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By J. W. Town

This report summarizes the results of laboratory investigations conducted by the Federal Bureau of Mines to obtain hydrometallurgical information on the dissolution of mercury sulfides from ores, flotation concentrates, and pure mercuric sulfides. Statistical methods were used to design the experiments and evaluate the resulting data. Studies demonstrated that cinnabar is readily soluble in sodium sulfide, partly soluble in potassium sulfide, and essentially insoluble in ammonium sulfide. Additions of sodium hydroxide or potassium hydroxide to sodium sulfide solutions increased mercury extraction slightly; when either was added to potassium sulfide or ammonium sulfide solutions, mercury extraction was equal to that of sodium sulfide. Tests at the Albany Metallurgy Research Center showed that sodium sulfide would completely dissolve chemically pure mercuric sulfide, more than 95 percent of the cinnabar in 5-percent mercury flotation concentrates, and 60 to 90 percent of the cinnabar in low-grade ores. The double-leach tests showed that potassium sulfide would dissolve over 90 percent of the arsenic in mercury-arsenic products and 1 to 10 percent of the mercury; then sodium sulfide-hydroxide solutions would dissolve 80 to 90 percent of the remaining mercury and 5 to 10 percent of the arsenic.

Jan 1, 1961

By J. E. Shelton

Flotation tests are described on samples of two lowgrade nickeliferous ores of Oregon and Washington. The sample from the Congress mine, Ferry County, Wash., contained 1.2 percent Ni, occurring chiefly as millerite. The sample from the Shamrock mine, Jackson County, Oreg., contained 2.20 percent Ni and 0.78 percent Cu occurring chiefly as pentlandite, nickeliferous pyrrhotite, and chalcopyrite. The millerite in the Congress ore was concentrated by flotatioin with aulfydric collectors in a series of locked tests to recover 73 percent of the nickel as a 7 percent bulk concentrate. By successively regrinding and floating the bulk concentrate, it was further concentrated to 12.4 percent Ni at a recovery of 59 percent and 21.8 percent Ni at a recovery of 50 percent. Attempts at selective concentration of the copper-nickel Shamrock ore were only partly successful because of the intimate association of pentlandite and chalcopyrite. The nickel concentrate, which contained 86 percent of the nickel, had an analysis of 4.42 percent Ni and 1.03 percent Cu. The copper concentrate had an analysis of 18.8 percent Cu and 1.96 percent Ni and contained 48.5 percent of the copper. A bulk sulfide concentrate contained 92 percent of the copper and 01 per¬cent of the nickel and had an analysis of 4.17 percent Ni and 1.63 percent Cu.

Jan 1, 1956

By J. L. Holman

The Bureau of Mines is conducting research to recover strategic and critical metals such as Ni, Co, and Cr from mixed contaminated super-alloy scrap. One approach being studied involves melt refining of superalloy scrap to produce anodes for electrolytic deposition of Ni-Co alloy. This melt refining of superalloy turnings is described based on melt-oxidation and oxidation-carburization experiments, using roasted superalloy grinding sludge to supply the 0 needed to oxidize Cr and other readily oxidized elements to the slag. Controlled melt-carburization subsequent to oxidation improved the metal phase recovery of Ni and Co to well over 90 pct and decreased electrolytic solubility of Cr, Mo, and W by carbide formation. Electrolytic refining experiments were conducted using a controlled-potential mode (preset cathode potential). Data show effects of Fe and Cr impurities, cation concentration, electrolyte pH, S04-Cl electrolyte ratio, temperature, cathode potential, and cation-selective membrane use on current efficiency, current density, and deposit composition. Disposition of Ni, Co, Cr, MO, W, and Fe is compared for melt-oxidized versus oxidized-plus-carburized anodes. Deposits containing >97 pct Ni + Co (major impurity Fe) have been routinely obtained from scrap anodes. Research is continuing to improve deposit quality in sustained deposition and to recover Cr and other metals from refining slags and anode sludges.

Jan 1, 1986

By Sidney Katell

This report is an economic evaluation of the production of hydrogen in a continuous system by the steam oxidation of partially reduced iron oxide in a fluidized bed at 7 atmospheres using producer gas to reduce the iron oxide. The oxidation-reduction step is based on experimental data obtained by the Bureau of Mines at the Pittsburgh Coal Research Center. The estimated capital requirement for a plant producing 30 million std. c.f.d.3 of 99.8 percent purity hydrogen at a discharge pressure of 450 p.s.i.g. is $13,100,000, using January 1961 equipment cost data. Based on a 330-day operating year, the operating cost before profit and taxes with coal price as a variable is estimated to be:

