Search Documents

By O. C. Baptist

This report presents results of an investigation undertaken by the Bureau of Mines to determine the clay content of typical petroleum reservoir sands in Wyoming and the effect of clay content on the permeability behavior of the sands. These results should have significance in determining the feasibility of injecting water into the sands for secondary recovery and in estimating the probable damage incurred by these sands if invaded with filtrates from water-base drilling muds. The results of air-, brine-, and water-permeability determinations are given for reservoir sands in three Wyoming fields. The amounts of materials of "fine silt and clay size" (Wentworth scale) in the sands and the types of clay minerals present, as identified by X-ray diffraction methods, are also presented and discussed.

Jan 1, 1955

By Charles Sabine

In 1984 and 1985 at the request of the U.S. Bureau of Land Management, the U.S. Bureau of Mines studied a 27,420-acre part of the 36,600-acre Southern Inyo Wilderness Study Area, CA-010-056, in order to evaluate the mineral resources. The study area is located in Inyo County, CA, near the town of Lone Pine, about 180 miles north of Los Angeles. The study area takes in most of the western slope of the southern Inyo Mountains. Terrain is steep and rugged; the climate is arid. The study area is underlain by folded and faulted marine sedimentary rocks dating from Ordovician to Triassic, Triassic volcanic rocks, and Jurassic to Cretaceous plutonic rocks. Most mineralization was along faults and shear zones in sedimentary rocks. The study area includes most of the Russ and Lone Pine mining districts which produced over one million dollars in gold, silver, lead, and zinc, mostly between 1860 and 1890. A few mines produced ore as late as 1951. Most production was from the Reward, Silver Spur, Long John, and Pennsylvania mines which are outside the study area. Presently, there is no mining activity in the study area; some development work was done at the Reward mine between 1981 and 1984. Dolomite marble is quarried from the base of the range outside the study area. There are currently about 70 mining claims in the study area.

Jan 1, 1986

By C. J. Chindgren

Two air classification systems were built and tested as separatory devices for recovering the nonferrous metal values from shredded automotive nonmagnetic reject scrap. A horizontal air system with a capacity up to 16 tons per hour was used to obtain preliminary separations, and a smaller capacity vertical system was used as a cleaning device. Shredded automobile reject material containing aluminum, copper, and zinc values of about $55 per ton were air-classified in the horizontal elutriator. Ninety-six percent of the metal was recovered in a 74-percent metal concentrate. Tandem operation of both classifiers recovered 92 percent of the metal in an 80-percent concentrate while rejecting 87 percent of the nonmetallics. Heavy media separation of the air-classified concentrate produced an overall recovery of 91 percent of the metal in the form of a 99-percent metal concentrate.

Jan 1, 1971

By J. G. Kirby

According to the Bureau of Mines annual survey, as of January 1, 1954 there were 337 refineries with a total daily crude-oil throughput capacity of 8,006,897 barrels. The total daily capacity increased 368,236 barrels during the year while the total number of refineries declined 6. The capacity of the average refinery to process crude oil therefore increased during 1953 from 22,270 barrels to 23,759. With the exception of the Texas Inland, all refining districts reported gains in the installed capacity for the year, the largest being the Louisiana Gulf Coast with an increase of 20 percent. A total of 397,500 barrels of additional crude oil capacity was reported as under construction January 1, 1954. Accounting for 129,500 barrels of this total are facilities for 3 new refineries in North Dakota, 2 in Washington and I each in Ohio and Utah. Equipment being installed to replace existing units, totaled 180,750 barrels daily.

