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By Jun Li, Marc Le Vier, Rong Yu Wan, Jan D. Miller

The hydrometallurgical treatment of gold and silver ores by ammoniacal thiosulfate solutions in the presence of a copper catalyst has been actively studied in recent years. Such a process strategy is very attractive due to the low toxicity of the lixiviant and the efficient recovery of the precious metals from difficult-to-treat ores. Important features of the ammoniacal thiosulfate system for the recovery of precious metals from various sources are reviewed in this paper, including leaching, metal recovery, and system stability.

Jan 1, 1995

By Surendra K. Mishra

With increasing regulatory pressure from the environmental authorities, waste management has become a focal point of industrial operation. To offset the waste management costs, industry has made conscious effort to recover usable resources from the waste streams. This paper reviews the technical developments and current practices in processing of waste materials. Methods for recovering metallic, non-metallic and organic species from solid wastes and effluents generated by operating plants are discussed.

Jan 1, 1997

By Wei Li

Carbothermic reduction kinetics of ilmenite concentrates catalyzed by sodium chloride and the microwaveabsorbing characteristics of the resulting reductive products were investigated; the reduction degree of the reaction was deduced to be . Results show that the activation energy is 112.03 kJ/ mol when NaCl is used as catalyst, lowering to 23.11 kJ/mol for the final stage activation energy using sodium silicate as a catalyst. There is a sharp change in the reduction rate constant at temperature ranges of 1,223 K - 1,273 K and 1,373 K - 1,423 K. Microwave-absorbing characteristics of reductive products were measured by the method of microwave cavity perturbation. It was found that microwave-absorbing characteristics of reductive products obtained at temperatures of 850° C, 1,100° C and 1,150° C show sharp changes. Through X-ray diffraction (XRD) characterization, it was found that the formation of Fe occurs at a temperature of 900° C during the reduction process of ilmenite concentrate. The decrease of FeTiO3 content results in the decrease of microwave-absorbing characteristics, while the increase of Fe content gives rise to the increase of microwaveabsorbing characteristics. The decreasing trend is larger than the increasing trend, which is the main reason for the sharp changes in the microwave-absorbing characteristics of reductive products at the temperature range of 850° C to 900° C. When the decreasing trend is smaller than the increasing trend, it becomes the main reason for the sharp changes in microwave-absorbing characteristics of reductive products at the temperature range of 1,100° C to 1,150° C. Kinetics results show that sodium chloride can catalyze the carbothermic reduction of ilmenite, and microwave-absorbing characteristic investigations indicate that microwave heating can be used in the carbothermic reduction of ilmenite.

By Alan C. Noble

Ore reserve estimation is a multi- disciplinary process involving not only tonnage and grade estimation (resource estimation), but also consideration of technical and legal aspects such as mining the deposit, beneficiating the ores, and selling the product. This paper provides a background to under- standing resource estimation including geologic modelling, manual estimation methods, conventional computer methods. and geostatistical methods. Mine planning, metallurgical studies, legal/environmental, and marketing considerations are also discussed as they relate to estimating ore reserves.

Jan 1, 1991

By W. K. Tolley

The U.S. Bureau of Mines (USBM) is currently investigating the electrochemistry of mineral flotation. A significant need in this area is greater reliability of sensors. The USBM is testing electrolytic methods to clean and condition redox-sensing electrodes to improve the reliability and extend the service life of these instruments in the harsh physical and chemical environment of mineral processing slurries. A novel method for removing scale from fouled electrodes has been developed that includes anodic polarization to 1.2 V versus the Ag/AgCl reference potential, followed by brief potentiodynamic conditioning. Laboratory results show that this technique removes calcarious deposits from gold sensing electrodes and returns the electrode to useful service within approximately 10 min. Mechanical abrasion to remove the scale is thereby avoided.

Jan 1, 1994

By Wolfgang Baum

The selection of roasting technology is a complex task which is primarily dependent on the ore mineralogy. Key roasting parameters are directly linked to mineralogical characteristics of the feed and vary considerably between different ore types even in the same deposit. In addition to sulfide refractoriness, other refractory conditions frequently exist. Together with various mineralogical features of the feed, they may complicate roasting testwork and process design. For most roasting scenarios, the critical economic factors are gold recovery, capital cost and environmental performance. This paper will show how these economic factors are influenced by the mineralogical ore characteristics.

