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By Alim Gül, Güven Önal

"Recently, there have been some attemps on the treatment of low grade ores and old plant tailings due to the decrease in high grade ores and the increase in the metal consumption with increasing world population. Cost of mining and beneficiation of low grade ores become prohibitive since the costs of grinding before flotation make the process unfeasable. Therefore, preconcentration of these ores prior to flotation becomes more important. The concentration of ores preconcentrated in coarse sizes provides a decrease in investment costs as well as grinding and flotation costs. Additionally, the requirements of less space for tailing disposal and less reagent consumption are also important from the viewpoint of environmental considerations.In this study, ore sample containing 0.6 % Cu and taken from Küre-Asiköy ore body was used. Ores contained chalcopyrite and pyrite as main minerals and diabaz, quartz, chlorite and sericite as gang minerals.Samples were all crushed under 9 mm by considering the preliminary studies and float and sink experiments were carried out with the sample in the size range of –9+1 mm using different densities of heavy liquids. As a result of these tests, it was shown that 60 % of the material should be discarded as tailings with 0.1 % Cu content. By considering float and sink test results, the following experiments were performed by using heavy medium cyclone and jigs.As a result of heavy medium cyclone tests, which are conducted on the sample in size range of –9+1 mm, 57 % of the feed material was discarded as tailing with 0.08 % Cu content and 7 % Cu loss, while a concentrate containing 1.43 % Cu was produced with 93 % efficiency (Table 1). Jig tests were done with the samples in the size range. As a result of jig tests with –9+1 mm size group sample, approximately 46 % of feed material was discarded as tailings with 0.13 % Cu content and 10.6 % Cu loss, while a concentrate with 0.94 % Cu content was obtained (Table 2)."

Jan 1, 2003

By Thomas Pretz, Alexandra Pehlken

Sampling of municipal solid waste is known to be difficult to sample if it has to be representative. When dealing with municipal solid waste, the usual method is to study separately waste material below 40 mm and particles bigger than 40 mm. The material < 40 mm cannot be sorted manual and is termed the “fine fraction”. The particles > 40 mm can be separated manually and are usually sorted into pre-defined groups of materials. These groups can be defined depending on the demand of quality assurance. But standardisation of procedures is not far progressed, even for the widely practised sorting methods.

Jan 1, 2003

By Nicolás Caussade

"The IMPC 2014 slogan "Optimizing Water and Energy Usage for Sustainable Mining" refers to the ever decreasing availability of fresh water and energy, which has turned out to be a crucial aspect in assuring the competitiveness of the mining sector in Chile and the Andes region in general. The concern for sustainability and the supply of water and energy is nowadays part of the top priorities of mining countries and communities. This is also the case for Antofagasta Minerals. Several years ago its mining group implemented an energy policy based on intelligent, strategic and sustainable management, in order to successfully face the challenges imposed by the market. It is called an intelligent policy because it intends to provide energy through a diversified range of sources, which includes the development of in-house alternatives. It is also a policy focused on efficient energy consumption and one that is strategic. Because it is in line with the characteristics of the mining activity, it is developed for the long term. Finally, what makes the policy sustainable is that it gives priority to energy usage from renewable resources and as such, the required capacities have been developed to generate innovative solutions that respond to the restrictions that characterize the industry today."

Jan 1, 2014

By John Starkey

"The development of the SAG Power Index (SPI) Test in Canada has created a new and accurate way to measure ore hardness in a SAG environment. Coupled with the standard Bond Ball Mill Work Index Test it is now possible to determine from these two relatively inexpensive laboratory tests, the amount of energy required to grind an ore from the primary crushed size to the desired liberation size. By testing multiple samples to discover where the hard and soft ore zones are located, the representative hardness distribution for the ore body can be determined and grinding equipment selected that is capable to meet production targets for all mining areas of the deposit.Previously, it was deemed prudent to select up to 50 t samples of ore for Semi Autogenous Grinding (SAG) pilot plant tests and a second 5 t sample for metallurgical pilot plant work. The methods outlined in this paper show how the 50 t sample is no longer required for SAG design because it is better to measure the representative hardness distribution of the ore body than the hardness of a “chosen” representative sample. This is demonstrated to be true by the fact that the lower horizons of an ore zone cannot initially be accessed to recover 150mm pieces, and the bulk samples taken, rarely represent the desired design hardness of the ore. Median hardness will not yield a good result in most cases and a clear understanding of the location and extent of the hardest zones is imperative to achieve a truly successful grinding circuit design.This paper discusses two plants (Kubaka and Agnico Eagle) that have been designed using SPI and Bond with no pilot plant test backup. Both have been very successful in that they can grind design tonnage on the hardest ores in the mine. This guarantees that the mine’s profitability is protected in any mining sequence. It also allows the extra power to be converted to higher throughput on softer ores if additional cash flow is needed. The advantages from the owner’s point of view are dramatic. This procedure will be attractive as well when considering the costs for test work, and the samples for testing. Existing diamond drill core is normally used and this allows the inclusion of data from the deepest regions of the mine. In addition, it is also clear that the decision to use a crusher can now be made at the design stage of a project based on measured parameters and the estimated capital costs of alternative designs."

