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The molybdenum ores currently utilized in China are mostly molybdenum sulfide ores whereas oxidized molybdenum ores, being finely disseminated and difficult to process, have not been exploited and utilized effectively. In this article the beneficiation process of a molybdenum ore occurred in an oxidized ore zone was investigated in order to provide a new way for the development and utilization of the oxidized molybdenum ores in China. The molybdenum mineral in the ore was mainly wulfenite and the associated minerals included barite, limonite, quartz and small amount of cerusite. Limonite in the ore occurred in a crust and honeycomb-like colloidal state and composed the framework for the formation of the other minerals in the ore, which filled the pores in the framework. Wulfenite was mainly fine-grained and occurred in the fine porous crust and honeycomb-like framework. The finely disseminated ore structure made the separation and recovery of the molybdenum mineral in the ore very difficult. On the basis of the mineralogical study of the ore, experiments were conducted to compare the various mineral processing methods for the beneficiation of the ore, including single gravity concentration, single magnetic separation, single flotation, and a combination of high intensity magnetic separation and gravity concentration. The results indicated that with single gravity concentration a molybdenum concentrate containing 5.85 % Mo with a yield of 11.76 % and a Mo recovery of 43.5 % was produced. With single high intensity magnetic separation it was very hard to obtain a molybdenum concentrate product. With single flotation process a molybdenum concentrate containing 7.06 % Mo with a yield of 15.14 % and a Mo recovery of 62.63 % was produced. With a combination of high intensity magnetic separation and gravity concentration a molybdenum concentrate containing 6.46 % Mo with a yield of 11.81 % and a Mo recovery of 42.11 % was produced. In conclusion, compared to the other methods the flotation process can produce more reasonable technological and economical results and is the best process for the exploitation and utilization of the finely disseminated oxidized molybdenum ore.

Jan 1, 2014

By A. I. A. Salama

In this paper, the problem of sedimentation and consolidation of poly-disperse suspensions is considered. The solid particles are assumed to be of different densities. If the sediment solids stresses are dropped out of the system equations and using the Richardson and Zaki hindered settling model, it has been found that in the limit, i.e., as time approaches infinity, the fluid is completely displaced to the top of the sediment zone. Furthermore, the species segregate completely with the heavier and coarser particles at the bottom of the sediment and the lighter and finer particles at the top of the sediment. Practical observations do not support these behaviors and physical-ly such behaviors do not exist; consequently, results of this kind in the literature are unrealistic. Here, a mathematical structure of the poly-disperse sedimentation and consolidation problem has been proposed. In this case the compaction zone species solids stresses are introduced in the momentum balance equations of the system. The species solid stresses in the sediment are constrained so that the system equations are consistent, i.e., sedimentation and consolidation of two or more identical species should behave as a mono-disperse system. Such a condition has not been recognized and imposed in some of the studies in the literature, which has led to unreliable results. Two practical forms of species stresses that satisfy the system consistency condition are here proposed. It should be noted that the study of sedimentation and consolidation of poly-disperse suspensions could result in more realistic suspension interfaces compared to mono-disperse suspensions, and could lead to more reliable engineering designs of tailings ponds. Predictions of sedimentation and consolidation in models of poly-disperse suspensions are demonstrated using published data.