Jan 1, 1992

The Sage Mill Project w approved by Santa Fe Pacific Gold Corporation's Board of Directors in October 1994. The Sage Mill Project included a pressure oxidation plant designed and constructed to process refractory carbonaceous ore using fine grinding/autoclaving technology developed specifically to treat Twin Creeks ore. The project was constructed in two phases. The first phase was put into operation on May 5, 1997, just hours before the transfer of ownership to Newmont Gold Company occurred. The second phase started in October 1997. This paper reviews schedule, costs, scope changes, and methodology used on the project that spanned almost five years from project definition through commercial operation.

Jan 1, 1999

By Chulho C. Song, Liam Coleman

Alkaline pressure oxidation (POX) is an oxidative pre-treatment option that is commercially used for high-carbonate sulfidic gold ores. The high carbonate grades within the feed ore shifts the ideal operating pH to a basic regime. Compared with acidic POX, alkaline POX typically requires additional steam input due to a lower sulfur oxidation load and a high rate of in-situ carbon dioxide generation that needs to be vented along with steam. The cost of this steam addition is the largest differentiator between acid POX operation and alkaline POX from a cost comparison. However, alkaline POX can offset these costs through reduced acid usage for pre-acidulation and decreased alkali reagent consumption for subsequent neutralization. This paper reviews the specific operating cost impacts of acid/base consumption between alkaline and acidic POX with ores which require pre-acidulation, the overall economics of alkaline POX, and the regimes in which alkaline POX is economically favorable. The findings aim to guide industry professionals in making informed decisions for alkaline POX adoption by providing a summary view of its operational benefits and costs, contributing to the development of cost-effective and sustainable gold ore processing techniques.

Feb 1, 2025

By Joseph W. Leonard

Much progress has been made in the application of geostatistics to hard rock ore deposits.1,2,3 4,8 Progress in the application of geostatistics to coal deposits has developed over a period of time out of hard rock technology.5,7 Exploratory drilling in many hard rock deposits is frequently significantly more productive than exploratory drilling in coal deposits. For example, hundreds of feet of drilling and/or many drill setups are frequently necessary to obtain a few samples from a typical 4 to 6 foot thick coal seam. With hard rock deposits, which are frequently thick or volumetric, less drilling dead work is involved in sampling the deposit. To produce a variogram, which is the basic element needed for geostatistical analysis, a few well positioned holes drilled into a hard rock deposit where the core(s) can be divided into many sections can produce a detailed variogram. To produce a similar type variogram in coal, it is necessary to drill many dozens of holes with much of the core length consisting of overburden data which is frequently of only secondary importance. To apply geostatistics to coal, not only are many separate sample sites needed, but frequently a problem exists in that the interval distance between samples cannot be controlled with the ease that hard rock drilling intervals can be controlled where it is only necessary to cut core segments according to some preassigned interval of distance. Because the uses of existing coal deposit samples are frequently handicapped by irregular sample distances and lack of sampling density along certain directions needed for the development of variograms, the application of geostatistics to coal deposits frequently does not proceed with the same efficiency and rapidity as when these techniques are applied to ore deposits. Grid-fitting was developed by the writers, as a logical and evolutionary improvement over the long and successful application of geostatistics to coal seams.6,9 Grid-fitting combines the trending of variance as well as other aspects of probability theory to optimize informational yields from the commonly less productive data derived from coal exploratory programs. Grid-fitting is basically a technique where a hypothesis involving numerous grid patterns, where each pattern is of a given geometry, size and direction is repeatedly matched against actual sample data to determine which match results in the closest fit of the hypothesis to the data. To determine the closest fit, a special index known as a selectivity index was developed. The selectivity index is basically the product of the mean and variance of the variances contained within each of the grids. hence, if SI is the selectivity index then [SI = Xs E (S i - Xs) /N] where [X]s is the mean of individual grid variances Si2 for any pattern of given geometry, direction and size.