Jan 1, 1954

By D. Harrington

For several years, or from about 1932 to 1935, inclusive, the coal industry of the United States had an excellent record as to coal-mine explosions. In 1937 and in 1938 to date there has been a definite increase in the number of explosions attended by considerable loss of life and property damage. In most of these explosions one important underlying and contributing cause has been lack of sufficient (or at least efficient) ventilation to properly dilute and remove explosive gas from the mine. This increase in explosions indicates that. the lesson taught through bitter experience, many times in the not far-distant past, of the need for good ventilation is frequently being overlooked, partly because the relatively good experience of the industry in the past several years has made many mining people forgetful. Moreover mining practices are rapidly changing, and in some instances the changes are being made with little if any regard for safety. It appears, therefore, that a review of some ventilation principles and practices should be of value in preventing further disasters; this paper has been prepared with that object in mind. In coal mining the need for thorough ventilation of all underground working places is recognized by both mining practice and law; such ventilation is generally obtained by the use of fans that circulate a quantity of air much in excess of the quantity of coal produced, by weight as well as by volume. For example, in a relatively small mine producing 1,000 tons of coal per day and circulating 100,000 cubic feet of air, which is by no means abnormal, 2,000,000 pounds of coal and approximately 10,900,000 pounds of air would be moved out of the mine every 24 hours. Because of the need for adequate dilution and removal of methane issuing or likely to issue from mine strata and for removal of the carbon dioxide formed by coal and timber oxidation up-to-date coal mines usually provide an air volume which if adequately coursed not only removes these gases but also the gaseous products of the detonation of explosives (which may include carbon monoxide, hydrogen sulphide, nitrogen oxides, carbon dioxide, and nitrogen) and the carbon

Jan 1, 1938

By J. C. Franklin

The Bureau of Mines substantially reduced shale degradation in a coal mine by two spray coat applications of a water-base epoxy sealant. More than 12,700 square feet of passageways were treated, and in 18 months only one failure occurred. This failure was due to improper spray application, Material costs averaged 13 cents per square foot, and labor costs were 7 cents per square foot. Labor included moving all materials into the mine, the setup time for each of the areas coated, and application of coatings.

Jan 1, 1977

The first phase of our work for PMSRC on this contract was devoted to a comprehensive and in-depth assessment of electromagnetic (EM) noise measurements and data taken by several contractors for use in the design of operational and emergency mine communications. Pertinent measurements and data of other selected investigators were also included in the evaluation. This assessment treated the measurements and instrumentation used, the data analysis and presentation methods, and the utility of the final results. This phase concluded with the identification of the most useful results and methods, the remaining data gaps, the contractor most qualified to fill these data gaps, and the definition (with PMSRC and this contractor - NBS, National Bureau of Standards) of a follow-on noise measurement program, instrumentation system, and data processing methods tailored to obtain the necessary but missing noise data. A partial bibliography of references related to electromagnetic and seismic noise and propagation in the frequency bands of interest was also compiled during this first phase. The body of this Part of the final report presents a summary of the findings of our EM noise assessment, together with detailed recommendations regarding the new noise measurements to be taken and the instrumentation and data processing methods to be used. This work was done during the latter part of 1971 and the early part of 1972. During subsequent phases of the contract ADL was asked to perform on-going evaluations of the continuing program of electromagnetic (EM) noise and propagation measurements made by Bureau contractors, and to utilize pertinent data from these measurements to make performance estimates for

Jan 1, 1974

By A. Gene Collins

Some of the geochemical relationships that exist between subsurface fluids and the associated geologic strata in petroleum producing areas of Louisiana have been determined. Samples of petroleum-associated water were obtained from 126 wells in Louisiana that produced from sediments of three geologic ages: Tertiary, Cretaceous, and Jurassic. The samples were trans-ported to a central laboratory for analysis of chemical composition, using standard methods, to determine if the compositions varied with the geologic strata of their source and, if so, why. The dissolved constituents were com-pared with those of a brine that was concentrated by evaporation. The concentrations of bromide, calcium, and strontium were useful in distinguishing the brines produced from sediments of a late age from those of an earlier age. The concentration ratios of Mg' (total equivalent magnesium) and bromide indicated that dolomitization probably had occurred and altered the composition of the brines. A principal-components analysis of the data indicated an inverse relationship between depth and concentrations of bromide, strontium, calcium, and lithium.

Jan 1, 1970

By D. P. Desmond

The U.S. Bureau of Mines investigated leaching automobile catalysts with sodium cyanide (NaCN) solutions at high temperatures to recover platinum-group metals (PGM). The feed was virgin monolith rejects, used monolith, and used pellet catalysts. Leaching with a 5-pct NaCN solution for 1 h at 160° C dissolved over 97 pct of the PGM in the virgin monolith, over 85 pct of the PGM in the used monolith, and over 90 pct of the PGM in the used pellet catalyst. Over 99.8 pct of the dissolved PGM was recovered as a precipitate by heating the solution to 250° C for 1 h in an autoclave. The cyanide complexes were decomposed, and free cyanide was destroyed.