Jan 1, 2014

By C. Tokoro

Co-precipitation of dilute toxic anions with ferrihydrite is an important removal mechanism in wastewater treatment system. Although, numerous qualitative studies have been published on removal characteristic from wastewater of dilute anions by co-precipitation treatment, detail mechanism or quantitative characteristic is not well understood. This paper discussed the co-precipitation mechanism of As(V) and Cr(VI) with ferrihydrite by comparative experiments between co-precipitation and simple adsorption. In this study, co-precipitation experiments and simple adsorption ones were distinguished closely. In the former, precipitation of hydroxides and adsorption of anions develop simultaneously, but in the latter, anions adsorb onto prepared hydroxides. Although high affinity anions for hydroxides (e.g. As(V) for ferrihydrite) showed quantitative difference of removal ratio between co-precipitation experiments and simple adsorption ones, low affinity anions (e.g. Cr(VI) for ferrihydrite) showed quantitative agreement in spite of deferent forms of ferrihydrites between them, that is, amorphous ferrihydrite was formed in co-precipitation experiments, but goethite was formed in simple adsorption ones. In order to discuss the mechanism of co-precipitation phenomena, three experimental studies have been carried out: (i) adsorption isotherm measurement in the co-precipitation experiments of As(V) or Cr(VI) with ferrihydrite, (ii) zeta potential measurement of co-precipitated or simple ad-sorbed ferrihydrite with As(V) or Cr(VI), and (iii) XRD analysis of co-precipitated As(V) for ferrihydrite. All experimental results suggested the main mechanism in co-precipitation phenomena of As(V) was not only a surface complexation (simple adsorption) but also a surface precipitation.

Jan 1, 2014

By P. Fecko

The objective of the paper was application of bacterial leaching on two brown coal samples from locality Mine Druzba, seams Antonin and Josef (Sokolov brown coal basin, Czech republic). Based on the results of bacterial leaching and petrologic analyses of the given samples, it is possible to say that application of bacterial leaching gived good results. Applying bacterial leaching it is possible to remove from 34% to 47% of total sulphur and from 45% to 64% of pyritic sulphur from the coal.

Jan 1, 2014

By C. Y. Sun

China is a country with abundant resources of tungsten, taking one of the world?s top-positions regarding both the total reserve and the amount of industrial production. China?s tungsten resources occur mostly in multi-metallic deposits rather than in single-metallic deposits. China?s multi-metallic tungsten ores have the characteristics of coexistence with other valuable components such as molybdenum, bismuth, copper, sulfur and fluorite. These ores are usually low in grade and difficult to process. The technological challenge in mineral processing lies in separation of multi-metallic components in these complex ores and a comprehensive utilization of natural resource. Several cases of industrial practice of processing China?s typical multi-metallic tungsten ores are presented.

Jan 1, 2014

The relative abundance of coal in India compared to other fossil fuels makes it a natural choice as the primary source of fuel, be it for steel making, power generation or for other uses. The wide variations in nature and type of Indian coals formed during lower Gondawana period and categorized as difficult-to-wash due to its typical mineral matter association with the organic matrix call for suitable beneficiation techniques as the preferred option for quality upgradation. The good quality coking coals of the upper seams are fast depleting leaving behind the inferior quality lower seam coal. The lower seam coals presently being mined are mostly low volatile coking coal (LVC). They constitute about 50% of the total coking coal reserves in India. The beneficiation of Low Volatile Coking coals pose a major challenge and detailed R & D studies was taken up to study the beneficiation characteristics of these coals. The studies revealed that the liberation characteristics at coarser sizes are very poor and the coal is to be ground to finer sizes for liberation. The most important factor that determines coal cleaning efficiency is liberation of organic matter from mineral matter. To achieve liberation grinding is necessary as a result range amount of ultra fines (-0.063 mm) coal is generated. Presence of these large amount of ultrafine in the coal fines, often impose severe technical constraints affecting not only its floatability but also in the downstream treatment of the products like dewatering and cake formation particularly when it is beneficiating through froth flotation. In the present paper optimization of ultra fines (-0.063 mm) has been tried for a LVC coal of Jharia coal field for the better liberation and beneficiation of the above coal fines. It is observed that by optimized, combination of size and number of balls generation of fines can be controlled with liberation. Keywords: coking coal, liberation, floatability, dewatering

