liquor, by controlling the NaCI input with recovered bleach plant effluent, and iii) changing metallurgy of a portion of the bottom section of the final stage superheater platens from ferritic steel T-22 (2.25% Cr, 1% Mo) to austenitic steel Incoloy 800H (21% Cr, 32% Ni, 46% Fe, 1.5% Mn, 1% Si, 0.6% Al) (Fig. 1). Details of the superheater corrosion experienced in the closed cycle mil! have been reported in previous papers(l ·2,) ."

Jan 1, 1984

By W. Qin

The nucleation of d hydride in Zircaloy-4 has been studied using electron backscatter diffraction. Hydrides prefer to nucleate at intergranular rather than intragranular sites. (0001) a -Zr//(111) d -ZrHx is the most common crystallographic relationship. The hydride platelets are generally interlinked each other and form a chain-like configuration. Based on thermodynamic model, the formation mechanisms of the hydrides at different sites and the interlinked structure were analyzed. We found that the misorientation of two adjacent grains has a crucial effect on hydride nucleation sites, and the tensile stress near the tips of hydride platelets is a key factor affecting the appearance of interlinked structure.

Aug 1, 2010

The original JKMRC AG/SAG mill model was developed over 30 years ago and has been upgraded a number of times since then, with the current published version being the Variable Rates model that is now over 15 years old. Since this model was developed further enhancements have been derived, some of which are applied in-house and some which have yet to be incorporated. The published and the commercially available model in JKSimMet is currently undergoing a comprehensive overhaul with a vastly extended data base for model evolution and validation. Improvements developed within the AMIRA P9 project, in-house development and a number of collaborative projects, are being incorporated into the upgraded model structure. Enhanced capabilities will include: power-based breakage rates scaling; a far wider mill filling range (from 10% to 40%) that exhibits peak in throughput as mill filling increases; higher ball loads; improved pebble discharge function; improved slurry discharge function incorporating important mill design and operational influences; and the new size dependent breakage function. The model will also be able to accommodate some influence of liner design and multi-component ores (blends of hard and soft components). This upgrade is still a work in progress but substantial changes have been made to date. This paper presents some of the new improvements and their influence on the predictive capability of the model.

Jan 1, 2012

By V. Caps

Gold has been often used as an alloying component in order to increase or modify the catalytic properties of an active metal. For example, in the hydroconversion of methylcyclopentane, Riahi et al [1] shown that the addition of gold to palladium or platinum enhances the activity which becomes greater than that of the pure metals whereas the selectivity towards products resulting from ring expansion increases. Molenbroek et al [2] presented a detailed study on Ni-Au catalysts which exhibit activity for steam reforming and have been proved to be more resistant toward carbon formation than the pure Ni catalysts. Blocking of highly reactive Ni edge and kink sites by Au atoms is assumed to be the reason for the increased robustness of the Ni-Au catalyst. Nevertheless, the own catalytic properties of pure gold have been almost ignored up to the pioneering work of Haruta et al [3] which demonstrates the high activity of gold for CO oxidation at low temperatures. Other reactions such as WGS reaction, propylene epoxidation or benzene total oxidation have then been shown to be catalyzed by gold [4]. This discovery induced the publication of papers devoted to analyze the different factors controlling the activity of gold catalysts. Among them the most relevant appears to be the gold particle size, the nature of the support [5] and the preparation methods [6]. Clearly distinguish between support and size effect is not straightforward. Indeed, the calcination step often needed to synthesize supported catalysts on different supports, leads to different particle sizes showing that particle size and support are interdependent. To circumvent this difficulty, Au-based supported catalysts have been synthesized by using laser vaporization and low energy cluster beam deposition. The as prepared catalysts have then been characterized and tested in CO oxidation reaction.

Oct 1, 2003

By M. C. Bluteau, G. P. Demopoulos

Arsenic reports in the effluents of many non-ferrous metallurgical operations. The production of scorodite, a crystalline ferric arsenate, is considered as an attractive option for the fixation of arsenic from aqueous effluents. However, scorodite solubility and long-term stability in the pH region of interest for tailings disposal have not been thoroughly investigated. In this study the long-term stability of scorodite in the pH 5 to 9 region and the mechanism of scorodite dissolution were studied. Construction of eh-pH diagrams indicated that scorodite stability is highly dependant on the nature (stability) of co-existing iron-hydroxide/oxyhydroxide. It was also found that when scorodite dissolves, a ferrihydrite phase having very small particles size (nano-scale) forms and that the growth and crystallization of this material are delayed by the presence of arsenate even under accelerated (75°C) ageing conditions. Around neutral pH and ambiant temperature (22°C) scorodite seems to reach an equilibrium with ferrihydrite after 48 weeks yielding soluble arsenic concentrations < 5 ppm.