Jan 1, 2003

By R. Bugueño, W. Calderón, G. Montes-Atenas

From the point of view of industrial performance of metal extraction, the efficiency of a column leaching operation depends strongly on the leaching agent and the ore properties such as mineral composition, mineral liberation and particle size distribution. One aspect that has become particularly important is how the leaching solution flows through the porous structure which contains the valuable minerals. It is known that the output flow rate of leaching solution depends mainly on factors of the input flow, environmental condition and porous bed properties. The latter factor is often evaluated and reported under saturated conditions but in practical leaching systems unsaturated conditions are dominant. This investigation has the purpose of determining the residence time of the leaching solution in columns with different diameters under unsaturated conditions by using experimental data and numerical simulations. Laboratory leach test were performed using isothermal jacketed columns with top cap to reduce the evaporation. The simulations were performed using the software SVFlux® which incorporates material properties such as Soil Water Characteristic Curve (SWCC) and Unsaturated Hydraulic Conductivity. Preliminary results indicate a non-linear asymptotic behavior of the saturation rate with respect to the operation time. Results from numerical simulations show the same non-linear behavior and a considerable delay between input and output flows. Further analysis concerning with the effect of transpiration and evaporation mechanisms is discussed.

Jan 1, 2014

By Claudio L. Schneider, Reiner Neumann

Any serious study of stereological conversion procedures must be based on an as accurate as possible complete fractionation of a real mineralogical texture. The original work on the Dolomite- Sphalerite Magstream? separation provided excellent data for establishing a working stereological conversion procedure, which has been successfully applied to a number of ores since its implementation. The linear grade distributions measured from these fractionated particles have been published and are accessible. The procedure for stereological conversion from areal measurements is exactly equal to the procedure for linear measurements. Particle composition from the dolomite-sphalerite density-fractionated particle sets, derived from both linear and areal data (Figures 1 and 2, respectively) are redundant, after proper transformation, and match the particle’s compositional range (plotted against S.G.) expected from Magstream?; direct density measurements by Hemicropicnometry plots within the ranges. Linear data cannot be used without conversion, but areal measurements are often directly applied as liberation spectra. Our areal measurements, without stereological conversion (Figure 3), differ completely from the results after transformation, and its density range falls mostly out of the expected/measured values. Therefore non-transformed areal data cannot be directly applied as useful liberation information.

Jan 1, 2003

By Fernando Concha

"Thickening development and innovation in the 20th Century occurred in two decades periods. From 1900 to 1920, Dorr invented the continuous thickener and the first method of thickener design was proposed by Coe & Clevenger. From 1920 to 1940, the operating variables of continuous thickening were discovered by Comings at the University of Illinois. From 1940 to 1960, the first theory of sedimentation was proposed by Kynch and several authors, Talmage and Fitch, Ysioka and Hasset used this theory to develop new thickener design methods. From 1960 to 1980 Shannon and Tory demonstrated that this theory applied exactly for the sedimentation for small rigid spheres in water and Scott showed that it is not valid for flocculated suspensions. From 1970 to 1990 the phenomenological theory of thickening was developed based on the theory of mixtures. Papers by Kos, Bascur, Thacker and Lavelle, Concha and Bascur, Concha and Barrientos, Auzeris, Buscal and White, Landman, White and Buscal show the application of this theory to thickening and Adorjan presented the first thickener design method based on this theory. In 1980s the mathematical analysis and solutions of Kynch’s model for batch and continuous thickeners was obtained by Bustos. The new Century brought solution to the phenomenological thickening model which was applied to thickener design, simulation and control. The method of thickener parameter determination was improved by designing new laboratory and on-line instruments and advanced control strategies was designed and validated in plants. Structural thickener design produced improved feedwells and feed dilution mechanism, stronger raking mechanism and different thickener shapes according to new ambient requirements, such as high rate thickener and paste thickeners that increase the water recovery. New challenges include better flocculation and advanced control strategies."