Sep 1, 2012

By Z. S. Abisheva

Rare and rare earth metals use quite often is an indicator of national economy development. The world structure of the rare-earth metals manufacturing countries in 2015 was presented as follows: China – 94.2%, India – 2.0%, Russia – 1.8%, the USA – 1.2%, Brazil – 0.5%, Malaysia – 0.3%. In Russia, large reserves of rare-earth metals, which reach nearly 28 million tons, are revealed. Kazakhstan, possessing a raw materials source of rare-earth metals, has all prerequisites for development of branch. Rare metals are manufactured in Kazakhstan incidentally by non-ferrous metals production. The production of indium, thallium, cadmium, selenium, tellurium, bismuth is made at the Ust-Kamenogorsk lead plant; tantalum, beryllium, niobium and molybdenum – at the enterprises of “National Atomic Company Kazatomprom” JSC. Production of a titanium, magnesium and vanadium is adjusted on “Ust-Kamenogorsk Titanium-magnesium Plant” JSC. Capacities for beryllic production yield are available on “Ulba Metallurgical Plant” JSC. The main producer of perrhenic production and osmium-187 is "Zhezkazganredmet" RSE. The single producer of gallium in Kazakhstan is “Aluminium of Kazakhstan” JSC; the capacity of enterprise is 25 t a year. In Kazakhstan innovative technologies for rare and rare earths mineral raw materials processing are created. The technology has been developed and a vacuum distillation apparatus has been created to purify crude selenium, which makes it possible to obtain a metal with a main component content of 99.9-99.99%. Technologies for processing of technogenic wastes and byproducts of the copper industry are developed. Implementation of technologies allow to obtain ammonium perrhenate, perrhenic acid, osmium isotope -187, tribasic lead sulphate, silver-concentrate. The technology of complex processing of black shales of Balasauskandyk deposit with the production of gold, vanadium, rare earth elements, uranium and ferrosilicon has been proposed. The processing was carried out using methods of autoclave leaching, sorption, extraction, precipitation. A highly profitable sorption technology for recovery of rhenium from solutions of underground leaching of uranium ores containing 0.2-0.4 mg/L of Re has been created. The organization of ammonium perrhenate production from solutions of uranium ore will significantly increase the volume of its production in Kazakhstan.

Jan 1, 2018

By N. S. Voiloshnikova

Large-scale continuous ?Resin-In-Pulp? process tests were conducted at Irgiredmet. The object for testing was the sample of oxidized gold ore from one of Siberian deposit. Weak-base ion ex-change resin PuroGold was used as adsorbent. The duration of ?Resin-In-Pulp? tests was sufficient for a completing of three cycles ?Adsorption/Elution?. Gold in feed was 0.95 mg/L. Gold in solid phase of adsorption tails? 0.065 g/t. Gold in liquid phase of adsorption tails? 0.026 mg/L. Total gold in adsorption tails ?0.11 g/t. Gold recovery ?94.3 %. The use of regenerated resin had practically no effect on gold losses with adsorption tails. Alkaline cyanide solution (NaCN-20g/L, NaOH- 5g/L) was used as eluent for gold elution from loaded resin. Elution temperature ?60 °C. Number of eluent bed volumes passed ?10. Loaded resin analysis was following (g/ton): Au? 1700~1250; Ag? 400~460; Cu? 250~450; Zn? 5100~9600; Fe? 860~1200. Elution efficiency: Au? 95.3%~97.8%; Ag? 84.0%~88.0%; Cu? 84.0%~88.0%; Zn? 97.0%~99.0%. Although high zinc resin loading was shown zinc was eluted efficiently. The adsorption properties of fresh PuroGold resin, PuroGold resin after 3 cycle ?Adsorp-tion-Elution?cycles in comparison with AM-2B resin were tested. It was shown from adsorption isotherms that selectivity of PuroGold resin slightly less in comparison with AM-2B resin mainly due to its higher zinc adsorption properties. It was founded on base of test results that adsorption properties of PuroGold resin was practically constant during three ?Adsorption/Elution? cycles. Gold may be efficiently recovered by resin tested. There were no difficulties during gold elution from loaded resin and its regeneration. PuroGold resin was recommended for industrial use in RIP process. Process design criteria were developed and plant design is on progress at the moment.