Jan 1, 1962

By Dean H. Ambrose

Using three-dimensional (3-0) graphics computing to evaluate new technologies for computer-assisted mining systems illustrates how these visual techniques can redefine the way researchers look at raw scientific data. The U.S. Bureau of Mines is using 3-D graphics computing to obtain cheaply, easily, and quickly information about the operation and design of current and proposed mechanical coal and metal-nonmetal mining systems. Bureau engineers developed a graphics simulator for a continuous miner that enables a realistic test for experimental software that controls the functions of a machine. Some of the specific simulated functions of the continuous miner are machine motion, appendage motion, machine position, and machine sensors. The simulator uses data files generated in the laboratory or mine using a computer-assisted mining machine. The data file contains information from a laser-based guidance system and a data acquisition system that records all control commands given to a computer-assisted mining machine. This report documents the first phase in developing the simulator and discusses simulator requirements, features of the initial simulator, and several examples of its application. During this endeavor, Bureau engineers discovered and appreciated the simulator's potential to assist their investigations of machine controls and navigation systems.

Jan 1, 1992

By Martin H. Stanczyk

The Bureau of Mines studied continuous closed-circuit attrition grinding of a coarse commercial filler-grade kaolin to produce paper-coating-grade clay having a particle size analysis of at least 70 percent minus 2-micron equivalent spherical diameter (esd). The coarse clay, containing about 12 percent minus 2-micron-esd material, was ground in a Bureau-developed 10-inch-diameter attrition grinder in closed circuit with a 5-foot-diameter bowl classifier. In the best test, a finished product containing 82.7 percent minus 2-micron-esd material was obtained when grinding 20 pounds of raw clay per hour at percent solids with a 100-percent circulating load. Energy consumption was about 341 kilowatt-hours per ton of clay feed, or 487 kilowatt-hours per ton of minus 2-micron-esd material produced. Closed-circuit grinding gave some-what greater particle size reduction and lower energy consumption than either batch or continuous open-circuit grinding.

Jan 1, 1965

By M. J. Ferrante

A process was investigated for preparing Specification-grade nickel (containing less than 1 percent cobalt) by stripping it electrolytically from a nickel sulfate-boric acid solution and using the stripped electrolyte for the preferential dissolution of nickel from basic carbonates of nickel and cobalt. The basic carbonates were produced at the plant at Nicaro, Cuba, owned by the U.S. Government. Determination of the optimum conditions for deposition of Specification-grade nickel indicated that the upper limit of cobalt concentration was 0.1 gram per liter. The pH, temperature, and concentrations of nickel and boric acid in the electrolyte were not critical. An aluminum cathode and two lead anodes were used at a cathode current density of 1.2 amperes per square decimeter.

Jan 1, 1959

By James F. Neill, O&apos

Investigation of the Gilley fluorite deposit was based upon examinations made by several of the Bureau's mining engineers. Fluorspar was found in the dump talus of sloughed and water-filled trenches and shafts, and there were indications that faulting or other dynamic distortions favorable to deposition of this mineral in minable quality and quantity might exist. The inference was based upon a field study of the area and its comparison with fluorspar deposits in Kentucky. The proximity of this deposit to the iron furnaces at Gadsden and Birmingham was a factor that influenced its investigation, as the demand for metallurgical grades of this critical mineral is acute. The present supply for the district is obtained from out-of-State sources, and the value of any local deposit would be enhanced by the saving in freight charges. The Gilley fluorspar deposit is 17 miles east of Gadsden and 50 miles northeast of Birmingham, Ala. Mineral deposits occur as thin veinlets and small bunches of fluorite in upturned bode of siliceous limestone. The ore-bearing structure is a reverse fold, and the mineral deposit appears as a replacement along crumbled zone fractures of the contorted limestone.

Jan 1, 1950

By T. A. Henrie

One objective of Project Gnome is to study the feasibility of a phase of the Plowshare program recovering thermal energy from an underground nuclear explosion. The test will be conducted in an underground salt deposit. It is anticipated that some of the energy thus released will be stored as thermal energy in molten salt. This report describes the pre-Gnome experiments conducted at the Federal Bureau of Mines Metallurgy Research Laboratory, Boulder City, Nev. The objectives of this study were to determine the problems involved in the recovery of thermal energy from molten salts to assist in planning the experimental program for the Gnome project.