Jan 1, 2010

By G. E. McElroy

"The development of certain mines in the East Tintic mining district, Utah, has been hindered considerably by the presence in the rock strata of heavy irrespirable gases which at times flood the lowest working places, as well as by abnormally high rock temperatures in the lower horizons. A study of these features was completed in the spring of this year, and the information obtained is summarized here.Heavy gases.Only four mines have been affected to date by the presence of heavy gas, and only one of these is producing lead-silver ores in quantity. These four embrace a territory extending about three miles north and south and about two miles east and west, while both within and fringing on this territory are a number of prospects which have not been affected.Thus far no fatalities have resulted from gas inflows, but a number of men have been temporarily overcome, and a few have had narrow escapes from death by suffocation. That the record is not more serious is mainly due to the fact that the gas inflow, as a rule, is relatively slow, mining operations have been quite carefully conducted, and the presence and extent of a gas inflow can be easily determined by its extinguishing action on the flame of miners' lights.When first encountered, about 1910, gas inflows occasioned much lost time. In some months the lost time averaged as much as ten days, while one mine cites for a certain month a maximum of 26 days lost out of a possible 28 working days. With improvements in mechanical ventilation and the passing of time, interference with work from the presence of gas has gradually lessened. During the last few winters, the main trouble has been with the mines being flooded with gas overnight when fans were not operated, although men have been driven out of the lowest development openings several times each winter with fans operating. At present, the main danger is in the lowest development openings having only one exit, wherein men might be trapped and possibly suffocated during an unusual and extremely rapid inflow of gas, or during an ordinary inflow, should the one source of power for the fan be disabled."

Aug 1, 1921

By H. S. Caldwell

Molten zinc, condensed from zinc vapor, was used by the Federal Bureau of Mines to leach aluminum from an aluminum-silicon alloy made by carbothermic reduction of silicious aluminum ores. Zinc requirements were minimized by re-fluxing condensed zinc in a low-pressure, Soxhlet-type distillation unit. The minimum ratio of zinc used to aluminum in the crude alloy was approximately 2:1. When the system pressure was reduced from atmospheric pressure to 100 microns or less, the rate of aluminum extraction increased by a factor of 20. Leaching rates were much higher when the zinc vapor was condensed directly on the crude alloy than when molten zinc was passed over the alloy in the absence of appreciable zinc vapors. Observations indicated higher extraction efficiencies from crude alloys containing greater amounts of iron. Complete extraction was obtained with negligible loss of zinc. Assuming complete removal of zinc, the aluminum products will contain 1 to 6 percent silicon and about 0.5 percent iron plus titanium. The leached crude-alloy residue is a highly friable spongelike material containing about 80 percent silicon, several percent iron and titanium, with the remainder aluminum. This extraction method has been patented (Patent 2,810,637) and assigned to the Government. Research and development investigations are continuing at the College Park Metallurgy Research Center.

Jan 1, 1961

By Mah Alla D.

Previously existing heat-of-formation values for the oxides of vanadium were rudimentary. They were subject to uncertainties of 1 to 5 kilocalories per gram-atom of contained oxygen. This fact has been the only adverse influence on the accuracy of thermodynamic calculations involving these substances, as the requisite entropy and high-temperature heat-content data are known with reasonable accuracy. This report presents new heat-of-formation data for four oxides of vanadium (VO, V203, V02, and V205), obtained by combustion calorimetry. It is believed that the uncertainties have been reduced to 0.1 to 0.3 kilocalorie per gram-atom of contained oxygen. The new heat-of-formation data were combined with existing entropy and high-temperature heat-content values to obtain free energies of formation of the four oxides at temperatures up to 2,000° K.