Jan 1, 2014

By Yi-jun Cao, Jin-cai Ran, Guo-sheng Li, Jiong-tian Liu, Li-jun Deng, Shu-lei Li

A fly ash sample from a power station in Guangdong province has been characterized by size separation, X-ray diffraction, contact angle measurements and X-ray Fluorescence. The ash sample had a loss-on-ignition (LOI) (%) of 15.54% and a large proportion of the unburned carbon was distributed in the +74 µm and -20 µm fractions. Contact angle measurements suggested that the removal of unburned carbon from the fly ash using flotation would present some challenges. The effects of various operating variables on the removal rate of unburned carbon (RUC) (%) and (LOI) (%) were determined using a cyclonic-static micro bubble flotation column (FCSMC). Within the range studied, the optimum diesel oil dosage was 1200 g/t, abies oil (frother) dosage was 600 g/t, pulp density was 20%, superficial gas velocity was 1.4 cm/s and circulating pressure was 0.20Mpa. Column flotation tests indicated that the FCSMC method a viable and effective separation process for removing the unburned carbon from the fly ash. Under the optimized conditions, a clean ash with 2.13% LOI and 94.21% RUC was obtained.

Jan 1, 2014

By Gus Van Weert, Samuel A. Bolorunduro, David B. Dreisinger

"INTRODUCTIONThe objective of this work was to deport silver into a residue suitable for subsequent extraction without compromising the high base metal extraction during the pressure oxidation.RESULTS AND DISCUSSIONThe complex sulphide from the tailing pond of Cannington mine, Australia, was re-grounded and a bulk concentrate was recovered by flotation. The major economic sulphides are galena and sphalerite. The chemical analyses revealed 17.22% Fe; 4.88% Zn; 8.22% Pb; 9.49% S2- and 422 g/t Ag. The baseline cyanidation yielded 36.60% of silver at high cyanide consumption (24.17 kg/t NaCN). Pressure oxidation at 150°C (in the absence of iodide), followed by cyanidation of the residue yielded 8% silver extraction. Pressure oxidation was carried out at 110-150°C in sulphate media with additions of potassium iodide and the resulting residue was subjected to cyanidation. High recovery of silver was achieved because its incorporation into lead-hydronium jarosite during the pressure oxidation was minimised, while its deportment into the cyanide-soluble silver iodide was favoured (Figure 1). Silver recovery decreased slightly at high temperatures (140° and 150°C) because of the enhanced stability and kinetics of leadhydronium jarosite, but this could be overcome by increasing acidity and iodide concentration of the slurry."

Jan 1, 2003

By James A. Finch, Linda Restrepo, Mitra Mirnezami, Amy Buchanan, Maryam Hashemi

Settling rate studies on slurries from Cu/Zn flotation plants occasionally reveals two aggregation maxima at pH 8-10 and 10-12 (Figure 1). From measurements on sphalerite and silica suspensions the double maxima could be replicated. These maxima correspond to the effects of Zn and Mg ions. The aggregation mechanism of both ions is related to the formation of the corresponding hydroxide precipitate. A combination of chemical and electrostatic bridging by the hydroxides is considered to be the aggregation mechanism.

Jan 1, 2003

By Willis Forsling, Prabhakar Swarna, Hanumantha Rao Kota

"The solubility of wollastonite and its Hallimond flotation behavior as a function of dodecylamine concentration and pH are examined. The flotation response is characterized by adsorption and surface energy in the presence of amine. The methods of UV-Visible and FT-IR spectroscopy for adsorption and sessile-drop contact angle for surface energy estimation are employed.The results of wollastonite dissolution clearly showed its non uniform dissolution. The surfaces are depleted with calcium ions and became rich in silicon within 10 min of flotation time. Maximum flotation of wollastonite corresponds to a half monolayer coverage of amine, which is substantiated by the surface energy parameters as shown in figure 1."