Jan 1, 1984

By D. Tao

The presence of insoluble slimes in potash ore poses a serious processing problem to the potash industry. These insolubles must be removed prior to potash flotation because of their high adsorptive capacity for amines which are generally used as collectors in the subsequent sylvite flotation. This is usually accomplished by scrubbing of the ore in brine followed by hydrocyclone classification to separate slimes from the salt particles. Insoluble slimes that remain in the ore after the desliming procedure are depressed by reagents such as guar gum or starch during sylvite flotation. In this research, the feasibility of using GP clay binders to replace guar gum for potash flotation was investigated. Batch mechanical flotation tests were conducted with the potash samples provided by a leading potash company. It has been found that GP clay binders increased potash concentrate yield and recovery at the same product grade. Effects on potash flotation efficiency of flotation process parameters such as impeller rotation speed, slurry temperature, binder type, dosage and conditioning time have been investigated to establish the optimum conditions for flotation. Binder GP374G33 has been identified as the optimum substitute for guar gum as slime depressant in potash flotation.

Jan 1, 2008

By James Thompson

Mine planning at Consolidation Coal Company's (Consol) Glenharold Mine in North Dakota is being constrained by environ¬mental concerns that did not exist when the mine opened in 1965. One such concern which developed in the mid-1970's is the impact of mining on woodlands that are considered impor¬tant wildlife habitat. To better coordinate mine planning with permitting, a cooperative task force was created to evaluate woodlands for their wild¬life habitat potential. The task force included representatives from Consol and state and federal agencies. This cooperative process is seen as a method of communication between industry and government and as a way of developing decision-making tools for mine planners and regulatory agencies.

Jan 1, 1981

By Marcelino Cortina

It is known that underground bituminous coal mining in the Central Asturian Coal Basin (North of Spain) is a complicated task, due basically to the difficult geological conditions: thin and steep Seams with many faults and other disturbances. Therefore, it is not easy to decide what is the most suitable mining method for each of the seams, and problems in making the correct decision are encountered frequently. Because selections in the past have been inadequate an Expert System, ASTURLABOR;hulla, has been designed and will be developed' to provide accurate advice in the mining method selection process. The paper describes the major features of this Expert System and outlines the ASTURLABOR general project, which includes five other mining Expert Systems to complement ASTURLABOR-hulla.

Jan 1, 1989

By Bond. F. C.