Jan 1, 2014

By E. Barsky

Physical principles of two-phase flows with a polyfractional solid phase have not received a sufficient theoretical interpretation as yet. Two-phase flows in the separation mode with a counter-flow of particles are even more complicated. Only statistical methods give an insight into general regularities of such processes. These processes can be interpreted best by analogy with the statistical model of an ideal gas developed by L. Boltzmann, although here a number of difficulties arise. The notion of a statistical system for such flows is substantiated. A mathematical estimation of a statistical system is presented. New notions are introduced, namely, potential extraction of a system and lifting factor. A relationship having the physical meaning of entropy is derived for a two-phase flow in the separation modes. The connection of this new entropy with flow parameters, such as the number of particles, separation factor and chaotizing factor, is established. Properties of this entropy are analyzed, as well as the analogy and difference between this entropy and Boltzmann?s entropy. The notion is formulated and the definition of the chaotizing factor of a process is suggested. In the framework of a statistical approach to two-phase flows in the separation mode, the notion of flow mobility has been formulated. Principal regularities of mass transfer in zone/apparatus sys-tem are analyzed. Principal ideas of a cellular model of the process are formulated, and main relationships for its description are derived. Proceeding from the cellular model, a dependence describing the degree of fractional separation of a narrow size grade is found. The analysis of this dependence makes it possible to reveal the crucial role of the Froude criterion for gravitational separation processes. It is found empirically that this parameter is a basis for the affinization of separation curves (Barsky E, Barsky M, 2006; Barsky, 1980).

Jan 1, 2014

By A. De1

Because of the extremely low utilization of strain energy in the breakage of solid particles, the energy efficiency prevalent in comminution technology is extremely poor. Schoenert considered that single-particle comminution under slow compression is the most energy-efficient mode of comminution and that energy efficiency should be compared to that. The usual method for grinding minerals and cement has been the ball mill, in which the hit-and-miss aspect of loose-bed comminution severely reduces energy efficiency. The fine grinding of minerals is a particularly energy-intensive process. Schoenert showed that the energy consumed in the comminution of particles in confined beds is second only to that of single-particle comminution under slow compression and developed the method of conducting particle-bed comminution continuously in a high-pressure roll mill. Since its first industrial installation in 1985, the high-pressure roll mill has established itself as the comminution device of choice for significantly improving the productivity and energy efficiency of size reduction from coarse size feeds down to products finer than 20 microns. The first of several hundred installations were in cement plants. The preliminary design and optimization of the industrial operation of high-pressure grinding roll (HPGR) systems, owing to the continuous nature of the device, cannot be efficiently done through laboratory experiments and needs to be achieved through proper system modeling. While the energetics of size reduction in high-pressure grinding rolls has been modeled very well, no model exists for the macroscopic variables in HPGR comminution. In high-pressure roll mill grinding, size reduction results from confined particle-bed comminution under compressive stresses such that the daughter particles produced are highly fractured, stressed, or otherwise weakened. This paper attempts to relate the comminution / compaction behavior for confined particle-bed under compression in a piston-die press with the macroscopic variables in HPGR comminution. A model describing the pressure-densification relationship is presented and used to accurately simulate the macroscopic variables in high-pressure grinding rolls, utilizing experimental data for particle-bed comminution with the piston-die press. The accuracy of the predictive simulations strongly suggests that, starting with a few batch-mode laboratory-scale experiments, it should be possible not only to identify the optimal operating conditions for existing operations but also to successfully design new industrial high- pressure grinding roll systems.