Jan 1, 1961

By G. W. Birge

Carbonizing properties of the principal coalbeds of Elk, Clarion, Jefferson, Clearfield, and Centre Counties, Pa,, are described in this Bureau of Mines report, Twenty-six samples, representing the Upper Freeport, Lower Freeport, Upper Kittanning, Middle Kittanning, Lower Kittanning, and Brookville beds, were carbonized by the Bureau of Mines--American Gas Association (BM-AM) method, and yields of products and physical properties of cokes were determined. Expansion or contraction of the majority of the samples was measured in the Bureau of Mines sole-heated oven. Chemical analyses, agglutinating values, and free-swelling indexes are given for all samples. In this area the coals generally are characterized by high sulfur and moderately high ash content, and their suitability for metallurgical use would depend largely upon satisfactory cleaning. The samples from Elk, Clarion, and Jefferson Counties were high-volatile A bituminous In rank, whereas, most samples from Clearfield County and all those from Centre County were of medium-volatile rank. Coals from Clarion County had dry, mineral- matter-free fixed-carbon contents ranging from 56.5 to 60.3 percent and were weakly coking. With the exception of two samples which contained excessive ash, the medium-volatile coals of Clearfield and Centre Counties were strongly coking and, as indicated by sole-oven expansion results, would require blending with lower rank coal to avoid oven damage.

Jan 1, 1963

By F. D. Stevenson

A metal diaphragm pressure relay system was constructed to measure vapor pressures of the metal halides, oxyhalides, and other substances at temperatures up to 700° or 800° C. The vapor pressure of arsenic (III) oxide (As2O3) was determined to verify the reliability of the apparatus for such measurements. The data for the liquid AS2 Os (2820 to 4830 C) are represented by the equation, log Pmm = 6.875 - 2,929/T, from which the normal boiling point was calculated to be 461° C. The heat of vaporization calculated from this equation was 13.40 ±0.09 kcal/g mole As4OS and is essentially constant over the interval studied. The melting point of the octahedral arsenic (III) oxide was determined to be 278° C from the inter-section of the solid and liquid vapor pressure curves, A thermal analysis apparatus is also described by which melting and transition temperatures could be checked by a method independent of vapor pressure data. The melting points of the monoclinic and octahedral forms were determined to be 314.4 ±1.4° C and 278 ±5° C, respectively.

Jan 1, 1963

By A. W. Khair, L. D. Gehl

"This paper describes the mechanism of coal and rock cutting from quasi-static indentation through dynamic indentation to rotary cutting. The results indicate that during quas~static indentation, a crushed zone, and subsurface fractures develop. The crushed zone is a potential source of dust generation. Dynamic indentation produces a crushed zone due to the frictional resistance offered by the coal or rock during penetration of the bit. Confining pressure changes the mode of failure from tension to mixed tension and shear. The wider bit causes larger crushed zone and more dust generation. The rotary cutting is a combination of quasi-static and dynamic indentation which results in chip formation. 1. INTRODUCTIONThe trend from conventional mining to continuous machine-cutting of coal, using more productive machinery is inexorable. Intolerable levels of dust generated at the face is an indication of inefficient coal or rock cutting by these machines. The Federal Government of the United States paid about 11.7 billion dollars workman compensation to more than 470,000 miners with Coal Workers Pneumoconiosis (Newmeyer, 1981). Bieniawski and Zipf (1985) reported that annual benefit payments were about 2 billion dollars. The need for research m improving coal cutting 1s therefore paramount. The enactment of Health and Safety Act in 1969 in the United States triggered the initial investigation into coal cutting mechanism and cutting tool design. The European countries were also engaged in the same area of research, however, their emphasis was in the use of wedge shaped bits. In 1981, the United States Bureau of Mines commissioned the South West Research Institute to investigate the effect of operating parameters mainly on airborne respirable dust in order to provide a healthier and safer atmosphere for coal mine workers.A research program by the Department of Mining Engineering, West Virginia University, USA was initiated to study the fragmentation mechanism during coal/ rock cutting. The research program was divided into three areas of research, namely quasi-static indentation, dynamic indentation and rotary cutting."

Dec 1, 1995

By Steven M. Shope

An essential element of the Bureau of Mines electromagnetic location and communication system for trapped miners is a quantitative knowledge of the surface and above-surface electromagnetic fields created by an underground transmitter. The field solutions given in this report use approximations in which the displacement currents are negligible for low frequencies. The earth is represented by a homogeneous half-space model in which a dipole source is immersed. The vertical magnetic field equipotential contours at and above the surface are graphically mapped. The volumes of the regions bounded by these contours are directly related to the geometrical zones of signal detectability. Knowledge of the detectability zones will enable the proper search strategies to be developed for airborne detection of trapped miners.