Introduction Although autogenous grinding applications date back to the early years of mineral processing when tumbling-type mills were first used, there has been a renewed interest in this type of grinding over the past few decades. A review of the historical aspects of autogenous grinding is provided which follows the development of the various types of mills and processes. Wet and dry grinding operations using either autogenous or semiautogenous mills, including the Aerofall mill, are described. Em¬phasis has been placed on the test work required to evaluate the feasibility of using autogenous or semiautogenous grinding for a spe¬cific application. The factors which must be considered to establish the appropriate design criteria for these types of grinding circuits are discussed in detail. Successful application of these grinding circuits results from a thorough test program, a careful analysis of the test results, and a practical engineering approach to the design of the process flowsheet and milling equipment. Certain pebble milling applications, where the pebbles consist of the ore or rock itself, can be classified as autogenous pebble mill grinding, or better known as ore-pebble mill grinding. In the generic sense, pebble milling includes those grinding operations using a tum¬bling mill in which the grinding media consists of various types of pebbles, either ore or other pebbles, instead of metal balls. Conse¬quently, this subject is covered separately in Chapter 5, Pebble Mills. Operating data from many of the installations located throughout the world are included in this chapter. Our appreciation is extended to those companies who contributed this important information. History of Autogenous Grinding F. C. BOND Autogenous grinding, the grinding of ore by itself rather than by special metallic or nonmetallic grinding bodies distinct from the ore, has an old and honorable place in the art of mineral processing. It antedates the use of the rod mill and is only a few years younger than the development of the continuously fed rotating tumbling mill in which it is accomplished. Its history71, 72 is inextricably bound up with that of gold mining. Every important early development of autogenous grinding took place on ores of gold, except in one case of silver ore. In common with many other features of modern mineral processing, autogenous grinding would have been greatly retarded if the winning of gold had been so small a part of mining in the past as it is today. Gold unlocked the secrets of rock-on-rock grinding. In years past gold ores were crushed in stamp batteries and then flowed over copper plates covered with mercury which amalgamated the gold. The McArthur Forrest cyanide process for the dissolution of gold in a dilute alkaline cyanide solution appeared in 1890. With finer grinding it recovered more gold than could be won by amalgama¬tion alone. The first response was to stamp in cyanide solution and finer mesh screens guarding the stamp discharge. However, the fine screens greatly restricted the tonnage stamped, and they wore out rapidly. Rotating tumbling mills70, 73 were the obvious choice to grind the coarse product from stamps. Many of these were Gates tube mills; more than 1,000 of these were sold between 1907 and 1913. They were made in 6, 51h, and 5 ft diam, with lengths of 20 and 22 ft. The 5 x 22-ft size was the most popular. The term tube mill did not refer to the mill shape, but included all tumbling mills using grinding pebbles. The flint or chert rocks found along the coasts of Denmark and Normandy are probably the most durable and resistant to abrasive and tumbling wear of any on earth. They were much used in the early tube mills. The early linings were all silex or Danish flint blocks, cemented into place with portland cement. Local hard stones or cast iron blocks were also used later. The cast iron liners carried lifters and were not bolted to the shell, but were held in a tight circle against it by steel wedges hammered home between them. The first ribbed metal liners designed to hold grinding pebbles pounded into them by the mill action were developed at El Oro, Mexico, about 1905. These and the Forbes, Komata, and Tonopah types, as well as the Osborne type developed in South Africa within about five years, were very successful in reducing liner wear. They sometimes lasted two years or more, and equalled or exceeded the life of silex lining at a lower cost. Some of the types were patented. The pioneer name recorded in the history of autogenous grinding is that of Kenneth L. Graham. In 1907 at the Geldenhuis Deep Ltd. mine near Johannesburg, he ran a comparative test on two tube mills. One mill used pieces of the common gold ore, or banket, and the other used the customary imported Danish pebbles as grinding media. He published the first account of autogenous grinding.'' In a test lasting 81 days the ore pebbles showed a definite saving over the Danish pebbles. Graham's historic paper also describes the invention of B. Chew of the Crown Deep Mines of the first trammel to be attached to a grinding mill discharge. The first known account of autogenous grind¬ing printed outside of South Africa was the description of the Graham test in Mining and Scientific Press's The use of grate- vs. overflow¬discharge was also described at this time." The news of this successful test appears to have had immediate effect, for by the end of 1908 the number of tube mills on the Rand had increased from 72 to 120.76 Presumably, most of these mills were now using autogenous grinding. The ore was principally a hard conglomerate of quartz peb¬bles cemented by silica, and was eminently suitable for use as a grind¬ing media. It is unfortunate that in South Africa the new autogenous process continued to be called by its old name of pebble milling, since the name does not distinguish between grinding with ore and grinding with extraneous pebbles. For increased clarity the former is called rock pebble milling. The first historical stage in the development was what is now designated as secondary autogenous grinding, or rock pebble milling. It consists of grinding a feed all passing 'A in. or finer with ore pebbles about 2 to 4 in. in diameter. The next stage to develop was that now called intermediate autogenous grinding, where larger amounts of larger pebbles about 5 in. in size were used to grind ore which had been crushed to about rod mill feed size or somewhat finer. It was developed on the Rand and in other places where coarse stamp screens were used to increase mill tonnage. In many cases the early secondary and intermediate autogenous mills have now been replaced by conventional ball mills and rod mill-ball mill circuits, with the object of further increasing grinding capacity. The third stage to develop is designated as wet primary autogenous grinding, in which run-of-mine ore or a primary crusher product is all fed to the autogenous mill together. It developed many years later indepen¬dently in the United States and in South Africa. The fourth and most recent stage is that of dry primary autogenous grinding, which developed in the United States and Canada. All four stages originated in gold mining. The first use of commercial autogenous grinding outside of the Rand apparently took place five years later in 1912 at the Santa Gertrudis gold mine at Pachuca, 55 miles northeast of Mexico City. This was followed closely by an installation at Goldfields, Nevada, in 1914-1915. The first name associated with autogenous grinding

Jan 1, 1985

By Benjamin K. Pocock

When considering alternative equipment choices in mill or process flowsheets, it is important to determine both capital and operating costs of such equipment as well as other possible savings related to downstream operations. This paper presents a few case studies and shows cursory guidelines for the selection of equipment for new installations or in the retrofitting of existing plants. Based upon recent plant experience, suggestions are given to improve the operation of clarifiers, thickeners and vacuum filters.

Jan 1, 1986

By Y. S. Roditis

Traditionally, open pit optimization has been used to produce a single outline which can guide the pit design. This paper describes how a series of optimum nested pits are utilized to: a. produce different mining sequences and to help in mine planning and phase design; b. evaluate different metallurgical processes, production scenarios and equipment size; c. investigate the sensitivity of a project to prices, recoveries, production rates, costs, ultimate pit slopes etc.