Jan 1, 2003

By Olli Haavisto, Heikki Häkkänen, Tommi Kauppinen, Navid Khajehzadeh

Raman analysis is a well-established method for finding the abundant minerals in an ore sample. In this study, Raman spectroscopy is tested as a method for rapid and contactless on-line mineral analysis. Rapidness might enable on-site analysis of rock drillcore, which in turn would lead to more cost-efficient solutions in mineral exploration. This paper discusses the use of Raman analysis to identify minerals and to measure their concentration. The sample set under study consists of rock drillcore collected from Agnico-Eagle Kittilä Mine, Finland. Selected parts of the sample set are measured by Raman spectroscopy and the minerals are identified using reference spectra from a public source. Moreover, the direct measurement of concentration of different minerals with the help of Non-negative least squares (NNLS) optimisation algorithm is considered. The optimisation algorithm was constructed to form a linear combination of reference spectra which best represent the measured spectrum, or an average of measured spectra, from an ore sample. The results show that NNLS can identify abundant minerals in a given sample. Also through this method of analysis the results of a traditional point-count method can be expanded: It was observed that, due to grain size, multiple minerals consistently appear in the spectra measured over an area, which means that point-count method is not a proper way to interpret the spectra. This can be seen as a new result, as formerly the discussion has attended to other methods.

Jan 1, 2014

By Haghi. Hamed, Javad Vazifeh Mehrabani, Mehdi Sedigh

In this investigation, the possibility of physical separation methods such as attrition scrubbing, hydro-cycloning and also reverse flotation were investigated for silica and calcite removal from relatively low grade kaolin. The head sample was provided by the Iran China Clay Company and the major oxides contained in the head sample were Al2O3, SiO2, CaO and Fe2O3 with grades of 15.07%, 71.05%, 4.35% and 0.52% respectively. The liberation degree of calcite and iron impurities from kaolin particles were over 80% for particles finer than 210µm and 53µm respectively. Attrition scrubbing tests were carried out with scrubber cell of the conventional Denver flotation cell model D-12. Laboratory scale hydro cyclone was applied for the beneficiation of kaolin. Attrition scrubbing tests with control screen of 106µm did not achieve the desirable yield for purification of this kaolin sample, but hydro cyclone experiments resulted in better results. Hydro cyclone with 2.54 cm diameter used and the only variable was the cyclone inlet pressure ranging from 68.65kPa to 98.07kPa. The best inlet pressure was found to be 68.65kPa. Based on the optimized condition, Al2O3 and CaO amount in the hydro-cyclone overflow was 23% and 1.47% respectively. However weight recovery of the overflow in each cyclone experiment was less than 30% and multi stages of hydro-cyclones would have to be applied for higher weight recovery and better yield. All of the flotation tests were carried out in the conventional Denver flotation cell model D-12. Reverse floatation tests for calcite removal were carried out under alkali pH based on full factorial design of variables in 2 levels including one center point. The three parameters tested were collector dosage (gr/ton), pH and depressant dosage (gr/ton). The collected data from flotation tests were analyzed and optimized collector and depressant dosage were 1000 gr/ton and optimized pH was 8.5. Under the above mentioned conditions, calcite removal was about 75% and CaO content in the final product was reduced from 4.35% to 1.33%. However calcite removal will increase to more than 83% if the feed particle size in flotation tests is reduced from 210µm to finer than 53µm. Finally after optimization, the best working condition and possible flow sheet were developed.

Jan 1, 2014

By Yimin Zhu, Dezhou Wei, Haijun Liang, Zhifu Zhou

Pyrite is one of sulfide minerals most widely distributed in the earth. During the flotating separation of metal sulfide and the floating desulfation of coal, it is often requaired to restrain pyrite. However, the result is not very satisfactory because of the little difference of floatability of minerals to be separated. The problem is extremely outstanding for the floating desulfation of coal. Researchers carried out a number of experiments with T. ferrooxidans (Yang et al, 2001; Zhou et al, 2000; Zhou et al, 2001; Wei et al, 2001) for an enhanced restraint to pyrite. The results showed that the T. ferrooxidans after being cultured works the best in restraining pyrite. After 10 min pretreatment, the removal rate of pyrite from coal is up to 80%~90%. The research results by Yuan Xin et al (Yuan et al, 2000) show that T. ferrooxidans can restrain effectively the floatability of pyrite and can reduce the recovery of pyrite from 95% to 8%. Though the restraining properties of T. ferrooxidans to pyrite have been proved by many tests and experiments, there are very limited reports on its restraining mechanism. Thus, a systematic experimental research is carried out in this paper.