Sep 1, 2012

By Danfeng Xu

The majority of the world?s nickel (Ni) resources occur as laterite ores, which are exceptionally complex, lower grade (<1.5% Ni) and expensive to treat using conventional smelting and high temperature/pressure autoclave methods. Heap leaching is a promising, less costly, alternative technology for processing low grade nickel laterite ores. However, significant technical challenges remain with Nickel laterite heap leaching, preventing its general adoption. This paper presents some highlights of laboratory column leaching studies undertaken to characterise, evaluate and optimise sulphuric acid leaching behaviour of Nickel laterite agglomerates. They provide basic but valuable information regarding Nickel laterite agglomerate structure stability and leaching performance under industrially-relevant, continuous acid irrigation conditions. In particular, Nickel and other key metals? (e.g. Co, Fe, Al and Mn) extraction rates, free acid concentration, bed slump and structural changes were determined at a given acid percolation rate as a function of time. Potential implications of the findings, for devising strategies for improved Nickel laterite plant heap leach operations are discussed. Keywords: nickel laterite, column leaching, agglomerates, leaching kinetics, acid consumption

Sep 1, 2012

By W. Rubarth

The kaolin losses in hydrocyclone classification are determined by the fines, which are discharged together with the water to the underflow. This paper presents an improved technique of water injection to the conical part of the cyclone applied especially for small cyclones in kaolin preparation. In small hydrocyclones water, injection is a sensitive process. Therefore, the process was stabilized by controlled water injection dependent on the measurement of the underflow shape. Three applications of this innovation are presented. In the first case, the water injection is applied for the separation stage in dilute suspension where the final product is produced in the overflow of a 50mm hydrocyclone. The underflow contains sand and residual kaolin. For a higher kaolin recovery, the underflow is usually treated downstream in washing cyclones. The wash water injection results in a 45 ? 50% - reduction of the kaolin fraction <25µm in the underflow. Thus, water injection to the classifying cyclone leads to a separation comparable with a downstream washing stage. An additional hydrocyclone stage can be deleted. The second application refers to a classification in dense suspension. Here, the underflow of the last hydrocyclone stage was directed to a washing in a 50mm hydrocyclone. The additional injection of 3L/min water in to the conical part of the cyclone reduced the kaolin losses by half.The third application was executed in the washing stage equipped with 75mm hydrocyclones where the underflow is directed to flotation. Using the water injection the kaolin recovery in this stage was increased by approximately 20%. Keywords: hydrocyclone, classification, kaolin beneficiation, water injection, underflow washing

Sep 1, 2012

By T. Wajima

We tried to convert paper sludge ash (PSA) into zeolitic product with high cation exchange capacity (CEC) through acid leaching. Typically, PSA from incineration of paper sludge contains a high percentage of calcium in the form of anorthite (CaAl2Si2O8) and gehlenite (Ca2Al2SiO7). It is difficult to convert the ash with a high Ca content into zeolites, or at least into more desirable zeolite phases. Acid leaching with HCl was applied to reduce the Ca content to synthesize zeolitic product with high CEC. The raw ash was treated with 1 M, 3 M, and 5 M HCl solution for 0.5~24 hours (the ratio of the ash to volume of HCl solution was 1/4), and then zeolitic product was synthesized from leached ash through the reaction with 2.5 M NaOH solution at 80 oC for 24 hours. During acid leaching, gehlenite is readily dissolved in a lower HCl concentration solution than anorthite. With increasing HCl concentration, the amounts of Ca, Mg, Si, Al, Fe and Ti extracted from the ash increased. Ca and Mg contents were easily extracted from ash than other elements. The contents of Ca and Mg extracted rapidly at initial stage, and then levelled off. The saturation times of Mg and Ca are almost 0.5 h using all concentrations of HCl solutions. After the synthesis from leached ashes, zeolite-A and -P were synthesized from ash leached in 1 M HCl solution, and 3 M and 5 M HCl solutions, respectively, regardless of leaching time. With in-creasing HCl concentration, the Ca content eluted from the product decreased, due to the removal of Ca via acid leaching before the synthesis, while the Na content eluted from the product increased to 3 M HCl and then decreased, which was almost similar to the CEC of the product, due to the ion exchange of Na-type zeolitic phase in the product. The change of zeolite phases in the product and the CEC of the product depend on the concentrations of Si and Al in the solution during the synthesis. The highest CEC of the product is about 220 cmol/ kg, which was synthesized from the ash leached in 3 M HCl solution.