Jan 1, 2004

By J. Jara

Oxygen, ozone and air were evaluated in the oxidation of ferrous iron in the presence of hydrochloric acid ranging from 0.1 to 4 M HC1. Stoichiometric coefficients were determined through mass balances of gases and ferrous titration. The molar ratio ferrous to ozone increases from two at 0.1 M HC1 concentration to six at 4 M HC1. For oxygen the same ratio is constant and equal to 2 and it is in agreement with other works. The stoichiometric coefficient of hydrogen ion was not defined due to the effect of hydrolysis of ferrous and in particular ferric ion on measuring acid concentration by titration with sodium hydroxide. Agitation, gas flow and pressure contribute in the utilization of gas. A technique to compare the gas efficiency at several conditions is discussed and it is based on the relationship between oxygen and ferric during time. There is a strong compromise between gas efficiency and ferrous conversion. Oxygen efficiency decreased with time due to ferrous depletion. The gas efficiency ranged from 3 % (low level of agitation) producing 25 g Fe(III)/h to 12 % at 1000 rpm with 60 g Fe(III)/h converted. At 405 kPa absolute the oxygen efficiency was in the range of 80 % producing 300 g Fe(III)/h. The replacement of chlorine with oxygen to enrich molybdenite concentrates by reducing copper to less than 0.2 % was evaluated. Oxygen can be employed in batch or continuous operation and it can treat molybdenite concentrates with high variation of copper content. The dissolution rate is mainly controlled by oxygen addition in which utilization of oxygen plays an important role. Improvement on safety and environmental conditions is feasible by using oxygen instead of chlorine gas. The economics indicate good opportunities to implement oxygen without significant modifications to the actual circuit and enough benefit when oxygen is well used.

Jan 1, 2007

By Carlos Antônio de Morais, Renata Dias Abreu

The present work describes a study of the separation of terbium and dysprosium from heavy RE concentrate through a solvent extraction circuit in a counter-current system. As the efficiency of the REE extraction by acid extractants rises with the increase of the atomic number of the element, the aim of this work is to extract the elements with higher atomic number maintaining Tb and Dy in the aqueous phase. Thus, terbium was separated first with subsequent separation of dysprosium. The experiments were carried out by using IONQUEST®801 as the extractant and a REE-hydrochloric liquor as feed solution. The optimum operational circuit in terbium separation was comprised of 37 stages: extraction, scrubbing, stripping, and solvent washing. For the dysprosium separation 39 stages were required. Terbium separation over 92% with over 95% purity and a Dy separation over 97% with over 95% purity were obtained.

Jan 1, 2014

By Christopher H. Clement

The International Commission on Radiological Protection (ICRP) is an independent, international organization that advances for the public benefit the science of radiological protection, in particular by providing recommendations and guidance on all aspects of protection against ionizing radiation. This presentation touches on aspects of The 2007 Recommendations of the ICRP, a fundamental document that lays out the system of radiological protection for all exposure situations and types, and focuses on other recent publications relevant to the uranium industry. Of particular relevance are the 2009 ICRP Statement on Radon and the accompanying report on lung cancer risk from radon.

Aug 1, 2010

By Murray D. Fredlund

The consolidation of soil material is central to many types of engineering analysis. Problems such as the building of highway structures, landfills, or buildings over saturated soft clays require application of such theory. It has been found in industry that the application of consolidation theory has lagged significantly behind the theory which has been developed some time ago. The application of small-strain saturated consolidation theory was first proposed in a 1D form by Terzaghi. Although this theory has been available for some time it?s implementation into software packages in 2D and 3D forms has been slow due to inherent complexities in the coupling equations. The flow and stress equations are also inherently somewhat unstable and this further complicates software implementation. Of particular interest in the mining industry is the consolidation of uranium tailings. One such disposal method that has been utilized is the subaqueous deposition of uranium tailings in large pit structures. When performing such deposition the calculation of consolidation rates is central to determining final pit capacity and expected life. Consolidation software can be successfully used in such cases in order to determine pit filling rates. The primary complexity, however, is that tailings are typically deposited in slurry form and therefore the potential deformations are large. Large-strain consolidation theory is therefore required in order to properly solve the deformations over time. This paper presents the use of a large-strain consolidation analysis in order to predict long-term filling rates in a uranium tailings pit.