Jan 1, 1961

By W. W. Culter

"This paper is the outcome of thorough investigation into the value of the previous methods used for deriving production decline curves. It is highly important that methods be employed that are fundamentally sound and also practicably applicable. Six methods commonly used were studied. Some of these were found to be fundamentally in error; some save reliable curves but involved much work and time in the preparation; others gave reliable curves with less time and effort.It was found that of the methods previously employed the ""family curve"" method described in Bull. 134 Amer. Inst. Feb. 1918, pp. 499-500 by Lewis and Beal, was probably the most satisfactory. The now method given in this paper ploys the same principles as the ""family curve"" method, but is mathematical instead of graphical,The engineer and the oil man should carefully boar in mind both the use and the limitations of the average production curve such as is derived by the ""family curve"" method or other methods mentioned. Estimations of future productions or of underground oil reserves of a particular tract or well should be made from the production records of the tract or the well itself wherever such records are satisfactory. The use of the average curve of a district or field should be applied only to those properties or wells where there are not sufficient data to construct individual or tract production records, or where the productive life so short that a satisfactory individual record can not be obtained."

Jul 1, 1920

By Wilbert J. Huff, Raymond H. Moore

"Black powder is employed widely in peace and war. Its properties are therefore of considerable interest to many. The Bureau of Mines frequently is asked to furnish information on its use and safe handling in the mining and mineral industries in times of peace and is now engaged in studies of its application to the arts of war.Black powder has been the agent in many accidents - some very disastrous - and its handling and use are deemed very hazardous. The belief is widespread that the hazards are due principally to the ease with which the powder is ignited by a hot spark or flame in contradistinction to high explosives; these usually are ignited only with difficulty, and some burn incompl0tely and to a certain extent are self-extinguishing. Primary precautions, .therefore, should be taken to prevent the access of heat, spark, and flame.In black powder manufacturing operations a frequent source of disaster is the initiation of fires and explosions in the wheel mills in which the sulfur, charcoal, and nitrate are incorporated. Long experience has indicated that the wheel mill probably will fire if the powder is not kept moist enough; manufacturing supervision calls for the maintenance of a minimum moisture content, at least during the milling. Accidents occur elsewhere in the manufacturing line, and in an endeavor to minimize these, particularly those happening in corning mills, one of the writers suggested many years ago that a suitable humidity be maintained in other operations in the hope that it would serve protectively as in the wheel mill. The experience of one company for many years with this practice was favorable. It seemed desirable therefore, to explore the question experimentally."

Nov 1, 1944

By G. L. Hundley

The Bureau of Mines has devised a procedure to recover chromium chemicals from concentrates derived from low-grade domestic chromites. These domestic chromites contain silicon and aluminum impurities at levels that are too high to permit processing by present industrial processes. The Bureau procedure consists of reacting chromite with molten NaOH under oxidizing conditions to form sodium chromate (Na2Cr04)' The reaction product is leached with methanol to recover the majority of the unreacted NaOH, then with water to extract the Na2Cr04 and the remainder of the NaOH. The Na2Cr04 product is recovered by evaporative crystallization from the aqueous solution. This report presents laboratory results of studies to determine the optimum leaching conditions for the reaction products of several domestic chromite concentrates. Results of solution purification and crystallization studies are also presented. The concentrates are from a variety of sources including the Stillwater Complex in Montana, Red Bluff Bay and the Kenai Peninsula in Alaska, and a Ni-Co laterite from southern Oregon. Sodium chromate crystals were produced that contained less than 0.01 pct NaOH.

Jan 1, 1988

By R. W. Huber, R. C. Wiley, V. C. Petersen

"Three arc- melted ingots, two of a t itanium-7 percent manganese all oy and the third of unalloyed titanium, were forged and rolled into 3/ 4-inch plate; comparative data were obtained on these processes. The finished plate, part of which was used by the Naval Bureau of Ordnance, was tested for mechanical and other properties.These properties were correlated with sponge purity, forging technique, rolling temperature, and cooling rate from the rolling temperature. For the alloy material, transformation data were obtained, and their age-hardening characteristics were studied. The temperature-impact relationship was established for rolled sections from all three ingots.INTRODUCTIONArc -melted ingots of unalloyed titanium and a titanium-manganese alloy were fabricated into plate under closely controlled conditions by personnel of the Metals and Alloys Section, Physical Metallurgy Branch, Bureau of Mines, College Perk, Md. This program was cosponsored by the Naval Bureau of Ordnance. Bureau of Mines interest lay in correlating the processing procedures with the mechanical properties of the finished plate.Considerable data have been published recently on constitution diagrams and properties of titanium-manganese alloys in genera1. 3/ 4/5/6/ However, little if any correlation between processing schedules and end results has been published, particularly with respect to the present commercial production of the proprietary titanium manganese alloys . Several factors in the production of titanium and titanium alloys have a pronounced influence on the physical and mechanical properties of the finished product: (1) The degree and nature of impurities in the base materials, ( 2) the amount of impurities introduced during the melting cycle and their distribution, (3) the homogeneity of the alloy, (4) forging, (5) rolling, and ( 6) final heat-treating cycles. All of these item£ are important from a metallurgical standpoint in producing the desired end properties in the metal."