Jan 1, 2014

By V. I. Ryaboy, V. P. Kretov, S. E. Levkovets, I. V. Ryaboy

"Using the flotation of a gold-containing ore from a deposit in Kazakhstan as an example, we have conducted a study designing dialkyldithiophosphate collectors, in addition to xanthates, for the flotation of hard-toenrich gold-containing ores to increase gold recovery.The increased flotational ability of the dialkyldithiophosphates was determined by their surface activity at the liquid-gas interface and their hydrophobic ability, the changing of which allowed us to control the collecting power and selective ability of the dialkyldithiophosphates. The studying of the surface activity of aqueous solutions was done using the stalagmometric method and the evaluation of the hydrophobic ability was done in percentage of the relative value of the zinc ion binding in the solution in standard conditions.Studying the influence of surface activity in our designed dialkyldithiophosphate collectors, with their close hydrophobic ability, showed that even with a small increase in surface activity in their aqueous solutions, gold recovery increased by 2-3% in laboratory conditions. Using this enabled us first to apply the dialkyldithiophosphate collector BTF-161 at a plant in Kazakhstan, and then to introduce the specially designed dialkyldithiophosphate collector BTF-163, which has been in use since. Further study of dialkyldithiophosphate activity based on this concept showed us that for the range of short-chain dialkyldithiophosphate collectors with a chain length of up to ?5, the effectiveness of ore processing became lower the higher their surface activity got, with relatively small differences in their hydrophobic ability. For long-chain dialkyldithiophosphates with a chain length of over ?5, ore processing effectiveness increased with the increase of their hydrophobic ability.Based on these studies, a new effective dialkyldithiophosphate collector, BTF-1517, was designed. Using this reagent in continuous gold recovery tests allowed us to reach an 84.21% recovery with a concentrate quality of 15.66 g/t, while using the applied collector BTF-163 in similar conditions led to the recovery of 82.87% with a concentrate quality of 15.65%. As a result, the Kazakhstan processing plant decided to conduct industrial tests with the BTF-1517 collector."

Jan 1, 2018

By V. Panayotov, M. Panayotova

"Wastewater from ores processing is often polluted by molybdate and sulfate (SO42-) ions. Sorption is one of suitable methods for removing those pollutants when presenting in low concentrations. This work reports results on adsorption of sulfate and molybdate ions on metal modified (with barium - Ba and lead - Pb) and organic reagent modified (with Hexadecyl-trimethyl-ammonium bromide - HDTMA) clinoptilolite. Zeolite’s modification with Pb, Ba and HDTMA increases its uptake capacity with respect to Mo(VI) at pH 3, with the uptake capacity decreasing in the order CL-Pb > CL-HDTMA > CL-Ba. Lead-modified clinoptilolite shows high uptake with respect to Mo(VI) in acidic, neutral and slightly alkaline conditions. The presence of SO42- in concentrations twice higher than the amount of Mo(VI) do not interfere with the Mo(VI) removal by CL-Pb. Zeolite’s modification with Ba and Pb renders it able to immobilize SO42- from water in the pH range 3-9. Kinetics of the uptake process is best described by the pseudo-first order kinetic equation. Increasing the initial concentrations of Mo(VI) and SO42- increases the removed amount of pollutants. INTRODUCTION Wastewater from copper-molybdenum ores processing is often polluted by molybdate and sulfate ions. Molybdenum (Mo) migrates easily in water and consequently the Mo polluted areas could extend for hundreds and thousands of meters (Ryzhenko, 2010). Molybdate anion is the only Mo(VI) species in natural water, i.e. at pH > 6.0. Its median freshwater hazardous concentration affecting 5% of the species (HC 5.50%) is 38.2 mg Mo/L (De-Schamphelaere et al., 2010). The marine water chronic toxicity (HC 5.50%) is assessed at 5.74 mg Mo/L (Heijerick et al., 2012). The predicted no-effect concentrations (PNEC) are 12.7 mg Mo/L and 1.92 mg Mo/L correspondingly for freshwater and marine water (Heijerick et al., 2012a). When sulfates present in drinking water in excess of 250 mg/L they cause a cathartic action (especially in children) in the presence of sodium and magnesium, and when the concentration exceeds 600 mg/L, diarrhea. When sulfate-rich effluents are discharged into the environment, they may increase the acidity of water bodies and soils (Guimarães and Leão, 2014). Because of the adverse effects to human health and the environment, limits are set for SO42- concentrations in waters and wastewaters in the range of 250 / 500 mg/L."