Aug 1, 2010

By Cheryl L. Allen

Increasing energy costs associated with mining have become an issue that must be addressed by industry to ensure sustainable production. As underground mine ventilation systems account for 40% to 50% of a mine?s total energy requirement, initiatives to maximize their efficiency have been introduced worldwide. A control method known as Ventilation-On-Demand (VOD), which adjusts the ventilation system by responding to the activities of mine personnel and air quality, has been commissioned at Vale?s Coleman Mine. This initiative is an effort to reduce energy consumption, maximize efficiency of the ventilation system while ensuring air quality. There are five control strategies that can be executed with the VOD control system in place at Coleman Mine: Manual real time control Time-of-Day Scheduling Event-based control Environmental control Activity Based Control/Tagging This paper describes the system, control strategies and impact on energy consumption and flexibility of airflow distribution as applied at Vale?s Coleman Mine.

May 1, 2011

By M. K. Aly

"ABSTRACTThis paper briefly describes the mining method proposed for the iron ore deposits in Wadi Shatti, western Libya. The iron ore produced will be used in the steel plant at Misurata on the Mediterranean coast. GeologyThe Wadi Shatti is located in the central part of western Libya. Flat iron-bearing sedimentary rocks are exposed with remarkable regularity in this valley. It occupies an area 200 km long by approximately 20 km wide trending in an eastnortheast direction between Jabal Fazzan in the north and Zel1af Sand Dunes in the south (Fig. I). Only a part of this valley has been ful1y explored by drilling on a 400- by 200-m pattern in an area of 18 km2 south of the town of Taroot. Farther to the south, no exploration by drilling can be done due to the presence of sand dunes .The iron-bearing bed is about 10to 15m thick, with a dip of 2 to 4 degrees in a southerly direction . The overburden consists mainly of clayey sandstones, 4 to 5 m thick, in the northern part, increasing to 35 m in the southern part. The iron ore bed consists of three different layers, from the floor upward: (1) Lower Reduced Ore (LRO), having a varying thickness of 1 to 7 m; (2) Magnetic Ore (MO), with a thickness varying from 4 to 12 m mainly in the central part of the area; and(3) Upper Reduced Ore (URO), with a bed thickness varying from 0 to 7 m."

Jan 1, 1980

By C. O. Aksoy

Operating the underground marble quarries effectively, it is important to evaluate the deposit blocks economically which are affected by the suitability of the topography and configuration of bedding. The joint sets within the deposit and the spacing between these discontinuties are also of great importance. In this study, the marble deposits that could be geomechanically eligible for underground excavation have been selected throughout Turkey and these selected reserves have been classified accordingly by Q-Rating System. These classified marble deposits that forms groups of 1,2, and 3 (groups were determined by evaluating the O-rating, topography, quarry situation, cracks, joints etc.) are convenient for this type of production. Nevertheless, when the auxiliary factors (topography, location, production method etc.) regarding the deposit have also been investigated, the most convenient sub-group of deposits (Afyon Tiger Skin, Burdur Beige, Diyarbakir Pink and Mugla White) have emerged. The sizing of the pillars have been performed utilising Bieniawski?s stress profile. The LAMODEL software, developed by National Institute for Occupational Safety and Health (NIOSH), USA and run under the laminated displacement discontinuity method, has been used to size the pillars. This work brings in a novel opportunity to Turkey, in which no underground marble quarry has been attempted up-to-date similar to its several examples in Italy, USA, etc. This study serves as a reference for the marble operators and for the pioneering application of laminated displacement discontinuity method in hard rocks.