Mar 1, 1955

This report describes the new Bureau of Mines Core Repository System (CORES) and presents the methods for selecting, processing, and storing physical samples and descriptive data for future reference by earth scientists. The system preserves splits of chip samples and longitudinally sliced segments of core. A records retrieval system provides for storage of data on microfilm and magnetic tapes and uses the keysort parameters of location and commodity for the identification of data.

Jan 1, 1978

By J. W. Miller

Wyoming County had for many years supplied large quantities of coking coals to coke plants throughout the eastern United States and Canada. Up to the present most of the coal has been produced from relatively few beds, but in the future the coal will be produced from beds not previously mined in quantity. This trend is shown in the entire Winding Gulf field, of which Wyoming County is a part. This publication is one of a series of Bureau of mines reports appraising the Nation's coking coal, which y be used to determine the practicability of upgrading marginal deposits to metallurgical standards. This investigation of the preparation characteristics of Wyoming County coals is the third of the series undertaken in West Virginia.

Jan 1, 1955

By W. F. Watts

In 1980 the Bureau of Mines developed the Mine Inspection Data Analysis System (MIDAS). MIDAS is a computerized, industrial hygiene data base capable of statistically analyzing environmental data collected in coal and noncoal mines and mills by Mine Safety and Health Administration (MSHA) inspectors or mine operators. The objectives of this report are to describe the current contents of MIDAS, to report analyses of coal and noncoal mine respirable dust samples collected by MSHA inspectors and to evaluate the proposed change in the metal and nonmetal respirable dust standard from a formula based upon the percentage of quartz identified in the sample to 100 µg/m3 of respirable quartz. Based on samples collected by MSHA inspectors, changing the noncoal respirable dust standard would result in 4 pct fewer samples with dust concentrations exceeding the standard. Analysis of respirable coal dust data collected by MSHA inspectors showed that mines with longwall plows or shears had the highest geometric mean concentrations (1.64 and 1.29 mg/m3, respectively). Mine operations using continuous rippers out-numbered longwall mine operations about 10 to 1 and had a geometric mean concentration of 0.66 mg/m3.

Jan 1, 1987

By Robert B. Hoekzema

The Bureau of Mines and U.S. Geological Survey completed a 4-yr (1979-82) mineral appraisal of the Chugach National Forest (CNF), AK. This report summarizes the Bureau's placer gold studies in the CNF. Placer mining from the mid-1890's through 1982 produced an estimated 133,800 oz of gold, of which two-thirds was produced prior to 1920. As much as 6,800 oz of placer gold was produced from 1979 to 1982. Most production came from Crow, Canyon, and Resurrection Creeks. Five types of placer gold deposits were identified in the CNF: (1) alluvial placers, (2) bench placers, (3) eluvial placers, (4) glacial placers, and (5) marine placers. Placer sampling indicated a potential for gold production from alluvial and bench placers associated with historically mined drainages such as Crow, Canyon, Resurrection, Sixmile, and Mills Creeks and from unmined drainages including the Avery, Kings, Snow, Copper, and Tasnuna Rivers and several smaller streams throughout the CNF. Results of fineness tests indicated that gold from the CNF ranges from 455 to over 950 fine. Subsequent investigations in drainages with anomalous placer sample values also identified previously unknown lode mineralization.

Jan 1, 1986

By Lewis V. Wade

This report provides background information concerning a mine roof simulator currently being considered by the Bureau of Mines. The simulator is a mechanical device with the ability to simulate the forces and displacements associated with mine roof over an area 20 by 20 feet. The topics covered in the report include a conceptual description of the system, definition of system capabilities, discussion of how such capabilities were decided upon, description of available control modes, and a comparison between the mine roof simulator facility and similar facilities existing elsewhere.

Jan 1, 1974

By John Nagy

Dust explosion data obtained in laboratory tests by the Bureau of Mines are presented for 181 miscellaneous materials that present an explosion hazard. Data are given also for 50 dusts that present primarily a fire hazard and for 88 dusts that did not present an explosion hazard.

Jan 1, 1968

By E. Morrice

The metallurgical laboratory data developed in this study indicate an improved electrowinning process for producing higher purity cerium ingot. A typical sample of the Reno electrocerium contains 99.9 weight-percent cerium and the following impurities: Total other rare-earth elements, less than 0.04 percent; iron not detected; silicon and aluminum, less than 0.02 percent each; calcium plus magnesium, less than 0.01 percent; carbon, 0.01 percent; oxygen, 0.002 percent; hydrogen, 0.0003 percent; and nitrogen, 0.0015 percent.

Jan 1, 1960