Jan 1, 2018

By Montaser S. EL Salmawy, Takahide Wakamatsu, Eishi Kusaka

"In conventional flotation, fluoride ions selectively would react with the aluminum site on the microcline surface and produce negative charged sites for amine to be adsorbed (Smith, 1976). According to this view, aluminum site is considered as a key feature in feldspar flotation. Generally, fluoride ion has been widely used as a modifying agent in silicate flotation. Since O'Meara's patent appeared on HF -amine reagent system to selectively float feldspar from quartz in 1942, relatively few contributions have been devoted in this issue. The reason might be that the process works very well, and accordingly there is no initiative to investigate in this area. However, due to the awareness of international community to restrict using of hazardous reagents like HF, sound engineering practice to search for alternative methods, not utilizing HF, has been launched. Inspection of literature, one can find several works dealing with this issue.In this contribution, the effect of ethoxylation of long chain alcohols on the quartz and feldspar flotation behaviors was investigated for surfactants of the octylphenol polyoxyethylene family. The tests were carried out with an average of 7.5 (Triton X 114), 9.5 (Triton X 100), 30 (Triton X305), 40 (Triton X 405) and 70 (TritonX 705) oxyethylene units. Electrokinetic and flotation studies on quartz have shown that at low pH values, quartz could be floated with polyoxyethylene octytlphenols. The possible mode of adsorption of these nonionic surfactants may be suggested to be due to hydrogen bonding between the oxygen of ether and hydrogen in the free hydroxyl groups on quartz surface. It was anticipated that the selectivity between quartz and microcline would decrease as oxyethylenic chain length increases."

Jan 1, 2003

By Hamid-Reza Manouchehri, Hassna Aitahmed-Ali, Stellan Sundberg

"In flotation practices as the particle size becomes fine, e.g., p<20µm, the process efficiency declines markedly. When flotation of fine particles is necessary, one method to improve the recovery is selective agglomeration of fines. Different agglomerating methods have been introduced and tested; however, one method which has recently received great attention is to aggregate fine particles by magnetic force. A selective aggregation of the fine paramagnetic particles, e.g., sulfide minerals, can be achieved by applying a high intensity magnetic field during flotation conditioning. The method is simple, selective and effective for fines, and has a low operation cost. However, a minimum magnetic susceptibility of fine grains is required for this process. This method has been demonstrated in different sulfide minerals flotation plants. The implementation of the magnetic conditioning device, ProFlote, in both the Cu-Pb and the Zn circuit of Boliden’s Garpenberg plant in Sweden, where a complex massive sulfide ore is treated, is discussed herein. The preliminary results have shown an increase in the recovery of value minerals, in particular Zn and Ag and considerable reduction in Zn deportment to the final tail. Increases in Cu grade and decreases in Pb grade in Cu-con have been achieved as well."