Jan 1, 1993

By J. G. Pippenger

The Coteau Properties Company's Freedom Mine is a surface lignite mining operation located near Beulah, North Dakota. As part of the mining process, Coteau removes and replaces thin layers of suitable plant growth material (SPGM) generally ranging in thickness between one and five feet. Historically, tractor-scrapers completed this work; however, rising tractor-scraper costs and increasing haulage distances sent Coteau in search of a lower cost method resulting in the acquisition of a backhoe/truck fleet in 1995.

Jan 1, 1997

By S. K. Kawatra

In order to meet federal air pollution guidelines, it is necessary to remove a considerable quantity of sulfur from many North American coals. This may be accomplished by oxidizing the sulfur to water soluble forms, followed by washing the coal. Selective oxidation of the various sulfur forms can be accomplished through the use of a variety of types of bacteria. In this paper, the various bacteria and their requirements are described, and processes using bacteria to remove coal sulfur are discussed.

Jan 1, 1987

By Veliko Kertikov

Complicated processes of heat exchange and evaporation, leading to changes in the temperature and humidity of the ventilating air flow, take place during the driving of headings. In the case when virgin rock temperature is high, the increase in air temperature and humidity is significant. This causes a deterioration of climatic conditions in the headings. Procedures for predicting the changes in air temperature and humidity are discussed, together with appropriate calculations and computer programmes. Predicted results for example scenarios are used as a background for the selection of approaches and means to improve the climatic conditions in a dead-end heading using auxiliary ventilation.

Jan 1, 1997

By Michael Michaylov

INTRODUCTUCTICN The coal seams at Bobov dol basin are highly prone to spontaneous combustion in Bulgaria. The risks of endogenous fires (SPONCOM) exist mainly in gob area. During the last 15 years three different technologies for preventing and fighting SPONCOM have been applied in underground mines of this basin: pulp from hard material and water, foam and inerting with nitrogen. On the basis of experimental application of these technologies as well as theoretical and experimental research a new technology - Foam Pulp Technology (FPT) was worked out. It is very effective in difficult to reach places in a gob. BACKGROUND AND THE NEED OF FPT Application of the three methods mentioned above showed advantages as well as some disadvantages, allowing determination of their effective application scope depending on geological and working conditions. Their advantages can be summarized as follows: - Foaming: high viscosity at low density, which allows forming a thick layer; good surfactant wetting properties; excellent effective cooling during evaporation in high temperature zones. - Pulping with mixture of solid particles (e.g., fly ash) and water from surface installation: easy to apply in a mine; low operational and energy costs due to gravity transport from the surface to the gob: good ecological results because the waste material is returned back underground. - Inerting with nitrogen: volumetric action which doesn't restrict the thickness of treated coal pile; easy to apply in a mine; controllable nitrogen delivery depending on fire hazard conditions. Main disadvantages of the same three methods are: - Foaming: rapid disintegration due to intrusion into heterogeneous and porous media and high costs due to the need of frequent large volume foam flows (short foam's life); - Pulping: inapplicable for coal piles with high thickness which is of great importance in the cases of seams with ununiform hypsometry (rapid and frequent changes in a seam configuration) and/or great volumes of coal or ore piles particularly heated to a high temperature; strong dependence on gob floor declination; water draining of the working face area which impedes the movement of supports and chain conveyor's. - Inerting: relatively high costs hardly depending on the rate of face advance (fig.1) in comparison with the other methods; it is difficult to ensure sufficient oxygen at the exit end of the face. This problem is crucial in faces with a high level of methane emissions; accelerating of the oxidation and spontaneous heating of the pile after turning off the nitrogen supply. Inerting should be applied again at higher capacity of nitrogen supply (fig.2) and what is more important, it shouldn't be

Jan 1, 1995

By Thomas P. Oxford

The impact of recent legislation on Florida phosphate industry operations has been dramatic. The most significant influences are described: the National Environmental Policy Act of 1969; the Federal Water Pollution Control Act Amendments of 1972; and implementation of the Florida Environmental Land and Water Management Act of 1972. Further discussion includes: critical examination of the recently completed EPA Areawide EIS; potential effects of the Resource Conservation and Recovery Act of 1976; the Surface Mining Control and Reclamation Act of 1977; current local and state laws; and summary of studies on radiochemical effects of mining, seepage from gypsum ponds, and dewatering of waste clays.

Jan 1, 1979