Apr 1, 2005

By S. Y. Mostowy, P. W. M. Shibley

"When Texas Gulf Sulphur Company discovered the Kidd Creek ore body in 1964, a crash program began almost immediately for the design and construction of a modern concentrator. It was necessary to mill two distinct ore types; one containing copper and zinc, the other lead, silver and zinc minerals. The final concentrator design was to handle 9,000 tons of ore daily in three circuits. One circuit was to treat copper-zinc and another lead-zinc ore exclusively on a permanent basis. A central circuit was designed with adequate flexibility to treat either of the above ore types in accordance with planned mining schedules. Ecstall Mining Limited, a wholly owned subsidiary, now operates the mine and concentrator complexes for Texas Gulf. The mine is located 15 miles north of Timmins and the concentrator 15 miles to the north-east along Highway 101. The ore is hauled from the mine to the concentrator over a 17-mile railroad. Initial milling operations began in November, 1966.1 - ABSTRACTThis paper deals with bulk reagent handling at the Kidd Creek concentrator. The reagent section at Kidd Creek has operated excellently since milling began in 1966. The bulk handling techniques are satisfactory. They have contributed substantially to good working conditions, economical practices and metallurgical efficiencies. The bulk handling features described should be considered in existing and proposed concentrators."

Jan 1, 1970

By A. B. Szwilski

The paper outlines the factors taken into account for the selection of steel arch supports. The results are based on experience using the long wall system of coal mining where roadway closure can be extreme. Results of tests on scale-model steel arches and full-scale yield elements are also presented.

Jan 1, 1979

By K. Shitogiden, Y. Samada, T. Miki

Steelmaking slag contains nutrition such as Si, P and Fe for acceleration of phytoplankton growth. Phytoplankton can fixate carbon dioxide more than any other species on earth. Hence, suppression of CO2 can be achieved by applying the potential of steelmaking slag as the nutrition for their propagation. When it is considered to supply nutrition from steelmaking slag to seawater, we must avoid dissolution of hazardous elements or change of pH of seawater by steelmaking slag addition into seawater. The protection against dissolution of fluorine into artificial seawater has been studied based on dissolution behavior of steelmaking slag and synthesized substances into artificial seawater in the present work. The dissolution mechanism of fluorine from steelmaking slag and buffering action of pH change are discussed by using stability diagram in seawater.

Jan 1, 2004

By Jonathan Tsang, Ali Merati, Jonathan Beddoes

Due to economic factors, many aircraft in service today have been operating for more than 30 years even though they were initially designed with a service life of 20 years. Improved damage management models are therefore needed for use in life prediction and management of the aging fleets of aircraft. Currently, the generally accepted procedure in fatigue life prediction methodologies is to back calculate the equivalent initial flaw size (EIFS) using established long crack growth data. However, it was observed from studies carried out at the National Research Council Canada that nucleation and short crack growth constitute up to -95% of the fatigue life. As a result, it seems that the significance of the short crack regime has been underestimated and must be further investigated and fully understood before an accurate holistic life prediction methodology can be realized. Unlike long cracks, local microstructural features such as grain boundary, grain size, inter-particle spacing, and texture play dominant roles in the behavior of short cracks. An extensive study has been carried out to evaluate different crack detection and monitoring techniques in the short crack regime for AA2024-T3. The results will be presented in detail.

Jan 1, 2004

By D. H. Whiting, A. J. Sinclair

"The San Antonio gold mine, in the Archean Rice Lake Greenstone Belt, was in continuous production from 1932 to 1968, during which period the mine yielded 1.35 million ounces (41 985 kg) of gold and 195,000 ounces (6065 kg) of silver from 4.88 million tons (4.44 Mt) of ore for average grades of 0.28 ounces per ton (9.0 g/t) gold and 0.04 ounces per ton (1.3 g/t) silver. After the 1968 closure, several publications appeared implying that gold grade of ore decreased with increasing depth.Recent observations by the authors show that the relatively low grades in the middle levels of the mine are controlled geologically. However, the reduced average are grade in the lower levels of the mine was due to inadequate mining control that led to a high level of dilution. The similarity of geological factors such as vein styles within structural domains, variations in mining control, recent ore muck sampling results and lithogeo chemical profiles all indicate the similarity of ore in both upper and lower levels.Strict mining control should yield improved grades of gold for future production from the lower levels at San Antonio, in contrast with the production grades of the late 19605that represented extensively diluted ore. High-quality production records are an essential component in re-evaluating a past producer, particularly where workings are accessible. Poorly founded conclusions which cannot be checked by access to workings can have a negative impact on the evaluation procedure."

Jan 1, 1990