Jan 1, 1983

By J. G. Groetsch

Municipal solid waste (MSW) contains about 8 pct ferrous metallics which are typically recovered by magnetic separators at municipal resource recovery facilities. At present, only about 182,500 ton/yr of MSW magnetics are being processed for remelting out of the -11 MMton/yr discarded. The Sn in MSW magnetics makes this material difficult to recycle to the steel industry. An electrolytic method using stannous fluoborate-fluoboric acid for removing Sn was evaluated. Optimum concentrations of Sn in the electrolyte and the effects of impurities such as Al, Cu, Fe, and Pb on Sn recovery from the electrolyte were evaluated. Operating parameters were 60 to 65 g/L fluoboric acid and 20 to 30 g/L Sn using stainless steel electrodes at a current density of 60 A/ft2. Tests were run with postconsumer scrap4 and MSW magnetics. Good results were obtained with MSW magnetics, after pretreatment by reshredding, magnetic separation, and air classification. The final Sn content of the MSW magnetics scrap was reduced from 0.18 to 0.017 wt pct. Heat and solvent treatments of MSW magnetics to remove coatings did not significantly improve Sn removal beyond that obtained with material that had only been mechanically pretreated.

Jan 1, 1984

By T. H. Jeffers

The U.S. Bureau of Mines has developed porous beads containing immobilized biological materials such as sphagnum peat moss for extracting metal contaminants from waste waters. The beads, designated as BIO-FIX beads, have removed toxic metals from over 100 waters in laboratory tests. These waters include acid mine drainage (AMD) water from mining sites, metallurgical and chemical industry waste water, and contaminated ground water. Following the laboratory studies, cooperative field tests were conducted to evaluate the metal adsorption properties of the beads in column and low-maintenance circuits, determine bead stability in varied climatic situations, and demonstrate the beads' potential as a viable waste water treatment technique. Field results indicated that BIO-FIX beads readily adsorbed cadmium, lead, and other toxic metals from dilute waters; effluents frequently met drinking water standards and other discharge criteria. The beads exhibited excellent handling characteristics in both column and low-maintenance circuits, and continued to extract metal ions after repeated loading-elution cycles. Based on laboratory and field data, cost evaluations for using BIO-FIX technology to treat two AMD waters were prepared. Operating costs for BIO-FIX treatment, which ranged from $1.40 to $2.30 per 1,000 gal of water treated, were comparable with chemical precipitation costs.

Jan 1, 2010

By A. W. Deurbrouck

Four samples of Pittsburgh-bed coal, of various size consist and ash content were dewatered in a pilot-size vacuum-disk filter partially enclosed with a steam jacket. Steam fed at 2.5 to 12.5 pounds per minute reduced the moisture content of the filter cakes from 2.8 to 13.8 percentage points more than normal vacuum dewatering. Approximately 1.5 pounds of steam was required to remove 1 pound of water.

Jan 1, 1966

By Mark W. Ryan

The U.S. Bureau of Mines conducted a study to determine if commercially available automatic sprinklers could withstand the high static pressures in deep underground coal mines without leaking and if exposure to the mine environment affected their leak pressures. New sprinklers and sprinklers exposed to the mine environment were subjected to increasing pressures until leakage occurred. The average leak pressures of the new sprinklers ranged from 640 to 2,300 psig and were significantly different for sprinklers from different manufacturers and for different types of sprinklers. Generally, standard-response sprinklers withstood higher pressures than fast-response sprinklers. The results indicated that most commercially available sprinklers would withstand the high static pressures in deep underground coal mines; however, they would not provide the same reliability and safety factor as sprinklers used aboveground at or below their rated pressure of 175 psig. The average leak pressures of the sprinklers exposed to the mine environment ranged from 740 to 1,180 psig. The mine environment affected the ability of 66% of the sprinklers to withstand high static pressures. New sprinklers were also evaluated at pressures of at least 500 psig for 30 days to determine their ability to withstand long-term exposure to high static pressures; no leakage was observed.

Jan 1, 2010