Jan 1, 2003

By Jorge Menacho

"A typical Chilean producer in the Large Copper Mining Industry today is characterized by high production level with economical results decreasing but still attractive. Operational activities are developed within a low-productivity environment, with high cost and complex relationship between the company and communities, government authorities, providers, clients and their own workers. Decreasing copper grades and limited availability of energy, water and workforce are structural problems which require the State intervention in collaboration with the relevant actors and benefits would be evident in the middle or long term. Main opportunities in the short term are found in the sub optimal conditions we have at many plants today. Robust solutions to control existing operational management system as well as to supply systematic optimization options are needed. These should be oriented toward effective fulfillment of specific operational set points and also to reduce variability in crosscutting tasks. Solutions should include easy connectivity to existing information systems as well as to a suite of simulation and optimization tools settled in a highly interactive communication platform. Relevant issues include minimization of specific energy and fresh water consumption, maximization of the use and performance of critical equipments, minimization of damage to environment and control of effective application of good operational practices. Several specific examples are given."

Jan 1, 2014

By Isaak I. Maksimov, Tatyana E. Koltunova, Mikhail F. Yemelyanov, Liudmila A. Otrozhdyonnova

"INTRODUCTIONMetals losses amount up to 50% in coarse fractions in (>100 µm) and composite particles, and to 20- 25% in fine fractions (<10 µm) at non-ferrous floatation concentrating plants of the CIS. Therefore, reduction of metals losses in difficult fractions is of high significance.IMPROVEMENT OF FLOATABILITY OF COARSE AND COMPOSITE PARTICLESReagent regimes with application of strong collectors – xanthates ?5-?8, combination of butyl xanthates and aerofloats ?10-?12, butyl xanthates with hydrocarbons are proposed for this purpose. Application of such reagent regimes for copper and copper-molybdenum ores permitted to increase copper and molybdenum recovery by 0.5-3.9%.Studies, performed by means of specially designed non-frothing flotation machine with independently controlled agitation intensity and narrow size-ranges of air bubbles, established that the best results are achieved with employment of bubbles of 0.5-0.8 mm size regarding particles of any size, with small amounts of up to 2 mm size “transport” bubbles to be expediently used for floatation of coarse particles.Energy dissipation in the main volume of floatation cells must be lower than 0.2-0.25 m2/s3.Performed experiments permitted to formulate requirements to development of machine for floatation of coarse and composite particles. Such floatation machine with volume of 8.5 m3 provided for weak agitation in the main volume of floatation cell and uniform distribution of coarse particles throughout the depth owing to establishing of pulp circulation with upward flows. In addition, in the upper part of floatation cell where agitation is considerably weaker, favorable conditions are created for attachment of particles to bubbles. Testing of this floatation machine demonstrated a 7.5% increase in recovery of +0.2 mm particles in pyrite floatation and a 12-14% increase in recovery of +0.2 mm particles in apatite floatation as compared with a reference floatation machine."

Jan 1, 2003

By Ming’an Wei, Chuanyao Sun, Yangge Zhu, Fayu He, Yanbo Shang, Xingrong Zhang

In order to discuss the separation mechanism of copper-molybdenum ore, surface electronic structures of chalcopyrite and molybdenite were studied in the paper, by using First Principles method of quantum chemistry. So, the separation mechanism of thioglycolic acid (TGA) with chalcopyrite and molybdenite was revealed better. The results showed that differences of the electronic structure of chalcopyrite and molybdenite could directly affect their interactions with TGA, such as band structure, density of states, Mulliken populations, and so on. And the frontier orbitals of chalcopyrite and molybdenite were also calculated by Dmol3 after the optimization by CASTEP, from which the interaction energies between minerals and TGA were obtained and compared. So, the essence of flotation separation of copper and molybdenum were well revealed.