Jan 1, 2014

By H. Ding

Calcium carbonate/Titanium dioxide composite, characterized by coating TiO2 on the surface of CaCO3 particles, is an important substitute for titanium dioxide. This paper studies preparation method of CaCO3/TiO2 ,composites based on mechano-chemical effects, measures its properties as a pigment, analyzes the binding form and interface reaction mechanism between CaCO3 and TiO2. Through single finely grinding of CaCO3, co-grinding of CaCO3 together with TiO2, and mecha-no-chemical effects produced in the course of grinding, CaCO3/TiO2 composites can be prepared successfully. Results indicate that grinding fineness of CaCO3, co-grinding time of CaCO3 and TiO2, the weight ratio of grinding media to mineral feeding, and the amount of TiO2 have much influence on the properties of CaCO3/TiO2 composites. CaCO3/TiO2 composites have the properties same as titanium dioxide pigment, oil adsorption and ultraviolet adsorption same as TiO2, and 90% of hiding power as that of TiO2. Wet grinding of CaCO3 causes the production of mechano-chemical effect and hydroxyl group, through which CaCO3 and TiO2 can be bonded together. Repulsion occurs between the particles of CaCO3 and the particles of TiO2, respectively, they are both in good dispersion. But attraction occurs between CaCO3 and TiO2. TiO2 particles are distributed evenly on the surface of CaCO3. Therefore, coating of TiO2 on the surface of CaCO3 particles and chemical bond between them make CaCO3/TiO2 compo-sites have pigment properties of Titanium.

Jan 1, 2014

As a kind of collector, Xanthates are generally used to make sulfide minerals hydrophobic in flotation process. Xanthate adsorption on a galena surface has been widely studied experimentally. In this paper, DFT methods were employed to investigate the local adsorption interactions about the collectors,such as ethyl xanthate (CH3CH2OCS2?, EO) and ethyl trithiocarbonate (CH3CH2SCS2?, ES), absorbing on two different PbS clusters. From the results, it can be easily found that, on the edge or at the apex, both collectors, with two S atoms bidentate coordinating on the clusters, have surprising interaction energies, while on the surface, its interaction is relatively weak in the form of monodentate ligand. NBO analysis results reveal that there is at least a covalence bond with sulfur atom about 10% and lead atom about 90% when the absorbed lead is on the lattice edge or at apex, but, if the absorbed lead is on the lattice surface, no covalence band would be found. Meanwhile, the S-Pb bond, formed by the absorbed Xanthate and galena lattice, seems to have much more covalence characteristic than that formed in the PbS lattice inner. Furthermore, those data also imply that the difference of the collecting effect between the EO and the ES may be not notable, because of the similar distance and the interaction energy for the same interaction mode.

Jan 1, 2014

By Xiaojing Li, Yueyuan Zhou, Shengyao Ma

The paper presented the acnalysis of field intensity of rare-earth permanent magnet with high BH product and the research of magnet configuration with narrow pole pitch on open magnet surface, both using ANSYS. The possibility to separate micro-disseminated feebly magnetic minerals by improving the field intensity and the capture line distribution rate on open magnet surface were verified. The research on the method to pile up magnets to increase peak value of field intensity on the open magnet to 1.0T was done through correlation analysis between shape and dimensions of magnetic material and field intensity. And the research on technology method to improve capture line distribution rate in the separating field to 1.25×105/m2 was done through optimization design of magnet configuration of the open magnet with narrow pole pitch. Laboratory tests were performed with hematite sample from ore dressing plant such as Hainan mine, Qidong iron ore, etc. The separation results acquired were at the same level as using the electromagnetic separator, verifying the possibility to separate micro-disseminated feebly magnetic minerals with open magnet. The research suggested a new idea about the development of magnetic separator with high efficiency and low costs to separate feebly magnetic minerals and non-magnetic gangues.

Jan 1, 2014