Jan 1, 2014

By Joseph Kelly, Christopher Kelsey

This revolutionary super-fine crusher has the unique capacity to generate fine and ultra-fine products from single stage reductions of coarse or fine mineral feeds. The crusher consists of a rotating compression chamber and an internal gyrating mandrel. The axis of rotation of the shell is displaced relative to the axis of the vertically mounted mandrel. The inner surface of the compression chamber is machined as double cone frustums at an angle equal to the displacement angle. Crusher feed is accelerated into a compacted particle bed, which lines the inside of the compression chamber. The depth of the compacted bed progressively increases until the mandrel is engaged. The mandrel is then free to rotate with the compression chamber. Continued feeding increases power draw and triggers the counter rotating mandrel gyration drive. The gyrating mandrel delivers multiple compressions at high pressure to the rotating particle bed. High concentrations of energy are harnessed within a small active volume over short retention times. The combination of extraordinarily high power intensity and extreme compressive force results in primary compressive fracture and induced secondary tensile failure. The axially displaced rotation of the compression chamber effectively distributes the breakage forces throughout the particle bed. This paper covers open circuit, pilot trials on magnetite, perlite, garnet, marble and a copper/pyrite concentrate. Particular emphasis is placed on the extraordinary results achieved with trials on zircon and highly refractory fly ash. The extreme duties were deliberately chosen to demonstrate the crusher’s application scope and potential to impact capital operating and maintenance costs as the technology matures. Super-fine crushing, once considered impracticable has the potential to offer compelling options for the generation of ultra-fine products.

Jan 1, 2014

By A. J. Lynch, L. Ergun, M. Oner

"A research program on modelling cement grinding circuits has been in operation at Hacettepe University, Ankara, for four years. It has concentrated so far on tube mill and air separator grinding circuits for cement clinker, with emphasis on plant sampling surveys, including axial sampling inside the tube mills. The methodology is to use plant data to build the models and to supplement this by laboratory data where necessary, for example the determination of breakage functions. The plant data come from comprehensive sampling surveys and so far 33 surveys of clinker grinding circuits have been carried out in 9 plants. The operating conditions have been• mill sizes – 3.2 to 4.8 metres diameter and 8.5 to 15 metres long,• mill feed rates – 46 to 158 tonnes per hour,• air flow through mills – 25000 to 125000 cubic metres per hour,• cement clinker work indexes – 10.3 to 18,• separator sizes – 2. to 3.1 metres diameter,• separator feed rates – 132 to 689 tonnes per hour,• separator speeds – 12.3 to 21 metres per second.The ball mill model is Whiten’s perfect mixing model and the separator model is the Tromp curve with a fish-hook. This paper emphasises on the importance of calculating the breakage rates and the discharge functions with three case studies at five different circuits which were selected for discussion because they show how particular features of circuit operation can be included in the general models. Size distributiongraphs are used to illustrate every aspect of the discussion.In case I the special emphasis on calculating the breakage rates and discharge rates separately is given in a high pressure grinding roll-ball mill-separator circuit. The tonnes of each size fraction in the mill and the calculated values of R/D, D and R are determined. The values of R per mw are also given to allow comparison with mills of other sizes. The circuit allows the comparison of the static type (V Sep) and dynamic type separators (SKS). Comparing the reduced efficiencies shows that the dynamic separator is slightly more efficient than the static one.In case 2 data are given from two compartment tube mills having the same diameter and the motor power but different ball size gradation. The breakage rate particle size variation of the second chamber of two mills indicate that having finer ball size distribution causes higher breakage rate values."

Jan 1, 2003

By Aziza A. Yousef, Suzan S. Ibrahim, Mahmoud A. Arafa, Mohamed A. Abdel Khalek

Due to the shortage of fresh water in the Middle East, seawater has been used as an alternative in flotation beneficiation. The flotation process requires about 7 m3 of water/mt ore. This article aims to study the effect of seawater cations and anions on the flotation. Natural pure francolite, calcite, dolomite and quartz were characterized by chemical, thermal and x-ray diffraction analyses, surface area, solubility and zeta potential. Synthetic seawater was prepared with the major chemical composition similar to natural seawater as follow; 2.45% NaCl, 0.52% MgCl2, 0.41% Na2SO4, 0.116% CaCl2 and 0.07% KCl. Also, natural seawater was used in application. The point zero of charge was estimated at pH 6.5, 7.8, 9.2 and 2.2 for francolite, calcite, dolomite and quartz, respectively. Calcium ions were released from the three minerals with Mg2+ and P2O5 3– released from dolomite and phosphate, respectively. The adsorption of collector, zeta-potential and floatability of pure minerals were studied. The effect of individual cations and anions predominant in seawater are studied on individual mineral or group. The troublesome Ca2+ and Mg2+ ions should be controlled by soda ash addition. Sodium silicate improved the selectivity of mineral mixtures and natural ore. At optimum conditions the calcareous phosphate ore yielded a concentrate of 34% P2O5, at 83% recovery with 0.61% MgO, from an ore assaying 25.3% P2O5 and 9.4% MgO. To minimize the Clcontent, fresh water of about 0.5 m3 /t was used and the Cl- decreased to about 0.09 %

Jan 1, 2003